Gauge Institute Journal Vol.1 No 4, November 2005, H.

Vic Dannon
1
Zero Point Energy: Thermodynamic
Equilibrium and Planck Radiation Law
H. Vic Dannon
November , 2005
[email protected]
Abstract: In a recent paper, we proved that Plancks radiation
law with zero point energy is equivalent to the combined
assumptions of zero point energy hypothesis, the quantum law
and the approximated Boson statistics.
Here, we apply the principle of maximal entropy to show that
Plancks radiation law with zero point energy represents a state
of thermodynamic equilibrium.
Introduction In a recent paper [1], we proved that Plancks
radiation law with zero point energy [2] is equivalent to the
combined assumptions of the zero point energy hypothesis, the
quantum law and the approximated Boson statistics.
Planck applied the principle of maximal entropy to a volume in
space, to obtain the state of thermodynamic equilibrium for ideal
mono-atomic gases [3].
Bose, in a 1924 paper, translated and published by Einstein [4],
applied the principle of maximal entropy to a volume in phase
space to obtain Plancks radiation law at a state of
thermodynamic equilibrium.
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
2
We apply the principle of maximal entropy in phase space to
show that Plancks radiation law with zero point energy is
obtained at a state of thermodynamic equilibrium.
Here, the maximal entropy principle is only a tool, that does not
replace any of the three combined assumptions that we proved
equivalent to the radiation law with zero point energy. Under the
three assumptions, the principle of maximal entropy implies that
the radiation law with zero point energy is obtained at a state of
thermodynamic equilibrium.
Maximal Entropy and ZPE radiation law:
Following Bose approach in [4], elaborated by Einstein in [5],
the momentum of a radiation quantum is
h
p p
c
v
= =

.
That is, radiation quanta with the same momentum are on the
surface of the sphere
2 2
2 2 2
2
x y z
h
p p p
c
v
+ + = .
Then, for each of its two polarizations, the momentum of the
radiation per volume element, in the spherical shell between v ,
and d v v + , is
2 2 2
2 3
2 3
4 4 4
h h d
p dp d h
c c c
v v v
t t v t = = .
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
3
Therefore, for both polarizations, there are
2
3
8
d
c
v v
t momentum
cells of size
3
h per volume element in the spherical shell between
v , and d v v + .
For the possible frequencies
l
v , 0,1,2,... l = there are
2
3
8
l l
l
d
n
c
v v
t =
momentum cells of size
3
h , per volume element, in the spherical
shell between
l
v , and
l l
d v v + .
Then,
(0) (1) (2) ( )
0
...
j
l l l l l
j
n n n n n

=
= + + + =

, (1)
l
where
(0)
l
n is the number of cells that have no quanta,
(1)
l
n is the number of cells that have one quanta,
(2)
l
n is the number of cells that have two quanta,

The
l
n momentum cells of size
3
h , per volume element, in the
spherical shell between
l
v and
l l
d v v + , can be arranged in
(0) (1) (2) ( )
0
! 1
!
! ! !... !
l
l
j
j
l l l l
n
n
n n n n

=
=
[
ways.
Thus, all the momentum cells of size
3
h , per volume element,
can be arranged in
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
4
( )
0 0
1
!
!
l
j
l j
l
w n
n

= =
=
[ [
ways.
The entropy per volume element is
( )
0 0 0
log log( !) log( !)
j
B B l B l
l l j
s k w k n k n

= = =
= =

,
where
B
k is Boltzman constant.
By Sterlings formula ln ! ln M M M M ~ ,
( ) ( ) ( )
0 0 0
( log ) ( log )
j j j
B l l l B l l l
l l j
s k n n n k n n n

= = =
~

( ) ( )
0 0 0
log log
j j
B l l B l l
l l j
k n n k n n

= = =
=

.
The number of radiation quanta
l
hv between
l
v , and
l l
d v v + is
(1) (2) (3) ( )
0
2 3 ...
j
l l l l
j
n n n jn

=
+ + + =

.
Following Plancks assumption of Zero Point Energy [2], we
assume zero point energy of
1
2 l
hv in each of the
l
n momentum
cells of size
3
h , per volume element, between
l
v and
l l
d v v + ,
Therefore, the radiation energy per volume element is
( ) ( )
1 1
2 2
0 0 0 0 0
( )
j j
l l l l l l l
l j l l j
u h jn h n h jn n v v v

= = = = =
= + = +

. (2)
At thermal equilibrium, the entropy has a maximum under the
constraints (1)
l
0,1,2, ,... l = , on the number of momentum cells,
and the constraint (2), on the radiation energy.
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
5
To find that maximum, we apply the Lagrange multiplier method
with multipliers
l
, 0,1,2, ,... l = , for the constraints (1)
l
0,1,2, ,... l = ,
and 0 | > , for the constraint (2), to the auxiliary function
( ) ( ) ( )
0 0 0
( , , ) log log
j j j
l l l l l l
l l j
F n n n n n |

= = =
=

( ) ( )
1
2
0 0 0 0
( ) ( ( ) )
j j
l l l l l
l j l j
n n u h j n | v

= = = =
+ + +

.
The critical points are at
( )
1
2
( )
0 log 1 ( )
j
l l l
j
l
F
n j h
n
| v
c
= = +
c
, (3)
( )
0
0
j
l l
j
l
F
n n

