Ou3 2018 I 3
Ou3 2018 I 3
Ou3 2018 I 3
Balance
ARRIBA ABAJO
L2 7685 G2 5287.2 L1 8397.8 G1 6000
Ls 7685 Gs 5280 Ls 7685 Gs 5280
Lg2 0 Gg2 7.2 Lg1 712.8 Gg1 720
x2 0 y2 0.001362 x1 0.084879 y1 0.12
X2 0.000 Y2 0.001 X1 0.093 Y1 0.136
3 ETAPAS
L0 1000 L1 905.26275 L2
Lg0 150 Lg1 55.26275 Lg2
Ls 850 Ls 850 Ls
x0 0.15 x1 0.061046089 x2
X0 0.1765 X1 0.065015 X2
G1 483.3129647 G2 423.4761827 G3
Gg1 94.73720003 Gg2 34.90041803 Gg3
Gs 388.5757647 Gs 388.5757647 Gs
y1 0.196016261 y2 0.082414123 y3
Y1 0.24380625 Y2 0.08981625 Y3
L1 905.26275 L2 870.35835 L3
Lg1 55.26275 Lg2 20.35835 Lg3
Ls 850 Ls 850 Ls
x1 0.061046089 x2 0.023390768 x3
X1 0.0650 X2 0.0240 X3
3 ETAPAS EN CONTRACORRIENTE
Benceno-Aire Absorbente HC
y0 6% M 250
Q 500 m3/h
T 20 °C Recuperación 95%
P 1 atm
Psat 76 mmHg
FLUJO DE GAS
G 20800.13978
ETAPAS TEORICAS
N
0.53125 0.063829787
0.53125 0.035940803
0.286915591 0.035940803 1
0.286915591 0.02280322
0.171817682 0.02280322 2
0.171817682 0.014880681
0.102408594 0.014880681 3
0.102408594 0.009376636
0.054187853 0.009376636 4
0.054187853 0.005166805
0.017305672 0.005166805 5
0.017305672 0.001704027
-0.01303161 0.001704027 6
CURVA DE EQUILIBRIO
0.001
X Y
0 0
0.001 0.0023
0.002 0.0046
0.003 0.0069
0.004 0.0092
0.005 0.0115
0.006 0.0138
0.007 0.0161
0.7
0.6
0.5
0.4
0.0331 0.3
0.0000 0.2
0.1
-0.19736842
0
0 0.05 0.1 0.15 0.2 0.25
870.35835
20.35835 0.8
850
0.7
0.023390768 X0Y01 0.1765 0.0000
0.6
0.023951 X1Y1 0.065015 0.24380625
-2.18747444 0.5
388.5757647 X1Y02 0.065015 0.0000 0.4
0 X2Y2 0.023951 0.08981625
0.3
388.5757647 -2.18722604
0 X2Y03 0.023951 0.0000 0.2
0.0000 X3Y3 0.008823529 0.033088235 0.1
-2.18729464
0
401.433051 0 0.05 0.1
12.85728633
388.5757647
0.03202847 "=-Ls/Gs -2.18747559
0.033088235
857.5
7.5
0.8
850
0.008746356 0.7
0.6
0.5
0.8
0.7
0.008823529
0.6
0.5
X1Y0 0.008823529 0
0.4
X4Y3 0.1765 0.277650318
1.656159789 -0.01461317 0.3
Ls/Gs
X Y Ls/Gs 0.2
0.1765 0.277650318 850
0.074040085 0.277650318 Gs 0.1
0.074040085 0.108009036 513.2355015
0
0.02880241 0.108009036 0.0000 0.0500
0.02880241 0.033088218
-0.1
0.008823525 0.033088218
0.008823525 -7.55038E-09
0.08
Y0 0 0.063829787
1.8 0.063829787 0.07
0.06
X1,Y0 0.85 0.063829787 0.05
0.04
0.03
0.02
0.07
0.06
0.05
XN+1,YN 0 0.003191489 0.04
0.03
Lsmin/Gs 0.071339174
0.02
0
0 0.5 1 1.5
0.08
0.07
X1,Y0 0.53125 0.063829787
0.06
XN+1,YN 0 0.003191489
0.05
0.01
0
-0.5 0 0.5 1
Y
0.018
0.016
0.014
0.012
0.01
0.008
0.006
0.004
0.002
0
0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.00
0.018
0.016
0.014
0.012
0.01
0.008
0.006
0.004
0.002
0
0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009
La distribución de equilibri
Donde X e Y son las concen
Se requiere calcular la can
en A de acuerdo a los sigui
Arriba
L1
Ls/Gs 1.508823529 Ls
Lg1
x1
X1
0.8
0.7
0.6
0.5
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0.0000 0.0500 0.1000 0.1500 0.2000 0.2500
-0.1
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6
1 1.5 2 2.5
1 1.5 2 2.5
Abajo
1282.5 G1 857.5 L2 1425 G2 1000
1282.5 Gs 850 Ls 1282.5 Gs 850
0 Gg1 7.5 Lg2 142.5 Gg2 150
0 y1 0.008746356 x2 0.1 y2 0.15
0 Y1 0.008823529 X2 0.111111111 Y2 0.176470588
4 1.6
ARRIBA ABAJO
L0 4000 G1 1503.8 LN 3996.2 GN+1 1500
Ls 3996 Gs 1500 Ls 3996 Gs 1500
Lg0 4 Gg1 3.80019 LgN 0.19981 GgN+1 0
x0 0.001 y1 0.002527 xN 5E-05 yN+1 0
X0 0.001001 Y1 0.002533 XN 0.000050 YN+1 0
Chart T
EQ 5E-05
X Y X0Y1 0.001001 0.002533 0.003
0 0 XNYN+1 0.000050 0
5E-05 0.000218 2.664 -0.00013 0.0025
0.0001 0.000435 0.001001 0.002533
0.00015 0.000653 0.000582 0.002533
0.002
0.0002 0.00087 Nr 20 0.000582 0.001418
0.00025 0.001088 efic 50% 0.000326 0.001418
0.0015
0.0003 0.001305 0.000326 0.000735
0.00035 0.001523 N 10 0.000169 0.000735
0.0004 0.00174 0.000169 0.000317 0.001
0.00045 0.001958 7.29E-05 0.000317
0.0005 0.002175 7.29E-05 6.1E-05 0.0005
0.00055 0.002393 RPTA SI 1.4E-05 6.1E-05
0.0006 0.00261
0
0 0.0002 0.0004 0.00
Se desea absorber H2S en agua a 15°C. El agua que se emplea es pura. El gas alimentado tiene una fracción molar de H2S igual a 0.0012 y
contaminante con el agua. El flujo total del gas es de 10 kmol/h. El flujo total de líquido es de 2000 kmol/h. La presión total es
constantes
a. Calcular las composiciones de los gases de salida
b. Calcular el número de etapas de equilibrio
c. Si L/V = M × (L/V)min, encontrar el multiplicador M (M > 1).
d. Por qué esta operación no es práctica? ¿Qué debería hacer un ingeniero para desarrollar un proceso práctico?
T (°C) 0 5 10 15 20 25 30 35 40
H (atm) 268 315 367 423 483 545 609 676 745
T (°C) 45 50 60 70 80 90 100
H (atm) 814 884 1030 1190 1350 1440 1480
m 0.00591
0.9
x y X Y
0 0 0 0
0.9 0.005319 9 0.005348
0 0
0 0
0 0
0 0
0 0 X0Y1
XNYN+1
ARRIBA ABAJO
L0 2000 G1 9.98836 LN 2000.012 GN+1 10
Ls 2000 Gs 9.988 Ls 2000 Gs 9.988
Lg0 0 Gg1 0.00036 LgN 0.01164 GgN+1 0.012
x0 0 y1 3.6E-05 xN 5.82E-06 yN+1 0.0012
X0 0 Y1 3.6E-05 XN 0.000006 YN+1 0.001201
Two flash distillation chambers are hooked together as shown in the diagram. Both are at 1 atm
pressure. The feed to the first drum is a binary mixture of methanol and water that is 55 mol%
methanol. Feed flow rate is 10,000 kmol/h. The second flash drum operates with (V/F)2 = 0.7 and
the liquid product composition is 25 mol% methanol. Equilibrium data are given in Table 2-7.
a. What is the fraction vaporized in the first flash drum?
b. What are y1, y2, x1, T1, and T2?
x1 0 2 4 6 8 10 15 20 30
y1 0 13.4 23 30.4 36.5 41.8 51.7 57.9 66.5
T 100 96.4 93.5 91.2 89.3 87.7 84.4 81.7 78
T2
79.7
Comp z2 x2 y2
MetOH 0.5125 0.25 0.625
x2 0.25 100 H2O 0.4875 0.75 0.375
0.25 0
T2 0 79.7
1 79.7 II SEPARADOR
105
y2 0.625 100
100
0.625 0
95
90 xT
yT
85 x2
II SEPARADOR
105
100
95
z2 0.5125
90 xT
a 0.1125 yT
b 0.2625 85 x2
T2
80 y2
L/V 0.428571 Calc
75
0.428571 Dato
70
65
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Chart Title
0.003
0.0025
0.002
0.0015
0.001
0.0005
0
0 0.0002 0.0004 0.0006 0.0008 0.001 0.0012
0.005
0.004
0.003
0.002
0.001
0
0 1 2 3 4 5 6 7 8 9 10
0.002
0.001
0
0 1 2 3 4 5 6 7 8 9 10
0 3.6E-05
0.000006 0.001201
AQE
40 50 60 70 80 90 95 100
72.9 77.9 82.5 87 91.5 95.8 97.9 100
75.3 73.1 71.2 69.3 67.6 66 65 64.5
z1 0.55 100 T2
0.55 0 72.8
Comp z1 x1 y1
x1 0.5125 100 MetOH 0.55 0.5125 0.785
0.5125 0 H2O 0.45 0.4875 0.215
T1 0 72.8
1 72.8
I SEPARADOR
y1 0.785 100 105
0.785 0
100
95
xT 90
yT
x2 85
I SEPARADOR
105
100
z2 0.55 95
a 0.235
xT 90
yT
b 0.0375
x2 85
T2 L/V 6.266667
y2 80
Y 0.137615 75
70
65
60
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
8 9 10
8 9 10
I SEPARADOR
xT
yT
z1
I SEPARADOR
xT
yT
z1
x1
T1
y1
DATOS
A B C
Bz 15.9008 2788.51 -52.36
Tol 16.0137 3096.52 -53.67
P
760
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 110.6259747 1784.46236 760 2.347976789 1 0.0000
0.1 0.9 106.136844 1589.75991 667.8044545 2.091789355 0.878690072 0.2092
0.2 0.8 102.1037277 1429.100808 592.724798 1.8803958 0.77990105 0.3761
0.3 0.7 98.45794887 1294.886718 530.7628352 1.703798313 0.698372152 0.5111
0.4 0.6 95.1432433 1181.495952 479.0026988 1.554599937 0.630266709 0.6218
0.5 0.5 92.11336983 1084.713431 435.286569 1.427254514 0.572745486 0.7136
0.6 0.4 89.3301428 1001.336869 397.9946967 1.317548512 0.523677233 0.7905
0.7 0.3 86.76184944 928.9023351 365.8945515 1.222239915 0.481440199 0.8556
0.8 0.2 84.38199112 865.4909764 338.0360942 1.138803916 0.444784335 0.9110
0.9 0.1 82.168286 809.5912965 313.6781145 1.065251706 0.412734361 0.9587
1 0 80.10188524 760 292.2358044 1 0.384520795 1.0000
P
152
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 62.28258999 424.0852677 152 2.790034656 1 0.0000
0.1 0.9 58.01497056 364.7269696 128.3636338 2.399519537 0.844497591 0.2400
0.2 0.8 54.30149852 318.6637037 110.3340741 2.096471735 0.725882066 0.4193
0.3 0.7 51.03337558 282.1005516 96.24262076 1.855924681 0.633175137 0.5568
0.4 0.6 48.12813664 252.5062921 84.99580527 1.661225606 0.559182929 0.6645
0.5 0.5 45.52247455 228.1446695 75.85533053 1.500951773 0.499048227 0.7505
0.6 0.4 43.16714216 207.7939819 68.30902714 1.36706567 0.449401494 0.8202
0.7 0.3 41.02332093 190.5745071 61.99281686 1.253779652 0.407847479 0.8776
0.8 0.2 39.06002355 175.8394595 56.64216184 1.15683855 0.372645802 0.9255
0.9 0.1 37.25221882 163.1043294 52.06103556 1.073054799 0.342506813 0.9657
1 0 35.57946245 152 48.1015924 1 0.316457845 1.0000
P
7600
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 218.0177454 13989.43978 7600 1.840715761 1 0.0000
0.1 0.9 212.9955118 12997.14241 7000.31751 1.710150317 0.921094409 0.1710
0.2 0.8 208.3013759 12114.53056 6471.36736 1.594017179 0.851495705 0.3188
0.3 0.7 203.9061521 11326.5613 6002.9023 1.490337013 0.789855566 0.4471
0.4 0.6 199.7833152 10620.49622 5586.335852 1.397433713 0.735044191 0.5590
0.5 0.5 195.9088675 9985.538389 5214.461611 1.31388663 0.68611337 0.6569
0.6 0.4 192.2611641 9412.521427 4881.21786 1.238489661 0.642265508 0.7431
0.7 0.3 188.8207186 8893.64633 4581.491896 1.170216622 0.602827881 0.8192
0.8 0.2 185.5700049 8422.260429 4310.958283 1.108192162 0.567231353 0.8866
0.9 0.1 182.4932644 7992.672712 4065.945588 1.051667462 0.534992841 0.9465
1 0 179.576324 7599.999963 3843.326758 1 0.505700889 1.0000
Se dispone de 200 kmol/h de una mezcla de 45% de benceno y el resto tolueno, que se introduce a un separador flash a 1 atm
se desea obtener una corriente de vapor de 60%. Considerese sistema ideal
a.- Determine la temperatura de operación
b.- Realice el balance en el separador
DATOS
F 200 xy 0.322 0
zi 0.45 0.322 0.537
Y 0.6 0 0.537
Diagrama xy
F 200 BALANCE z x y
V 120 1 0.45 0.322 0.537
L 80 2 0.55 0.678 0.463
m=-L/V -0.66666667
BALANCE F L V
z 0.45 0.45 1 90 25.76 64.44
0.45 0 2 110 54.24 55.56
200 80 120
xy 0 0.75
z 0.45 0.45
Diagrama Txy
(L/V) 0.666666667
z 0.45 110
0.45 0
T 0 97.7
1 97.7
xy 0.322 0
0.322 97.7
0.536 97.7
0.536 0
L/V 0.671875
METODP ANALITICO
P Y T
760 0.6 97.73977856
Comp zi Ki f() x y F L
Bz 0.45 1.670572905 -0.21518106 0.3209 0.5361 90.00 25.67
Tol 0.55 0.683141923 0.215181056 0.6791 0.4639 110.00 54.33
2.83107E-09 1 1 200 80
Determinar la fraccion vaporizada, las composiciones de las corrientes y sus flujos, de la mezcla anterior, si la temperatura de
Txy
z 0.45
T 0 96
1 96
x 0.374 0 BALANCE z x y
0.374 96 1 0.45 0.374 0.595
2 0.55 0.626 0.405
y 0.595 0
0.595 96 BALANCE F L V
1 90 49.08 40.92
L/V 1.907894737 2 110 82.14 27.86
200 131.22 68.78
F/V 2.907894737
F 200
V 68.77828054
L 131.2217195
ANALITICO
P Y T
760 0.347205584 96
Comp zi Ki f() x y F L
Bz 0.45 1.592155589 -0.22102694 0.3733 0.5943 90.00 48.73
Tol 0.55 0.647339715 0.221026937 0.6267 0.4057 110.00 81.83
2.14374E-05 1 1 200 130.56
Determinar la temperatura y la fracción vaporizada, si se desea tener una composición de 0.55 de Benceno en la fase vapor
P Y T
760 0.539730786 97.33479371
98
Comp zi Ki f() x y F L
Bz 0.45 1.652058443 -0.21704156 0.3329 0.5499 90.00 30.64 f(x) = 6
97.5 R² = 0.9
Tol 0.55 0.674670602 0.21704156 0.6671 0.4501 110.00 61.41
1.79665E-05 1 1 200 92.05
97
96.5
96
95.5
95
0.3 0.35
We are feeding 100 kmol/h of a 45 mol% propane, 55 mol% n-pentane feed to a flash distillation
system. We measure the outlet vapor and liquid mole fractions leaving the flash drum, which is an
equilibrium stage, and obtain, ypropane = 0.8, xpropane = 0.2162.
