Ou3 2018 I 3

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Recupera 99%

Balance
ARRIBA ABAJO
L2 7685 G2 5287.2 L1 8397.8 G1 6000
Ls 7685 Gs 5280 Ls 7685 Gs 5280
Lg2 0 Gg2 7.2 Lg1 712.8 Gg1 720
x2 0 y2 0.001362 x1 0.084879 y1 0.12
X2 0.000 Y2 0.001 X1 0.093 Y1 0.136

pendiente X1Y1 0.093 0.136


Ls/Gs 1.455492 X2Y2 0.000 0.0014
m 1.455492 intercept 0.001364
Curva de Equilibrio
Xeq Yeq Etapas N 24
0 0 0.093 0.136
0.02 0.0264 0.093 0.122433 Nreal 60
0.04 0.0528 0.083181 0.122433 1
0.06 0.0792 0.083 0.109799
0.08 0.1056 0.074501 0.109799 2
0.1 0.132 0.075 0.098341
0.250
0.12 0.1584 0.066628 0.098341 3
0.14 0.1848 0.067 0.08795
0.059489 0.08795 4
Linea de Operación 0.059 0.078526
Xop Yop 0.053014 0.078526 5 0.200
0 0.001364 0.053 0.069979
0.02 0.030473 0.047142 0.069979 6
0.04 0.059583 0.047 0.062228
0.06 0.088693 0.041817 0.062228 7
0.08 0.117803 0.042 0.055198 0.150
0.1 0.146913 0.036987 0.055198 8
0.12 0.176023 0.037 0.048823
0.14 0.205133 0.032607 0.048823 9
0.033 0.043042
0.100
0.028635 0.043042 10
0.029 0.037798
0.025032 0.037798 11
0.025 0.033043
0.021765 0.033043 12 0.050
0.022 0.02873
0.018802 0.02873 13
0.019 0.024819
0.016115 0.024819 14
0.016 0.021272 0.000
0.000 0.020 0.040 0.060
0.000
0.000 0.020 0.040 0.060
0.013678 0.021272 15
0.014 0.018055
0.011468 0.018055 16
0.011 0.015137
0.009463 0.015137 17
0.009 0.012492
0.007646 0.012492 18
0.008 0.010092
0.005997 0.010092 19
0.006 0.007916
0.004502 0.007916 20
0.005 0.005942
0.003146 0.005942 21
0.003 0.004152
0.001916 0.004152 22
0.002 0.002529
0.000801 0.002529 23
0.001 0.001057
-0.00021 0.001057 24
0.000 -0.00028
-0.00113 -0.00028 25
N
Eq
Op

0 0.020 0.040 0.060 0.080 0.100 0.120 0.140 0.160


0 0.020 0.040 0.060 0.080 0.100 0.120 0.140 0.160
La distribución de equilibrio del soluto C entre dos solventes A y B esta dada por Y=3.75X
Donde X e Y son las concentraciones de C en A y B respectivamente (en masa). A y B son practicamente inmiscib
Se requiere calcular la cantidad de B requerida para separar el 95% de C de una solución de 1000 kg al 15% de C
en A de acuerdo a los siguientes esquemas
a.- Una etapa ideal
b.- 3 etapas ideales en fujo cruzado, la cantidad de solvente en cada etapa sera igual
c.- 3 etapas en flujo paralelo
d.- 3 etapas en flujo en contracorriente

BALANCE Recupera 95%


L0 1000 L1 857.5
Lg0 150 Lg1 7.5
Ls 850 Ls 850
x0 0.15 x1 0.0087
X0 0.1765 X1 0.0088
X1Y1 0.0088
G01 G1 4449.17 X0Y01 0.1765
Gg01 0 Gg1 142.5
Gs Gs 0 Ls/Gs
y01 0 y1 0.03202847
Y01 0.0000 Y1 0.0331

3 ETAPAS
L0 1000 L1 905.26275 L2
Lg0 150 Lg1 55.26275 Lg2
Ls 850 Ls 850 Ls
x0 0.15 x1 0.061046089 x2
X0 0.1765 X1 0.065015 X2

G01 388.5757647 G02 388.5757647 G03


Gg01 0 Gg02 0 Gg03
Gs 388.5757647 Gs 388.5757647 Gs
y01 0 y02 0 y03
Y01 0.0000 Y02 0.0000 Y03

G1 483.3129647 G2 423.4761827 G3
Gg1 94.73720003 Gg2 34.90041803 Gg3
Gs 388.5757647 Gs 388.5757647 Gs
y1 0.196016261 y2 0.082414123 y3
Y1 0.24380625 Y2 0.08981625 Y3

L1 905.26275 L2 870.35835 L3
Lg1 55.26275 Lg2 20.35835 Lg3
Ls 850 Ls 850 Ls
x1 0.061046089 x2 0.023390768 x3
X1 0.0650 X2 0.0240 X3

3 ETAPAS EN CONTRACORRIENTE

Benceno-Aire Absorbente HC
y0 6% M 250
Q 500 m3/h
T 20 °C Recuperación 95%
P 1 atm
Psat 76 mmHg

CURVA DE EQUILIBRIO Ki 0.1


0.1
x y X Y
0 0 0 0
0.1 0.01 0.111111111 0.01010101
0.2 0.02 0.25 0.020408163
0.3 0.03 0.428571429 0.030927835
0.4 0.04 0.666666667 0.041666667
0.5 0.05 1 0.052631579
0.6 0.06 1.5 0.063829787
0.7 0.07 2.333333333 0.075268817

FLUJO DE GAS
G 20800.13978

CANTIDAD MINIMA DE ABSORBENTE

LN+1 GN 19614.53181 L1 G0 20800.13978


Ls Gs 19552.13139 Ls Gs 19552.13139
LgN+1 0 GgN 62.40041933 Lg1 1185.607967 Gg0 1248.008387
xN+1 0 yN 0.003181336 x1 y0 0.06
XN+1 0 YN 0.003191489 X1 Y0 0.063829787

