The 2666Mbps is per data line, not the overall data speed of a fully populated memory DIMM. you are looking at a memory chip, not a DIMM.
A DIMM module consisting of these 2666Mbps chips will have a peak transfer rate of
2666 (data line transfer rate) * 64 (DIMM Memory transfer width)
That gives a peak transfer rate of 170,624 megabits bits per second.
If you divide that by 8 that will give you 21,328 megabytes per second which is 21.328 Gigabytes per second.
That 23.328 Gigabytes per second corresponds to a DDR4-2666 module per Wikipedia.
The reason your Samsung page is listing it in Mbps is because you are looking at a memory chip, not a memory DIMM module. PCB designers, who may use more exotic memory layouts, may only use 2 or 4 chips connected directly to a CPU and so they might not have a "standard" 64-bit wide memory data bus. They might have only a 16-bit or 32-bit bus, in which case they use the Mbps figure and multiply by their bus width to obtain their expected data bandwidth using the calculation I did above.
DDR4 DIMMS typically list an equivalent figure of 2666 MT/s which is "Mega Transfers per second". It is essentially the same as a per data line Mbps figure, but assumes you know what your memory transfer width is. For DDR4 DIMMs that transfer is 64 bits per transfer.