Find: (a) L and V. (b) xpentane and ypentane. (c) Tdrum and pdrum. P 160
Use the DePriester charts. Note: This is not trial and error. T 10
Comp zi xi yi F L V
C3 0.45 0.2162 0.8 45 12.9616307 32.0383693
nC5 0.55 0.7838 0.2 55 46.99040767 8.009592326
100 59.95203837 40.04796163
Y
0.400479616 10
50
T P Y 509.67
505 21.5105073 0.396880093
Comp z K f x y
C3 0.45 3.700255755 -0.58653673 0.217215249 0.803751976
nC4 0.55 0.250704966 0.586536726
-4.8108E-06
We have a flash drum separating 50 kmol/h of a mixture of ethane, isobutane, and n-butane. The
ratio of isobutane to n-butane is held constant at 0.8 (that is, ziC4/znC4 = 0.8). The mole fractions of
all three components in the feed can change. The flash drum operates at a pressure of 100 kPa and
a temperature of 20°C. If the drum is operating at V/F = 0.4, what must the mole fractions of all
three components in the feed be? Use Figure 2-11 or 2-12 or Eq. (2-30).
three components in the feed be? Use Figure 2-11 or 2-12 or Eq. (2-30).
20 1000
68
T+P2A204:R22P Y
527.67 145.0382433 0.4
Comp z K f
C2 0.489297658 2.804997396 -0.51288126
iC4 0.22697891 0.348722246 0.199903359
nC4 0.283723637 0.234613411 0.312977903
1.000000204 0
0.8
ziC4/znC4 0.8
Compuesto A B C
BENZENE 15.9008 2788.51 -52.36
TOLUENE 16.0137 3096.52 -53.67
110 0.8
0.8 0.8
y2 Sy a12 y1*
0.7 0.7 0.7
1 1 2.35 0.0000
100
0.790821064 1 2.38 0.2164 0.6
0.6 0.6
0.62392084 1 2.41 0.3832
0.488860506 1 2.44 0.5157 90 0.5 0.5 0.5
0.378160025 1 2.47 0.6236
0.286372743 1 2.49 0.7131 0.4 0.4 0.4
1 1 1.84 0.0000
0.828984968 1 1.86 0.1753
0.681196564 1 1.87 0.3235 Chart Title
0.552898896 1 1.89 0.4505 50
1.0
0.441026515 1 1.90 0.5605
0.343056685 1 1.91 0.6567 0.9
0.256906203 1 1.93 0.7415 Chart Title
0.8
0.180848364 1 1.94 0.8169 3.50
0.113446271 1 1.95 0.8844 0.7 0
3.00 0 0.2 0.4 0.6
0.053499284 1 1.97 0.9451 0.6
2.50
0 1 1.98 1.0000 Column C Column C
11 1.91 2.00 0.5 Column C P=7600
1.50 0.4
1.00 0.3
0.50 0.2
separador flash a 1 atm de presión 0.00 0.1
0 2 4 6 8
0.0
0 0.1 0.2Column0.3
K Column 0.5
0.4 K Col
0.6
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
120
110
120
110
100
90
80
70
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
V
64.33
55.67
120
99
98
97
96
95
94
93
92
91
90
0.3 0.35 0.4 0.45 0.5 0.55 0.6
92
91
90
0.3 0.35 0.4 0.45 0.5 0.55 0.6
V
41.27
28.17
69.44
96
95.5
Chart Title
95 0.62
0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65
0.6
f(x) = − 0.230349903322963 x + 0.674267765678312
0.58 R² = 0.999999224828584
0.56
0.54
0.52
0.5
0.3 0.35 0.4 0.45 0.5 0.55 0.6
kPa
°C
Ki
3.700277521
0.255167134
1.0 3.0
0.9
2.5
0.8
0.7
2.0
0.6
0.5 1.5
0.4
1.0
0.3
0.2
0.5
0.1
0.0 0.0
0.20
0.40.3 0.1 0.60.5
0.3
0.50.4 0.2
0
0.4 0.1
0.3 0.80.7
0.5
0.70.6 0.2
0.4 0.9 0.8
0.6 0.3
0.5
0.7 0.4
0.6
0.8
1 0.9 0.5
0.7
10.9 0.6
10.8 0.7
0.9 0.8
1 0.9 1
Chart Title
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0.2 0.5
0.1 0.4 00.3 0.6 0.4 0.7
0.2 0.50.1 0.5 0.8
0.30.60.2 0.6 0.9
0.4 0.70.3 0.5 0.80.4 1 0.90.5
0.7 0.6 0.8 0.7 1 0.6
0.9 0.8 0.71 0.9 0.8 1 0.9 1
1.0
0.5
0.0
0.2 0.5
0.1 0.4 00.3 0.6 0.4 0.7
0.2 0.50.1 0.5 0.8
0.30.60.2 0.6 0.9
0.4 0.70.3 0.5 0.80.4 1 0.90.5
0.7 0.6 0.8 0.7 1 0.6
0.9 0.8 0.71 0.9 0.8 1 0.9 1
Chart Title
Chart Title
6 8 10 12
Column 0.5
0.4 K Column K0.7
0.6 0.8 0.9 1
0.6
0.6
8312
0
6.90224
0
0
0
Una mezcla ideal, benceno tolueno que tiene una composición de 45% de benceno, se alimenta a una columna de destilación
200 mol/h, si se desea obtener un destilado con 97% de benceno y unos fondos con 2.5% máximo de benceno, si la alimentac
en su punto de burbuja y la volatilidad es de 2.5. Calcular
a.- Balances externos CURVA alfa 2.5
b.- Ubicar xD, z, xB x y
c.- Nmin 0 0
d.- Rmin 0.1 0.217391304
e.- R si R/Rmin=1.4 0.2 0.384615385
f.- Balances Internos 0.3 0.517241379
g.- Lineas de operación 0.4 0.625
h.- N 0.5 0.714285714
i.- Nf 0.6 0.789473684
0.7 0.853658537
0.8 0.909090909
0.9 0.957446809
1 1
BALANCE
Comp z xD xB F D B
Bz 0.36 0.85 0.25 36.00 15.58 20.42
Tol 0.64 0.15 0.75 64.00 2.75 61.25
100 18.33 81.67
xD 0.85 0
0.85 0.85
z 0.36 0
0.36 0.36
xB 0.25 0
0.25 0.25
Nmin
0.85 0.85
0.693877551 0.85
0.693877551 0.693877551 1
0.475524476 0.693877551
0.475524476 0.475524476 1
0.266144814 0.475524476
0.266144814 0.266144814 1
0.126688402 0.266144814
0.126688402 0.126688402 1
0.054844238 0.126688402
0.054844238 0.054844238 1
0.022684152 0.054844238
0.022684152 0.022684152 1
0.009198862 0.022684152
0.009198862 0.009198862 1
0.003699966 0.009198862
0.003699966 0.003699966 1
Rmin
LOF 0.36 0.36
0.36 1
LORmin 1
Rmin xD 0.9
b m 0.7
LOR 0.5
R 1.96 0.2
0.1
0
F D B q R 0 0.1 0.2 0.3
BALANCES INTERNOS
Ln Vn Lm Vm Vn
35.93 54.27 135.93 54.27 54.26666667
LINEAS DE OPERACIÓN
z xD xB
0.36 0.85 0.25 LOR 0.85
0
mLOR bLOR
0.662162162 0.287162162 LOS 0.25
alfa 0.36
mLOS bLOS
2.504914005 -0.3762285 2.5
N 15
0.85 0.85 Nf
0.693877551 0.85 7
0.693877551 0.746621622 1
0.541003672 0.746621622
0.541003672 0.645394323 1
0.421300826 0.645394323
0.421300826 0.566131628 1
0.342943271 0.566131628
0.342943271 0.51424622 1
0.297487618 0.51424622
0.297487618 0.484147206 1
0.272946717 0.484147206
0.272946717 0.46789715 1
0.260209681 0.46789715
0.260209681 0.275574373 1
0.132066182 0.275574373
0.132066182 -0.04541407 1
-0.01768377 -0.04541407
-0.01768377 -0.42052483 1
-0.1343192 -0.42052483
-0.1343192 -0.71268654 1
-0.19968635 -0.71268654
-0.19968635 -0.87642564 1
-0.22975326 -0.87642564
-0.22975326 -0.95174067 1
-0.2423205 -0.95174067
-0.2423205 -0.98322052 1
-0.2473616 -0.98322052
-0.2473616 -0.99584805 1
-0.24935025 -0.99584805
-0.24935025 -1.00082942 1
D7.*
a. A distillation column with a total condenser is separating acetone from ethanol. A distillate
concentration of xD = 0.90 mole fraction acetone is desired. Since CMO is valid, L/V =
constant. If L/V is equal to 0.8, find the composition of the liquid leaving the fifth stage below
the total condenser.
b. A distillation column separating acetone and ethanol has a partial reboiler that acts as an
equilibrium contact. If the bottoms composition is xB = 0.13 mole fraction acetone and the
boilup ratio /B = 1.0, find the vapor composition leaving the second stage above the partial
reboiler.
c. The distillation column in parts a and b is separating acetone from ethanol and has xD = 0.9, xB
= 0.13, L/V = 0.8, and /B = 1.0. If the feed composition is z = 0.3 (all concentrations are mole
fraction of more volatile component), find the optimum feed plate location, total number of
stages, and required q value of the feed. Equilibrium data for acetone and ethanol at 1 atm
(Perry et al., 1963, pp. 13–4) are
x y
0 0
0.1 0.262
0.15 0.348
0.2 0.417
0.25 0.478
0.3 0.524
0.35 0.566
0.4 0.605
0.5 0.674
0.6 0.739
0.7 0.802
0.8 0.865
0.9 0.929
1 1
a. A distillation column with a total condenser is separating acetone from ethanol. A distillate
concentration of xD = 0.90 mole fraction acetone is desired. Since CMO is valid, L/V =
constant. If L/V is equal to 0.8, find the composition of the liquid leaving the fifth stage below
the total condenser.
1
Ln/Vn 0.8 N
xD 0.9 0.9 0.9 0.9
0.2
0.1
0
0.5
0.4
0.3
0
0 0.1
LOR 0.9 0.9
0 0.18
b. A distillation column separating acetone and ethanol has a partial reboiler that acts as an
equilibrium contact. If the bottoms composition is xB = 0.13 mole fraction acetone and the
boilup ratio Vm /B = 1.0, find the vapor composition leaving the second stage above the partial
reboiler. 1
xB 0.13
0.9
Vm/B 1 N
B 100 0.13 0.13 0.8
Vm 100 0.13 0.32
0.7
Lm 200 0.225 0.32 1
0.225 0.45 0.6
xB 0.13 0 0.29 0.45 1
0.5
0.13 0.13
0.4
0.3
c. The distillation column in parts a and b is separating acetone from ethanol and has xD = 0.9, xB=0.13
Ln/Vn = 0.8, and Vm/B = 1.0. If the feed composition is z = 0.3 (all concentrations are mole
fraction of more volatile component), find the optimum feed plate location, total number of
stages, and required q value of the feed. Equilibrium data for acetone and ethanol at 1 atm
(Perry et al., 1963, pp. 13–4) are
mLOF bLOF
xD 0.9 0 -2.08 0.924
0.9 0.9
q 0.675324675
z 0.3 0
0.3 0.3 N
0.9 0.9
xB 0.13 0 0.855 0.9
0.13 0.13 0.855 0.864 1
0.8 0.864
mLOR bLOR 0.8 0.82 1
0.8 0.18 0.73 0.82
mLOS bLOS 0.73 0.764 1
2 -0.13 0.64 0.764
0.64 0.692 1
interseccion 0.53 0.692
0.258333333 0.386666667 0.53 0.604 1
0.4 0.604
LOR 0.9 0.9 0.4 0.5 1
0.258333333 0.386666667 0.273 0.5
0.273 0.3984 1
LOS 0.13 0.13 0.184 0.3984
0.258333333 0.386666667 0.184 0.238 1 nNf
0.088 0.238
LOF 0.3 0.3 0.088 0.046 1
0.258333333 0.386666667
9N
D8.* For Problem 4.D7c for separation of acetone from ethanol, determine:
a. How many stages are required at total reflux?
b. What is (L/V)min? What is (L/D)min? 1
c. The L/D used is how much larger than (L/D)min?
d. If EMV = 0.75, how many real stages are required for L/V = 0.8? 0.9
0.8
Nmin
0.9 0.9 0.7
0.855 0.9 0.6
0.855 0.855 1
0.785 0.855 0.5
0.268 0.268 1 0
0.103 0.268 0 0.1 0.2 0.3 0.4
0.103 0.103 1
1
(L/D)min 0.9
0.8
mLOF bLOF LOF 0.3 0.3
0.7
-2.08 0.924 0 0.924
0.6
xD 0.9 LORmin 0.9 0.9
0.5
0 0.290322581
Rmin 2.1 0.4
0.3
0.2
0.6
0.5
0.4
0.3
LORmin mLORmin bLORmin
0.677419355 0.290322581 0.2
0.1
(L/D)min (V/D)min
2.1 3.1 0
0 0.1 0.2 0.3 0.4 0.
d. If EMV = 0.75, how many real stages are required for L/V = 0.8?
y *n yn 1 0.75
N
0.9 0.9 0.9 0.891
0.855 0.9 0.855 0.891
0.855 0.864 1 0.855 0.853
0.8 0.864 0.8 0.853
0.8 0.82 1 0.8 0.806
0.73 0.82 0.73 0.806
0.73 0.764 1 0.73 0.746
0.64 0.764 0.64 0.746
0.64 0.692 1 0.64 0.67
0.53 0.692 0.53 0.67
0.53 0.604 1 0.53 0.578
0.4 0.604 0.4 0.578
0.4 0.5 1 0.4 0.4746
0.273 0.5 0.273 0.4746
0.273 0.3984 1 0.273 0.3583
0.184 0.3984 0.184 0.3583
0.184 0.238 1 nNf 0.184 0.19
0.088 0.238 0.088 0.19
0.088 0.046 1 0.088 0.0345
9N
12
D10.* A distillation column is separating phenol from p-cresol at 1 atm pressure. The distillate
composition desired is 0.96 mole fraction phenol. An external reflux ratio of L/D = 4 is used, and
the reflux is returned to the column as a saturated liquid. The equilibrium data can be represented
by a constant relative volatility, αphenol−cresol = 1.76 (Perry et al., 1963, pp. 13–3). CMO can be
assumed.
a. What is the vapor composition leaving the third equilibrium stage below the total condenser?
