Distillation
Distillation
Distillation
Distillation. Introduction
Unit operation Separation process A feed mixture of two or more components is separated into two or more products whose compositions differ from that of the feed.
Distillation Examples
T Composition diagram.
T Composition diagram.
Dew point is the point at which first drop of gaseous/vapor mixture begins to condense
T Composition diagram.
By Daltons law of partial pressures, the total pressure is equal to the summation of partial pressures.
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Raoults Law
In an ideal gas/vapor, the partial pressure of a constituent is proportional to its mole fraction.
For an ideal mixture, the partial pressure of a constituent is related to the liquid phase concentration by Raoults law.
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Hence
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Riedel Equation:
Clapeyron Equation:
Where
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As
Where
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Example 11.1
The vapor pressure of nheptane and toluene at 373 K are 106 and 73.7 kN/m2, respectively. What are the mole fractions of nheptane in the vapor and in the liquid phase at 373 K, if the
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Example 11.2
The following data have been reported for acetone by AMBROSE et al.(12): Pc = 4700 kN/m2,
Tc = 508.1 K,
Po1= 100.666 kN/m2 when T1 = 329.026 K. What is Po when T = 350.874 K ?
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Example 11.3
The constants in the Antoine equation, Equation 11.6, are: For benzene: For toluene: k1 = 6.90565 k1 = 6.95334 k2 = 1211.033 k2 = 1343.943 k3 = 220.79 k3 = 219.377
where Po is in mm Hg, T is in oC and log10 is used instead of loge. Determine the vapor phase composition of a mixture in equilibrium with a liquid mixture of 0.5 mole fraction benzene and 0.5 mole fraction of toluene at 338 K. Will the liquid vaporize at a pressure of 101.3 kN/m2?
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Example 11.4
What is the boiling point of a equimolar mixture of benzene and toluene at 101.3 kN/m2?
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Example 11.5
What is the dew point of a equimolar mixture of benzene and toluene at 101.3 kN/m2 ?
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Volatility
Volatility is defined as the ratio of partial pressure of a
Relative Volatility
The ratio of these two volatilities is known as the relative
volatility.
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Relative Volatility
For a binary mixture
This gives relations for determination of composition of liquid or vapor phases, if the composition of the other phase is known.
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Otherwise
the
equilibrium
curve
must
be
constructed
incrementally by calculating the relative volatility at several points along the column.
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K-Value (1)
Phase-equilibrium ratio is the ratio of mole fractions of a species in two phases at equilibrium. For vaporliquid systems, the constant is referred to as the K-value or vaporliquid equilibrium ratio.
For many systems K is constant over an appreciable temperature range, So it is often much more useful than the simple vapor
pressure.
Using K-values is particularly useful while dealing with multicomponent systems.
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K-Value (2)
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Distillation
Single-stage separation
Multistage separation
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or
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then
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Component A balance
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Equation of straight line that passes through point (xf ,yf) and has a slope
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Example 11.6
An equimolar mixture of benzene and toluene is subjected to flash distillation at 100 kN/m2 in the separator. Using the equilibrium data given in Figure 11.9, determine the
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Rectification
The term rectification is derived from the Latin words rectefacere, meaning to improve. Distillation process that enables successive vaporization and condensation to be accomplished in one unit.
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Condenser
Reflux drum / Accumulator
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Reflux stream
Boil-up stream Utilities
Hot Cold
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diffusion.
It occurs in the distillation column when the molar latent heats of the two components are the same. The more volatile component is transferred from liquid to vapor, and the less volatile components is transferred from vapor to liquid. If the molar latent heats of the two components are equal, the condensation of a given amount of less volatile component releases exactly the amount of latent heat required to volatilize the same molar quantity of the more volatile component.
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Heat and material balances over the trays, the condenser, and the reboiler Thermodynamic Phase equilibrium data
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Example 11.7
A mixture of benzene and toluene containing 40 mole per cent benzene is to be separated to give a product containing 90 mole per cent benzene at the top, and a bottom product containing not more than 10 mole per cent benzene. The feed enters the column at its boiling point, and the vapour leaving the column which is condensed but not cooled, provides reflux and product. It is proposed to operate the unit with a reflux ratio of 3
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Since the top and bottom operating lines are straight lines, so they
can be plotted on the same graph as the equilibrium curve. When all three ( the equilibrium curve and the two operating lines) are on the same graph, number of plates can be determined graphically. Top operatingline is drawn using 2 points. Bottom operating line is drawn using 1 point and its slope
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Hence top operating line passes through the points (xd,xd) and
(0,Dxd/Vn).
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Hence bottom operating line passes through the point (xw,xw) and has aslope Lm/Vm.