=
c
= =
c

, (4)
( )
1
2
0 0
0 ( )
j
l l
l j
F
u h j n v
|

= =
c
= = +
c

. (5)
From (3),
( )
1
2
log 1 ( )
j
l l l
n j h | v = + , (6)
or,
1
2
1
( )
l l l
h
j h j
l
n e e
| v
| v


= . (7)
By (5), and (6),
1 1
2 2
1
2
1 1
1
( )
0 0
1 1
l l l l
l l l
l l
h h
h
j h j
l l
h h
j j
e e
n n e e
e e
| v | v
| v
| v
| v | v
+

= =
= = = =


. (8)
Therefore,
1
2
1 log log
1
l
l
h
l l
h
e
n
e
| v
| v
+ + =

. (9)
The quotient
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
6
( )
( 1)
( )
0
1
1
l
l
j
j h
l
h
j
l
j
n
e
e
n
| v
| v
+

=
=

is the Bose-Einstein distribution function.

By (8),
1
2
1
( )
0 0 1
(1 ) ( )
( )
l l l l l
h
j h h j h j
l l
j j j
l
d
jn e je n e e
d h
| v
| v | v | v
| v



= = =
= =

.
The series
1
l
j h
j
e
| v

converges uniformly to
1
1 e
l
h | v

, and can be
differentiated term by term with respect to
l
h | v . Thus,
2
1 0
1
( )
( ) 1 (1 )
l
j h j
j j
l
d d d e
e e
d h d d e e

| v

| v




= =
= = =


.
Therefore,
( )
2
0
(1 )
(1 ) 1
l
l
l l
h
h j
l
l l
h h
j
n e
jn n e
e e
| v
| v
| v | v

=
= =

. (10)
By (5), and (4), and (10),
( )
1 1
2 2
0 0 0
1
( ) ( )
1
l
j
l l l l
h
l j l
u h j n n h
e
| v
v v

= = =
= + = +

. (11)
By (6),
( )
1
2
0 0 0
log ( 1 ( ) )
j
B l l B l l l
l l j
s k n n k n j h | v

= = =
~ +

.
( )
1
2
0 0 0
(1 log ) ( )
j
B l l l B l l
l l j
k n n k h j n | v

= = =
= + + + +

.
Substituting (9), and (10), and (4),
1
2
1
2
0 0
1
( ) log ( )
1 1
l
l l
h
B l B l l
h h
l l
e
s k n k n h
e e
| v
| v | v
| | v

= =
= + +


Using (11),
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
7
1
2
0
( ) log
1
l
l
h
B l B
h
l
e
s k n k u
e
| v
| v
| |

=
= +

. (12)
Hence,
1
B
s
k
T u
|
c
= =
c
.
That is,
max
1
B
k T
| = ,
and
max
| is positive as required.
Then,
1
2
/
max /
0
( ) log
1
l B
l B
h k T
B l h k T
l
e u
s k n
e T
v
v
|

=
= +

(13)
is the maximal entropy.
To confirm that the entropy is maximal, we recall that the
Lagrange multiplier method produces either a maximum or a
minimum for the function in question, which here is the entropy.
Thus, to confirm a maximum, it is enough to check the value of
the entropy at any other point. For instance, take
1 | = .
Then,
/ 2 / 2
/
1 1
l l B
l l B
h h k T
h h k T
e e
e e
v v
v v
<

,
and for 1
B
k T < ,
1 1
2 2
/
max
/
0 0
(1) log log ( )
1 1
l l B
l l B
h h k T
B l B B l
h h k T
l l
e e u
s k n k u k n s
e e T
v v
v v
|

= =
= + < + =


.
Gauge Institute Journal Vol.1 No 4, November 2005, H. Vic Dannon
8
Therefore, at
max
| | = , the entropy is maximal, and at the attained
thermodynamic equilibrium
1
max
2 /
0 0
1
( ) ( )
1
l B
l l l
h k T
l l
u n h n
e
v
v
| v c

= =
= + =

.
Then,
1
2 /
1
( )
1
l B
l
h k T
h
e
v
v
c v = +

is Plancks radiation law with zero point energy.

REFERENCES
1. Dannon, H. Vic, Zero Point Energy: Planck Radiation Law, Gauge
Institute Journal of Math and Physics Vol.1 No 3, August 2005.
2. Planck, M., {Annalen der physik 37 (1912):p.642}.
3. Planck, M. The Theory of Heat Radiation, Dover 1959. Page 129.
4. Bose, S., {Zeitschrift fur Physik 26, 178 (1924)} translated into Plancks
Law and the Light quantum Hypothesis in Pauli and the Spin-Statistics
Theorem by Ian Duck, and E C G Sudarshan, World Scientific 1997, page
78.
5. Einstein, A. {S. B. d. Preuss. Akad. Wiss. Ber. 22, 261 (1924)} translated
into Quantum Theory of Mono-Atomic Ideal Gas in Pauli and the Spin-
Statistics Theorem by Ian Duck, and E C G Sudarshan, World Scientific
1997, page 82.