Solve this by an analytical stage-by-stage calculation alternating between the operating equation
and the equilibrium equation.
b. What is the liquid composition leaving the sixth equilibrium stage below the total condenser?
Solve this problem graphically using a McCabe-Thiele diagram plotted for αp−c = 1.76.
alfa 1.76
x y N
0 0 0.96 0.96
0.1 0.163568773 0.931677019 0.96
0.2 0.305555556 0.931677019 0.937341615 1
0.3 0.429967427 0.894734046 0.937341615
0.4 0.539877301 0.894734046 0.907787237 1
0.5 0.637681159 0.848334512 0.907787237
0.6 0.725274725 0.848334512 0.87066761 1
0.7 0.804177546 0.792746484 0.87066761
0.8 0.875621891 0.792746484 0.826197187 1
0.9 0.940617577 0.72979806 0.826197187
1 1 0.72979806 0.775838448 1
0.66290424 0.775838448
xD 0.96 0.66290424 0.722323392 1
R 4
mLOR bLOR
0.8 0.192
xD 0.96 0.96
0.96 0
D9. A distillation column with two feeds is separating ethanol (E) and water at a pressure of 1.0 atm.
The column has a total condenser with saturated liquid reflux and a partial reboiler. Feed 1 is a
saturated liquid and is 42 mol% ethanol. Feed 2 flow rate is F2 = 100 kmol/h. Feed 2 is 18 mol%
ethanol and is a two-phase mixture that is 30% vapor. The external reflux ratio is L/D = 1/2, and
the distillate flow rate is D = 80 kmol/h. We desire a distillate mole fraction of xD = 0.66 mole
fraction ethanol and a bottoms that is xB = 0.04 mole fraction ethanol. You can assume that CMO
is valid. Equilibrium data are in Table 2-1.
a. Find the flow rates F1 and B.
b. Find the liquid and vapor flow rates in the middle section, L′ and V′.
c. Determine and plot the operating lines. Be neat.
d. Find both optimum feed locations (above partial reboiler) and the total number of equilibrium
stages needed. Step off stages from the bottom up. Be neat.
x y
0 0
0.019 0.17
0.0721 0.3891
0.0966 0.4375
0.1238 0.4704
0.1661 0.5089
0.2337 0.5445
0.2608 0.558
0.3273 0.5826
0.3965 0.6122
0.5198 0.6599
0.5732 0.6841
0.6765 0.7385
0.7472 0.7815
0.8943 0.8943
1 1
BALANCES EXTERNOS
F1 F2 D B z1 z2 xD
93.68 100 80 113.68 0.42 0.18 0.66
BALANCES INTERNOS
F1 F2 D B R q1 q2
93.68 100.00 80.00 113.68 0.5 1 0.7
Ln Vn Li Vi Lm Vm
40 120.00 133.6842105 120 203.6842105 90.00
LOI
N
0.04 0.04
0.04 0.268
0.139937008 0.268 1
0.139937008 0.486
0.335622047 0.486 1
0.335622047 0.583
0.429 0.583 1
0.429 0.624
0.552 0.624 1
0.552 0.672
0.672 0.672 1
D11. A mixture of methanol and water is being separated in a distillation column with open steam. The
feed is 100.0 kmol/h. Feed is 60.0 mol% methanol and is at 40°C. The column is at 1.0 atm. The
steam is pure steam (yM = 0) and is a saturated vapor. The distillate product is 99.0 mol%
methanol and leaves as a saturated liquid. The bottoms is 2.0 mol% methanol and since it leaves
an equilibrium stage must be a saturated liquid. The column is adiabatic. The column has a total
condenser. External reflux ratio is L/D = 2.3. Assume CMO is valid. Equilibrium data are in
Table 2-7. Data for water and methanol are available in Problem 3.E1.
a. Estimate q.
b. Find optimum feed stage and total number of equilibrium stages (step off stages from top down). Use a McCabe-Thiele di
c. Find (L/D)min. Use a McCabe-Thiele diagram.
MetOH-W
x y F 100 yS 0
0 0 z 0.6 xD 0.99
0.02 0.134 P 1 atm xB 0.02
0.04 0.23 TF 40 °C
0.06 0.304
0.08 0.365 L/D 2.3
0.1 0.418
0.15 0.517 S 50
0.2 0.579
0.3 0.665 F S D B
0.4 0.729 MetOH 60 0 58.18 1.82
0.5 0.779 W 40 50 0.59 89.41
0.6 0.825 100 50 58.76 91.24
0.7 0.87
0.8 0.915 F S D B
0.9 0.958 100 50 58.7628866 91.2371134
0.95 0.979 Ln Vn Lm Vm
1 1 135.1546392 193.9175258 91.24 50
xD 0.99 0.99
0.99 0
N 10 Nf
0.99 0.99 8
0.975 0.99
0.975 0.979545455 1 1
0.951 0.979545455
0.951 0.962818182 1 0.9
0.911 0.962818182
0.8
0.911 0.934939394 1
0.845 0.934939394 0.7
0.845 0.888939394 1
0.743 0.888939394 0.6
0.743 0.817848485 1
0.582 0.817848485 0.5
0.582 0.705636364 1
0.4
0.36 0.705636364
0.36 0.550909091 1 0.3
0.172 0.550909091
0.172 0.277360825 1 0.2
0.05 0.277360825
0.05 0.054742268 1 0.1
0.01 0.054742268
0
0.01 0 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Rmin
1
mLOF bLOF
0.305157593 0.416905444 0.9
0.8
LOF 0.6 0.6
0 0.416905444
0.7
Rmin 0.6
0.5
0.4
0.7
0.6
1.65
LORmin 0.5
0.99 0.99
0.4
0 0.373584906
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
D26. A distillation column with a partial condenser and a total reboiler is separating acetone and
ethanol. There are two feeds. One feed is 50.0 mol% acetone, flows at 100.0 mol/min, and is a
superheated vapor where approximately 1 mole of liquid will vaporize on the feed stage for each
20 moles of feed. The other feed is a saturated liquid, flows at 150.0 mol/min and is 35.0 mol%
acetone. We desire a distillate product that is yD = 0.85 mole fraction acetone and a bottoms
product that is xB = 0.10 mole fraction acetone. The column has a partial condenser and a total
reboiler. Boilup is returned as a saturated vapor. Column operates at a pressure of 1.0 atm.
Assume CMO and use a McCabe-Thiele diagram. VLE data are given in Problem 4.D7.
a. Find ( Vm/B)min. (Plot both feed lines to decide which one to use.)
b. Operate at Vm/B = 3 × ( Vm/B)min. The partial condenser is an equilibrium contact. If the stages
each have a Murphree liquid efficiency of 0.75, find optimum feed locations for each feed and
total number of real stages. (It is easiest to start at top and step down.)
columna de destilación a una razón de
benceno, si la alimentación se encuentra
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2
Chart Title
1
Chart Title
1
0.9
0.8
0.7
0.6
Chart Title
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6
Rb
0.664489796 0.5
0
.4 .3 .2 .1 16 0.
1
0.
2
0.
3
0.
4
0.85 -0 -0 -0 -0 E-
6
0.287162162 51
462
02 -0.5
223
0.25 10
.1
-1
0.525540541
-1
-1.5
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
0.8
0.7
0.6
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
Analitico Ki
0.1 0.262 2.62
0.15 0.348 2.32 0.8
0.7
0.9
0.8
0.2 0.417 2.085
0.25 0.478 1.912
0.3 0.524 1.746666667
0.7
0.35 0.566 1.617142857
0.4 0.605 1.5125
0.5 0.674 1.348
0.6 0.739 1.231666667 0.6
0.7 0.802 1.145714286
0.8 0.865 1.08125
0.9 0.929 1.032222222 0.5
1.637680225
L/V 0.8
0.4
EMV V/L 1.25
0.75 S 2.047100281
0.3
Eo 0.809018613
Nreal 11.12458953
0.2
0.1
0
0 0.1 0.2 0.3 0.4
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
xB
0.04
0.9
0.8
0.7
0.6
0.66 0.66
0.42 0.58 0.5
0.42 0.58
0.3
0.141526718 0.269770992
0.42 0.58
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
z yS xD xB
0.6 0 0.99 0.02 0.1
0.4 1 0.01 0.98 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
R q
2.3 -0.43917526
0.6 0.6
0.298371191 0.507955679
0.99 0.99
0 0.3
0.02 0
0.298371191 0.507955679
N
xy
x=y
xD z xB
LOF LOR LOS
xy
x=y
xD z xB
LOF
LORmin
xy
x=y
xD z xB
LOF
LORmin
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Chart Title
Chart Title
Chart Title
1 2 3 4 5 6 7 8 9 1
0. 0. 0. 0. 0. 0. 0. 0. 0.
8 0.9 1
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9 1
0.9 1
0.9
0.8
0.7
0.6
0.5
xy 0.4
x=y
0.3
0.2
0.1
0.9
0.8
0.7
0.6
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
1
N
xy
x=y
xD z xB
LOF LOR LOS
0.8 0.9 1
xy
x=y
xD z xB
LOF LOR LOS
z xD xB F D B
Ace 0.3 0.9 0.1 300 225.00 75.00
EtOH 0.7 0.1 0.9 700 25.00 675.00
1000 250.00 750.00
Lm/Vm 1.169590643
F D B z xD xB
54.5 47.86874632 6.631253679 0.545 0.835 0.1554
45.5 9.459093584 36.04090642 0.455 0.165 0.8446
100 57.32783991 42.67216009
F 204 Comp z xD xB F
z 0.6 Bz 0.6 0.95 0.05 122.40
xD 0.95 Tol 0.4 0.05 0.95 81.60
xB 0.05 204
Nmin 6.43
1.00
0.90
0.80
0.70
1.00
0.95 0.95 0.90
0.88372093 0.95
0.80
0.88372093 0.88372093
0.752475248 0.88372093 0.70
0.752475248 0.752475248 0.60
0.548736462 0.752475248 0.50
0.548736462 0.548736462
0.40
0.548736462 0.548736462
0.327233584 0.548736462 0.30
0.327233584 0.327233584 0.20
0.327233584 0.327233584
0.10
0.162871685 0.327233584
0.162871685 0.162871685 0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.072204738 0.162871685
0.072204738 0.072204738
0.030189803 0.072204738
0.030189803 0.030189803
Rmin
0.20
0.00
R 1.69 0 0.1 0.2
F D B R q Ln
204 124.6666667 79.33333333 1.69 0.388888889 210.6866667
LOR LOS
0.95 0.497113843 0.05 0.497113843
0.95 0.665473009 0.05 0.665473009
N
0.95 0.95
0.88372093 0.95
0.88372093 0.90835999 1
0.798586304 0.90835999
0.798586304 0.854873923 1
0.702046124 0.854873923 y3 0.854873923
0.702046124 0.794222286 1
0.606894303 0.794222286
0.606894303 0.734442889 1
0.525226458 0.734442889
0.525226458 0.683134838 1
0.463048792 0.683134838
0.463048792 0.618580881 1
0.393467081 0.618580881
0.393467081 0.522798418 1
0.304696174 0.522798418
0.304696174 0.400601135 1
0.210942812 0.400601135 y3 0.400601135
0.210942812 0.271545269 1
0.129759446 0.271545269
0.129759446 0.159792588 1
0.070694953 0.159792588
0.070694953 0.078487566 1
0.032946564 0.078487566
0.032946564 0.026525151 1
N 12
Nr 18
1
0.9
0.8
0.7
0.6
0.5
0.4
1
0.3
0.9
0.2
0.8
0.7 0.1
0
0.6 0 0.1 0.2
0.5
LOF 0.3 0.46 0.4
0.3 0.3
0.3
0.2
Li1 Ln
Vi1 Vn 0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
x1 y1 x2 y2
0 0 1 1
0.1 0.314 0.9 0.686
0.2 0.508 0.8 0.492
0.3 0.64 0.7 0.36
0.4 0.734 0.6 0.266
0.5 0.806 0.5 0.194
0.6 0.862 0.4 0.138
0.7 0.905 0.3 0.095
0.8 0.943 0.2 0.057
1 1 0 0
1
0.9
0.8
F 76.7723704 N 0.7
0
LOR 0 0.4175 0 0.1
0.835 0.835
D B
118.43 3.97
6.23 75.37
124.67 79.33
1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
.7 0.8 0.9 1
.00
.90
.80
.70
.60
.50
.40
.30
.20
.10
.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Vn Lm Vm
335.3533333 290.02 210.6866667
bLOF 1.00
0.90
0.80
1.00
0.981818182
0.90
0.80
0.497113843
0.665473009 0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1
.9
.8
.7
.6
.5
.4
.3
.2
.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
K1 K2
#DIV/0! 1 0
3.14 0.762222222 4.119533528 0.314771396
2.54 0.615 4.130081301 0.508255339
2.133333333 0.514285714 4.148148148 0.639229346
1.835 0.443333333 4.139097744 0.733773629
1.612 0.388 4.154639175 0.80523159
1.436666667 0.345 4.164251208 0.861139159
1.292857143 0.316666667 4.082706767 0.906074241
1.17875 0.285 4.135964912 0.942978392
1 #DIV/0! 1
4.134302848
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.8 0.9 1
1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
A B C Tb
METHANOL 18.5875 3626.55 -34.29 337.8
WATER 18.3036 3816.44 -46.13 373.2
x y T x1 x2 T Psat1
0 0 100 0 1 100 3.497240278
0.02 0.134 96.4 0.02 0.98 96.4 3.117572209
0.04 0.23 93.5 0.04 0.96 93.5 2.836780983
