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    Solubility Equilibria: End of Chapter 16

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    AndreaMarkham
    The document discusses solubility equilibria and provides examples of solubility product constants (Ksp) for various ionic solids that dissolve in water such as AgCl, MgF2, Ca3(PO4)2. It also discusses the conditions needed for a saturated, unsaturated and supersaturated solution. Additionally, it provides an example calculation to determine the solubility of AgCl in g/L and determines if a precipitate will form when NaOH is added to a solution of CaCl2.

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    Solubility Equilibria: End of Chapter 16

    Uploaded by

    AndreaMarkham
    41 views8 pages
    The document discusses solubility equilibria and provides examples of solubility product constants (Ksp) for various ionic solids that dissolve in water such as AgCl, MgF2, Ca3(PO4)2. It also discusses the conditions needed for a saturated, unsaturated and supersaturated solution. Additionally, it provides an example calculation to determine the solubility of AgCl in g/L and determines if a precipitate will form when NaOH is added to a solution of CaCl2.

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    AP Ksp

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    The document discusses solubility equilibria and provides examples of solubility product constants (Ksp) for various ionic solids that dissolve in water such as AgCl, MgF2, Ca3(PO4)2. It also discusses the conditions needed for a saturated, unsaturated and supersaturated solution. Additionally, it provides an example calculation to determine the solubility of AgCl in g/L and determines if a precipitate will form when NaOH is added to a solution of CaCl2.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    41 views8 pages

    Solubility Equilibria: End of Chapter 16

    Uploaded by

    AndreaMarkham
    The document discusses solubility equilibria and provides examples of solubility product constants (Ksp) for various ionic solids that dissolve in water such as AgCl, MgF2, Ca3(PO4)2. It also discusses the conditions needed for a saturated, unsaturated and supersaturated solution. Additionally, it provides an example calculation to determine the solubility of AgCl in g/L and determines if a precipitate will form when NaOH is added to a solution of CaCl2.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    of 8

    Solubility Equilibria

    End of Chapter 16

    Solubility Equilibria
    AgCl (s) Ksp = [Ag+][Cl-] MgF2 (s) Ag2CO3 (s) Ag+ (aq) + Cl- (aq)

    Ksp is the solubility product constant Ksp = [Mg2+][F-]2 Ksp = [Ag+]2[CO32-]

    Mg2+ (aq) + 2F- (aq) 2Ag+ (aq) + CO32- (aq)

    Ca3(PO4)2 (s)

    3Ca2+ (aq) + 2PO43- (aq)

    Ksp = [Ca2+]3[PO33-]2

    Dissolution of an ionic solid in aqueous solution: Q < Ksp Unsaturated solution

    No precipitate
    Precipitate will form
    16.6

    Q = Ksp
    Q > Ksp

    Saturated solution
    Supersaturated solution

    16.6

    Molar solubility (mol/L) is the number of moles of solute dissolved in 1 L of a saturated solution. Solubility (g/L) is the number of grams of solute dissolved in 1 L of a saturated solution.

    16.6

    What is the solubility of silver chloride in g/L ?

    AgCl (s)

    Initial (M)
    Change (M) Equilibrium (M)

    Ag+ (aq) + Cl- (aq) 0.00 0.00 +s s [Cl-] = 1.3 x 10-5 M +s s

    Ksp = 1.6 x 10-10

    Ksp = [Ag+][Cl-] Ksp = s2


    s = Ksp s = 1.3 x 10-5

    [Ag+] = 1.3 x 10-5 M

    1.3 x 10-5 mol AgCl 143.35 g AgCl Solubility of AgCl = x = 1.9 x 10-3 g/L 1 L soln 1 mol AgCl

    16.6

    16.6

    If 2.00 mL of 0.200 M NaOH are added to 1.00 L of 0.100 M CaCl2, will a precipitate form? The ions present in solution are Na+, OH-, Ca2+, Cl-. Only possible precipitate is Ca(OH)2 (solubility rules). Is Q > Ksp for Ca(OH)2? [Ca2+]0 = 0.100 M [OH-]0 = 4.0 x 10-4 M

    2 Q = [Ca2+]0[OH-]0 = 0.10 x (4.0 x 10-4)2 = 1.6 x 10-8

    Ksp = [Ca2+][OH-]2 = 8.0 x 10-6

    Q < Ksp

    No precipitate will form

    16.6

    Qualitative Analysis of Cations

    16.11

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