1. Calcular el volumen molar parcial de mezcla a cualquier XORTOSA.

Hoja de cáculo y gr

1000°C Albita Ortoclasa Datos Ideal

X(Fp, NaAlSi3O8) X(Fp, KAlSi3O8) V(Fp, [J/bar-Mol]) V(Fp, [J/bar-Mol])
1 0 10.029 10.029
0.9528 0.0472 10.064 10.069
0.9053 0.0947 10.129 10.109
0.8574 0.1426 10.182 10.150
0.8094 0.1906 10.233 10.191
0.761 0.239 10.281 10.232
0.7124 0.2876 10.346 10.273
0.6634 0.3366 10.373 10.315
0.6142 0.3858 10.442 10.357
0.5647 0.4353 10.494 10.399
0.5149 0.4851 10.535 10.441
0.4648 0.5352 10.573 10.484
0.4144 0.5856 10.613 10.527
0.3637 0.6363 10.664 10.570
0.3127 0.6873 10.692 10.613
0.2613 0.7387 10.731 10.657
0.1578 0.8422 10.802 10.745
0.1055 0.8945 10.822 10.789
0.0529 0.9471 10.864 10.834
0 1 10.879 10.879
0.6 0.15 10.36900
XORTOSA. Hoja de cáculo y graficos

USANDO LOS VALORES DE LA RECTA:

-0.3739 1.2457 10.014

X 2
X incpt
-0.3739 1.2389 10.014

Polinómico 0.8500 VALORES MOLARES PARCIALES DE LA MEZ

V(Fp, [J/bar-Mol])
10.0290 ORTOSA
10.0716 X(Fp, KAlSi3O8)
10.1280 0
10.1831 0.05
10.2366 0.1
10.2887 0.15
10.3394 0.2
10.3887 0.25
10.4363 0.3
10.4824 0.35
10.5270 0.4
10.5700 0.45
10.6113 0.5
10.6509 0.55
10.6889 0.6
10.7251 0.65
10.7922 0.7
10.8230 0.75
10.8520 0.8
10.8790 0.85
10.1914 0.9
y 0.95
1
 Para cualquie X en ese rango
10.8858 -0.0068 pendiente XB tg
10.879 0.15 1.12673

Feldespatos
S MOLARES PARCIALES DE LA MEZCLA: 11.0

EL VALOR DEL INTERSECTO EN EL VALOR DE 1 :

f(x) = − 0.3739187878383 x² + 1.24574166172192 x + 10.01
Vp albita VpOrtoclasa 10.8
10.0140000 11.2529 incpt 10.02241275
10.01493475 11.2164 x=1 11.1491
10.017739 11.1819 10.6
10.02241275 11.1491
10.028956 11.1183
10.03736875 11.0893 10.4
10.047651 11.0622
10.05980275 11.0370
10.07382 11.01360
10.2
10.0436605 10.9461
10.017236 10.8822
10.12710475 10.9547
10.0
10.148604 10.9388
10.17197275 10.9248
10.197211 10.9127
9.8
10.22431875 10.9024
10.253296 10.8940
10.28414275 10.8874
10.022413 11.14914 9.6
0 0.1 0.2 0.3 0.4 0.5 0.6 0
10.02241275 11.1491
10.3879 10.8790
 incpt y(0.4) Y1
10.0224128 10.19142 11.14914275

Feldespatos

187878383 x² + 1.24574166172192 x + 10.0137449645823

.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X(Fp, KAlSi3O8) DHex [Kj/mol] DHM cal/mol" DHM ideal cal/mol

0.0000 0 -0.3811 0.3839

0.1000 2.327 2.4035 0.3074
0.2000 4.307 4.5863 0.2309
0.3000 5.875 6.1673 0.1544
0.4000 6.968 7.1465 0.0779
0.5000 7.523 7.5239 0.0014
0.6000 7.476 7.2995 -0.0751
0.7000 6.764 6.4733 -0.1516
0.8000 5.323 5.0453 -0.2281
0.9000 3.089 3.0155 -0.3046
1.0000 0 0.3839 -0.3811

Calores extrapolados
X(Fp, KAlSi3O8) DHex [Kj/mol]
0.0000 -0.3811
1.0000 0.3839

m = -11.2752x + 14.36594
0 14.36594
0.1 13.23842
0.2 12.1109
0.3 10.98338
0.4 9.85586
0.5 8.72834
0.6 7.60082
0.7 6.4733
0.8 5.34578
0.9 4.21826
1 3.09074
Recta que pasa por el punto
buscado ΔH vs X(ortosa)
30.855 16
24.8364
18.8178 14 f(x) = − 11.2752 x + 14.36594
12.7992
12
6.7806
0.762 10
-5.2566
-11.2752 8
-17.2938 f(x) = − 30.0925407925408 x² + 30.8545407925408 x − 0.381062937062938
6 R² = 0.991244414518972
-23.3124
-29.331 4