0.06 0.304 91.2 0.06 0.94 91.2 2.629079666
0.08 0.365 89.3 0.08 0.92 89.3 2.467036174
0.1 0.418 87.7 0.1 0.9 87.7 2.337008446
0.15 0.517 84.4 0.15 0.85 84.4 2.08653147
0.2 0.579 81.7 0.2 0.8 81.7 1.898398936
0.3 0.665 78 0.3 0.7 78 1.663470447
0.4 0.729 75.3 0.4 0.6 75.3 1.507633772
0.5 0.779 73.1 0.5 0.5 73.1 1.389763354
0.6 0.825 71.2 0.6 0.4 71.2 1.294205478
0.7 0.87 69.3 0.7 0.3 69.3 1.204159766
0.8 0.915 67.6 0.8 0.2 67.6 1.128060936
0.9 0.958 66 0.9 0.1 66 1.060131902
0.95 0.979 65 0.95 0.05 65 1.019430792
1 1 64.5 1 0 64.5 0.999573272
Mezcla Methanol + Water
A12 A21
#N/A #N/A
Psat2 g1 g2 K1 K2 y1 y2 Sy
0.999925016
0.878114611
0.789192889
0.72411506
0.673786248
0.633699729
0.557284399
0.500644563
0.430927248
0.385366396
0.351305681
0.323966123
0.298443968
0.27706881
0.258148086
0.246887308
0.241414781
DATA
NUMBER COMPONENT MOLE WT FREEZE BOILING
POINT POINT
K K
(TFP) (TB)
0 1 2 3 4
A21
1396.6398
-506.8519
545.2942
1482.2133
-345.07
113.562
374.78
1689.3
-550.89
59.6233
1694.0241
1902.66
-212.107
266.6118
953.2792
570.0349
2084
2738.13
227.2126
-172.9317
520.6458
176.318
42.5767
307.37
847.4348
-40.9238
269.707
1966.7
2189.2896
1844.7926
-180.84
2050.2569
1180.804
3708.3
-1341.7
1143.85
1874.96
VAPOR HEAT CAPACITY LIQUID VISCOSITY STD HEAT STD ENERGY
CP=A+(B*T)+(C*T^2)+(D*T^3) LOG(V)=B*(1/T-1/C) FORM FORM
CAL/G-MOLE-K T AS K AND V AS CP KCAL/G-MOLE KCAL/G-MOLE
(A) (B) (C) (D) B C DELHG DELGF
13 14 15 16 17 18 19 20
1.790 4580
4.950 0
0.000 7960
0.000 7790
0.000 7570
0.000 0
3.170 6860
1.870 5100
0.000 0
0.000 0
0.000 7240
3.910 6570
0.000 9490
0.000 9180
0.000 9570
8.800 10880
7.270 9380
0.000 5800
3.020 5560
3.300 7650
0.000 7500
0.000 7510
0.000 6590
0.000 12940
7.220 9330
0.000 5370
0.000 13500
0.000 8690
0.000 9410
0.000 6010
0.000 6561
2.460 5238
0.000 5970
0.000 0
0.000 7170
0.000 12000
9.900 9240
13.100 10270
0.000 15600
0.000 11500
5.700 7430
105.900 -13117
0.000 11600
4.540 6760
0.000 8040
7.180 9290
0.000 0
8.390 9110
-6.815 7.2
7.230 9180
8.410 0
0.000 11000
8.380 8680
0.000 0
0.000 12970
0.000 12100
6.980 8070
98.920 -12205.3
0.000 10600
3.420 6022
0.000 0
3.130 9980
92.474 -11329.2
0.000 6460
88.010 -10609.4
11.460 9770
4.323 6287
6.540 7650
0.000 8690
8.460 8430
0.000 8190
5.370 6919
0.000 8310
6.480 7411
0.000 7850
0.000 8130
0.000 8430
0.000 8070
3.310 5438
0.000 10300
6.720 7710
5.490 6970
4.472 6520
6.560 7730
0.000 8350
0.000 6900
6.610 7823
0.000 6550
0.000 7083
6.790 7936
5.580 7263
0.000 0
0.000 11300
6.740 7790
0.000 7050
0.000 11260
6.840 7800
0.000 0
0.000 11200
0.000 10600
0.000 9750
0.000 6370
0.000 6980
0.000 11300
3.550 5900
4.911 6640
0.000 6230
0.000 10800
3.470 6094
3.710 6287
0.000 6930
0.000 7879
7.120 8080
5.790 7330
0.000 11000
0.000 10600
0.000 8760
0.000 8600
0.000 6130
6.690 7760
5.490 7086
6.760 7953
0.000 0
0.000 11900
0.000 0
0.000 11800
0.000 8033
0.000 7399
4.579 6710
0.000 6510
0.000 10540
0.000 5760
0.000 9700
0.000 7838
0.000 6890
7.020 8100
5.720 7360
0.000 7000
0.000 8950
0.000 6590
6.980 8100
0.000 6680
0.000 6150
3.440 5660
0.000 9850
0.000 6960
3.490 7500
0.000 6850
0.863 4050
0.000 6770
0.000 11000
0.000 7800
0.000 9550
0.000 6475
0.000 8200
0.000 9150
0.820 5580
5.180 10000
0.000 0
0.264 1560
0.000 10200
3.610 7352
0.000 12100
6.530 0
0.000 12070
2.970 0
1.200 6140
0.000 7210
5.590 0
0.000 11700
0.000 8900
5.030 8220
0.000 7900
0.000 7900
0.000 0
0.703 4100
2.210 6390
0.284 1444
3.820 7170
0.000 2860
1.300 0
1.270 4880
4.980 8735
1.530 4826
2.960 7100
2.250 4650
1.300 3706
6.200 7790
0.000 7576
0.000 7840
6.290 8070
2.580 5580
0.000 6960
3.510 6240
0.000 6860
0.000 9400
1.510 0
0.000 5780
0.000 7900
4.220 7160
5.860 10870
0.000 9500
0.000 7280
0.000 6524
0.000 8740
0.000 6450
0.000 4790
0.000 292
0.000 9880
0.000 0
0.000 9500
0.000 0
0.000 4772
2.410 6690
2.220 5960
2.030 6330
3.730 6650
0.000 9010
4.730 8060
0.000 7590
0.000 13670
0.000 10900
0.000 7010
1.710 5140
0.000 0
0.000 6440
0.000 10900
0.000 11260
0.000 0
0.000 8840
0.000 0
1.073 3515
2.350 9260
4.010 7700
0.000 7950
2.080 6700
0.000 10700
2.290 6330
0.000 7600
0.000 8200
2.260 5900
3.400 6380
0.000 0
3.070 7200
5.660 8365
2.550 6400
4.980 8180
4.330 7290
5.750 8500
0.000 8200
0.000 7715
0.881 3237
0.000 12550
0.000 7660
0.000 6120
0.000 10000
0.210 1560
3.880 0
3.410 5500
0.000 5240
0.000 6474
0.000 14600
0.007 22
0.000 14500
1.630 10700
0.048 216
0.871 4220
0.717 3860
2.180 6027
1.840 1600
1.230 4724
0.871 4460
0.000 10000
6.460 9440
2.570 5090
0.000 10050
0.000 8568
0.000 7400
4.410 8170
0.000 9040
0.000 0
2.460 5286
0.000 7500
5.150 9830
0.000 9520
0.000 6500
0.000 6280
6.860 8970
0.000 0
0.000 8150
0.000 4930
0.448 2309
0.000 0
6.140 11330
0.000 9230
0.442 1955
1.860 8426
0.000 6950
3.080 7200
0.000 5290
0.000 7650
1.400 6210
0.000 10300
2.350 5715
4.980 8145
1.460 5120
2.450 5900
3.880 7460
0.000 7050
0.906 0
2.230 6740
0.000 0
2.840 6500
0.000 8500
4.790 7974
0.000 7070
0.000 7320
1.710 5870
0.000 8000
0.000 0
0.000 0
3.980 7780
0.000 0
5.230 7440
0.000 12140
0.000 0
0.000 12000
0.000 9000
0.000 0
0.000 10900
6.080 8690
0.000 0
0.000 10340
2.680 5352
0.000 10300
0.000 7670
0.000 8600
0.000 11690
0.000 9380
0.000 9200
0.000 7530
4.220 10040
10.200 9388
0.000 0
0.000 0
13.370 10430
0.000 12570
0.000 13740
0.041 440
0.000 12640
6.000 7576
0.000 10360
20.270 12240
0.000 14180
4.778 6896
0.000 9840
0.279 3300
0.264 1333
1.040 4555
0.679 0
3.080 8225
1.200 6140
0.743 3955
0.000 13390
8.690 8823
0.000 0
0.000 13020
7.310 8225
0.000 0
95.000 -11995.6
0.000 13780
3.680 61.6
5.100 8170
0.000 7100
4.010 7760
0.000 8690
0.000 9140
0.000 8620
0.000 8152
91.172 -11322.9
0.000 13380
0.000 0
0.000 12980
11.750 9920
0.000 11900
5.470 10800
0.000 9480
0.000 11490
0.000 0
0.000 10835
0.265 1630
6.110 8800
0.000 2670
5.420 11340
0.000 9270
5.310 0
6.040 0
1.340 0
1.530 3860
5.470 0
7.820 0
7.330 0
0.000 12100
0.000 0
0.000 0
4.420 10900
0.000 5830
0.000 0
0.000 11850
0.000 8180
0.000 4450
1.810 4487
0.000 6760
3.930 7700
4.280 7710
0.000 6510
1.630 4400
0.000 6450
0.000 0
0.000 10700
6.190 8600
0.000 8400
0.000 0
0.000 0
0.000 9070
0.000 0
0.000 6580
0.000 0
0.000 8800
0.000 0
1.320 5955
0.000 0
1.600 9716
0.000 9330
0.000 6550
0.000 8990
0.000 0
0.000 8300
0.000 7070
0.000 7520
4.840 7930
6.380 7860
0.000 7375
6.290 8090
6.200 7790
2.660 5439
4.730 6910
0.000 8200
3.620 6230
0.000 6920
0.000 9200
0.000 0
3.700 7500
2.850 5920
0.000 7500
0.000 0
0.000 0
2.590 5760
0.000 8040
0.000 0
1.850 5321
0.000 6330
0.000 0
0.000 7680
0.000 4550
0.000 5850
1.050 9717
0.804 3108
% 10°C 15°C 20°C 25°C
0 0.99973 0.99973 0.99913 0.99913 0.99823 0.99823 0.99708
1 785 0.99785 725 0.99725 636 0.99636 520
2 602 0.99602 542 0.99542 453 0.99453 336
3 426 0.99426 365 0.99365 275 0.99275 157
4 258 0.99258 195 0.99195 103 0.99103 0.98984
5 98 0.99098 32 0.99032 0.98938 0.98938 817
6 0.98946 0.98946 0.98877 0.98877 780 0.9878 656
7 801 0.98801 729 0.98729 627 0.98627 500
8 660 0.9866 584 0.98584 478 0.98478 346
9 524 0.98524 442 0.98442 331 0.98331 193
10 393 0.98393 304 0.98304 187 0.98187 43
11 267 0.98267 171 0.98171 47 0.98047 0.97897
12 145 0.98145 41 0.98041 0.9791 0.9791 753
13 26 0.98026 0.97914 0.97914 775 0.97775 611
14 0.97911 0.97911 790 0.9779 643 0.97643 472
15 800 0.978 669 0.97669 514 0.97514 334
16 692 0.97692 552 0.97552 387 0.97387 199
17 583 0.97583 433 0.97433 259 0.97259 62
18 473 0.97473 313 0.97313 129 0.97129 0.96923
19 363 0.97363 191 0.97191 0.96997 0.96997 782
20 252 0.97252 68 0.97068 864 0.96864 639
21 139 0.97139 0.96944 0.96944 729 0.96729 495
22 24 0.97024 818 0.96818 592 0.96592 348
23 0.96907 0.96907 689 0.96689 453 0.96453 199
24 787 0.96787 558 0.96558 312 0.96312 48
25 665 0.96665 424 0.96424 168 0.96168 0.95895
26 539 0.96539 287 0.96287 20 0.9602 738
27 406 0.96406 144 0.96144 0.95867 0.95867 576
28 268 0.96268 0.95996 0.95996 710 0.9571 410
29 125 0.96125 844 0.95844 548 0.95548 241
30 0.95977 0.95977 686 0.95686 382 0.95382 67
31 823 0.95823 524 0.95524 212 0.95212 0.9489
32 665 0.95665 357 0.95357 38 0.95038 709
33 502 0.95502 186 0.95186 0.9486 0.9486 525
34 334 0.95334 11 0.95011 679 0.94679 337
35 162 0.95162 0.94832 0.94832 494 0.94494 146
36 0.94986 0.94986 650 0.9465 306 0.94306 0.93952
37 805 0.94805 464 0.94464 114 0.94114 756
38 620 0.9462 273 0.94273 0.93919 0.93919 556
39 431 0.94431 79 0.94079 720 0.9372 353
40 238 0.94238 0.93882 0.93882 518 0.93518 148
41 42 0.94042 682 0.93682 314 0.93314 0.9294
42 0.93842 0.93842 478 0.93478 107 0.93107 729
43 639 0.93639 271 0.93271 0.92897 0.92897 516
44 433 0.93433 62 0.93062 685 0.92685 301
45 226 0.93226 0.92852 0.92852 472 0.92472 85
46 17 0.93017 640 0.9264 257 0.92257 0.91868
47 0.92806 0.92806 426 0.92426 41 0.92041 649
48 593 0.92593 211 0.92211 0.91823 0.91823 429
49 379 0.92379 0.91995 0.91995 604 208
50 0.92126 0.92126 0.91776 0.91776 0.91384 0.91384 0.90985
51 0.91943 0.91943 555 0.91555 160 0.9116 760
52 723 0.91723 333 0.91333 0.90936 0.90936 534
53 502 0.91502 110 0.9111 711 0.90711 307
54 279 0.91279 0.90885 0.90885 485 0.90485 79
55 55 0.91055 659 0.90659 258 0.90258 0.8985
56 0.90831 0.90831 433 0.90433 31 0.90031 621
57 607 0.90607 207 0.90207 0.89803 0.89803 392
58 381 0.90381 0.8998 0.8998 574 0.89574 162
59 154 0.90154 752 0.89752 344 0.89344 0.88931
60 0.89927 0.89927 523 0.89523 113 0.89113 699
61 698 0.89698 293 0.89293 0.88882 0.88882 446
62 468 0.89468 62 0.89062 650 0.8865 233
63 237 0.89237 0.8883 0.8883 417 0.88417 0.87998
64 6 0.89006 597 0.88597 183 0.88183 763
65 0.88774 0.88774 364 0.88364 0.87948 0.87948 527
66 541 0.88541 130 0.8813 713 0.87713 291
67 308 0.88308 0.87895 0.87895 477 0.87477 54
68 74 0.88074 660 0.8766 241 0.87241 0.86817
69 0.87839 0.87839 424 0.87424 4 0.87004 579
70 602 0.87602 187 0.87187 0.86766 0.86766 340
71 365 0.87365 0.86949 0.86949 527 0.86527 100
72 127 0.87127 710 0.8671 287 0.86287 0.85859
73 0.86888 0.86888 470 0.8647 47 0.86047 618
74 648 0.86648 229 0.86229 0.85806 0.85806 376
75 408 0.86408 0.85988 0.85988 564 0.85564 134
76 168 0.86168 747 0.85747 322 0.85322 0.84891
77 0.85927 0.85927 505 0.85505 79 0.85079 647
78 685 0.85685 262 0.85262 0.84835 0.84835 403
79 442 0.85442 18 0.85018 590 0.8459 158
80 197 0.85197 0.84772 0.84772 344 0.84344 0.83911
81 0.8495 0.8495 525 0.84525 96 0.84096 664
82 702 0.84702 277 0.84277 0.83848 0.83848 415
83 453 0.84453 28 0.84028 599 0.83599 164
