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    BASE-2 Assignment: Q.1 Find Out The Basicity Order of The Given Following Compound

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    Mohit Garg
    1. The document provides information to determine the basicity order of various nitrogen-containing compounds. 2. It explains the basicity order of exception case 9, where compound I is more basic than compound II due to differences in sterics and angle strain effects after protonation. For compound I, relief of bond pair/lone pair repulsion outweighs steric effects, making the conjugate acid more stable. 3. The document provides 20 questions with various nitrogen compounds to rank in order of basicity based on factors like conjugation, resonance, inductive and steric effects.

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    BASE-2 Assignment: Q.1 Find Out The Basicity Order of The Given Following Compound

    Uploaded by

    Mohit Garg
    33 views4 pages
    1. The document provides information to determine the basicity order of various nitrogen-containing compounds. 2. It explains the basicity order of exception case 9, where compound I is more basic than compound II due to differences in sterics and angle strain effects after protonation. For compound I, relief of bond pair/lone pair repulsion outweighs steric effects, making the conjugate acid more stable. 3. The document provides 20 questions with various nitrogen compounds to rank in order of basicity based on factors like conjugation, resonance, inductive and steric effects.

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    1. The document provides information to determine the basicity order of various nitrogen-containing compounds. 2. It explains the basicity order of exception case 9, where compound I is more basic than compound II due to differences in sterics and angle strain effects after protonation. For compound I, relief of bond pair/lone pair repulsion outweighs steric effects, making the conjugate acid more stable. 3. The document provides 20 questions with various nitrogen compounds to rank in order of basicity based on factors like conjugation, resonance, inductive and steric effects.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    33 views4 pages

    BASE-2 Assignment: Q.1 Find Out The Basicity Order of The Given Following Compound

    Uploaded by

    Mohit Garg
    1. The document provides information to determine the basicity order of various nitrogen-containing compounds. 2. It explains the basicity order of exception case 9, where compound I is more basic than compound II due to differences in sterics and angle strain effects after protonation. For compound I, relief of bond pair/lone pair repulsion outweighs steric effects, making the conjugate acid more stable. 3. The document provides 20 questions with various nitrogen compounds to rank in order of basicity based on factors like conjugation, resonance, inductive and steric effects.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    BASE-2 Assignment

    Q.1 Find out the basicity order of the given following compound :
    1. N
    CH
    3
    C H
    3
    CH
    3
    N
    (a) (b)
    2.
    N
    N
    I II
    3.
    NH
    2
    N
    N
    H
    NH
    I II III IV
    4.
    CH
    2
    -
    O
    -
    I II III IV
    5. (I)
    NH
    2
    N H
    (II)
    NH
    2
    N H
    NH
    2
    (III)
    NH
    2
    N H
    N
    +
    O
    -
    O
    (IV)
    NH
    2
    N H
    Cl
    6. (I)
    N
    CH
    3
    C H
    3
    NO
    2
    NO
    2
    O
    2
    N
    (II)
    NH
    2
    NO
    2
    NO
    2
    O
    2
    N
    7.
    N
    H
    N
    H
    N
    H
    N
    I II III IV
    8.
    NH
    2
    N
    NH
    2
    N
    I II III
    9.(Exception) (I)
    N
    CH
    3
    C H
    3
    CH
    3
    (II)
    N
    CH
    3
    C H
    3
    C H
    3
    CH
    3
    10. (I)
    NH
    2
    (II)
    N H
    CH
    3
    (III)
    N
    CH
    3
    C H
    3
    11.
    N H
    CH
    3
    N H
    CH
    3
    I II
    12.
    N H
    CH
    3
    N CH
    3
    CH
    3
    I II
    13. (I)
    NH
    2
    (II)
    NH
    2
    N
    +
    O
    -
    O
    (III)
    NH
    2
    N
    +
    O
    -
    O
    (IV)
    NH
    2
    N
    +
    O
    -
    O
    14. (I)
    NH
    2
    C H
    3
    C H
    3
    CH
    3
    (II)
    Si
    C H
    3
    NH
    2
    C H
    3
    CH
    3
    15. (I)
    N CF
    3
    CF
    3
    CF
    3
    (II) C H
    3
    NH
    2
    16. (I)
    NH
    2
    (II)
    NH
    17. (I)
    N
    N
    H
    (II)
    N
    N
    H
    18. (I) C
    NH
    NH
    2
    N H
    2
    (II)
    C H
    3
    CH
    3
    NH
    2
    (III) C
    O
    NH
    2
    N H
    2
    19. (I) MeNH
    2
    (II)
    N
    H
    (III) N C H
    3
    20. (I)
    NMe
    2
    NMe
    2
    (II)
    NMe
    2
    NMe
    2
    Explanation of question number of 9,
    In (I) after protonation in N,N-dimethyl part repulsion is remove but SIR effect produce, but
    relief in repulsion is overcome the steric effect of -Me (methyl) group.
    N
    CH
    3
    C H
    3
    CH
    3
    N
    CH
    3
    C H
    3
    CH
    3
    H


    H
    +
    angle <
    due to bond pair and lone pair repulsion
    (II)
    N
    CH
    3
    C H
    3
    CH
    3
    C H
    3
    N
    CH
    3
    C H
    3
    CH
    3
    C H
    3
    H


    H
    +
    angle <
    but in II case SIR effect overcome the angle relief
    So conjugate acid of I is more stable than conjugate acid of II
    thats why I is more basic than II.

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