ETAPAS TEORICAS

LN+1 2231.732644 GN 19614.53181 L1 3417.340612 G0 20800.13978


Ls 2231.732644 Gs 19552.13139 Ls 2231.732644 Gs 19552.13139
LgN+1 0 GgN 62.40041933 Lg1 1185.607967 Gg0 1248.008387
xN+1 0 yN 0.003181336 x1 0.346938776 y0 0.06
XN+1 0 YN 0.003191489 X1 0.53125 Y0 0.063829787

N
0.53125 0.063829787
0.53125 0.035940803
0.286915591 0.035940803 1
0.286915591 0.02280322
0.171817682 0.02280322 2
0.171817682 0.014880681
0.102408594 0.014880681 3
0.102408594 0.009376636
0.054187853 0.009376636 4
0.054187853 0.005166805
0.017305672 0.005166805 5
0.017305672 0.001704027
-0.01303161 0.001704027 6

CURVA DE EQUILIBRIO

0.001
X Y
0 0
0.001 0.0023
0.002 0.0046
0.003 0.0069
0.004 0.0092
0.005 0.0115
0.006 0.0138
0.007 0.0161

RELACION MOLAR 3 gSO2 0.046875 X 0.0084375


100 gH2O 5.555555556

L0 100.84375 G1 LN 100.0375821 GN+1 60


Ls 100 Gs 60 Ls 100 Gs 60
Lg0 0.84375 Gg1 LgN 0.037582056 GgN+1 0
x0 0.008366904 y1 xN 0.000375679 yN+1 0
X0 0.0084375 Y1 XN YN+1 0

X0,Y1 0.0084375 0.013436132


N XN,YN+1 0.000375821 0
0.0084375 0.013436132
0.005841797 0.013436132 1.666666667 -0.00062637
0.005841797 0.00910996
0.003960852 0.00910996
0.003960852 0.005975053 xN 0.000375679
0.002597849 0.005975053
0.002597849 0.003703381 Desorbido 95.55%
0.001610166 0.003703381
0.001610166 0.002057242
0.000894453 0.002057242
0.000894453 0.000864387
0.000375821 0.000864387
0.000375821 6.28837E-18
n practicamente inmiscibles CURVA DE EQUILIBRIO
n de 1000 kg al 15% de C X Y
0 0
0.05 0.1875
0.1 0.375
0.15 0.5625
0.2 0.75
0.8

0.7

0.6

0.5

0.4

0.0331 0.3

0.0000 0.2

0.1
-0.19736842
0
0 0.05 0.1 0.15 0.2 0.25

870.35835
20.35835 0.8
850
0.7
0.023390768 X0Y01 0.1765 0.0000
0.6
0.023951 X1Y1 0.065015 0.24380625
-2.18747444 0.5
388.5757647 X1Y02 0.065015 0.0000 0.4
0 X2Y2 0.023951 0.08981625
0.3
388.5757647 -2.18722604
0 X2Y03 0.023951 0.0000 0.2
0.0000 X3Y3 0.008823529 0.033088235 0.1
-2.18729464
0
401.433051 0 0.05 0.1
12.85728633
388.5757647
0.03202847 "=-Ls/Gs -2.18747559
0.033088235

857.5
7.5
0.8
850
0.008746356 0.7

0.6

0.5
0.8

0.7
0.008823529
0.6

0.5
X1Y0 0.008823529 0
0.4
X4Y3 0.1765 0.277650318
1.656159789 -0.01461317 0.3
Ls/Gs
X Y Ls/Gs 0.2
0.1765 0.277650318 850
0.074040085 0.277650318 Gs 0.1
0.074040085 0.108009036 513.2355015
0
0.02880241 0.108009036 0.0000 0.0500
0.02880241 0.033088218
-0.1
0.008823525 0.033088218
0.008823525 -7.55038E-09

0.08
Y0 0 0.063829787
1.8 0.063829787 0.07
0.06
X1,Y0 0.85 0.063829787 0.05
0.04

0.03
0.02
0.07

0.06
0.05
XN+1,YN 0 0.003191489 0.04

0.03
Lsmin/Gs 0.071339174
0.02

Lsmin 1394.832903 0.01

0
0 0.5 1 1.5

0.08
0.07
X1,Y0 0.53125 0.063829787
0.06
XN+1,YN 0 0.003191489
0.05

PENDIENTE INTERCELPTO 0.04


0.114142678 0.003191489 0.03
0.02

0.01
0
-0.5 0 0.5 1

Y
0.018
0.016
0.014
0.012
0.01
0.008
0.006
0.004
0.002
0
0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.00
0.018

0.016

0.014

0.012

0.01

0.008

0.006

0.004

0.002

0
0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009
La distribución de equilibri
Donde X e Y son las concen
Se requiere calcular la can
en A de acuerdo a los sigui

Arriba
L1
Ls/Gs 1.508823529 Ls
Lg1
x1
X1

0.05 0.1 0.15 0.2 0.25

0.8

0.7

0.6

0.5
0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0.0000 0.0500 0.1000 0.1500 0.2000 0.2500

-0.1

0.07

0.06

0.05

0.04

0.03

0.02

0.01

0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6
1 1.5 2 2.5

1 1.5 2 2.5

0.006 0.007 0.008


distribución de equilibrio del soluto C entre dos solventes A y B esta dada por Y=3.75X
onde X e Y son las concentraciones de C en A y B respectivamente (en masa). A y B son practicamente inmiscibles
e requiere calcular la cantidad de B requerida para separar el 95% de C de una solución de 1000 kg al 15% de C
A de acuerdo a los siguientes esquemas

Abajo
1282.5 G1 857.5 L2 1425 G2 1000
1282.5 Gs 850 Ls 1282.5 Gs 850
0 Gg1 7.5 Lg2 142.5 Gg2 150
0 y1 0.008746356 x2 0.1 y2 0.15
0 Y1 0.008823529 X2 0.111111111 Y2 0.176470588
4 1.6
ARRIBA ABAJO
L0 4000 G1 1503.8 LN 3996.2 GN+1 1500
Ls 3996 Gs 1500 Ls 3996 Gs 1500
Lg0 4 Gg1 3.80019 LgN 0.19981 GgN+1 0
x0 0.001 y1 0.002527 xN 5E-05 yN+1 0
X0 0.001001 Y1 0.002533 XN 0.000050 YN+1 0
Chart T
EQ 5E-05
X Y X0Y1 0.001001 0.002533 0.003

