Lesson On Packed Scrubbers Technology
Lesson On Packed Scrubbers Technology
Lesson On Packed Scrubbers Technology
Objectives
At the end of this lesson, you will be able to do the following:
1. Describe the operation of packed tower scrubbers
2. Describe at least three different gas-liquid flow arrangements (designs) for packed tower
scrubbers
3. Describe major operating and maintenance problems associated with each packed scrubber
design
4. Identify the range of operating values for pressure drop, liquid-to-gas ratio, as well as the
collection efficiency of packed tower scrubbers for particles and gases
Introduction
In packed tower or wet-film scrubbers, liquid is sprayed or poured over packing material
contained between support trays. A liquid film coats the packing through which the exhaust
gas stream is forced. Pollutants are collected as they pass through the packing, contacting the
liquid film. Therefore, both gas and liquid phases provide energy for the gas-liquid contact.
A wet-film scrubber uses packing to provide a large contact area between the gas and liquid
phases, turbulent mixing of the phases, and sufficient residence time for the exhaust gas to
contact the liquid. These conditions are ideal for gas absorption. Large contact area and good
mixing are also good for particle collection; however, once collected, the particles tend to
accumulate and plug the packing bed. The exhaust gas is forced to make many changes in
direction as it winds through the openings of the packed material. Large particles unable to
follow the streamlines, hit the packing and are collected in the liquid. As this liquid drains
through the packing bed, the collected particles may accumulate, thus plugging the void
spaces in the packed bed. Therefore, wet-film scrubbers are not used when particle removal is
the only concern. Many other scrubber designs achieve better particle removal for the same
power input (operating costs).
2.0-7/98
5-1
Lesson 5
___________________________________________________________________________________
Gas Collection
For gas absorption, packed scrubbers are the most commonly used devices. The wet film
covering the packing enhances gas absorption several ways by providing:
Because of these features, packed towers are capable of achieving high removal efficiencies
for many different gaseous pollutants.
Numerous operating variables affect absorption efficiency. Of primary importance is the
solubility of the gaseous pollutants. Pollutants that are readily soluble in the scrubbing liquid
can be easily removed under a variety of operating conditions. Some other important
operating variables are discussed below.
Gas velocity - The rate of exhaust gas from the process determines the scrubber size to be
used. The scrubber should be designed so that the gas velocity through it will promote good
mixing between the gas and liquid phases. However, the velocity should not be too fast to
cause flooding.
Liquid-injection rate - Generally, removal efficiency is increased by an increase in the
liquid-injection rate to the vessel. The amount of liquid that can be injected is limited by the
dimensions of the scrubber. Increasing liquid-injection rates will also increase the operating
costs. The optimum amount of liquid injected is based on the exhaust gas flow rate.
Packing size - Smaller packing sizes offer a larger surface area, thus enhancing absorption.
However, smaller packing fits more tightly, which decreases the open area between packing,
thus increasing the pressure drop across the packing bed.
Packing height - As packing height increases, total surface area and residence time increases,
enhancing absorption. However, more packing necessitates a larger absorption system, which
increases capital cost.
Tower Designs
Packed towers are typically designated by the flow arrangement used for gas-liquid contact or
by the material used as packing for the bed. The most common flow configuration for packed
towers is countercurrent flow. Figure 5-1 shows a packed tower with this arrangement. The
exhaust stream being treated enters the bottom of the tower and flows upward over the
packing material. Liquid is introduced at the top of the packing by sprays or weirs, and it
flows downward over the packing material. As the exhaust stream moves up through the
packing, it is forced to make many winding changes in direction, resulting in intimate mixing
of both the exhaust gas and liquid streams. This countercurrent-flow arrangement results in
the highest theoretically achievable efficiency. The most dilute gas is contacted with the
purest absorbing liquor, providing a maximized concentration difference (driving force) for
the entire length of the column. In the other two flow arrangements, the scrubbing liquid
could theoretically reach the same concentration as the flue gas (since they are moving in
similar directions) and therefore absorption would stop.
