Calculos Acetona Agua

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CALCULO DE LA TEMPERATURA DE BURBUJA DEL SISTEMA ACETONA-AGUA

P (kPa) = 200.0 T0 (K) = 300 P0 (kPa) = 100


3
xi vi (m /kmol) aij (kcal/kmol) Ai Bi Ci Cpi/R Tis (K)
Acetona(1) 0.013 0.07405 0 291.70 14.3145 2756.22 228.06 8.840 77.64
Agua (2) 0.987 0.01807 1448.01 0 16.3872 3885.70 230.17 4.038 120.24

vector x = 0.013 0.987 TL (K) = 384.76 CpmL = 34.095


vector y = 0.250 0.750 TG (K) = 384.76 CpmG = 43.549
T (° C) s
P1 (kPa)(*) P2s (kPa) L12 L21 q1 q2 g1 g2 P*s (kPa)
119.69 594.99 196.49 0.1679 0.6406 0.1788 0.9953 7.4853 1.0008 471.414
109.76 471.41 142.09 0.1663 0.6105 0.1772 0.9949 7.7746 1.0009 500.555
112.27 500.55 154.46 0.1667 0.6181 0.1776 0.9950 7.7002 1.0009 493.009
111.63 493.01 151.23 0.1666 0.6162 0.1775 0.9950 7.7191 1.0009 494.918
111.79 494.92 152.04 0.1666 0.6167 0.1775 0.9950 7.7143 1.0009 494.432
111.75 494.43 151.84 0.1666 0.6166 0.1775 0.9950 7.7155 1.0009 494.555
111.76 494.56 151.89 0.1666 0.6166 0.1775 0.9950 7.7152 1.0009 494.524
111.76 494.52 151.88 0.1666 0.6166 0.1775 0.9950 7.7152 1.0009 494.532
111.76 494.53 151.88 0.1666 0.6166 0.1775 0.9950 7.7152 1.0009

T vs x1 T (° C) T vs y1
0.000 120.24 0.000
0.010 113.49 0.203 Txy de Acetona-Agua a 200 kPa
0.020 108.39 0.334 125.0
0.030 104.47 0.422
0.040 101.40 0.485 120.0
0.050 98.95 0.531
0.060 96.96 0.566
115.0
0.070 95.32 0.594
0.080 93.96 0.616
0.090 92.81 0.634 110.0
0.100 91.82 0.649
0.125 89.91 0.677 105.0
0.150 88.52 0.697
0.200 86.63 0.723
0.250 85.38 0.740 100.0
0.300 84.46 0.753
0.350 83.71 0.764 95.0
0.400 83.06 0.774
0.450 82.47 0.784 1.000
90.0
0.500 81.91 0.794
0.550 81.38 0.804
0.600 80.85 0.815 85.0
0.650 80.34 0.828
0.700 79.84 0.841 80.0
0.750 79.35 0.857
0.800 78.88 0.876
0.850 78.45 0.898 75.0
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80
0.900 78.07 0.924
0.950 77.78 0.957
0.960 77.74 0.965 T vs x1 T vs y1
0.970 77.70 0.973
0.980 77.67 0.982
0.990 77.65 0.991
1.000 77.64 1.000
Estos resultados son obtenidos a la temperatura y composición de la solución (TB, x)
Pis (kPa) yi gi fiL (kPa) dlnPs/dT ln(fiL/P0) ln(yiP/P0)
494.53 0.250 7.715 50.0 0.02387 -0.694 -0.694
151.88 0.750 1.001 150.0 0.03324 0.406 0.406
0.03311 0.391 0.131
hLGI - h0 = 2889.7939 hvap = 40754.83 (hL - h0) = -37801.68 kJ/kmol Entalpía molar
hGGI - h0 = 3691.11 hE = 63.35 (hG - h0) = 3691.11 kJ/kmol
Tcalc dT (sL - s0) = -100.527 kJ/kmol-K Entropía molar
109.763 -9.923 (sG - s0) = 9.748 kJ/kmol-K
112.265 2.502
111.628 -0.637
111.790 0.162
111.749 -0.041
111.759 0.010
111.757 -0.003
111.757 0.001

a a 200 kPa

0.60 0.70 0.80 0.90 1.00

T vs y1
CALCULO DE LA PRESIÓN DE BURBUJA DEL SISTEMA BINARIO ACETONA-AGUA

T (° C) = 50.00
vi
xi a (kcal/kmol) A B C Pis (kPa) L(i,j) qk
(m3/kmol) (i,j)
Acetona(1) 0.006 0.07405 291.70 14.3145 2756.22 228.06 81.63 0.1549 0.1600
Agua (2) 0.994 0.01807 1448.01 16.3872 3885.70 230.17 12.41 0.4293 0.9965

PB (kPa) = 17.61
A

gi yi

10.66 0.300
1.00 0.700

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