84 203 0.84203 0.83777 0.83777 348 0.83348 0.82913
85 0.83951 0.83951 525 0.83525 95 0.83095 660
86 697 0.83697 271 0.83271 0.8284 0.8284 405
87 441 0.83441 14 0.83014 583 0.82583 148
88 181 0.83181 0.82754 0.82754 323 0.82323 0.81888
89 0.82919 0.82919 492 0.82492 62 0.82062 626
90 654 0.82654 227 0.82227 0.81797 0.81797 362
91 386 0.82386 0.81959 0.81959 529 0.81529 94
92 114 0.82114 688 0.81688 257 0.81257 0.80823
93 0.81839 0.81839 413 0.81413 0.80983 0.80983 549
94 561 0.81561 134 0.81134 705 0.80705 272
95 278 0.81278 0.80852 0.80852 424 0.80424 0.79991
96 0.80991 0.80991 566 0.80566 138 0.80138 706
97 698 0.80698 274 0.80274 0.79846 0.79846 415
98 399 0.80399 0.79975 0.79975 547 0.79547 117
99 94 0.80094 670 0.7967 243 0.79243 0.78814
100 0.79784 0.79784 360 0.7936 0.78934 0.78934 506
30°C 35°C 40°C
0.99708 0.99568 0.99568 0.99406 0.99406 0.99225 0.99225
0.9952 379 0.99379 217 0.99217 34 0.99034
0.99336 194 0.99194 31 0.99031 0.98846 0.98846
0.99157 14 0.99014 0.98849 0.98849 663 0.98663
0.98984 0.98839 0.98839 672 0.98672 485 0.98485
0.98817 670 0.9867 501 0.98501 311 0.98311
0.98656 507 0.98507 335 0.98335 142 0.98142
0.985 347 0.98347 172 0.98172 0.97975 0.97975
0.98346 189 0.98189 9 0.98009 808 0.97808
0.98193 31 0.98031 0.97846 0.97846 641 0.97641
0.98043 0.97875 0.97875 685 0.97685 475 0.97475
0.97897 723 0.97723 527 0.97527 312 0.97312
0.97753 573 0.97573 371 0.97371 150 0.9715
0.97611 424 0.97424 216 0.97216 0.96989 0.96989
0.97472 278 0.97278 63 0.97063 829 0.96829
0.97334 133 0.97133 0.96911 0.96911 670 0.9667
0.97199 0.9699 0.9699 760 0.9676 512 0.96512
0.97062 844 0.96844 607 0.96607 352 0.96352
0.96923 697 0.96697 452 0.96452 189 0.96189
0.96782 547 0.96547 294 0.96294 23 0.96023
0.96639 395 0.96395 134 0.96134 0.95856 0.95856
0.96495 242 0.96242 0.95973 0.95973 687 0.95687
0.96348 87 0.96087 809 0.95809 516 0.95516
0.96199 0.95929 0.95929 643 0.95643 343 0.95343
0.96048 769 0.95769 476 0.95476 168 0.95168
0.95895 607 0.95607 306 0.95306 0.94991 0.94991
0.95738 442 0.95442 133 0.95133 810 0.9481
0.95576 272 0.95272 0.94955 0.94955 625 0.94625
0.9541 98 0.95098 774 0.94774 438 0.94438
0.95241 0.94922 0.94922 590 0.9459 248 0.94248
0.95067 741 0.94741 403 0.94403 55 0.94055
0.9489 557 0.94557 214 0.94214 0.9386 0.9386
0.94709 370 0.9437 21 0.94021 662 0.93662
0.94525 180 0.9418 0.93825 0.93825 461 0.93461
0.94337 0.93986 0.93986 626 0.93626 257 0.93257
0.94146 790 0.9379 425 0.93425 51 0.93051
0.93952 591 0.93591 221 0.93221 0.92843 0.92843
0.93756 390 0.9339 16 0.93016 634 0.92634
0.93556 186 0.93186 0.92808 0.92808 422 0.92422
0.93353 0.92979 0.92979 597 0.92597 208 0.92208
0.93148 770 0.9277 385 0.92385 0.91992 0.91992
0.9294 558 0.92558 170 0.9217 774 0.91774
0.92729 344 0.92344 0.91952 0.91952 554 0.91554
0.92516 128 0.92128 733 0.91733 332 0.91332
0.92301 0.9191 0.9191 513 0.91513 108 0.91108
0.92085 692 0.91692 291 0.91291 0.90884 0.90884
0.91868 472 0.91472 69 0.91069 660 0.9066
0.91649 250 0.9125 0.90845 0.90845 434 0.90434
0.91429 28 0.91028 621 0.90621 207 0.90207
0.91208 0.90805 0.90805 396 0.90396 0.89979 0.89979
0.90985 0.9058 0.9058 0.90168 0.90168 0.8975 0.8975
0.9076 353 0.90353 0.8994 0.8994 519 0.89519
0.90534 125 0.90125 710 0.8971 288 0.89288
0.90307 0.89896 0.89896 479 0.89479 56 0.89056
0.90079 667 0.89667 248 0.89248 0.88823 0.88823
0.8985 437 0.89437 16 0.89016 589 0.88589
0.89621 206 0.89206 0.88784 0.88784 356 0.88356
0.89392 0.88975 0.88975 552 0.88552 122 0.88122
0.89162 744 0.88744 319 0.88319 0.87888 0.87888
0.88931 512 0.88512 85 0.88085 653 0.87653
0.88699 278 0.88278 0.87851 0.87851 417 0.87417
0.88446 44 0.88044 615 0.87615 180 0.8718
0.88233 0.87809 0.87809 379 0.87379 0.86943 0.86943
0.87998 574 0.87574 142 0.87142 705 0.86705
0.87763 337 0.87337 0.86905 0.86905 466 0.86466
0.87527 100 0.871 667 0.86667 227 0.86227
0.87291 0.86863 0.86863 429 0.86429 0.85987 0.85987
0.87054 625 0.86625 190 0.8619 747 0.85747
0.86817 387 0.86387 0.8595 0.8595 407 0.85407
0.86579 148 0.86148 710 0.8571 266 0.85266
0.8634 0.85908 0.85908 470 0.8547 25 0.85025
0.861 667 0.85667 228 0.85228 0.84783 0.84783
0.85859 426 0.85426 0.84986 0.84986 540 0.8454
0.85618 184 0.85184 743 0.84743 297 0.84297
0.85376 0.84941 0.84941 500 0.845 53 0.84053
0.85134 698 0.84698 257 0.84257 0.83809 0.83809
0.84891 455 0.84455 13 0.84013 564 0.83564
0.84647 211 0.84211 0.83768 0.83768 319 0.83319
0.84403 0.83966 0.83966 523 0.83523 74 0.83074
0.84158 720 0.8372 277 0.83277 0.82827 0.82827
0.83911 473 0.83473 29 0.83029 578 0.82578
0.83664 224 0.83224 0.8278 0.8278 329 0.82329
0.83415 0.82974 0.82974 530 0.8253 79 0.82079
0.83164 724 0.82724 279 0.82279 0.81828 0.81828
0.82913 473 0.82473 27 0.82027 576 0.81576
0.8266 220 0.8222 0.81774 0.81774 322 0.81322
0.82405 0.81965 0.81965 519 0.81519 67 0.81067
0.82148 708 0.81708 262 0.81262 0.80811 0.80811
0.81888 448 0.81448 3 0.81003 552 0.80552
0.81626 186 0.81186 0.80742 0.80742 291 0.80291
0.81362 0.80922 0.80922 478 0.80478 28 0.80028
0.81094 655 0.80655 211 0.80211 0.79761 0.79761
0.80823 384 0.80384 0.79941 0.79941 491 0.79491
0.80549 111 0.80111 669 0.79669 220 0.7922
0.80272 0.79835 0.79835 393 0.79393 0.78947 0.78947
0.79991 555 0.79555 114 0.79114 670
0.79706 271 0.79271 0.78831 0.78831 388
0.79415 0.78981 0.78981 542 100
0.79117 684 247 0.77806 0.77806
0.78814 382 0.77946 0.77946 507
75 641 203
15°C 20°C 25°C 30°C 35°C 40°C
0.91776 0.91384 0.90985 0.9058 0.90168 0.8975
555 160 760 353 0.8994 519
333 0.90936 534 125 710 288
110 711 307 0.89896 479 56
0.90885 485 79 667 248 0.88823
659 258 0.8985 437 16 589
433 31 621 206 0.88784 356
207 0.89803 392 0.88975 552 122
0.8998 574 162 744 319 0.87888
752 344 0.88931 512 85 653
523 113 699 278 0.87851 417
293 0.88882 446 44 615 180
62 650 233 0.87809 379 0.86943
0.8883 417 0.87998 574 142 705
1.2
597 183 763 337 0.86905 466
364 0.87948 527 100 667 227
1
130 713 291 0.86863 429 0.85987
0.87895 477 54 625 190 747
0.8
660 241 0.86817 387 0.8595 407
424 4 579 148 710 266
187 0.86766 0.6 340 0.85908 470 25
0.86949 527 100 667 228 0.84783
710 287 0.4 0.85859 426 0.84986 540
470 47 618 184 743 297
229 0.85806 0.2 376 0.84941 500 53
0.85988 564 134 698 257 0.83809
747 322 0 0.84891 455 13 564
0 20 40 60 80 100 120
505 79 647 211 0.83768 319
262 0.84835 403 0.83966 523 74
18 590 158 720 277 0.82827
0.84772 344 0.83911 473 29 578
525 96 664 224 0.8278 329
277 0.83848 415 0.82974 530 79
28 599 164 724 279 0.81828
0.83777 348 0.82913 473 27 576
525 95 660 220 0.81774 322
271 0.8284 405 0.81965 519 67
14 583 148 708 262 0.80811
0.82754 323 0.81888 448 3 552
492 62 626 186 0.80742 291
227 0.81797 362 0.80922 478 28
0.81959 529 94 655 211 0.79761
688 257 0.80823 384 0.79941 491
413 0.80983 549 111 669 220
134 705 272 0.79835 393 0.78947
0.80852 424 0.79991 555 114 670
566 138 706 271 0.78831 388
274 0.79846 415 0.78981 542 100
0.79975 547 117 684 247 0.77806
670 243 0.78814 382 0.77946 507
360 0.78934 506 75 641 203
100 120
AJUSTE van Laar
A B C A
ETHANOL 18.9119 3803.98 -41.68 ln 1
x
WATER 18.3036 3816.44 -46.13
1
x
P A12 A21 ln 2
760 1.677638831 0.908474813 x
1
x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 100 1695.628333 759.9430125 5.352901932 1 11.9428055
0.019 0.981 95.5 1447.895348 645.7493081 4.776835506 1.00108384 9.100470929
0.0721 0.9279 89 1143.554379 506.2459246 3.607526471 1.01440781 5.42816144
0.0966 0.9034
Chart Title
86.7 1049.522117 463.3508815 3.221900875 1.025010953 4.44928451
0.1238 0.8762
1.2 85.3 995.5050447 438.7604024 2.872482883 1.039666138 3.762593685
0.1661 0.8339 84.1 951.0680201 418.5606944 2.451450343 1.067901277 3.067757927
0.2337 0.7663 82.7 901.3280763 395.9838679 1.986879173 1.125153985 2.356355241
0.2608 0.7392 82.3 887.5224056 389.7240297 1.849795312 1.15186862 2.160177349
1
0.3273 0.6727f(x) = 0.999289227219007
81.5 860.4403571
x 377.4528707 1.592750786 1.225659365 1.803246125
0.3965 0.6035R² = 0.999962955890422
80.7 834.0522099 365.5072841 1.408437293 1.313892794 1.545671364
0.5198 0.4802 79.7 802.0214891 351.0227067 1.205068178 1.497240645 1.271698125
0.5732 0.8
0.4268 79.3 789.5006013 345.3653606 1.148574545 1.586275007 1.193158282
0.6765 0.3235 78.74 772.2464187 337.5738147 1.07355717 1.773905754 1.090856157
0.7472 0.2528 78.41 762.2273782 333.0518868 1.041043664 1.913462812 1.044094714
0.8943 0.1057
0.6 78.15 754.4104331 329.5250895 1.006088962 2.231035234 0.998689486
1 0 78.3 758.9119752 331.5559306 1 2.480536365 0.998568388
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1
A12
ln 1 2
x1 A12
1
1.59161691 0.964660414 0.002154181
x 2 A21
1.596483324 0.964187815 0.002078768
1.587113105 0.931186687 0.001516951
A21 1.689568789 0.93696514 0.001037034
ln 2 2 1.677638831 0.908474813 0.000226553
x 2 A21
1
x1 A12
K2 y1 y2 Sy y error
0.999925016 0 0.999925016 0.999925016 0 0
0.850591049 0.172908948 0.834429819 1.007338767 0.17 8.46198E-06
0.675710289 0.39137044 0.626991577 1.018362017 0.3891 5.1549E-06
0.624920696 0.429800884 0.564553357 0.99435424 0.4375 5.92764E-05
0.600216228 0.465809098 0.525909459 0.991718557 0.4704 2.10764E-05
0.588133553 0.509554592 0.49044457 0.999999161 0.5089 4.2849E-07
0.586240562 0.55068022 0.449236143 0.999916362 0.5445 3.81951E-05
0.590672211 0.563374252 0.436624898 0.999999151 0.558 2.88826E-05
0.608721903 0.590202457 0.409487224 0.999689681 0.5826 5.77973E-05
0.631891299 0.612858696 0.381346399 0.994205095 0.6122 4.3388E-07
0.691533505 0.661028685 0.332074389 0.993103074 0.6599 1.27393E-06
0.720847947 0.683918327 0.307657904 0.991576231 0.6841 3.3005E-08
0.78792649 0.73796419 0.254894219 0.99285841 0.7385 2.87092E-07
0.838529474 0.78014757 0.211980251 0.992127821 0.7815 1.82907E-06
0.967344849 0.893128008 0.102248351 0.995376358 0.8943 1.37357E-06
1.082153346 0.998568388 0 0.998568388 1 2.04951E-06
15.96911833 0.000226553
16
1 1.2
100
95
90
85
80
75
70
0 0.2 0.4 0.6 0.8 1 1.2
Ejemplo 9.1 Un destilador disconttnuo SC carga con 100 kmol de un líquido que contiene
una mezcla binaria de 50 moles ‘L de benceno cn tolueno. Constrúyanse representaciones
gráficas, en funcicín del tiempo, de (a) la temperatura de la caldera, (b) la composición instantánea
del vapor, (c) la composición del líquido de la caldera del destilador, y (d) la composición
media total del destilado. Supongase una velocidad dc vaporización constante de
10 kmol/h y una volatilidad relativa constante dc 2.41 para una presión de 101.3 kPa (1 atm).