0 0 XNYN+1 0.000050 0
5E-05 0.000218 2.664 -0.00013 0.0025
0.0001 0.000435 0.001001 0.002533
0.00015 0.000653 0.000582 0.002533
0.002
0.0002 0.00087 Nr 20 0.000582 0.001418
0.00025 0.001088 efic 50% 0.000326 0.001418
0.0015
0.0003 0.001305 0.000326 0.000735
0.00035 0.001523 N 10 0.000169 0.000735
0.0004 0.00174 0.000169 0.000317 0.001
0.00045 0.001958 7.29E-05 0.000317
0.0005 0.002175 7.29E-05 6.1E-05 0.0005
0.00055 0.002393 RPTA SI 1.4E-05 6.1E-05
0.0006 0.00261
0
0 0.0002 0.0004 0.00

Se desea absorber H2S en agua a 15°C. El agua que se emplea es pura. El gas alimentado tiene una fracción molar de H2S igual a 0.0012 y
contaminante con el agua. El flujo total del gas es de 10 kmol/h. El flujo total de líquido es de 2000 kmol/h. La presión total es
constantes
a. Calcular las composiciones de los gases de salida
b. Calcular el número de etapas de equilibrio
c. Si L/V = M × (L/V)min, encontrar el multiplicador M (M > 1).
d. Por qué esta operación no es práctica? ¿Qué debería hacer un ingeniero para desarrollar un proceso práctico?
T (°C) 0 5 10 15 20 25 30 35 40
H (atm) 268 315 367 423 483 545 609 676 745
T (°C) 45 50 60 70 80 90 100
H (atm) 814 884 1030 1190 1350 1440 1480

m 0.00591
0.9
x y X Y
0 0 0 0
0.9 0.005319 9 0.005348
0 0
0 0
0 0
0 0
0 0 X0Y1
XNYN+1
ARRIBA ABAJO
L0 2000 G1 9.98836 LN 2000.012 GN+1 10
Ls 2000 Gs 9.988 Ls 2000 Gs 9.988
Lg0 0 Gg1 0.00036 LgN 0.01164 GgN+1 0.012
x0 0 y1 3.6E-05 xN 5.82E-06 yN+1 0.0012
X0 0 Y1 3.6E-05 XN 0.000006 YN+1 0.001201

Two flash distillation chambers are hooked together as shown in the diagram. Both are at 1 atm
pressure. The feed to the first drum is a binary mixture of methanol and water that is 55 mol%
methanol. Feed flow rate is 10,000 kmol/h. The second flash drum operates with (V/F)2 = 0.7 and
the liquid product composition is 25 mol% methanol. Equilibrium data are given in Table 2-7.
a. What is the fraction vaporized in the first flash drum?
b. What are y1, y2, x1, T1, and T2?

x1 0 2 4 6 8 10 15 20 30
y1 0 13.4 23 30.4 36.5 41.8 51.7 57.9 66.5
T 100 96.4 93.5 91.2 89.3 87.7 84.4 81.7 78

x1 0 0.02 0.04 0.06 0.08 0.1 0.15 0.2 0.3


y1 0 0.134 0.23 0.304 0.365 0.418 0.517 0.579 0.665
T 100 96.4 93.5 91.2 89.3 87.7 84.4 81.7 78

T2
79.7
Comp z2 x2 y2
MetOH 0.5125 0.25 0.625
x2 0.25 100 H2O 0.4875 0.75 0.375
0.25 0

T2 0 79.7
1 79.7 II SEPARADOR
105
y2 0.625 100
100
0.625 0
95

90 xT
yT
85 x2
II SEPARADOR
105

100

95
z2 0.5125
90 xT
a 0.1125 yT
b 0.2625 85 x2
T2
80 y2
L/V 0.428571 Calc
75
0.428571 Dato
70

65

60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Chart Title
0.003

0.0025

0.002

0.0015

0.001

0.0005

0
0 0.0002 0.0004 0.0006 0.0008 0.001 0.0012

cción molar de H2S igual a 0.0012 y se desea remover el 97% de este


2000 kmol/h. La presión total es de 2.5 atm. Los flujos de gas y liquido son
0.006

0.005

0.004

0.003

0.002

0.001

0
0 1 2 3 4 5 6 7 8 9 10
0.002

0.001

0
0 1 2 3 4 5 6 7 8 9 10

0 3.6E-05
0.000006 0.001201

AQE

2.D2. Hint: Work backwards (start with stage 2).


a. (V/F)1 = 0.148
b. x1 = 0.51, y1 = 0.78, x2 = 0.25, y2 = 0.62

40 50 60 70 80 90 95 100
72.9 77.9 82.5 87 91.5 95.8 97.9 100
75.3 73.1 71.2 69.3 67.6 66 65 64.5

0.4 0.5 0.6 0.7 0.8 0.9 0.95 1


0.729 0.779 0.825 0.87 0.915 0.958 0.979 1
75.3 73.1 71.2 69.3 67.6 66 65 64.5

z1 0.55 100 T2
0.55 0 72.8
Comp z1 x1 y1
x1 0.5125 100 MetOH 0.55 0.5125 0.785
0.5125 0 H2O 0.45 0.4875 0.215

T1 0 72.8
1 72.8
I SEPARADOR
y1 0.785 100 105
0.785 0
100

95

xT 90
yT
x2 85
I SEPARADOR
105

100

z2 0.55 95
a 0.235
xT 90
yT
b 0.0375
x2 85
T2 L/V 6.266667
y2 80

Y 0.137615 75

70

65

60
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
8 9 10
8 9 10

I SEPARADOR

xT
yT
z1
I SEPARADOR

xT
yT
z1
x1
T1
y1

4 0.5 0.6 0.7 0.8 0.9 1


Se va a trabajar con una mezcla Benceno tolueno a 1 atm de presión, considerando mezcla ideal
a.- Graficar los diagramas Txy - xy
b.- Calcular la volatilidad relativa y graficar el diagrama xy a volatilidad constante
c.- Graficar xy considerando volatilidad constante
d.- repetir los calculos para P=10 atm
e.- repetir los calculos para P= 0.2 atm