0
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
rtosa)

x − 0.381062937062938

0 0.8000 1.0000 1.2000

T (°K) R=
323 8.314
DH [Kj/mol]
ex X(Fp, KAlSi3O8) RTlngA RTlngB gA gB
-0.3811 0.0000
2.4035 0.1000 0.26705556 21.6315 1.00009945 1.00808769
4.5863 0.2000 1.146575 18.3452 1.00042705 1.00685479
6.1673 0.3000 2.64312857 14.3903667 1.00098474 1.00537308
7.1465 0.4000 4.76433333 10.71975 1.00177572 1.00399981
7.5239 0.5000 7.5239 7.5239 1.00280569 1.00280569
7.2995 0.6000 10.94925 4.86633333 1.00408562 1.00181377
6.4733 0.7000 15.1043667 2.77427143 1.00564043 1.00103362
5.0453 0.8000 20.1812 1.261325 1.0075434 1.0004698
3.0155 0.9000 27.1395 0.33505556 1.01015747 1.00012478
0.3839 1.0000
 aA aB W/RT DGex DSex DGM,id DGM Ω

0.90008951 0.10080877 0.00994464 2.4035 -0.00744118 -872.984969 -870.581469 26.7055556

0.80034164 0.20137096 0.01067407 4.5863 -0.01419907 -1343.79168 -1339.20538 28.664375
0.70068931 0.30161192 0.01093612 6.1673 -0.01909381 -1640.42844 -1634.26114 29.3680952
0.60106543 0.40159992 0.01108842 7.1465 -0.02212539 -1807.32034 -1800.17384 29.7770833
0.50140284 0.50140284 0.01120703 7.5239 -0.02329381 -1861.39269 -1853.86879 30.0956
0.40163425 0.60108826 0.01132581 7.2995 -0.02259907 -1807.32034 -1800.02084 30.4145833
0.30169213 0.70072353 0.01147873 6.4733 -0.02004118 -1640.42844 -1633.95514 30.8252381
0.20150868 0.80037584 0.01174234 5.0453 -0.01562012 -1343.79168 -1338.74638 31.533125
0.10101575 0.9001123 0.01247683 3.0155 -0.00933591 -872.984969 -869.969469 33.5055556

Actividad de la Ortosa vs X(Ortosa)

1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.80
a Ortosa vs X(Ortosa)

000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

 T(K) R
323 8.314

X(Fp,
X(albita) ΔHex [Kj/mol]Δhex[Kj/mol] RTlnyA RTlnyB yA Yb
KAlSi3O8)
1 0 0.00 0 0 24.8004 1.00000 1.00928
0.9 0.1 2.327 2.327289 0.1630454 21.8025914 1.00006 1.00815
0.8 0.2 4.307 4.306742 0.7382672 18.5819312 1.00027 1.00694
0.7 0.3 5.875 5.874854 1.8511738 15.2639278 1.00069 1.00570
0.6 0.4 6.968 6.968125 3.6292736 11.9760896 1.00135 1.00447
0.5 0.5 7.523 7.523050 6.200075 8.845925 1.00231 1.00330
0.4 0.6 7.476 7.476127 9.6900864 5.9999424 1.00361 1.00224
0.3 0.7 6.764 6.763854 14.2268162 3.5656502 1.00531 1.00133
0.2 0.8 5.323 5.322726 19.9367728 1.6695568 1.00745 1.00062
0.1 0.9 3.089 3.089243 26.9464646 0.4381706 1.01008 1.00016
0 1 0 0 35.3844 0 1.01326 1.00000

Ecuacion de la curva
y=-10.5838x3-14.2167x2+24.8004x
-10.5838 -31.7514
pendiente de la curva -14.2167 -28.4334
m=-31.7514x2-28.4334x+24.8004 24.8004 24.8004
8.3469
 Ln(γ(ortosa))/(Xalbita)^2 Ln(γ(albita))/(Xortosa)^2

0.010023295968445 0.006071500121768
0.010811808162739 0.006872916063099
0.011599991755942 0.007659354015041
0.012387965673758 0.00844670223153
0.013176215879664 0.009235159315742
0.013964151630544 0.010023343320591
0.014753113497825 0.010811827256763
0.015542778751346 0.011600116294571
0.016316638502248 0.012388086582635

Según Hildedran una solucion regular se define como :

Para que sea regular debe cumplir

(𝐿𝑛(𝛾(𝑜𝑟𝑡𝑜𝑠𝑎)))/ 〖𝑋 ^2 〗 _𝑎𝑙𝑏𝑖𝑡𝑎 =
Ω/𝑅𝑇 = 𝐿𝑛(𝛾(𝑎𝑙𝑏𝑖𝑡𝑎))/ 〖𝑋 ^2 〗 _𝑜𝑟𝑡𝑜𝑠𝑎

SOLUCION NO REGULAR

ya que los datos no son iguales