Quantum resources

In this thesis we study the informational underpinnings of thermodynamics and statistical mechanics. To this purpose, we use an abstract framework—general probabilistic theories—, capable of describing arbitrary physical theories, which allows one to abstract the informational content of a theory from the concrete details of its formalism. In this framework, we extend the treatment of microcanonical thermodynamics, namely the thermodynamics of systems with a well-defined energy, beyond the known cases of classical and quantum theory. We formulate two requirements a theory should satisfy to have a well-defined microcanonical thermodynamics. We adopt the recent approach of resource theories, where one studies the transitions between states that can be accomplished with a restricted set of physical operations. We formulate three different resource theories, differing in the choice of the restricted set of physical operations.

To bridge the gap between the objective dynamics of particles and the subjective world of probabilities, one of the core issues in the foundations of statistical mechanics, we propose four information-theoretic axioms. They are satisfied by quantum theory and more exotic alternatives, including a suitable extension of classical theory where classical systems interact with each other creating entangled states. The axioms identify a class of theories where every mixed state can be modelled as the reduced state of a pure entangled state. In these theories it is possible to introduce well-behaved notions of majorisation, entropy, and Gibbs states, allowing for an information-theoretic derivation of Landauer's principle. The three resource theories define the same notion of resource if and only if, on top of the four axioms, the dynamics of the underlying theory satisfy a condition called “unrestricted reversibility”. Under this condition we derive a duality between microcanonical thermodynamics and pure bipartite entanglement.

We extend the tools of quantum resource theories to scenarios in which multiple quantities (or resources) are present, and their interplay governs the evolution of physical systems. We derive conditions for the interconversion of these resources, which generalise the first law of thermodynamics. We study reversibility conditions for multi-resource theories, and find that the relative entropy distances from the invariant sets of the theory play a fundamental role in the quantification of the resources. The first law for general multi-resource theories is a single relation which links the change in the properties of the system during a state transformation and the weighted sum of the resources exchanged. In fact, this law can be seen as relating the change in the relative entropy from different sets of states. In contrast to typical single-resource theories, the notion of free states and invariant sets of states become distinct in light of multiple constraints. Additionally, generalisations of the Helmholtz free energy, and of adiabatic and isothermal transformations, emerge. We thus have a set of laws for general quantum resource theories, which generalise the laws of thermodynamics. We first test this approach on thermodynamics with multiple conservation laws, and then apply it to the theory of local operations under energetic restrictions.