DATOS
A B C
Bz 15.9008 2788.51 -52.36
Tol 16.0137 3096.52 -53.67

P
760
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 110.6259747 1784.46236 760 2.347976789 1 0.0000
0.1 0.9 106.136844 1589.75991 667.8044545 2.091789355 0.878690072 0.2092
0.2 0.8 102.1037277 1429.100808 592.724798 1.8803958 0.77990105 0.3761
0.3 0.7 98.45794887 1294.886718 530.7628352 1.703798313 0.698372152 0.5111
0.4 0.6 95.1432433 1181.495952 479.0026988 1.554599937 0.630266709 0.6218
0.5 0.5 92.11336983 1084.713431 435.286569 1.427254514 0.572745486 0.7136
0.6 0.4 89.3301428 1001.336869 397.9946967 1.317548512 0.523677233 0.7905
0.7 0.3 86.76184944 928.9023351 365.8945515 1.222239915 0.481440199 0.8556
0.8 0.2 84.38199112 865.4909764 338.0360942 1.138803916 0.444784335 0.9110
0.9 0.1 82.168286 809.5912965 313.6781145 1.065251706 0.412734361 0.9587
1 0 80.10188524 760 292.2358044 1 0.384520795 1.0000

P
152
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 62.28258999 424.0852677 152 2.790034656 1 0.0000
0.1 0.9 58.01497056 364.7269696 128.3636338 2.399519537 0.844497591 0.2400
0.2 0.8 54.30149852 318.6637037 110.3340741 2.096471735 0.725882066 0.4193
0.3 0.7 51.03337558 282.1005516 96.24262076 1.855924681 0.633175137 0.5568
0.4 0.6 48.12813664 252.5062921 84.99580527 1.661225606 0.559182929 0.6645
0.5 0.5 45.52247455 228.1446695 75.85533053 1.500951773 0.499048227 0.7505
0.6 0.4 43.16714216 207.7939819 68.30902714 1.36706567 0.449401494 0.8202
0.7 0.3 41.02332093 190.5745071 61.99281686 1.253779652 0.407847479 0.8776
0.8 0.2 39.06002355 175.8394595 56.64216184 1.15683855 0.372645802 0.9255
0.9 0.1 37.25221882 163.1043294 52.06103556 1.073054799 0.342506813 0.9657
1 0 35.57946245 152 48.1015924 1 0.316457845 1.0000
P
7600
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 218.0177454 13989.43978 7600 1.840715761 1 0.0000
0.1 0.9 212.9955118 12997.14241 7000.31751 1.710150317 0.921094409 0.1710
0.2 0.8 208.3013759 12114.53056 6471.36736 1.594017179 0.851495705 0.3188
0.3 0.7 203.9061521 11326.5613 6002.9023 1.490337013 0.789855566 0.4471
0.4 0.6 199.7833152 10620.49622 5586.335852 1.397433713 0.735044191 0.5590
0.5 0.5 195.9088675 9985.538389 5214.461611 1.31388663 0.68611337 0.6569
0.6 0.4 192.2611641 9412.521427 4881.21786 1.238489661 0.642265508 0.7431
0.7 0.3 188.8207186 8893.64633 4581.491896 1.170216622 0.602827881 0.8192
0.8 0.2 185.5700049 8422.260429 4310.958283 1.108192162 0.567231353 0.8866
0.9 0.1 182.4932644 7992.672712 4065.945588 1.051667462 0.534992841 0.9465
1 0 179.576324 7599.999963 3843.326758 1 0.505700889 1.0000

Se dispone de 200 kmol/h de una mezcla de 45% de benceno y el resto tolueno, que se introduce a un separador flash a 1 atm
se desea obtener una corriente de vapor de 60%. Considerese sistema ideal
a.- Determine la temperatura de operación
b.- Realice el balance en el separador

DATOS
F 200 xy 0.322 0
zi 0.45 0.322 0.537
Y 0.6 0 0.537

Diagrama xy
F 200 BALANCE z x y
V 120 1 0.45 0.322 0.537
L 80 2 0.55 0.678 0.463
m=-L/V -0.66666667
BALANCE F L V
z 0.45 0.45 1 90 25.76 64.44
0.45 0 2 110 54.24 55.56
200 80 120
xy 0 0.75
z 0.45 0.45

Diagrama Txy

(L/V) 0.666666667
z 0.45 110
0.45 0

T 0 97.7
1 97.7

xy 0.322 0
0.322 97.7

0.536 97.7
0.536 0

L/V 0.671875

METODP ANALITICO
P Y T
760 0.6 97.73977856
Comp zi Ki f() x y F L
Bz 0.45 1.670572905 -0.21518106 0.3209 0.5361 90.00 25.67
Tol 0.55 0.683141923 0.215181056 0.6791 0.4639 110.00 54.33
2.83107E-09 1 1 200 80

Determinar la fraccion vaporizada, las composiciones de las corrientes y sus flujos, de la mezcla anterior, si la temperatura de

Txy
z 0.45
T 0 96
1 96

x 0.374 0 BALANCE z x y
0.374 96 1 0.45 0.374 0.595
2 0.55 0.626 0.405
y 0.595 0
0.595 96 BALANCE F L V
1 90 49.08 40.92
L/V 1.907894737 2 110 82.14 27.86
200 131.22 68.78
F/V 2.907894737
F 200
V 68.77828054
L 131.2217195

ANALITICO
P Y T
760 0.347205584 96
Comp zi Ki f() x y F L
Bz 0.45 1.592155589 -0.22102694 0.3733 0.5943 90.00 48.73
Tol 0.55 0.647339715 0.221026937 0.6267 0.4057 110.00 81.83
2.14374E-05 1 1 200 130.56

