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    Appendix: Results of Calculation of Polar HSP Via Equation (Continued) Appendix A1 Table A1-5 % Difference Mpa

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    This document discusses the calculation of polar Hansen solubility parameters (HSP) via Equation C5-4, which uses the molar volume and dipole moment of solvents. A table shows the results of this calculation for various solvents compared to values reported by Dr. Hansen, finding inconsistent outcomes. Specifically, Equation C5-4 produced very high polar HSP values for certain fluorinated solvents compared to Dr. Hansen's practical experience. While Equation C5-4 provides a method for estimating polar HSP, it has limitations and may not always agree with experimentally determined values.

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    Appendix: Results of Calculation of Polar HSP Via Equation (Continued) Appendix A1 Table A1-5 % Difference Mpa

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    palanaruva
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    This document discusses the calculation of polar Hansen solubility parameters (HSP) via Equation C5-4, which uses the molar volume and dipole moment of solvents. A table shows the results of this calculation for various solvents compared to values reported by Dr. Hansen, finding inconsistent outcomes. Specifically, Equation C5-4 produced very high polar HSP values for certain fluorinated solvents compared to Dr. Hansen's practical experience. While Equation C5-4 provides a method for estimating polar HSP, it has limitations and may not always agree with experimentally determined values.

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    This document discusses the calculation of polar Hansen solubility parameters (HSP) via Equation C5-4, which uses the molar volume and dipole moment of solvents. A table shows the results of this calculation for various solvents compared to values reported by Dr. Hansen, finding inconsistent outcomes. Specifically, Equation C5-4 produced very high polar HSP values for certain fluorinated solvents compared to Dr. Hansen's practical experience. While Equation C5-4 provides a method for estimating polar HSP, it has limitations and may not always agree with experimentally determined values.

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    Appendix: Results of Calculation of Polar HSP Via Equation (Continued) Appendix A1 Table A1-5 % Difference Mpa

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    palanaruva
    This document discusses the calculation of polar Hansen solubility parameters (HSP) via Equation C5-4, which uses the molar volume and dipole moment of solvents. A table shows the results of this calculation for various solvents compared to values reported by Dr. Hansen, finding inconsistent outcomes. Specifically, Equation C5-4 produced very high polar HSP values for certain fluorinated solvents compared to Dr. Hansen's practical experience. While Equation C5-4 provides a method for estimating polar HSP, it has limitations and may not always agree with experimentally determined values.

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    of 1

    Estimation of HSP from Correlations

    Appendix

    C5

    Table C5-4 Results of Calculation of Polar HSP via Equation C5-4 (Continued)

    Dipole
    Moment D

    Vm
    cc/mol

    n-Propanol

    1.71

    74.8

    n-Propyl Acetate

    1.8

    n-Propyl Bromide

    2.18

    Octane

    Pentane
    Perchloroethylene

    Solvent Name

    Pentyl Propionate
    PFC

    Eq. C5-4

    MPa

    % Difference

    7.41

    6.8

    8.90%

    114.9

    6.28

    4.3

    46.00%

    92.3

    8.48

    5.8

    46.30%

    162.5

    115.3

    102.3

    5.7

    1.8

    164.6

    5.25

    5.2

    0.90%

    5060

    201.2

    Propylene Carbonate

    4.98

    84.7

    20.23

    Propylene Glycol

    2.66

    73.5

    11.6

    Propylene Glycol
    Monoethyl Ether

    1.29

    115.9

    Tertiary Butyl Acetate

    1.9

    134

    Tetrahydrofuran

    2.69

    81.1

    Trichloroethylene

    1.26

    89.8

    Styrene

    0.06

    Toluene

    0.36

    18

    12.40%

    9.4

    23.40%

    4.49

    6.5

    30.90%

    6.14

    3.4

    80.80%

    11.17

    5.7

    96.00%

    4.95

    3.1

    59.80%

    115

    0.21

    79.40%

    106.3

    1.31

    1.4

    6.70%

    So the calculation of polar HSP is done by using Equation


    C5-418 which only requires knowledge of the molar
    volume and dipole moment.

    C.3.1. Results of Calculation of the Polar


    Solubility Parameter
    Equation C5-4 should be used with care. It is not correct to
    declare the polar HSP as zero for a solvent with no
    measured dipole moment (m 0).
    As determined from solubility experiments (Appendix
    C9), the polar HSP value for trans-1,2-dichloroethylene is
    not zero, but 7.8 MPa.
    Outcomes of such calculations, and comparison with
    values reported by Dr. Hansen in Chapter 2, Endnote I, are
    tabulated in Table C5-4.

    18

    Appendix A1 Table
    A1-5

    The units for d in Equation C5-4 are those commonly used in this
    book, MPa.

    Its clear from this table that Equation C5-4 produces


    inconsistent outcomes19.
    The three solvents with the poorest agreement between
    using Equation C5-4 and values reported by Dr. Hansen are
    the valued cleaning solvents HFE-7100 and HFE-7200 (as
    well as HFE-7500).
    The reason that Equation C5-4 produces high values for
    these three solvents is the high value used for the dipole
    momentE. Yet practical experience with these solvents
    suggests that the polar HSP values from Dr. Hansen are
    much more nearly correct. The reason for the difference is
    unknown.
    The results of Table C5-4 are plotted in Figure C5-13.

    19

    One reason for concern about use of Equation C5-4 is that


    information about dipole moments is often obtained from molecular
    orbital calculations and not from empirical measurements. Values
    obtained from molecular orbital calculations do not include the effect of
    the environment. Multiple entries for a solvent in Table C5-4 result from
    different reported values of dipole moment.

    611

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