5-2
2.0-7/98
Mist eliminator
Liquid sprays
Packing
Figure 5-1.
The countercurrent-flow packed tower does not operate effectively if there are large
variations in the liquid or gas flow rates. If either the liquid-injection rate or the gas flow rate
through the packing bed is too high, a condition called flooding may occur. Flooding is a
condition where the liquid is "held" in the pockets, or void spaces, between the packing and
does not drain down through the packing. Flooding can be reduced by reducing the gas
velocity through the bed or by reducing the liquid-injection rate.
In another flow arrangement used with packed towers, cocurrent flow, both the exhaust gas
and liquid phases enter at the top of the absorber and move downward over the packing
material. This allows the absorber to operate at higher liquid and gas flow rates since flooding
is not a problem. The pressure drop is lower than with countercurrent flow since both streams
move in the same direction. The major disadvantage is that removal efficiency is very limited
due to the decreasing driving force (concentration differential) as the streams travel down
through the column. This limits the areas of application for cocurrent absorbers. They are
used almost exclusively in situations where limited equipment space is available, since the
tower diameter is smaller than that for countercurrent or plate towers for equivalent flow
rates. Cocurrent flow is illustrated in Figure 5-2.
2.0-7/98
5-3
Lesson 5
___________________________________________________________________________________
Liquid sprays
Packing
Figure 5-2.
In packed towers using the crossflow arrangement, the exhaust gas stream moves
horizontally through the packed bed. The bed is irrigated by the scrubbing liquid flowing
down through the packing material. The liquid and exhaust gas flow in directions
perpendicular to each other. A typical crossflow packed tower is shown in Figure 5-3. Inlet
sprays aimed at the face of the bed may also be included. If included, these sprays scrub both
the entering gas and the face of the packed bed. The leading face of the packed bed is slanted
in the direction of the oncoming gas stream. This ensures complete wetting of the packing by
allowing time for the liquid at the front face of the packing to drop to the bottom before being
pushed back by the entering gas.
5-4
2.0-7/98
Liquid sprays
Inlet sprays
(optional)
Packing
Figure 5-3.
Crossflow absorbers can be designed to be smaller and have a lower pressure drop than any
other packed or plate tower for the same application (i.e. removal efficiency and flow rates).
In addition, they are better suited than other wet-film scrubbers to handle exhaust streams
with high particle concentrations. By adjusting the liquid flow rate, incoming particles can be
removed and washed away in the front half of the bed. This also results in a liquid savings by
enabling the crossflow packed tower to use less liquid in the rear sprays. This practice is
carried one step further by actually constructing the tower into sections as shown in Figure
5-4. The front section can be equipped with water sprays and used for particulate matter
removal. In the second section, sprays may contain a reagent in the scrubbing liquor for gas
removal. The last section can be left dry to act as an entrainment separator. Crossflow packed
towers do require complex design procedures since concentration gradients exist in two
directions in the liquid: from top to bottom and from front to rear.
Liquid sprays
Packing
Figure 5-4.
2.0-7/98
5-5
Lesson 5
___________________________________________________________________________________
Another crossflow packed tower is the fiber-bed scrubber. The fiber-bed scrubber has
packed beds that are made with fibrous material such as fiberglass or plastic (Figure 5-5).
Liquid is sprayed onto the fiber beds to provide a wetted surface for pollutant removal and to
wash away any collected material.
Liquid sprays
Fiber bed
Figure 5-5.
Fiber-bed scrubber
Packing Material
Packing material is the heart of the tower. It provides the surface over which the scrubbing
liquid flows, presenting a large area for mass transfer to occur. Packing material represents
the largest material cost of the packed tower. Pictured in Figure 5-6 are some of the more
commonly used packings. These materials were originally made of stoneware, porcelain, or
metal, but presently, a large majority are made of high-density thermoplastics (polyethylene
and polypropylene). A specific packing is described by its trade name and overall size. For
example, a column can be packed with 5-cm (2-in.) Raschig rings or 2.5-cm (1-in.) Tellerette
packing. The overall dimensions of packing materials normally range from 0.6 to 10 cm (0.25
to 4 in.).