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The assumption of constant molar overflow must be valid since in very few systems do the molar heats of vaporization differ by more than 10 per cent.
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Example : 11.8
Example 11.7 is now worked using McCabe - Thiele method. Thus, with a feed composition, xf = 0.4, the top composition, xd is to have a value of 0.9 and the bottom composition, xw is to
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plate 1
Overhead product A The still and condenser together
Subtracting
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The relation of Lm and Ln is a function of feed condition and temperature. The feed may completely or partially add to liquid, it may have no effect at all, and it can even evaporate some part of liquid
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Where
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After substituting
Rearranging
If xq = xf , then yq = xf Thus, the point of intersection of the two operating lines lies on
the straight line of slope q/(q 1) passing through the point (xf ,
xf ) When yq = 0, xq = xf /q. The line may thus be drawn through two easily determined points
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q>1
q line /
q=1
0<q<1 q=0 q<0
q line
q line \ q line q line /
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Reflux Ratio
Ratio of the top overflow to the quantity of product
then
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It can be written as
Finally
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Hence the value of reflux ratio changes the slope and intercept of top operating line, and consequently affects the required number of plates If R is known, top operating line can be drawn without calculating Ln and Vn. This is done by using two point (xd ,xd) and (0, xd/(R+1)) of the topoperating line.
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Total Reflux
If no product is drawn from the top of the column (D=0), then the column is said to be operating under total reflux. Using previously modified equation:
Minimum Reflux
If the top operating line intersects the bottom operating line (or
the qline) at the equilibrium curve, the steps become very close
together at liquid compositions near to xf. No enrichment occurs from the feed plate to the plate above. An infinite number of plates is required to pass from xd to xf under these conditions. This condition is known as minimum reflux and denoted by Rm.
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Any increment in R from Rm gives a work able system, where desired separation can be achieved in a finite number of plates. This finite number of plates is greater than the minimum number of plates (that are required at total reflux). The number of plates required for R near Rm is very large.
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If xnA and xnB are the mole fractions of two components A and B
in the liquid on any plate n then a material balance over the top portion of the column above plate n gives:
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Therefore
For plate n
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As separation of the feed is required, the minimum relevant value of Rm is that for the feed plate
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This equation can also be obtained by using the equilibrium relation for constant in the equation for Rm developed for saturated liquid feed.
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Stage numbering in the column starts from stage1 just above the reboiler to stage N just before the condenser.
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If for two components A and B, the concentrations in the still are xsA and xsB, then the composition on the first plate is given by
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Example 11.9
For the separation of a mixture of benzene and toluene, considered in example 11.7, xd= 0.9 xw= 0.1 xf= 0.4
If the mean volatility of benzene relative to toluene is 2.4, what is the number of plates required at total reflux? Determine minimum reflux ratio.
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Effect of Sidestream
Consider a binary system with one side stream
S = Flow rate of site stream
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Effect of Sidestream
Generally the sidestream is withdrawn as liquid,
Since Ls < Ln , the middle operating line has a smaller slope than top operating line but higher y-intercept. It intersects the x=y
Effect of Sidestream
Middle operating line intersect the top operating line at x = xs Same graphical method to calculate the number of stages with the addition of third operating line Withdrawn of sidestream decreases the liquid flow rate below the sidestream. Hence the required number of plates increased. For each additional feed stream or sidestream, there is an additional operating line
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Effect of Sidestream
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Condition for Varying Overflow in Non-Ideal Binary Systems The Heat Balance
Non ideal systems
Molar latent heat is no longer constant
Heat of mixing
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H x Chart
Upper curve is dew-point curve Lower curve is bubble point curve Phase mass, enthalpy and composition m = mass x = composition H = enthalpy per unit mass
A+B=C
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H x Chart
enthalpy from HA to HC
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H x Chart
The addition of two phases A and B is shown by point C on the straight line joining the two phases. The difference A B provides point C on the extension of the line AB
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H x Chart
Considering a phase C in the two phase region, separqted into two phases A and B Tie line AB through point C
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H x Chart
n = rectifying section
m = stripping section Hv and HL enthalpy per unit mass for vapors and liquids Qc = condenser duty QB = boiler duty
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H x Chart
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H x Chart
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H x Chart
H x Chart
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H x Chart
coordinate xw
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H x Chart
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Example 11.10
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Solution
Applying material balance
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Actual reflux
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Location of Point N
N has ordinate N has abscissa 437 + 1547 = 1984 0.995
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Solution
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Number of Plates
No. of theoretical plates are 5+ No. of plates with efficiency 60 % = 5/0.6 = 8.33 Boiler duty:
Heat input per unit mass of bottom product
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