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    Amagat's Law: Ideal Gas Mixture

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    Aar Aey
    A Gas Mixture will behave like an ideal gas when p = about 3 atm. To illustrate the above concepts, the next page presents the E-Z Solve model for an ideal gas mixture.

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    Amagat's Law: Ideal Gas Mixture

    Uploaded by

    Aar Aey
    28 views2 pages
    A Gas Mixture will behave like an ideal gas when p = about 3 atm. To illustrate the above concepts, the next page presents the E-Z Solve model for an ideal gas mixture.

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    idgas

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    A Gas Mixture will behave like an ideal gas when p = about 3 atm. To illustrate the above concepts, the next page presents the E-Z Solve model for an ideal gas mixture.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    28 views2 pages

    Amagat's Law: Ideal Gas Mixture

    Uploaded by

    Aar Aey
    A Gas Mixture will behave like an ideal gas when p = about 3 atm. To illustrate the above concepts, the next page presents the E-Z Solve model for an ideal gas mixture.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Ideal Gas Mixture

    Amagats Law
    The volume of an ideal gas mixture (V) is equal to the sum of the component volumes (V j s) of each individual component in the gas mixture at the same temperature (T) and total pressure (P) of the mixture. For example,

    Gas A T and P VA

    Gas B

    Gas Mixture

    T and P VB

    T and P VA + VB = V

    P VA = n A R T VA = nA VB = nB V n thus

    P VB = nB R T nA = n VA = V yA and

    PV = n RT nB = n VB = V yB

    Daltons Law
    The total pressure (P) of an ideal gas mixture is equal to the sum of the partial pressures (p j s) of each individual component in the gas mixture at the same temperature (T) and total volume (V) of the mixture. For example,

    Gas A T and V pA

    Gas B

    Gas Mixture

    T and V pB

    T and V pA + pB = P

    p A V = nA R T pA = nA pB = nB P n thus

    pB V = nB R T nA = n pA = P yA

    PV = n RT nB and = n pB = P yB

    Ideal Gas Mixture


    = xj nj = n Vj = V pj = P yj for each component j

    Thus, mole fraction (x j ) and volume fraction (y j ) for an ideal gas mixture are equivalent. To illustrate the above concepts, the next page presents the E-Z Solve model for an ideal gas mixture of 21 mol% O 2 and 79 mol% N 2 at 25C and 1 atm. Note that a gas mixture will behave like an ideal gas when P about 3 atm.
    v11.01.20 2011, Michael E. Hanyak, Jr., All Rights Reserved Page 1 of 1

    Ideal Gas Mixture


    click here , save the file to your desktop, and then open it from within the E-Z Solve program.

    E-Z Solve Mathematical Model


    // // //

    Amagat's Law and Dalton's Law for Ideal Gas Mixture


    21 mol% O2 and 79 mol% N2 at 25C and 1 atm

    Given Information:
    R = 0.08205746 T = 25 + 273.15 P = 1 n = 1 n_O2 = 0.21 * n n_N2 = 0.79 * n // L atm / mol K // K // atm // moles of mixture // moles of oxygen // moles of nitrogen

    //

    Amagat's Law:
    /* mixture */ /* oxygen */ /* nitrogen */ /* total volume */ /* volume fraction O2 */ /* volume fraction N2 */ P*V = n*R*T P * V_O2 = n_O2 * R * T P * V_N2 = n_N2 * R * T V_total = V_O2 + V_N2 y_O2 = V_O2 / V_total y_N2 = V_N2 / V_total

    //

    Dalton's Law:
    /* partial pressure O2 */ /* partial pressure N2 */ /* total pressure */ /* mole fraction O2 */ /* mole fraction N2 */ p_O2 * V = n_O2 * R * T p_N2 * V = n_N2 * R * T P_total = p_O2 + p_N2 x_O2 = p_O2 / P_total x_N2 = p_N2 / P_total

    Calculated Results
    V V_N2 V_O2 V_total y_N2 y_O2
    v11.01.20

    = = = = = =

    24.4654 19.3277 5.13774 24.4654 0.79 0.21

    liters liters liters liters vol frac vol frac

    p_N2 p_O2 P_total x_N2 x_O2

    = = = = =

    0.79 0.21 1 0.79 0.21

    atm atm atm mol frac mol frac


    Page 2 of 2

    2011, Michael E. Hanyak, Jr., All Rights Reserved

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