Pall ring
Intalox Metal
Berl saddle
Tellerette
Tri-packs
Raschig ring
Figure 5-6.
5-6
2.0-7/98
Specific packing selected for an industrial application depends on the nature of the
contaminants, geometric mode of contact, size of the absorber, and scrubbing objectives. The
following factors provide a general guide for selecting packing materials (MacDonald 1977):
Cost - Generally, plastic packing is less expensive than metal packing, with ceramic packing
being the most expensive. Packing costs are expressed in dollars per cubic meter ($/m3).
Low pressure drop - Pressure drop is a function of the volume of void space in a tower
when filled with packing: generally, the larger the packing size for a given bed size, the
smaller the pressure drop becomes.
Corrosion resistance - Ceramic or porcelain packings are commonly used in a very
corrosive atmosphere.
Large specific area - A large surface area per cubic foot of packing, m2/m3 (ft2/ft3), is
desirable for mass transfer.
Structural strength - Packing must be strong enough to withstand normal loads during
installation, service, physical handling, and thermal fluctuations. Ceramic packing may crack
under sudden temperature changes.
Weight - Heavier packing may require additional support materials or heavier tower
construction. Plastics have a big advantage in this area since they are much lighter than either
ceramic or metal packings.
Design flexibility - The efficiency of a scrubber changes as the liquid and gas flow rates
vary. Packing material must be able to handle the process changes without substantially
affecting removal efficiency.
Arrangement - Packing material may be arranged in an absorber in one of two ways. The
packing may be dumped into the column randomly or, in certain cases, systematically
stacked, as bricks are laid atop each other. Randomly packed towers provide a higher surface
area, m2/m3 (ft2/ft3), but also cause a higher pressure drop than stacked packing. In addition to
the lower pressure drop, the stacked packing provides better liquid distribution over the entire
surface of the packing. However, the large installation costs required to stack the packing
material usually make it impractical.
Liquid Distribution
As stated previously, one of the keys to effective packed tower operation is to intimately
contact the gas stream with the liquid stream. This contact must be maintained throughout the
entire column length. No packing material will adequately distribute liquid poured onto it at
2.0-7/98
5-7
Lesson 5
___________________________________________________________________________________
only one point. Liquid introduced into the tower in this manner tends to flow down over a
relatively small cross section of the tower diameter. Known as liquid channeling, the liquid
flows in little streams down through the tower without wetting the entire packing area. Liquid
should be distributed over the entire cross-sectional top of the packing.
Once the liquid is distributed over the packing, it flows down (by the force of gravity)
through the packing, following the path of least resistance. The liquid tends to flow toward
the tower wall, where the void spaces are greater than in the center. Once the liquid hits the
wall, it flows straight down the tower from that point (liquid channeling). A way must be
provided to redirect the liquid from the tower wall back to the center of the column. This is
usually done by using liquid redistributors, which funnel the liquid back over the entire
surface of packing. It is recommended that redistributors be placed at intervals of no more
than 3 m (10 ft) or 5 tower diameters, whichever is smaller (Zenz 1972).
Liquid can be distributed over the packing material by one of three devices: weirs, tubes, or
spray nozzles. Figure 5-7 shows both the commonly used weir and perforated-tube liquid
distributors. In the weir design, liquid is introduced into a trough with holes at the top. The
liquid fills to the top and "spills" over onto the packing or another trough for redistribution.
These weir designs have the advantage of being open and not plugged easily. However when
installed they must be level or else the liquid will not be evenly distributed.
The perforated-tube provides good liquid distribution patterns, however the holes are
subject to plugging if any particles or contaminants are in the liquid. The drilled tube is often
buried within the packing bed. This allows the liquid coming out of the holes to be distributed
over the packing without being blown against the side walls of the tower. Burying the tube
also allows the packing above the tube to act as an entrainment separator for countercurrent
flow towers.