Soluc~ión. Inicialmente, W,, = 100. x,, = 0.5. Obteniendo W a partir de (9-5) para valores
de .Y desde 0.5, a incrementos dc 0.05. y determinando los correspondientes valores del
tiempo a partir de t = (W,, - W)/lO, sc genera la siguiente tabla
1. h 2.12 3 75 5 . 0 4 h.OX 6 . 9 4 7.66 x.7x x.x3 9 . 3 5
W. kmot 7X.X( hl.5 I 49.59 Nlfl 3O.FY 3 3 . 3 8 17.19 II.69 6.52
x 0.4s 0 . 4 0 0 . 3 5 0 . 3 0 0.25 0.20 0.15 0.10 0.05
123456789
1.00
Tiempo, horas
0.90
xy 0.5 0 0.70
0 0.00 0.60
0.1 0.22 0.50
0.2 0.38 0.40
0.3 0.52
0.30
0.4 0.63
0.20
0.5 0.71
0.6 0.79 0.10
1 1.00
y x f
0.5
0.7 0.4827586 4.6031746
0.6 0.375 4.4444444
0.5 0.2857143 4.6666667
0.4 0.2105263 5.2777778
0.3 0.1463415 6.5079365
0.2 0.0909091 9.1666667
0.114 0.048948 15.372328
13.2. Differential distillation.
A mixture of 40 mol% isopropanol in water is distilled at 1 atm by x
differential distillation until 70 mol% of the charge has been vaporized 0
(equilibrium data are given in Exercise 7.33). What is the composition 0.0118
of the liquid residue in the still-pot and of the collected distillate? 0.0841
0.1978
xW0 0.4 0.3496
Recup 70% 0.4525
W0 100 0.6794
0.6854
xW0 0.7693
0.4 0.4 0.9442
0.4 0 1
yD x 1/(y-x) I W D xD d
100
0.57 0.35 4.5454545 -0.797297 45.054501 54.945499 0.535 29.395842
0.5 0.13 2.7027027 -0.147658 38.869708 6.184793 0.475 2.9377767
0.45 0.075 2.6666667 -0.050239 36.965172 1.9045362 0.425 0.8094279
0.4 0.057 2.9154519 -0.046217 35.295646 1.6695253 0.375 0.626072
0.35 0.042 3.2467532 -0.050144 33.569407 1.726239 0.325 0.5610277
0.3 0.0275 3.6697248 -0.037905 32.320763 1.2486448 0.275 0.3433773
0.25 0.018 4.3103448 -0.04435 30.918644 1.402119 0.225 0.3154768
0.2 0.0087 5.2273915 -0.02838 30.053499 0.8651446 0.175 0.1514003
0.15 0.004 6.8493151 -0.002317 29.983941 0.0695583 0.135 0.0093904
0.12 0.0037 8.5984523
70.016059 35.149791 xD
R 9
xD xD xD xD xD
0.63 0.6 0.55 0.5 0.45
mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.9 0.063 0.9 0.06 0.9 0.055 0.9 0.05 0.9 0.045
0.63 0.63 0.6 0.6 0.55 0.55 0.5 0.5 0.45 0.45
0 0.063 0 0.06 0 0.055 0 0.05 0 0.045
0.63 0.63 0.6 0.6 0.55 0.55 0.5 0.5 0.45 0.45
0.55 0.63 0.48 0.6 0.28 0.55 0.13 0.5 0.075 0.45
0.55 0.558 0.48 0.492 0.28 0.307 0.13 0.167 0.075 0.1125
0.32 0.558 0.11 0.492 0.03 0.307 0.006 0.167 0.002 0.1125
0.32 0.351 0.11 0.159 0.03 0.082 0.006 0.0554 0.002 0.0468
yD x 1/(y-x) I W D xD d
100
0.63 0.32 3.2258065 -0.552995 57.522421 42.477579 0.615 26.123711
0.6 0.11 2.0408163 -0.158556 49.088219 8.4342017 0.575 4.849666
0.55 0.03 1.9230769 -0.047368 46.817199 2.2710195 0.525 1.1922852
0.5 0.006 2.0242915 -0.008513 46.420342 0.3968571 0.475 0.1885071
0.45 0.002 2.2321429 -0.002369 46.310493 0.1098491 0.425 0.0466859
0.4 0.001 2.5062657 -0.000269 46.298059 0.0124345 0.375 0.0046629
0.35 0.0009 2.8645087
53.689507 32.400856
0.9
xW0 0.5 0.5
0.8
0.5 0
0.7
Rmin 0.6
1.69
0.5
LORmin 0.9 0.9
0.4
0 0.3345725
0.3
R 2.535 0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
xD R xD R xD R xD R xD R
0.9 2.535 0.9 3.5 0.9 4.5 0.9 5.5 0.9 6.5
mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.7171146 0.2545969 0.7777778 0.2 0.8181818 0.1636364 0.8461538 0.1384615 0.8666667 0.12
0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
0 0.2545969 0 0.2 0 0.1636364 0 0.1384615 0 0.12
0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
0.845 0.9 0.845 0.9 0.845 0.9 0.845 0.9 0.845 0.9
0.845 0.8605587 0.845 0.8572222 0.845 0.855 0.845 0.8534615 0.845 0.8523333
0.79 0.8605587 0.783 0.8572222 0.781 0.855 0.78 0.8534615 0.778 0.8523333
0.79 0.8211174 0.783 0.809 0.781 0.8026364 0.78 0.7984615 0.778 0.7942667
0.737 0.8211174 0.72 0.809 0.718 0.8026364 0.714 0.7984615 0.706 0.7942667
0.737 0.7831103 0.72 0.76 0.718 0.7510909 0.714 0.7426154 0.706 0.7318667
0.69 0.7831103 0.66 0.76 0.65 0.7510909 0.64 0.7426154 0.62 0.7318667
0.69 0.7494059 0.66 0.7133333 0.65 0.6954545 0.64 0.68 0.62 0.6573333
0.645 0.7494059 0.59 0.7133333 0.555 0.6954545 0.522 0.68 0.485 0.6573333
0.645 0.7171358 0.59 0.6588889 0.555 0.6177273 0.522 0.5801538 0.485 0.5403333
0.59 0.7171358 0.485 0.6588889 0.42 0.6177273 0.38 0.5801538 0.336 0.5403333
0.59 0.6776945 0.485 0.5772222 0.42 0.5072727 0.38 0.46 0.336 0.4112
0.51 0.6776945 0.38 0.5772222 0.3 0.5072727 0.24 0.46 0.195 0.4112
0.51 0.6203253 0.38 0.4955556 0.3 0.4090909 0.24 0.3415385 0.195 0.289
0.43 0.6203253 0.29 0.4955556 0.192 0.4090909 0.152 0.3415385 0.125 0.289
0.43 0.5629562 0.29 0.4255556 0.192 0.3207273 0.152 0.2670769 0.125 0.2283333
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
I W D D xD d t (h)
100 0 0
-0.536227 58.495087 41.504913 41.504913 0.4288793 17.800599 4.1504913
-0.447421 37.394444 21.100643 62.605556 0.3303571 6.9707482 2.1100643
-0.411236 24.786167 12.608277 75.213833 0.2481203 3.1283695 1.2608277
-0.416055 16.35004 8.4361271 83.64996 0.1784339 1.505291 0.8436127
-0.477884 10.138561 6.2114786 89.861439 0.1186253 0.7368384 0.6211479
-0.566325 5.7547238 4.3838372 94.245276 0.0699286 0.3065555 0.4383837
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.4
0.4
0
0.2
0.2
0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.5020247
xD xD 1
0.4 0.35 0.9
mLOR bLOR mLOR bLOR
0.8
0.9 0.04 0.9 0.035
0.7
0.4
0.3
0.2
0.1
0.7
0.6
0.5
0.4
0.6034858
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
(b) Assume the column has eight stages and the reflux rate is varied
continuously so that the top product is maintained constant at
0.9 mole fraction acetone. Make a plot of the reflux ratio versus
the still-pot composition and the amount of liquid left in the
still-pot.
(c) Assume the same distillation is carried out at constant reflux
ratio (and varying product composition). It is desired to have a residu
containing 0.1 and an (average) product containing 0.9 mole
fraction acetone. Calculate the total vapor generated. Which method
0.7 0.8 0.9 1 of operation is more energy-intensive? Suggest operating policies
0.7 0.8 0.9 1
other than constant reflux ratio and constant distillate compositions
xD R that lead to equipment or operating cost savings.
1
0.9 8
mLOR bLOR
0.9
0.8888889 0.1
0.8
0.9 0.9
0 0.1
0.7
0.6
0.9 0.9
0.845 0.9
0.845 0.8511111 0.5
0.776 0.8511111
0.776 0.7897778 0.4
0.7 0.7897778
0.7 0.7222222 0.3
0.605 0.7222222
0.605 0.6377778 0.2
0.453 0.6377778
0.453 0.5026667 0.1
0.295 0.5026667
0.295 0.3622222 0
0 0.1 0.2 0.3 0.4 0.5 0
0.163 0.3622222
0.163 0.2448889
0.1 0.2448889
0.1 0.1888889
Chart Title
18
16
14
12
10
8
0.2 6 0.114 0.114
0.2 0.048948 0.114
4
0.0909091 0.048948 0.048948
2
0
0 0.1 0.2 0.3 0.4 0.5 0.6
0.7 0.8 0.9 1
0.5 0.6 0.7 0.8 0.9 1
t at constant reflux
desired to have a residue
aining 0.9 mole
nerated. Which method
st operating policies
distillate compositions
F D B z xD xB
C3 5 5 0 0.05 0.1070091 0
iC4 15 15 0 0.15 0.3210273 0
nC4 (LK) 25 23.125 1.875 0.25 0.4949171 0.0351947
iC5 (HK) 20 3.6 16.4 0.2 0.0770465 0.3078367
C5 35 0 35 0.35 0 0.6569686
100 46.725 53.275 1
P [psi] T [R]
102.54018 680.2142
Comp xB K KixBi aB Tc
C3 0 4.7630975 0 4.4628386 369.8 665.64
iC4 0 2.5475099 0 2.3869185 408.1 734.58
nC4 (LK) 0.0351947 2.0464796 0.0720253 1.9174724 425.2 765.36
iC5 (HK) 0.3078367 1.0672798 0.3285479 1 460.4 828.72
C5 0.6569686 0.9121453 0.5992508 0.8546449 469.6 845.28
0.999824
P [psi] T [R]
101.04018 623.64137
Comp z K KixBi aF aprom
C3 0.05 3.2393044 0.1619652 5.4948728 9.8907711 5.4816229
iC4 0.15 1.6006617 0.2400993 2.7152226 4.8874008 2.713348
nC4 (LK) 0.25 1.2280615 0.3070154 2.0831763 3.7497173 2.0836591
iC5 (HK) 0.2 0.589514 0.1179028 1 1.8 1
C5 0.35 0.4946674 0.1731336 0.8391105 1.5103989 0.8385902
1.0001162
REFLUJO MÍNIMO
q T q1 q2 q3 q4
1 0 4.9329881 2.4613906 1.3684478 0.9252031
Comp z aF f1 f2 f3 f4
C3 0.05 5.4948728 0.488968 0.0905704 0.0665815 0.0601233
iC4 0.15 2.7152226 -0.183646 1.604539 0.3024139 0.2275301
nC4 (LK) 0.25 2.0831763 -0.182747 -1.376981 0.72866 0.4497462
iC5 (HK) 0.2 1 -0.050852 -0.136856 -0.542818 2.673909
C5 0.35 0.8391105 -0.071739 -0.181035 -0.554823 -3.411311
-1.513E-05 0.0002376 1.421E-05 -1.99E-06
DISTRIBUCION
Rmin
q3 q4
1.3684478 0.9252031
Comp d aF Lmin+D Lmin+D Lmin Rmin D B
C3 5 5.4948728 6.6581517 6.0123304 5 0
iC4 15 2.7152226 30.241387 22.753014 15 0
nC4 (LK) 23.125 2.0831763 67.401049 41.601528 23.125 1.875
iC5 (HK) 3.6 1 -9.77072 48.130362 3.6 16.4
C5 2.9366763 0.8391105 -4.655248 -28.62262 2.9366763 32.063324
49.661676 89.874619 89.874619 40.212943 0.8097379 49.661676 50.338324
0
REFLUJO
R/Rmin 1.2
R 0.9716855
NÚMERO DE ETAPAS
X 0.0821366
Y 0.568105 N 14.021451 N 15
ETAPA DE ALIMENTACIÓN
SELECCIÓN DE CLAVES
Comp z Ki ai,HK
C2H4 0.05 5.1 34
HCl 0.05 3.8 25.333333
C2H6 (LK) 0.1 3.4 22.666667
C2H5Cl (HK 0.8 0.15 1
Nmin suponer
Comp (xD/xB) ai,HK Nmin (d/b) (d/b) f b d xD
C2H4 34 57.493825 5 0.0854791 4.9145209 0.2534917
HCl 25.333333 24.79012 5 0.1938727 4.8061273 0.2479007
C2H6 (LK) 75 22.666667 18.037455 10 0.5252803 9.4747197 0.4887074
C2H5Cl (HK 0.01 1 0.002405 0.002405 80 79.808062 0.1919379 0.0099002
2.8590059 100 80.612694 19.387306
Rmin
q 1-q q1 q2 q3
1 0 30.820485 24.310077 4.3121709
Comp z ai,HK fun fun fun D F=LF (d/lF) (d/f)
C2H4 0.05 34 0.5346728 0.17544 0.0572625 5 1.4418177 1.4418177
HCl 0.05 25.333333 -0.230842 1.2378786 0.0602567 5 1.0637886 1.0637886
C2H6 (LK) 0.1 22.666667 -0.277988 -1.379245 0.1234938 9.4747197 10 0.947472 0.947472
C2H5Cl (HK 0.8 1 -0.026827 -0.03432 -0.241533 0.1919379 80 0.0023992 0.0023992
-0.000985 -0.000247 -0.00052
R 0.28434
Numero de etapas
R Rmin Nmin X Y N N
0.28434 0.18956 2.8590059 0.0737967 0.5788155 8.1622691 9
Etapa de Alimentación
Comp z F a D Nmin q
A 0.4 40 5
B (LK) 0.2 20 3
C (HK) 0.4 40 1
100 60 5 1
94.540177
99.540177
101.04018
102.54018
100
(d/b)i
10000
1000
100
10
0.1
0.01
0.1 1
xD xB
0.1006813 0
0.3020438 0
0.4656508 0.037248
0.0724905 0.3257955
0.0591337 0.6369565
Ns Nf Ns
8 1 6 15
xB xD/xB
0.0010604
0.002405
0.0065161 75
0.9900185 0.01
q3
4.3121709
d d b xD xB Rmin+1 Rmin
7.2090886 5 0 0.2542374 0 0.2911655
5.3189431 5 0 0.2542374 0 0.3063903
9.4747197 9.4747197 0.5252803 0.4817656 0.0065388 0.5949507
0.1919379 0.1919379 79.808062 0.0097596 0.9934612 -0.002947
19.666658 80.333342 1.18956 0.18956
Ns Nf Ns
3 1 5 9
P [psi]
200
K Comp Tc
13.046317 METHANE 190.6
2.7726152 ETHANE 305.4
1.0128361 PROPANE 369.8
0.4130212 ISOBUTANE 408.1
0.2868323 N-BUTANE 425.2
0.1242875 2-METHYL 460.4
0.1043442 N-PENTANE 469.6
(d/b)i
1 10
Un kmol de una mezcla equimolar de benceno y tolueno se introduce como alimentación
a un sistema de destilación que consta de tres etapas (incluyendo el calderín).