Determinar la temperatura y la fracción vaporizada, si se desea tener una composición de 0.55 de Benceno en la fase vapor

P Y T
760 0.539730786 97.33479371
98
Comp zi Ki f() x y F L
Bz 0.45 1.652058443 -0.21704156 0.3329 0.5499 90.00 30.64 f(x) = 6
97.5 R² = 0.9
Tol 0.55 0.674670602 0.21704156 0.6671 0.4501 110.00 61.41
1.79665E-05 1 1 200 92.05
97

96.5

96

95.5

95
0.3 0.35

We are feeding 100 kmol/h of a 45 mol% propane, 55 mol% n-pentane feed to a flash distillation
system. We measure the outlet vapor and liquid mole fractions leaving the flash drum, which is an
equilibrium stage, and obtain, ypropane = 0.8, xpropane = 0.2162.
Find: (a) L and V. (b) xpentane and ypentane. (c) Tdrum and pdrum. P 160
Use the DePriester charts. Note: This is not trial and error. T 10

Comp zi xi yi F L V
C3 0.45 0.2162 0.8 45 12.9616307 32.0383693
nC5 0.55 0.7838 0.2 55 46.99040767 8.009592326
100 59.95203837 40.04796163

Y
0.400479616 10
50
T P Y 509.67
505 21.5105073 0.396880093
Comp z K f x y
C3 0.45 3.700255755 -0.58653673 0.217215249 0.803751976
nC4 0.55 0.250704966 0.586536726
-4.8108E-06

We have a flash drum separating 50 kmol/h of a mixture of ethane, isobutane, and n-butane. The
ratio of isobutane to n-butane is held constant at 0.8 (that is, ziC4/znC4 = 0.8). The mole fractions of
all three components in the feed can change. The flash drum operates at a pressure of 100 kPa and
a temperature of 20°C. If the drum is operating at V/F = 0.4, what must the mole fractions of all
three components in the feed be? Use Figure 2-11 or 2-12 or Eq. (2-30).
three components in the feed be? Use Figure 2-11 or 2-12 or Eq. (2-30).
20 1000
68

T+P2A204:R22P Y
527.67 145.0382433 0.4
Comp z K f
C2 0.489297658 2.804997396 -0.51288126
iC4 0.22697891 0.348722246 0.199903359
nC4 0.283723637 0.234613411 0.312977903
1.000000204 0
0.8
ziC4/znC4 0.8
Compuesto A B C
BENZENE 15.9008 2788.51 -52.36
TOLUENE 16.0137 3096.52 -53.67

120 1.0 1.0 1.0

0.9 0.9 0.9

110 0.8
0.8 0.8
y2 Sy a12 y1*
0.7 0.7 0.7
1 1 2.35 0.0000
100
0.790821064 1 2.38 0.2164 0.6
0.6 0.6
0.62392084 1 2.41 0.3832
0.488860506 1 2.44 0.5157 90 0.5 0.5 0.5
0.378160025 1 2.47 0.6236
0.286372743 1 2.49 0.7131 0.4 0.4 0.4

0.209470893 1 2.52 0.7885 80


0.3 0.3 0.3
0.14443206 1 2.54 0.8529
0.088956867 1 2.56 0.9086 0.2 0.2
0.2
0.041273436 0.999999971 2.58 0.9572 70
0 1 2.60 1.0000 0.1 0.1 0.1
11 2.48
60 0.0 0.0 0.0
0 0.1 0 0.20.10 0.1
0.30.2 0.20
0.40.3 0.1 0.60.5
0.3
0.50.4 0.0
Chart Titl
70 1.0 1.0 1.0 3.5
y2 Sy a12 y1* 250
1 1 2.79 0.0000 0.9 0.9 0.9
60 3.0
0.760047832 0.999999785 2.84 0.2497
0.8 0.8 0.8
0.580705653 1 2.89 0.4281
0.443222596 1 2.93 0.5621 50 0.7 0.7 0.7 2.5
0.335509758 1 2.97 0.6663 200
0.249524114 1 3.01 0.7497 0.6 0.6 0.6
40 2.0
0.179760598 1 3.04 0.8179
0.122354244 1 3.07 0.8748 0.5 0.5 0.5

0.07452916 1 3.10 0.9230 30 1.5


0.4 0.4 0.4
0.034250681 1 3.13 0.9642 150
0 1 3.16 1.0000 20 0.3 0.3 0.3
1.0
10.99999979 2.99
0.2 0.2 0.2
10 0.5
0.1 0.1 0.1
100
0 0.0 0.0 0.0 0.0
0 0.1 0 0.2 0.1 0 0.3 0.2 0.1 0.4
0 0.3 0.2 0.5
0.1 0.4 00.3 0.6 0.4 0.7
0.2 0.50.1 0.
20 0.3 0.3 0.3
1.0

0.2 0.2 0.2


10 0.5
0.1 0.1 0.1
100
0 0.0 0.0 0.0 0.0
0 0.1 0 0.2 0.1 0 0.3 0.2 0.1 0.4
0 0.3 0.2 0.5
0.1 0.4 00.3 0.6 0.4 0.7
y2 Sy a12 y1* 0.2 0.50.1 0.