Figure 5-7.
Packed towers, designed with spray nozzles to distribute liquid, operate better with a few
large nozzles than with many small nozzles. Large nozzles are less susceptible to plugging.
Small nozzles that produce a finer spray are not needed in a packed tower because pollutant
collection occurs on the wetted packing and not by the liquid droplets. The advantages and
disadvantages of each liquid distributor are listed in Table 5-1.
5-8
2.0-7/98
Table 5-1.
Distributor
Weirs
Advantages
Handle dirty liquids with a high
solids content
Can use river or unfiltered water
Tubes
Disadvantages
Most costly to purchase
Do not distribute liquid as uniformly as other
methods
Maintenance Problems
A serious problem that can drastically affect the operation of a packed tower is the buildup of
solids in the packing. This can occur as a result of a number of situations. If the incoming
exhaust gas contains a high concentration of particulate matter, the beds can easily become
plugged. Precleaning sprays can reduce this problem by removing particles before the
exhaust gas enters the packed bed. Solids buildup can also occur as a result of a chemical
reaction between the scrubbing liquid and gaseous pollutant, producing a solid compound. In
this case, the packing may occasionally be flushed with a cleaning fluid to remove the solids.
For example, potassium permanganate is occasionally used in scrubbing solutions to control
odors. The use of potassium permanganate results in a residue buildup on the packing that
must periodically be cleaned with an acid backwash. No matter what the cause, plugging
presents an expensive maintenance problem. Tower internals are not easily accessible;
cleaning requires shutting the system down and then removing, cleaning, and, finally,
reinstalling the packing material.
Another critical problem in packed tower operation is maintaining the proper liquid and gas
flow rates. If the liquid or gas flow rate increases (one in relation to the other), a point is
reached where the rising exhaust gas starts to hold up the descending liquid. The liquid fills
the upper portion of the packing until its weight causes it to fall. This condition, known as
flooding, results in a high pressure drop, a pulsating airflow in the tower, and greatly reduced
pollutant removal efficiencies. Optimum operating flow rates are normally at 60 to 75% of
the flooding conditions. Conversely, a gas flow rate that is too low can also cause mixing
problems, resulting in gas channeling. Gas channeling occurs when the gas does not
distribute uniformly through the packing, but moves only through a small portion of the bed
(following the path of least resistance). This normally occurs near the walls of the tower,
2.0-7/98
5-9
Lesson 5
___________________________________________________________________________________
where the void spaces are the greatest. Table 5-2 lists problems that can occur in daily
operation of packed towers and some probable causes of these problems.
Table 5-2.
Problem
Static pressure drop
increases
Pressure drop
decreases, slowly
or rapidly
Pressure or flow
change in recycled
liquid causing
reduced liquid flow
5-10
2.0-7/98
Table 5-2.
Problem
Excessive liquid
carryover
(continued)
Operating problems associated with packed towers
Possible causes
Partially plugged entrainment separator, causing channeling and
reentrainment of the collected liquid droplets.
Airflow rate to absorber could have increased above the design capability,
causing reentrainment.
If a packed-type entrainment separator was used, packing may not be level,
causing channeling and reentrainment of moisture.
If a packed entrainment separator was used, and a sudden surge of air
through the absorber occurred, this could have caused the packing to be
carried out of absorber or to be blown aside, creating an open area "hole"
through separator.
Velocity through absorber has decreased to a point that absorption does not
effectively take place, and low removal is achieved.
Reading indicating
low airflow
Increase in airflow
Sudden decrease in
absorber efficiency
Liquid makeup rate to the absorber has been inadvertently shut off or throttled
to a low level, decreasing absorber efficiency.
Set point on pH control may have to be adjusted to allow more chemical feed.
Problem may exist with chemical metering pump, control valve, or line
pluggage.
Liquid flow rate to scrubber may be too low for effective removal.
