The document discusses several key concepts in chemistry including:
1) The definition of a true solution as particles that are 10-10 meters or smaller and cannot be separated through filtration or centrifugation.
2) Common units used to express concentrations such as parts per million (ppm).
3) Factors that influence gas solubility in liquids according to Henry's and Raoult's laws such as gas nature, liquid nature, and pressure.
4) The use of standard reduction potentials to calculate cell potentials in electrochemical cells and the differences between galvanic and electrolytic cells.
The document discusses several key concepts in chemistry including:
1) The definition of a true solution as particles that are 10-10 meters or smaller and cannot be separated through filtration or centrifugation.
2) Common units used to express concentrations such as parts per million (ppm).
3) Factors that influence gas solubility in liquids according to Henry's and Raoult's laws such as gas nature, liquid nature, and pressure.
4) The use of standard reduction potentials to calculate cell potentials in electrochemical cells and the differences between galvanic and electrolytic cells.
The document discusses several key concepts in chemistry including:
1) The definition of a true solution as particles that are 10-10 meters or smaller and cannot be separated through filtration or centrifugation.
2) Common units used to express concentrations such as parts per million (ppm).
3) Factors that influence gas solubility in liquids according to Henry's and Raoult's laws such as gas nature, liquid nature, and pressure.
4) The use of standard reduction potentials to calculate cell potentials in electrochemical cells and the differences between galvanic and electrolytic cells.
The document discusses several key concepts in chemistry including:
1) The definition of a true solution as particles that are 10-10 meters or smaller and cannot be separated through filtration or centrifugation.
2) Common units used to express concentrations such as parts per million (ppm).
3) Factors that influence gas solubility in liquids according to Henry's and Raoult's laws such as gas nature, liquid nature, and pressure.
4) The use of standard reduction potentials to calculate cell potentials in electrochemical cells and the differences between galvanic and electrolytic cells.
In a true solution, all the particles are of the molecular
size, i.e. upto 10-10m (diameter) and hence cant be
separated by filtration or centrifugation etc. The concentration of pollutants in water or atmosphere is often expressed in terms of parts per million (ppm). Solubility of a gas in a liquid depends upon- nature of the gas, nature of the solvent, pressure of the gas. According to Henrys law, mass (m) of a gas dissolved in a liquid solvent is directly proportional to the pressure (p) of the gas above the liquid. m p, or m = KH .p (KH is Henry constant). According to Raoults law, p = p0. x (p0 =max. value of pressure, x = mole fraction of solute). The extent, to which a solute undergoes association / dissociation in a solvent, is determined by Vant Hoff factor (i). Under standard conditions of concentration of all the electrodes, the emf of a cell is given by, Ecell = Ered (cathode) Ered (anode) (Ered is the value of reduction potential of the electrodes). In an electrochemical cell, spontaneous redox reactions are used to generate electric current; in electrolytic cell, electricity is used to perform chemical reactions. The unit of rate constants for a zero order reaction is mol L-1 s-1 while that of a first order reaction is s-1. Order of a reaction can be positive, negative or zero, while molecularity is always a positive number. A catalyst decreases the activation energy of reactants.