1 1 1.84 0.0000
0.828984968 1 1.86 0.1753
0.681196564 1 1.87 0.3235 Chart Title
0.552898896 1 1.89 0.4505 50
1.0
0.441026515 1 1.90 0.5605
0.343056685 1 1.91 0.6567 0.9
0.256906203 1 1.93 0.7415 Chart Title
0.8
0.180848364 1 1.94 0.8169 3.50
0.113446271 1 1.95 0.8844 0.7 0
3.00 0 0.2 0.4 0.6
0.053499284 1 1.97 0.9451 0.6
2.50
0 1 1.98 1.0000 Column C Column C
11 1.91 2.00 0.5 Column C P=7600

1.50 0.4

1.00 0.3

0.50 0.2
separador flash a 1 atm de presión 0.00 0.1
0 2 4 6 8
0.0
0 0.1 0.2Column0.3
K Column 0.5
0.4 K Col
0.6

P=152 P=760 P=7600

1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

120

110
120

110

100

90

80

70

60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

V
64.33
55.67
120

or, si la temperatura de operación es 96°C


100

99

98

97

96

95

94

93

92

91

90
0.3 0.35 0.4 0.45 0.5 0.55 0.6
92

91

90
0.3 0.35 0.4 0.45 0.5 0.55 0.6
V
41.27
28.17
69.44

nceno en la fase vapor

Chart Title 0.34 95.94933978 0.595934634


0.35 96.01964077 0.593644965
98
V y* error 0.36 96.08989585 0.591351886
f(x)59.36
= 6.89471851979729 x + 93.608512891223
0.55 -0.0001 0.4 96.37027612 0.582151448
97.5 R² = 0.999952061931255
48.59 0.5 97.0636785 0.559058985
97 107.95 0.6 97.73977856 0.536072422
0.539730786 97.33028185 0.55
96.5

96

95.5
Chart Title
95 0.62
0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65

0.6
f(x) = − 0.230349903322963 x + 0.674267765678312
0.58 R² = 0.999999224828584

0.56

0.54

0.52

0.5
0.3 0.35 0.4 0.45 0.5 0.55 0.6

kPa
°C

Ki
3.700277521
0.255167134

aT1 aT2 aT6 aP1 aP2


C1
C2 -687248.25 0 7.90694 -0.886 49.02654
C3 -970688.563 0 7.156059 -0.76984 0
iC4 -1166846 0 7.72668 -0.92213 0
nC4 -1280557 0 7.94986 -0.96455 0
iC5 -1524891 0 7.33129 -0.89143 0
P (atm)
2.36 1
3.67

1.0 3.0

0.9
2.5
0.8

0.7
2.0
0.6

0.5 1.5

0.4
1.0
0.3

0.2
0.5
0.1

0.0 0.0
0.20
0.40.3 0.1 0.60.5
0.3
0.50.4 0.2
0
0.4 0.1
0.3 0.80.7
0.5
0.70.6 0.2
0.4 0.9 0.8
0.6 0.3
0.5
0.7 0.4
0.6
0.8
1 0.9 0.5
0.7
10.9 0.6
10.8 0.7
0.9 0.8
1 0.9 1

Chart Title
3.5

3.0

2.5

2.0

1.5

1.0

0.5

0.0
0.2 0.5
0.1 0.4 00.3 0.6 0.4 0.7
0.2 0.50.1 0.5 0.8
0.30.60.2 0.6 0.9
0.4 0.70.3 0.5 0.80.4 1 0.90.5
0.7 0.6 0.8 0.7 1 0.6
0.9 0.8 0.71 0.9 0.8 1 0.9 1
1.0

0.5

0.0
0.2 0.5
0.1 0.4 00.3 0.6 0.4 0.7
0.2 0.50.1 0.5 0.8
0.30.60.2 0.6 0.9
0.4 0.70.3 0.5 0.80.4 1 0.90.5
0.7 0.6 0.8 0.7 1 0.6
0.9 0.8 0.71 0.9 0.8 1 0.9 1

Chart Title

Chart Title

0.4 0.6 0.8 1 1.2

umn C Column C Column H P=760


umn C P=7600 Column C

6 8 10 12

Column 0.5
0.4 K Column K0.7
0.6 0.8 0.9 1

P=760 P=7600 Column A


0.8 0.9 1

0.6
0.6

8312

0.55 0.6 0.65


aP3

0
6.90224
0
0
0
Una mezcla ideal, benceno tolueno que tiene una composición de 45% de benceno, se alimenta a una columna de destilación
200 mol/h, si se desea obtener un destilado con 97% de benceno y unos fondos con 2.5% máximo de benceno, si la alimentac
en su punto de burbuja y la volatilidad es de 2.5. Calcular
a.- Balances externos CURVA alfa 2.5
b.- Ubicar xD, z, xB x y
c.- Nmin 0 0
d.- Rmin 0.1 0.217391304
e.- R si R/Rmin=1.4 0.2 0.384615385
f.- Balances Internos 0.3 0.517241379
g.- Lineas de operación 0.4 0.625
h.- N 0.5 0.714285714
i.- Nf 0.6 0.789473684
0.7 0.853658537
0.8 0.909090909
0.9 0.957446809
1 1
BALANCE
Comp z xD xB F D B
Bz 0.36 0.85 0.25 36.00 15.58 20.42
Tol 0.64 0.15 0.75 64.00 2.75 61.25
100 18.33 81.67

xD 0.85 0
0.85 0.85

z 0.36 0
0.36 0.36

xB 0.25 0
0.25 0.25
Nmin
0.85 0.85
0.693877551 0.85
0.693877551 0.693877551 1
0.475524476 0.693877551
0.475524476 0.475524476 1
0.266144814 0.475524476
0.266144814 0.266144814 1
0.126688402 0.266144814
0.126688402 0.126688402 1
0.054844238 0.126688402
0.054844238 0.054844238 1
0.022684152 0.054844238
0.022684152 0.022684152 1
0.009198862 0.022684152
0.009198862 0.009198862 1
0.003699966 0.009198862
0.003699966 0.003699966 1

Rmin
LOF 0.36 0.36
0.36 1

LORmin 1

Rmin xD 0.9

1.4 0.85 0.8

b m 0.7

0.354166667 0.583333333 0.6

LOR 0.5

0.85 0.85 R/Rmin 1.4 0.4


0 0.354166667
0.3

R 1.96 0.2

0.1

0
F D B q R 0 0.1 0.2 0.3

100.00 18.33 81.67 1 1.96

BALANCES INTERNOS
Ln Vn Lm Vm Vn
35.93 54.27 135.93 54.27 54.26666667

LINEAS DE OPERACIÓN
z xD xB
0.36 0.85 0.25 LOR 0.85
0
mLOR bLOR
0.662162162 0.287162162 LOS 0.25
alfa 0.36
mLOS bLOS
2.504914005 -0.3762285 2.5