Summary
Packed towers are mainly used to remove gaseous pollutants. Because of plugging problems,
they are not used when particle removal is the only concern, or when a high concentration of
particulate matter is in the exhaust gas. Packed towers are capable of very high efficiencies
for removing many gaseous pollutants. Packed towers and plate towers are ideal when
pollutants are only slightly soluble, or when the gaseous pollutant removal efficiency must be
greater than 99%. In a packed tower, the optimum pressure drop through a packing section is
1.7 to 5.0 cm (0.2 to 0.6 in.) of water per foot of installed packing (Clark 1975). The overall
2.0-7/98
5-11
Lesson 5
___________________________________________________________________________________
pressure drops across packed towers are usually between 5 and 25 cm (2 and 10 in.) of water.
Thus, packed towers are generally considered as medium-energy scrubbers.
Packed towers are most suited to applications where a high gas-removal efficiency is required
and the exhaust gas is relatively free from particles. These include removing HCl, NH4, and
SO2 gases from a variety of process streams such as those from fertilizer manufacturing,
chemical processing, acid manufacturing, steel making, and metal pickling operations. One
important point that should be noted is that packed towers are not effective in removing
submicrometer-sized particles, even if the particles are very soluble. Inorganic salts or fumes
such as ammonium chloride or aluminum chloride are prime examples. These particles are
usually so small that they flow with the exhaust gas through the packing bed and are not
absorbed. Table 5-3 lists the general operating characteristics of wet-film scrubbers.
Table 5-3.
Pollutant
Pressure
drop
(p)
Liquid-inlet
pressure
(p )
L
Gases
2-8.5 cm/m
of column
packing
Particles
(0.25-1 in./ft
of column
packing)
0.13-2.0 L/m3
34-100 kPa
(5-15 psig)
Removal
efficiency
Applications
Very high,
99+%,
depending
on
operating
conditions
2.0 m
diameter
Acid plants
Metal operations
Chemical
process
industries
Plate towers (described in Lesson 3) are used to control emissions from many of the same
processes that could use packed towers. Therefore, when gas removal is the only objective,
the choice is often between a packed or plate absorber.
The following list gives some factors to consider when comparing plate towers to packed
towers:
1. Packed towers are not able to handle particulate matter or other solid materials in the flue
gas as well as plate towers.
2. Plate towers are chosen for operations that involve difficult gases to absorb or that must
handle large gas volumes. To achieve the same collection efficiency for difficult
absorption processes, packed towers must have either deep packed beds or multiple beds.
Packed towers can experience liquid channeling problems if the diameter or height of the
tower is too large. Redistribution trays must be installed in large-diameter and tall packed
towers to avoid channeling.
3. The total weight of a packed tower is more than that of a comparable plate tower.
5-12
2.0-7/98
4. Packed towers are much cheaper to construct than plate towers if corrosive substances are
to be handled. Packed towers can be constructed with a fiberglass-reinforced polyester
shell which is generally about half the cost of a carbon steel plate tower.
5. Packed towers cannot handle volume and temperature fluctuations as well as plate
towers. Expansion or contraction due to temperature changes can crush or melt packing
material.
2.0-7/98
5-13
Lesson 5
___________________________________________________________________________________
5-14
2.0-7/98
Review Exercise
1.
True or False? Packed towers have limited application for particulate removal.
2.
Packed towers are frequently used for removing gaseous pollutants because:
a.
b.
c.
d.
3.
Increasing the liquid flow rate in a packed tower will usually ____________________ the
gas removal rate.
a. Increase
b. Decrease
c. Have no effect on
4.
In a ____________________ packed tower, the gas stream being treated enters the bottom
and flows upward through the packing while the liquid is introduced over the top of the
packing and flows down through it.
a. Cocurrent
b. Crossflow
c. Countercurrent
5.
6.
Cocurrent
Countercurrent
Crossflow
Fiber-bed
7.
True or False? Crossflow packed towers can handle flue gas containing a high concentration
of particulate matter because they use liquid sprays that will remove and wash away
particles in the front half of the bed.
8.
2.0-7/98
Porcelain
Polyethylene
Polypropylene
All of the above
5-15
Lesson 5
___________________________________________________________________________________
9.
