Obtencion de Metanol

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Obtencion de metanol

http://www.supermethanol.eu/index.php?
id=21&rid=12&r=methanol_synthesis&PHPSESSID=c9ngo2ijq0pbon5n1jgd2d2
tr2

From synthesis gas[edit]


Carbon monoxide and hydrogen react over a catalyst to produce methanol. Today, the most
widely used catalyst is a mixture of copper, zinc oxide, and alumina first used by ICIin 1966. At
510 MPa (50100 atm) and 250 C (482 F), it can catalyze the production of methanol from
carbon monoxide and hydrogen with high selectivity (>99.8%):
CO + 2 H2 CH3OH
It is worth noting that the production of synthesis gas from methane produces
three moles of hydrogen gas for every mole of carbon monoxide, while the methanol
synthesis consumes only two moles of hydrogen gas per mole of carbon monoxide. One
way of dealing with the excess hydrogen is to inject carbon dioxide into the methanol
synthesis reactor, where it, too, reacts to form methanol according to the equation:
CO2 + 3 H2 CH3OH + H2O
Some chemists believe that the certain catalysts synthesize methanol using CO 2 as an
intermediary, and consuming CO only indirectly.
CO2 + 3 H2 CH3OH + H2O
where the H2O byproduct is recycled via the water-gas shift reaction
CO + H2O CO2 + H2,
This gives an overall reaction, which is the same as listed above.
CO + 2 H2 CH3OH
http://en.wikipedia.org/wiki/Methanol

http://bioweb.sungrant.org/Technical/Bioproducts/Bioproducts+from+Syngas/M
ethanol/Default.htm

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