N 15
0.85 0.85 Nf
0.693877551 0.85 7
0.693877551 0.746621622 1
0.541003672 0.746621622
0.541003672 0.645394323 1
0.421300826 0.645394323
0.421300826 0.566131628 1
0.342943271 0.566131628
0.342943271 0.51424622 1
0.297487618 0.51424622
0.297487618 0.484147206 1
0.272946717 0.484147206
0.272946717 0.46789715 1
0.260209681 0.46789715
0.260209681 0.275574373 1
0.132066182 0.275574373
0.132066182 -0.04541407 1
-0.01768377 -0.04541407
-0.01768377 -0.42052483 1
-0.1343192 -0.42052483
-0.1343192 -0.71268654 1
-0.19968635 -0.71268654
-0.19968635 -0.87642564 1

-0.22975326 -0.87642564
-0.22975326 -0.95174067 1
-0.2423205 -0.95174067
-0.2423205 -0.98322052 1
-0.2473616 -0.98322052
-0.2473616 -0.99584805 1
-0.24935025 -0.99584805
-0.24935025 -1.00082942 1

D7.*
a. A distillation column with a total condenser is separating acetone from ethanol. A distillate
concentration of xD = 0.90 mole fraction acetone is desired. Since CMO is valid, L/V =
constant. If L/V is equal to 0.8, find the composition of the liquid leaving the fifth stage below
the total condenser.
b. A distillation column separating acetone and ethanol has a partial reboiler that acts as an
equilibrium contact. If the bottoms composition is xB = 0.13 mole fraction acetone and the
boilup ratio /B = 1.0, find the vapor composition leaving the second stage above the partial
reboiler.
c. The distillation column in parts a and b is separating acetone from ethanol and has xD = 0.9, xB
= 0.13, L/V = 0.8, and /B = 1.0. If the feed composition is z = 0.3 (all concentrations are mole
fraction of more volatile component), find the optimum feed plate location, total number of
stages, and required q value of the feed. Equilibrium data for acetone and ethanol at 1 atm
(Perry et al., 1963, pp. 13–4) are

x y
0 0
0.1 0.262
0.15 0.348
0.2 0.417
0.25 0.478
0.3 0.524
0.35 0.566
0.4 0.605
0.5 0.674
0.6 0.739
0.7 0.802
0.8 0.865
0.9 0.929
1 1

a. A distillation column with a total condenser is separating acetone from ethanol. A distillate
concentration of xD = 0.90 mole fraction acetone is desired. Since CMO is valid, L/V =
constant. If L/V is equal to 0.8, find the composition of the liquid leaving the fifth stage below
the total condenser.
1
Ln/Vn 0.8 N
xD 0.9 0.9 0.9 0.9

0.855 0.9 0.8


Vn 100 0.855 0.864 1
Ln 80 0.8 0.864 0.7

D 20 0.8 0.82 1 0.6


0.73 0.82
R 4 0.73 0.764 1 0.5

0.64 0.764 0.4


mLOR bLOR 0.64 0.692 1
0.8 0.18 0.53 0.692 0.3

0.2

0.1

0
0.5

0.4

0.3

0.53 0.604 1 0.2


xD 0.9 0.9
0.9 0 0.1

0
0 0.1
LOR 0.9 0.9
0 0.18

b. A distillation column separating acetone and ethanol has a partial reboiler that acts as an
equilibrium contact. If the bottoms composition is xB = 0.13 mole fraction acetone and the
boilup ratio Vm /B = 1.0, find the vapor composition leaving the second stage above the partial
reboiler. 1
xB 0.13
0.9
Vm/B 1 N
B 100 0.13 0.13 0.8
Vm 100 0.13 0.32
0.7
Lm 200 0.225 0.32 1
0.225 0.45 0.6
xB 0.13 0 0.29 0.45 1
0.5
0.13 0.13
0.4

0.3

mLOS bLOS 0.2


2 -0.13
0.1

LOS 0.13 0.13 0


0 0
0.5 0.87

c. The distillation column in parts a and b is separating acetone from ethanol and has xD = 0.9, xB=0.13
Ln/Vn = 0.8, and Vm/B = 1.0. If the feed composition is z = 0.3 (all concentrations are mole
fraction of more volatile component), find the optimum feed plate location, total number of
stages, and required q value of the feed. Equilibrium data for acetone and ethanol at 1 atm
(Perry et al., 1963, pp. 13–4) are
mLOF bLOF
xD 0.9 0 -2.08 0.924
0.9 0.9
q 0.675324675
z 0.3 0
0.3 0.3 N
0.9 0.9
xB 0.13 0 0.855 0.9
0.13 0.13 0.855 0.864 1
0.8 0.864
mLOR bLOR 0.8 0.82 1
0.8 0.18 0.73 0.82
mLOS bLOS 0.73 0.764 1
2 -0.13 0.64 0.764
0.64 0.692 1
interseccion 0.53 0.692
0.258333333 0.386666667 0.53 0.604 1
0.4 0.604
LOR 0.9 0.9 0.4 0.5 1
0.258333333 0.386666667 0.273 0.5
0.273 0.3984 1
LOS 0.13 0.13 0.184 0.3984
0.258333333 0.386666667 0.184 0.238 1 nNf
0.088 0.238
LOF 0.3 0.3 0.088 0.046 1
0.258333333 0.386666667
9N
D8.* For Problem 4.D7c for separation of acetone from ethanol, determine:
a. How many stages are required at total reflux?
b. What is (L/V)min? What is (L/D)min? 1
c. The L/D used is how much larger than (L/D)min?
d. If EMV = 0.75, how many real stages are required for L/V = 0.8? 0.9

0.8
Nmin
0.9 0.9 0.7
0.855 0.9 0.6
0.855 0.855 1
0.785 0.855 0.5

0.785 0.785 1 0.4


0.67 0.785
0.67 0.67 1 0.3

0.495 0.67 0.2


0.495 0.495 1
0.268 0.495 0.1

0.268 0.268 1 0
0.103 0.268 0 0.1 0.2 0.3 0.4

0.103 0.103 1
1

(L/D)min 0.9

0.8
mLOF bLOF LOF 0.3 0.3
0.7
-2.08 0.924 0 0.924
0.6
xD 0.9 LORmin 0.9 0.9
0.5
0 0.290322581
Rmin 2.1 0.4

0.3

0.2
0.6

0.5

0.4

0.3
LORmin mLORmin bLORmin
0.677419355 0.290322581 0.2

0.1
(L/D)min (V/D)min
2.1 3.1 0
0 0.1 0.2 0.3 0.4 0.

d. If EMV = 0.75, how many real stages are required for L/V = 0.8?

