TETRACHLOROETHYLENE

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MSDS Number: T0767 * * * * * Effective Date: 08/16/05 * * * * * Supercedes: 05/08/03

TETRACHLOROETHYLENE
1. Product Identification
Synonyms: ethylene tetrachloride; tetrachloroethene; perchloroethylene; carbon bichloride; carbon dichloride CAS No.: 127-18-4 Molecular Weight: 165.83 Chemical Formula: Cl2C:CCl2 Product Codes: J.T. Baker: 9218, 9360, 9453, 9465, 9469 Mallinckrodt: 1933, 8058

2. Composition/Information on Ingredients
Ingredient --------------------------------------Tetrachloroethylene CAS No -----------127-18-4 Percent -----------99 - 100% Hazardous --------Yes

3. Hazards Identification
Emergency Overview -------------------------WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. SUSPECT CANCER HAZARD. MAY CAUSE CANCER. Risk of cancer depends on level and duration of exposure. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------------------------Health Rating: 2 - Moderate (Poison) Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate (Life) Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
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Storage Color Code: Blue (Health) ----------------------------------------------------------------------------------------------------------Potential Health Effects ---------------------------------Inhalation: Irritating to the upper respiratory tract. Giddiness, headache, intoxication, nausea and vomiting may follow the inhalation of large amounts while massive amounts can cause breathing arrest, liver and kidney damage, and death. Concentrations of 600 ppm and more can affect the central nervous system after a few minutes. Ingestion: Not highly toxic by this route because of low water solubility. Used as an oral dosage for hookworm (1 to 4 ml). Causes abdominal pain, nausea, diarrhea, headache, and dizziness. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. May be absorbed through the skin with possible systemic effects. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: May cause liver, kidney or central nervous system damage after repeated or prolonged exposures. Suspected cancer risk from animal studies. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance. The use of alcoholic beverages enhances the toxic effects.

4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Aspiration hazard. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Wash skin with soap or mild detergent and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Call a physician. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Note to Physician: Do not administer adrenaline or epinephrine to a victim of chlorinated solvent poisoning.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard but becomes hazardous in a fire situation because of vapor generation and possible degradation to phosgene (highly toxic) and hydrogen chloride (corrosive). Vapors are heavier than air and collect in low-lying areas. Explosion: Not considered to be an explosion hazard. Containers may explode when involved in a fire. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed containers cool. Special Information:

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In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage

Store in a cool, dry, ventilated area away from sources of heat or ignition. Isolate from flammable materials. Protect from direct sunlight. Wear special protective equipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 100 ppm (TWA), 200 ppm (ceiling), 300 ppm/5min/3-hour (max) -ACGIH Threshold Limit Value (TLV): 25 ppm (TWA), 100 ppm (STEL); listed as A3, animal carcinogen Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:

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Clear, colorless liquid. Odor: Ethereal odor. Solubility: 0.015 g in 100 g of water. Specific Gravity: 1.62 @ 20C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 121C (250F) Melting Point: -19C (-2F) Vapor Density (Air=1): 5.7 Vapor Pressure (mm Hg): 18 @ 25C (77F) Evaporation Rate (BuAc=1): 0.33 (trichloroethylene = 1)

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Slowly decomposed by light. Deteriorates rapidly in warm, moist climates. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hydrogen chloride gas and phosgene gas may be formed upon heating. Decomposes with moisture to yield trichloroacetic acid and hydrochloric acid. Hazardous Polymerization: Will not occur. Incompatibilities: Strong acids, strong oxidizers, strong alkalis, especially NaOH, KOH; finely divided metals, especially zinc, barium, lithium. Slowly corrodes aluminum, iron and zinc. Conditions to Avoid: Moisture, light, heat and incompatibles.

11. Toxicological Information

Oral rat LD50: 2629 mg/kg; inhalation rat LC50: 4100 ppm/6H; investigated as a tumorigen, mutagen, reproductive effector.
--------\Cancer Lists\--------------------------------------------------------NTP Carcinogen--Ingredient Known Anticipated IARC Category -------------------------------------------------------------Tetrachloroethylene (127-18-4) No Yes 2A

12. Ecological Information

Environmental Fate: When released into the soil, this material is expected to quickly evaporate. When released into the soil, this

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material may leach into groundwater. When released into the soil, this material may biodegrade to a moderate extent. When released to water, this material is expected to quickly evaporate. When released into water, this material is not expected to biodegrade. This material is not expected to significantly bioaccumulate. When released into the air, this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals. Environmental Toxicity: The LC50/96-hour values for fish are between 1 and 10 mg/l. The LC50/96-hour values for fish are between 10 and 100 mg/l. This material is expected to be toxic to aquatic life.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Domestic (Land, D.O.T.) ----------------------Proper Shipping Name: TETRACHLOROETHYLENE Hazard Class: 6.1 UN/NA: UN1897 Packing Group: III Information reported for product/size: 20L International (Water, I.M.O.) ----------------------------Proper Shipping Name: TETRACHLOROETHYLENE Hazard Class: 6.1 UN/NA: UN1897 Packing Group: III Information reported for product/size: 20L

15. Regulatory Information

--------\Chemical Inventory Status - Part 1\--------------------------------Ingredient TSCA EC Japan Australia ----------------------------------------------- ---- --- ----- --------Tetrachloroethylene (127-18-4) Yes Yes Yes Yes --------\Chemical Inventory Status - Part 2\----------------------------------Canada-Ingredient Korea DSL NDSL Phil. ----------------------------------------------- ----- ------ ----Tetrachloroethylene (127-18-4) Yes Yes No Yes --------\Federal, State & International Regulations - Part 1\----------------SARA 302------SARA 313-----Ingredient RQ TPQ List Chemical Catg. ----------------------------------------- ---------- -------------Tetrachloroethylene (127-18-4) No No Yes No --------\Federal, State & International Regulations - Part 2\----------------RCRA-TSCAIngredient CERCLA 261.33 8(d) ----------------------------------------- ----------------

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TETRACHLOROETHYLENE
Tetrachloroethylene (127-18-4) 100 U210 CDTA: No Pressure: No No

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Chemical Weapons Convention: No TSCA 12(b): No SARA 311/312: Acute: Yes Chronic: Yes Fire: No Reactivity: No (Pure / Liquid)

WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. Australian Hazchem Code: 2[Z] Poison Schedule: None allocated. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. SUSPECT CANCER HAZARD. MAY CAUSE CANCER. Risk of cancer depends on level and duration of exposure. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases call a physician. Product Use: Laboratory Reagent. Revision Information: MSDS Section(s) changed since last revision of document include: 3, 11. Disclaimer: ************************************************************************************************ Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. ************************************************************************************************ Prepared by: Environmental Health & Safety

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Phone Number: (314) 654-1600 (U.S.A.)

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