El liquido de reflujo está a su punto de burbuja y L/D = 4. ¿Cuál es la cantidad y composición
media del producto en el momento en que la composición instantánea del
producto es 55 moles % de benceno? Despréciese el líquido retenido en las etapas y
supóngase a = 2,5.
alfa 2.5
x y
0 0
0.1 0.2173913 xD 0.87 xD 0.8 xD 0.75 xD
0.2 0.3846154 mLOR bLOR mLOR bLOR mLOR bLOR mLOR
0.3 0.5172414 0.8 0.174 0.8 0.16 0.8 0.15 0.8
0.4 0.625
0.5 0.7142857 0.87 0.87 0.8 0.8 0.75 0.75 0.7
0.6 0.7894737 0.7280335 0.87 0.6153846 0.8 0.5454545 0.75 0.4827586
0.7 0.8536585 0.7280335 0.7564268 0.6153846 0.6523077 0.5454545 0.5863636 0.4827586
0.8 0.9090909 0.5540128 0.7564268 0.4287159 0.6523077 0.3618513 0.5863636 0.3075993
0.9 0.9574468 0.5540128 0.6172102 0.4287159 0.5029727 0.3618513 0.4394811 0.3075993
1 1 0.3920825 0.6172102 0.2881472 0.5029727 0.2387474 0.4394811 0.2009908
0.3920825 0.487666 0.2881472 0.3905177 0.2387474 0.3409979 0.2009908
x y I W D
100
0.3920825 0.87 2.0924112 -0.141613 86.795672 13.204328
0.2881472 0.8 1.9536866 -0.097742 78.713532 8.0821399
0.2387474 0.75 1.9559803 -0.098999 71.294295 7.4192379
0.2009908 0.7 2.0039711 -0.102281 64.36276 6.9315344
0.1709059 0.65 2.0872727 -0.107266 57.816201 6.546559
0.1461506 0.6 2.2033742 -0.237475 45.594821 12.221381
0.1072461 0.5 2.5461239
0.1072461 0.5 2.5461239
0.1072461 0.5
54.405179
z 0.5 0.5
0.5 0
0.7 0.65 0.65 0.6 0.6 0.5 0.5 0.5 0.5 0.5
0.7 0.4262295 0.65 0.375 0.6 0.2857143 0.5 0.2857143 0.5 0.2857143
0.5262069 0.4262295 0.4709836 0.375 0.42 0.2857143 0.3285714 0.2857143 0.3285714 0.2857143
0.5262069 0.2626023 0.4709836 0.2245989 0.42 0.1637011 0.3285714 0.1637011 0.3285714 0.1637011
0.3860794 0.2626023 0.3400818 0.2245989 0.2996791 0.1637011 0.2309609 0.1637011 0.2309609 0.1637011
0.3860794 0.1709059 0.3400818 0.1461506 0.2996791 0.1072461 0.2309609 0.1072461 0.2309609 0.1072461
0.3007927 0.1709059 0.2667247 0.1461506 0.2369205 0.1072461 0.1857969 0.1072461 0.1857969 0.1072461
xD d D xD
0.9
0.8
0.7
0.5
0.6
bLOR
0.5
0.1
0.4
0.5 0.3
0.5
0.2
0.3285714
0.3285714 0.1
0.2309609 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.2309609
0.1857969
d D xD d
0.023
0.9328
0.034
0.847
0.044
0.715
0.106
0.581
0.165
0.487
Refinado Extracto
CH3Cl H2O H Ac CH3Cl H2O H Ac
A B C A B C
0.9901 0.0099 0.0000 0.0084 0.9916 0
0.9185 0.0138 0.0677 0.0121 0.7369 0.251
0.8 0.0228 0.1772 0.073 0.4858 0.4412
0.7013 0.0412 0.2575 0.1511 0.3471 0.5018
0.6715 0.052 0.2765 0.1833 0.3111 0.5056
0.5999 0.0793 0.3208 0.252 0.2539 0.4941
0.5581 0.0953 0.3466 0.2885 0.2328 0.4787
SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 60 60 0 1
C 300 0 300 0.3 0
1000 60 1060
F 0 0.3
M 0.056603774 0.2830189
S 1 0
SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 70000 70000 0 1
C 300 0 300 0.3 0
1000 70000 71000
F 0 0.3
M 0.985915493 0.0042254
S 1 0
CANTIDAD DE AGUA
F S M R E xF ySmin
A 700 0 700 0.7 0
B 0 742.3 742.3 0 1
C 300 0 300 0.3 0
1000 742.3 1742.3
0 0.96
F 0 0.3 1 0
S 1 0 -0.3 0.3
0.7369 0.251
M 0.42605 0.1721862 0.0138 0.0677 0.2534919
0.05
0.9
0.05
0.82
0.051
0.742
0.052
0.675
0.054
0.611
A B C A B C 0.056
0.95 0.05 0 0.1 0.9 0 0.558
0.925 0.05 0.025 0.101 0.82 0.079
0.899 0.051 0.05 0.108 0.742 0.15 0.059
0.873 0.052 0.075 0.115 0.675 0.21 0.503
0.846 0.054 0.1 0.127 0.611 0.262
0.819 0.056 0.125 0.142 0.558 0.3 0.062
0.791 0.059 0.15 0.159 0.503 0.338 0.457
0.763 0.062 0.175 0.178 0.457 0.365
0.734 0.066 0.2 0.196 0.414 0.39 0.066
0.675 0.075 0.25 0.246 0.329 0.425 0.414
0.611 0.089 0.3 0.28 0.275 0.445
0.544 0.106 0.35 0.333 0.217 0.45 0.075
0.466 0.134 0.4 0.405 0.165 0.43 0.329
0.434 0.15 0.416 0.434 0.15 0.416
0.089
0.275
0.106
0.217
0.134
0.165
0.15
0.15
F S1 M1 R1 E1 xF yS1
A 70 0 70 59.333911 10.666089 59.333911 0.7 0
B 0 50 50 4.1512266 45.801443 4.198557 0 1
C 30 0 30 8.0877345 21.959596 8.040404 0.3 0
100 50 150 71.572872 78.427128
0.829
0.0586613
R1 S2 M2 R2 E2 0.1123387 x1 yS2
A 59.333911 0 59.333911 52.627891 6.7060193 52.627891 0.829 0
B 4.1512266 50 54.151227 3.0007131 50.774146 3.3770804 0.058 1
C 8.0877345 0 8.0877345 2.0774168 6.386685 1.7010494 0.113 0
71.572872 50 121.57287 57.706021 63.86685
0.912
0.0585221
R2 S3 M3 R3 E3 0.0294779 x2 yS3
A 52.627891 0 52.627891 46.972725 5.6551666 0.912 0
B 3.0007131 50 53.000713 2.500012 50.319442 0.052 1
C 2.0774168 0 2.0774168 0.5275025 1.7311735 0.036 0
57.706021 50 107.70602 50.000239 57.705782
E1 E2 E3 E y
10.666089 6.7060193 5.6551666 23.027275 0.1151365
45.801443 50.774146 50.319442 146.89503 0.734476
21.959596 6.386685 1.7311735 30.077454 0.1503875
199.99976
0.0121
A B C A B C 0.9932
0.981 0.0121 0.0069 0.005 0.9932 0.0018
0.971 0.0149 0.0141 0.007 0.9893 0.0037 0.0149
0.955 0.0161 0.0289 0.008 0.9841 0.0079 0.9893
0.917 0.0188 0.0642 0.01 0.9707 0.0193
0.844 0.024 0.132 0.019 0.9328 0.0482 0.0161
0.711 0.034 0.255 0.039 0.847 0.114 0.9841
0.589 0.044 0.367 0.069 0.715 0.216
0.451 0.106 0.443 0.108 0.581 0.311 0.0188
0.371 0.165 0.464 0.151 0.487 0.362 0.9707
0.024
0.9328
0.034
0.847
0.044
0.715
0.106
0.581
0.165
0.487
SOLVENTE MÍNIMO
F Smin M Rn E1 xF Ysmin
Agua 180 0 180 143.11475 36.885248 143.11475 0.6 0
IPE 0 316.6251184 316.62512 3.1111903 313.52461 3.1005064 0 1
H Acetico 120 0 120 9.3335708 110.65575 9.3442546 0.4 0
300 316.6251184 616.62512 155.55951 461.06561
1.999567
0.5
0.4
0.3
0.2
0.1
0
0 0.5 1 1.5 2
-0.1
F Smin M Rn E1 xF Ysmin
Agua 180 0 180 143.89961 36.100395 143.89961 0.6 0
IPE 0 443.2751657 443.27517 3.1282523 440.14691 3.1282523 0 1
H Acetico 120 0 120 9.3847569 110.61524 9.3847569 0.4 0
300 443.2751657 743.27517 156.41261 586.86255
2.0105328
0.5
0.4
F Smin M Rn E1 xF Ysmin
Agua 180 0 180 150.04439 29.955607 150.04439 0.6 0
0.3
0.2
0.4
0.3
IPE 0 0 0 -458.942 474.49681 -474.4968 0 1
H Acetico 120 0 120 9.7855039 94.659717 25.340283 0.4 0
300 0 300 -299.1121
0.2 599.11213
2.0963864
0.1
0
0 0.2 0.4 0.6 0.8 1 1.2 1.
0.0069
0.0018
0.0141
0.0037
0.0289
0.5
0.0079
0.45
0.0642 0.4
0.0193
0.35
0.133 0.3
0.0482 0.25
0.2
0.255
0.15
0.114
0.1
0.367 0.05
0.216
0
0 0.2 0.4 0.6
0.443
0.311
0.464
0.362
0.0099 0
0.9916 0
0.0138 0.0677
0.7369 0.251
0.0228 0.1772
0.4858 0.4412
0.6
0.0412 0.2575
0.3471 0.5018 0.5
xM 0.6000
x y
0.6603774 0.052 0.2765
0.4
0.05660380.5000 0.3111 0.5056
0.2830189
0.3
0.4000
0.2
0.3000
0.6000
0.4
0.5000
0.3
0.4000 0.0793 0.3208
0.2539 0.4941
0.2
0.3000
0.0953 0.3466
0.2328 0.4787 0.1
0.2000
0.0
0.1000 0 0.2
0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0.6000
xM x y
0.0098592 0.5000
0.9859155
0.0042254 0.4000
0.3000
0.2000
0.1000
0.0000
xM x y 0 0.2
0.4017678 0.4017678
0.42605 0.251 0.42602
0.1721862 0.1721942
0.0642018
0
0
0.025
0.079
0.05
0.15
0.075
0.21
0.1
0.262
0.125
0.3
0.15
0.338
0.175
0.365
0.2
0.39
0.25
0.425
0.3
0.445
0.35
0.45
0.4
0.43
0.416
0.416
0.5
0.45
xM1 x1 y1 F 0 0.3
0.4
0.4666667 0.829 0.136 M1 0.3333333 0.2
0.3333333 0.058 0.584 S1 1 0
0.35
0.2 0.113 0.28
1 1 1 R1 0.058 0.113
0.3
E1 0.584 0.28
0.25
0.2
0.15
0.3
0.25
xM2 x2 y2 R1 0.058 0.113
0.4880522 0.912 0.105 M2 0.445422 0.0665258 0.2
0.445422 0.052 0.795 S2 1 0
0.0665258 0.036 0.1 0.15
R2 0.052 0.036
E2 0.795 0.1 0.1
0.0069
0.0018
0.0141
0.0037
0.0289
0.0079
0.0642
0.0193
0.132
0.0482
0.255
0.114
0.367
0.216
0.443
0.311
0.464
0.362
xM xN y1 F 0 0.4
0.2919116 0.92 0.08 M 0.5134807 0.1946077 -0.4 0.4
0.5134807 0.02 0.68 Smin 1 0
0.1946077 0.06 0.24
1 1 1 Rn 0.02 0.06
E1 0.68 0.24 0.2727273 0.0545455
F 0 0.4
E 0.68 0.24 -0.235294 0.4
P 1.9462069 -0.057931
R 0.02 0.06
S 1 0 -0.061224 0.0612245
P 1.9462069 -0.057931
M 0.5135135 0.1945946
-3.278E-05
1.5 2 2.5
xM xN y1 F 0 0.4
0.2421714 0.92 0.0615142 M 0.596381 0.1614476 -0.4 0.4
0.596381 0.02 0.75 S 1 0
0.1614476 0.06 0.1884858
1 1 1 Rn 0.02 0.06
M 0.596381 0.1614476 0.1760079 0.0564798
E1 0.75 0.1884858
F 0 0.4
E 0.75 0.1884858 -0.282019 0.4
P 1.5343478 -0.032715
R 0.02 0.06
S 1 0 -0.061224 0.0612245
P 1.5343478 -0.032715
xM xN y1 E1 0.75 0.1884858
0.6 -0.501633 0.05 R1 0.044 0.35 -0.228774 0.360066
0 1.5343478 0.792
0.4 -0.032715 0.158 R1 0.04 0.35
1 1 1 P 1.5343478 -0.032715
E2 0.792 0.158
R2 0.038 0.31
R2 0.038 0.31
0.8 1 1.2 1.4 1.6 1.8
P 1.5343478 -0.032715
E3 0.831 0.128
R3 0.035 0.268
R3 0.035 0.268
P 1.5343478 -0.032715
E4 0.868 0.1
R4 0.028 0.19
R4 0.028 0.19
P 1.5343478 -0.032715
E5 0.92 0.058
R5 0.024 0.145
R5 0.024 0.145
P 1.5343478 -0.032715
E6 0.95 0.036
R6 0.02 0.1
R6 0.02 0.1
P 1.5343478 -0.032715
E7 0.97 0.017
R7 0.02 0.06
0.4 0.6 0.8 1 1.2
0.6
0.5
0.4
0.3
0.2
0.4
0.3
0.2
0.1
0.0
0 0.2 0.4 0.6 0.8 1 1.2
00
00
00
00
00
00
00
0 0.2 0.4 0.6 0.8 1 1.2
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.3
0.25
0.2
0.15
0.1
0.05
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
0 0.2 0.4 0.6 0.8 1 1.2
0.40
0.35
0.30
0.25
0.20
0.25
0.20
0.15
0.10
0.05
0.00
0 0.1 0.2 0.3 0.4
1 1.2
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
Fase acuosa x Fase orgánica y
W ChlorB Pyr W ChlorB Pyr
A B C A B C
0.9992 0.0008 0 0.0005 0.9995 0 0.0008 0
0.9482 0.0016 0.0502 0.0067 0.8828 0.1105 0.9995 0
0.8871 0.0024 0.1105 0.0115 0.799 0.1895
0.8072 0.0038 0.189 0.0162 0.7428 0.241 0.0016 0.0502
0.7392 0.0058 0.255 0.0225 0.6915 0.286 0.8828 0.1105
0.6205 0.0185 0.361 0.0287 0.6558 0.3155
0.5087 0.0418 0.4495 0.0395 0.61 0.3505 0.0024 0.1105
0.379 0.089 0.532 0.064 0.53 0.406 0.799 0.1895
0.132 0.378 0.49 0.132 0.378 0.49
0.0038 0.189
0.7428 0.241
0.0058 0.255
0.6915 0.286
0.0185 0.361
0.6558 0.3155
0.0418 0.4495
0.61 0.3505
0.089 0.532
0.53 0.406
0.378 0.49
0.378 0.49
SELECTIVIDAD
F S M R E xF yS xM
A 1000 0 1000 926.33863 73.661373 0.5 0 0.0392157
B 0 23500 23500 0.946209 23497.978 0 1 0.9215686
C 1000 0 1000 18.92418 982.15164 0.5 0 0.0392157
2000 23500 25500 946.20902 24553.791 1
10.4
F S M R E xF yS xM
A 1000 0 1000 955.62779 44.372215 0.5 0 0.25
B 0 2000 2000 7.3604194 1980.1101 0 1 0.5
C 1000 0 1000 263.74836 748.78113 0.5 0 0.25
2000 2000 4000 1226.7366 2773.2634 1
R1 S M2 R2 E2 xF yS xM
A 955.62779 0 955.62779 941.18074 14.447049 0.779 0 0.3895
B 7.3604194 1226.7366 1234.097 2.0175364 1235.2227 0.006 1 0.503
C 263.74836 0 263.74836 65.569933 195.03517 0.215 0 0.1075
1226.7366 1226.7366 2453.4731 1008.7682 1444.7049 1
R1 S M2 R2 E2 xF yS xM
A 941.18074 0 941.18074 938.0025 3.17824 0.933 0 0.4665
B 2.0175364 1008.7682 1010.7857 0.9581231 1008.5615 0.002 1 0.501
C 65.569933 0 65.569933 19.162462 47.6736 0.065 0 0.0325
1008.7682 1008.7682 2017.5364 958.12308 1059.4133 1
10.5
F S M R E xF yS xM
A 4050 0 4050 3566.3389 483.66111 0.5 0 0.2810633
B 0 6309.5636 6309.5636 21.969233 6287.5945 0 1 0.4378733
C 4050 0 4050 73.230778 3976.7692 0.5 0 0.2810633
8100 6309.5636 14409.564 3661.5389 10748.025 1
F S M R E xF yS xM
A 4050 0 4050 3671.0953 378.90474 0.5 0 0.2472527
B 0 8280 8280 3.7498419 8272.7535 0 1 0.5054945
C 4050 0 4050 74.996839 3978.4998 0.5 0 0.2472527
8100 8280 16380 3749.8419 12630.158 1
F S M R E xF yS xM
A 4050 0 4050 3969.9392 80.060813 0.5 0 0.4009901
B 0 2000 2000 30.577195 3572.7138 0 1 0.1980198
C 4050 0 4050 1095.6828 1351.0262 0.5 0 0.4009901
8100 2000 10100 5096.1992 5003.8008 1
0.6
R1 S M2 R2 E2 xF yS xM
A 3969.9392 0 3969.9392 3909.9222 60.016994 0.779 0 0.3895
B 30.577195 5096.1992 5126.7764 8.3813981 5131.453 0.006 1 0.503
C 1095.6828 0 1095.6828 272.39544 810.22942 0.215 0 0.1075
5096.1992 5096.1992 10192.398 4190.699 6001.6994 0.5 1
R1 S M2 R2 E2 xF yS xM
A 3909.9222 0 3909.9222 3896.7189 13.203278 0.4 0.933 0 0.4665
B 8.3813981 4190.699 4199.0804 3.9803053 4189.8403 0.002 1 0.501
C 272.39544 0 272.39544 79.606107 198.04917 0.065 0 0.0325
4190.699 4190.699 8381.3981 3980.3053 4401.0927 1
0.3
0.2
0.1
0
0 0.2 0.4 0.6 0.8
-0.1
0.6
0.5
0.4
0.3
x y F 0 0.5
0.2
0.3
0.1
x y F 0 0.5 0.6
0.779 0.016 M 0.5 0.25
0.006 0.714 S 1 0
0.215 0.27 0.50 0 0.2 0
1 1 R 0.006 0.215
E 0.714 0.27
0.4
x y R1 0.006 0.215
0.933 0.01 M2 0.503 0.1075
0.002 0.855 S 1 0 0.3
0.065 0.135
1 1 R2 0.002 0.065
E2 0.855 0.135 0.2
x y R1 0.002 0.065
0.979 0.003 M2 0.501 0.0325 0.1
0.001 0.952 S 1 0
0.02 0.045
1 1 R2 0.001 0.02
0
E2 0.952 0.045 0 0.1 0.