In a packed tower, liquid occasionally flows in little streams straight through the packing
without wetting the packing surface. This condition is called:
a.
b.
c.
d.
Flooding
Liquid channeling
Mixing
Plugging
Sprays
Sprays and small venturis
Sprays, weirs, and tubes
Chevron-shaped sheets and sprays
11. If the gas flow rate through a packed tower is too low, ____________________ may occur.
a.
b.
c.
d.
Flooding
Mixing
Gas channeling
Plugging
12. True or False? Packed towers are most suitable for industrial processes requiring high gasremoval efficiency, but not having a high concentration of particulate matter in the flue gas.
13. True or False? Packed towers remove particulate matter and other solids more easily and
with less maintenance problems than plate towers.
14. In processes having high-temperature flue gas, ____________________ towers are more
suitable because their internal components will expand and contract.
a. Plate
b. Packed
5-16
2.0-7/98
True
Packed towers have limited application for particulate removal.
2.
The packing provides good mixing of gas and liquid and a long residence time
3.
a. Increase
Increasing the liquid flow rate in a packed tower will usually increase the gas removal rate
because of increasing the potential solubility of the pollutant in the additional liquid.
4.
c. Countercurrent
In a countercurrent packed tower, the gas stream being treated enters the bottom and flows
upward through the packing while the liquid is introduced over the top of the packing and
flows down through it.
5.
b. Countercurrent
A countercurrent packed tower cannot handle large variations in liquid or gas flow rates
because flooding may occur.
6.
b. Lower
Cocurrent packed towers usually have lower pressure drops than countercurrent packed
towers. Because the liquid and gas streams move in the same direction in cocurrent packed
towers, there is less resistance to flow.
7.
True
Crossflow packed towers can handle flue gas containing a high concentration of particulate
matter because they use liquid sprays that will remove and wash away particles in the front
half of the bed.
8.
9.
b. Liquid channeling
In a packed tower, liquid occasionally flows in little streams straight through the packing
without wetting the packing surface. This condition is called liquid channeling.
2.0-7/98
5-17
Lesson 5
___________________________________________________________________________________
efficiency, but not having a high concentration of particulate matter in the flue gas. Packed
towers are susceptible to plugging.
13. False
Packed towers do NOT remove particulate matter and other solids more easily and with less
maintenance problems than plate towers. The tops of plates can usually be accessed through
openings, while the middle of the packed bed cannot.
14. a. Plate
In processes having high-temperature flue gas, plate towers are more suitable because their
internal components will expand and contract.
5-18
2.0-7/98
Bibliography
Bethea, R. M. 1978. Air Pollution Control Technology. New York: Van Nostrand Reinhold.
Clark, J. M. 1975. Absorption equipment. In F. L. Cross and H. E. Hesketh (Eds.), Handbook for
the Operation and Maintenance of Air Pollution Control Equipment. Westport: Technomic
Publishing.
MacDonald, J. W. 1977. Packed wet scrubbers. In P. N. Cheremisinoff and R. A. Young (Eds.), Air
Pollution Control and Design Handbook. Part 2. New York: Marcel Dekker.
MacDonald, J. W. 1982. Absorbers. In L. Theodore and A. J. Buonicore (Eds.), Air Pollution
Control Equipment, Design, Selection, Operation, and Maintenance. Englewood Cliffs:
Prentice-Hall.
McIlvaine Company. 1974. The Wet Scrubber Handbook. Northbrook, IL: McIlvaine Company.
Richards, J. R. 1995. Control of Particulate Emissions (APTI Course 413). U.S. Environmental
Protection Agency.
Richards, J. R. 1995. Control of Gaseous Emissions. (APTI Course 415). U.S. Environmental
Protection Agency.
Zenz, F. A. 1972. Designing gas absorption towers. Chemical Engineering. 79:120-138.
2.0-7/98
5-19
Lesson 5
___________________________________________________________________________________
5-20
2.0-7/98