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ME209x THERMODYNAMICS edX/IITBombayX/2014

Contents of this Course


Introduction to thermodynamics. Denitions and terms. System, surroundings,
boundaries, classication.
State of a system. Properties of systems. Classication of properties.
Thermodynamic state space. Equilibrium, processes, interactions.
The work interaction. Thermodynamic denition of work. Sign convention.
Characteristics of the work interaction. Modes of work. Simple and complex systems.
Evaluation of work.
Problem-solving technique. Units and dimensions. Conversion factors.
Adiabatic boundary. Adiabatic systems and processes. Adiabatic work. The First Law.
Basic form. Energy of a system. The heat interaction. Sign convention.
Diathermic boundary. Zeroth law. Isothermal states. Empirical temperature.
Principles of thermometry. Scales of temperature. Gas thermometer. The ideal gas.
Ideal gas temperature scale.
Classication of Fluids. Properties of Water. Phase Diagram of Water. Gibbs Phase
Rule. Introduction to Steam tables. Subcooled and Superheated Regions. Dryness
Fraction. Introduction to the Mollier diagram. Application of the rst law to uid
systems.
The Second Law. A multiplicity of statements. The Kelvin-Planck statement.
Hiearchy of temperatures. Denition of higher and lower temperature. Carnot
theorem. Thermodynamic temperature scales. Thermodynamic Kelvin scale. Carnot
engine. Equivalence of thermodynamic Kelvin scale and ideal gas Kelvin scale.
Clausius inequality. Denition of entropy. Evaluation of entropy. Principle of increase
of entropy. Formulation of second law for closed systems. Adiabatic, reversible, and
isentropic processes.
Auxiliary functions. Property relations. Maxwells equations. Applications to
equations of state.
First law for open systems. Derivation of the general form. Special cases. Steady-ow
energy equation. Second law for open systems. Applications to typical engineering
systems.

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