x y F 0 0.5 8100
0.974 0.045 M 0.4378733 0.2810633 -6.86E-05
0.006 0.585 S 1 0 0
0.02 0.37 1
1 1 R 0.006 0.02
E 0.585 0.37 0.006
0.585
x y F 0 0.5
0.979 0.03 M 0.5054945 0.2472527 F
0.001 0.655 S 1 0 E
0.02 0.315 P
1 1 R 0.001 0.02 S
E 0.655 0.315 R
x y F 0 0.5 F
0.779 0.016 M 0.1980198 0.4009901 P
0.006 0.714 S 1 0
0.215 0.27 R1
1 1 R 0.006 0.215 E1
E 0.714 0.27
R1
x y R1 0.006 0.215 P
0.933 0.01 M2 0.503 0.1075
0.002 0.855 S 1 0 R2
0.065 0.135 E2
1 1 R2 0.002 0.065
E2 0.855 0.135 R2
P
x y R1 0.002 0.065
0.979 0.003 M2 0.501 0.0325 R3
0.001 0.952 S 1 0 E3
0.02 0.045
1 1 R2 0.001 0.02
E2 0.952 0.045
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.2 0.4 0.6 0.8 1 1.
0.2 0.4 0.6 0.8 1 1.2
0.5
0 -0.5 0.5
0.02
0.37 0.6044905 0.0163731
0.6
0 0.5
0.655 0.315 -0.282443 0.5
1.8296089 -0.01676 0.5
1 0
0.01 0.02 -0.020202 0.020202
0.4
0.3
0.5
0.4
0 0.5
1.8296089 -0.01676
0.3
0.025 0.362
0.655 0.315
0.01 0.12
0.79 0.2 0.1
0.01 0.12
1.8296089 -0.01676
0
0 0.2 0.4 0.6
0.01 0.02
0.945 0.05
1 1.2
1
0.6 0.8 1 1.2
Fase acuosa Fase orgánica
W IPE H Ac W IPE H Ac
A B C A B C
0.981 0.0121 0.0069 0.005 0.9932 0.0018 0.0121
0.971 0.0149 0.0141 0.007 0.9893 0.0037 0.9932
0.955 0.0161 0.0289 0.008 0.9841 0.0079
0.917 0.0188 0.0642 0.01 0.9707 0.0193 0.0149
0.844 0.023 0.133 0.019 0.9328 0.0482 0.9893
0.711 0.034 0.255 0.039 0.847 0.114
0.589 0.044 0.367 0.069 0.715 0.216 0.0161
0.451 0.106 0.443 0.108 0.581 0.311 0.9841
0.371 0.165 0.464 0.151 0.487 0.362
0.0188
0.9707
0.023
0.9328
0.034
0.847
0.044
0.715
0.106
0.581
0.165
0.487
Refinado Extracto
CH3Cl H2O H Ac CH3Cl H2O H Ac
A B C A B C
0.9901 0.0099 0.0000 0.0084 0.9916 0
0.9185 0.0138 0.0677 0.0121 0.7369 0.251
0.8 0.0228 0.1772 0.073 0.4858 0.4412
0.7013 0.0412 0.2575 0.1511 0.3471 0.5018
0.6715 0.052 0.2765 0.1833 0.3111 0.5056
0.5999 0.0793 0.3208 0.252 0.2539 0.4941
0.5581 0.0953 0.3466 0.2885 0.2328 0.4787
SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 60 60 0 1
C 300 0 300 0.3 0
1000 60 1060
F 0 0.3
M 0.056603774 0.2830189
S 1 0
SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 70000 70000 0 1
C 300 0 300 0.3 0
1000 70000 71000
F 0 0.3
M 0.985915493 0.0042254
S 1 0
CANTIDAD DE AGUA
F S M R E xF ySmin
A 700 0 700 0.7 0
B 0 742.3 742.3 0 1
C 300 0 300 0.3 0
1000 742.3 1742.3
0 0.96
F 0 0.3 1 0
S 1 0 -0.3 0.3
0.7369 0.251
M 0.42605 0.1721862 0.0138 0.0677 0.2534919
0.05
0.9
0.05
0.82
0.051
0.742
0.052
0.675
0.054
0.611
A B C A B C 0.056
0.95 0.05 0 0.1 0.9 0 0.558
0.925 0.05 0.025 0.101 0.82 0.079
0.899 0.051 0.05 0.108 0.742 0.15 0.059
0.873 0.052 0.075 0.115 0.675 0.21 0.503
0.846 0.054 0.1 0.127 0.611 0.262
0.819 0.056 0.125 0.142 0.558 0.3 0.062
0.791 0.059 0.15 0.159 0.503 0.338 0.457
0.763 0.062 0.175 0.178 0.457 0.365
0.734 0.066 0.2 0.196 0.414 0.39 0.066
0.675 0.075 0.25 0.246 0.329 0.425 0.414
0.611 0.089 0.3 0.28 0.275 0.445
0.544 0.106 0.35 0.333 0.217 0.45 0.075
0.466 0.134 0.4 0.405 0.165 0.43 0.329
0.434 0.15 0.416 0.434 0.15 0.416
0.089
0.275
0.106
0.217
0.134
0.165
0.15
0.15
F S1 M1 R1 E1 xF yS1
A 70 0 70 59.333911 10.666089 59.333911 0.7 0
B 0 50 50 4.1512266 45.801443 4.198557 0 1
C 30 0 30 8.0877345 21.959596 8.040404 0.3 0
100 50 150 71.572872 78.427128
0.829
0.0586613
R1 S2 M2 R2 E2 0.1123387 x1 yS2
A 59.333911 0 59.333911 52.627891 6.7060193 52.627891 0.829 0
B 4.1512266 50 54.151227 3.0007131 50.774146 3.3770804 0.058 1
C 8.0877345 0 8.0877345 2.0774168 6.386685 1.7010494 0.113 0
71.572872 50 121.57287 57.706021 63.86685
0.912
0.0585221
R2 S3 M3 R3 E3 0.0294779 x2 yS3
A 52.627891 0 52.627891 46.972725 5.6551666 0.912 0
B 3.0007131 50 53.000713 2.500012 50.319442 0.052 1
C 2.0774168 0 2.0774168 0.5275025 1.7311735 0.036 0
57.706021 50 107.70602 50.000239 57.705782
E1 E2 E3 E y
10.666089 6.7060193 5.6551666 23.027275 0.1151365
45.801443 50.774146 50.319442 146.89503 0.734476
21.959596 6.386685 1.7311735 30.077454 0.1503875
199.99976
fase acuosa fase organica 0.0081
A B C A B C 0.995
0.9919 0.0081 0 0.005 0.995 0
0.8297 0.0123 0.158 0.013 0.7 0.287 0.0123
0.7311 0.0129 0.256 0.022 0.557 0.421 0.7
0.6229 0.0171 0.36 0.044 0.429 0.527
0.456 0.051 0.493 0.103 0.284 0.613 0.0129
0.345 0.098 0.557 0.186 0.204 0.61 0.557
0.0171
0.429
0.051
0.284
0.098
0.204
SOLVENTE MÍNIMO
F Smin M Rn E1 xF Ysmin
Agua 899.748 0 899.748 1303.2268 4.6865614 895.06144 0.9 0
CLOROFOR 0 555 555 10.563135 194.4923 360.5077 0 1
ACETONA 99.972 0 99.972 6.6019597 35.14921 64.82279 0.1 0
999.72 555 1554.72 1320.3919 234.32807
12.505596
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
-2 -1 0 0.5 1 1.5
F Smin M Rn E1 xF Ysmin
Agua 899.748 0 899.748 883.03792 16.710079 883.03792 0.9 0
IPE 0 555 555 7.1573489 547.84265 7.1573489 0 1
H Acetico 99.972 0 99.972 4.4733431 95.498657 4.4733431 0.1 0
999.72 555 1554.72 894.66861 660.05139
12.337606
F Smin M Rn E1 xF Ysmin
Agua 180 0 180 168.23567 11.764331 168.23567 0.6 0
IPE 0 0 0 -104.3745 186.347 -186.347 0 1
H Acetico 120 0 120 0.8522577 37.175285 82.824715 0.4 0
300 0 300 64.713389 235.28661
2.3505508
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
-2 -1 0 0.5
0.0069
0.0018
0.0141
0.0037
0.0289
0.5
0.0079
0.45
0.0642 0.4
0.0193
0.35
0.133 0.3
0.0482 0.25
0.2
0.255
0.15
0.114
0.1
0.367 0.05
0.216
0
0 0.2 0.4 0.6
0.443
0.311
0.464
0.362
0.0099 0
0.9916 0
0.0138 0.0677
0.7369 0.251
0.0228 0.1772
0.4858 0.4412
0.6
0.0412 0.2575
0.3471 0.5018 0.5
xM 0.6000
x y
0.6603774 0.052 0.2765
0.4
0.05660380.5000 0.3111 0.5056
0.2830189
0.3
0.4000
0.2
0.3000
0.6000
0.4
0.5000
0.3
0.4000 0.0793 0.3208
0.2539 0.4941
0.2
0.3000
0.0953 0.3466
0.2328 0.4787 0.1
0.2000
0.0
0.1000 0 0.2
0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0.6000
xM x y
0.0098592 0.5000
0.9859155
0.0042254 0.4000
0.3000
0.2000
0.1000
0.0000
xM x y 0 0.2
0.4017678 0.4017678
0.42605 0.251 0.42602
0.1721862 0.1721942
0.0642018
0
0
0.025
0.079
0.05
0.15
0.075
0.21
0.1
0.262
0.125
0.3
0.15
0.338
0.175
0.365
0.2
0.39
0.25
0.425
0.3
0.445
0.35
0.45
0.4
0.43
0.416
0.416
0.5
0.45
xM1 x1 y1 F 0 0.3
0.4
0.4666667 0.829 0.136 M1 0.3333333 0.2
0.3333333 0.058 0.584 S1 1 0
0.35
0.2 0.113 0.28
1 1 1 R1 0.058 0.113
0.3
E1 0.584 0.28
0.25
0.2
0.15
0.3
0.25
xM2 x2 y2 R1 0.058 0.113
0.4880522 0.912 0.105 M2 0.445422 0.0665258 0.2
0.445422 0.052 0.795 S2 1 0
0.0665258 0.036 0.1 0.15
R2 0.052 0.036
E2 0.795 0.1 0.1
0
0
fase acuoosa fase organica
0.158 A B C A B C
0.287 99.19 0.81 0.5 99.5
82.97 1.23 1.3 70
0.256 73.11 1.29 2.2 55.7
0.421 62.29 1.71 4.4 42.9
45.6 5.1 10.30.7 28.4
0.36 34.5 9.8 18.6 20.4
0.6
0.527
0.5
0.493
0.613 0.4
0.557 0.3
0.61
0.2
0.1
0
0 0.2 0.4
xM xN y1 F 0 0.1
0.5787203 0.987 0.02 M 0.3569775 0.0643023 -0.1 0.1
0.3569775 0.008 0.83 Smin 1 0
0.0643023 0.005 0.15
1 1 1 Rn 0.008 0.005
E1 0.83 0.15 0.176399 0.0035888
F 0 0.1
E 0.83 0.15 0.060241 0.1
P -1.454623 0.0123721
R 0.008 0.005
S 1 0 -0.00504 0.0050403
P -1.454623 0.0123721
M 0.3488116 0.0651188
1 1.5
0.0081658
xM xN y1 F 0 0.1
0.5787203 0.987 0.0253163 M 0.3569775 0.0643023 -0.1 0.1
0.3569775 0.008 0.83 S 1 0
0.0643023 0.005 0.1446837
1 1 1 Rn 0.008 0.005
M 0.3569775 0.0643023 0.1699315 0.0036405
E1 0.83 0.1446837
F 0 0.1
E 0.83 0.1446837 0.0538357 0.1
P -1.612874 0.0131697
R 0.008 0.005
S 1 0 -0.00504 0.0050403
P -1.612874 0.0131697
xM xN y1 E1 0.83 0.1446837
0.6 2.5997042 0.05 R1 0.044 0.35 -0.261217 0.3614935
0 -1.612874 0.792
0.4 0.0131697 0.158 R1 0.04 0.35
1 1 1 P -1.612874 0.0131697
E2 0.792 0.158
R2 0.038 0.31
R2 0.038 0.31
P -1.612874 0.0131697
E3 0.831 0.128
R3 0.035 0.268
0.7
R3 0.035 0.268
0.6
P -1.612874 0.0131697
0.5
E4 0.868 0.1
R4 0.028 0.19
0.4
R4 0.028 0.19
0.3
P -1.612874 0.0131697
R5 0.024 0.145
0
0 0.5 1 1.5
P -1.612874 0.0131697
E6 0.95 0.036
R6 0.02 0.1
R6 0.02 0.1
P -1.612874 0.0131697
E7 0.97 0.017
R7 0.008 0.005
0.4 0.6 0.8 1 1.2
0.6
0.5
0.4
0.3
0.2
0.4
0.3
0.2
0.1
0.0
0 0.2 0.4 0.6 0.8 1 1.2
00
00
00
00
00
00
00
0 0.2 0.4 0.6 0.8 1 1.2
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.3
0.25
0.2
0.15
0.1
0.05
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.35
0.30
0.25
0.20
0.25
0.20
0.15
0.10
0.05
0.00
0 0.1 0.2 0.3 0.4
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1