Las etapas teóricas son 9


yn  yn 1
EMV  EMV

y *n  yn 1 0.75

N
0.9 0.9 0.9 0.891
0.855 0.9 0.855 0.891
0.855 0.864 1 0.855 0.853
0.8 0.864 0.8 0.853
0.8 0.82 1 0.8 0.806
0.73 0.82 0.73 0.806
0.73 0.764 1 0.73 0.746
0.64 0.764 0.64 0.746
0.64 0.692 1 0.64 0.67
0.53 0.692 0.53 0.67
0.53 0.604 1 0.53 0.578
0.4 0.604 0.4 0.578
0.4 0.5 1 0.4 0.4746
0.273 0.5 0.273 0.4746
0.273 0.3984 1 0.273 0.3583
0.184 0.3984 0.184 0.3583
0.184 0.238 1 nNf 0.184 0.19
0.088 0.238 0.088 0.19
0.088 0.046 1 0.088 0.0345

9N

Nueva curva Nreal 0.9 0.9


1 1 0.867 0.9
0.855 0.891 0.867 0.8736 1
0.8 0.853 0.83 0.8736
0.73 0.806 0.83 0.844 1
0.64 0.746 0.785 0.844
0.53 0.67 0.785 0.808 1
0.4 0.578 0.73 0.808
0.273 0.4746 0.73 0.764 1
0.184 0.3583 0.665 0.764
0.088 0.19 0.665 0.712 1
0 0 0.59 0.712
0.59 0.652 1
Ln1  EMV  S  1  0.5 0.652
Eo 
Ln S 
0.5 0.58 1
0.401 0.58
0.401 0.5008 1
0.301 0.5008
mV 0.301 0.4208 1
S 0.228 0.4208
L 0.228 0.326 1
0.164 0.326
0.164 0.198 1
0.092 0.198
0.092 0.054 1

12

D10.* A distillation column is separating phenol from p-cresol at 1 atm pressure. The distillate
composition desired is 0.96 mole fraction phenol. An external reflux ratio of L/D = 4 is used, and
the reflux is returned to the column as a saturated liquid. The equilibrium data can be represented
by a constant relative volatility, αphenol−cresol = 1.76 (Perry et al., 1963, pp. 13–3). CMO can be
assumed.
a. What is the vapor composition leaving the third equilibrium stage below the total condenser?
Solve this by an analytical stage-by-stage calculation alternating between the operating equation
and the equilibrium equation.
b. What is the liquid composition leaving the sixth equilibrium stage below the total condenser?
Solve this problem graphically using a McCabe-Thiele diagram plotted for αp−c = 1.76.

alfa 1.76

x y N
0 0 0.96 0.96
0.1 0.163568773 0.931677019 0.96
0.2 0.305555556 0.931677019 0.937341615 1
0.3 0.429967427 0.894734046 0.937341615
0.4 0.539877301 0.894734046 0.907787237 1
0.5 0.637681159 0.848334512 0.907787237
0.6 0.725274725 0.848334512 0.87066761 1
0.7 0.804177546 0.792746484 0.87066761
0.8 0.875621891 0.792746484 0.826197187 1
0.9 0.940617577 0.72979806 0.826197187
1 1 0.72979806 0.775838448 1
0.66290424 0.775838448
xD 0.96 0.66290424 0.722323392 1
R 4

mLOR bLOR
0.8 0.192

xD 0.96 0.96
0.96 0

LOR 0.96 0.96


0 0.192

D9. A distillation column with two feeds is separating ethanol (E) and water at a pressure of 1.0 atm.
The column has a total condenser with saturated liquid reflux and a partial reboiler. Feed 1 is a
saturated liquid and is 42 mol% ethanol. Feed 2 flow rate is F2 = 100 kmol/h. Feed 2 is 18 mol%
ethanol and is a two-phase mixture that is 30% vapor. The external reflux ratio is L/D = 1/2, and
the distillate flow rate is D = 80 kmol/h. We desire a distillate mole fraction of xD = 0.66 mole
fraction ethanol and a bottoms that is xB = 0.04 mole fraction ethanol. You can assume that CMO
is valid. Equilibrium data are in Table 2-1.
a. Find the flow rates F1 and B.
b. Find the liquid and vapor flow rates in the middle section, L′ and V′.
c. Determine and plot the operating lines. Be neat.
d. Find both optimum feed locations (above partial reboiler) and the total number of equilibrium
stages needed. Step off stages from the bottom up. Be neat.

x y
0 0
0.019 0.17
0.0721 0.3891
0.0966 0.4375
0.1238 0.4704
0.1661 0.5089
0.2337 0.5445
0.2608 0.558
0.3273 0.5826
0.3965 0.6122
0.5198 0.6599
0.5732 0.6841
0.6765 0.7385
0.7472 0.7815
0.8943 0.8943
1 1
BALANCES EXTERNOS

F1 F2 D B z1 z2 xD
93.68 100 80 113.68 0.42 0.18 0.66

BALANCES INTERNOS

F1 F2 D B R q1 q2
93.68 100.00 80.00 113.68 0.5 1 0.7
Ln Vn Li Vi Lm Vm
40 120.00 133.6842105 120 203.6842105 90.00

xD 0.66 0.66 mLOR bLOR LOR


0.66 0 0.333333333 0.44
mLOS bLOS
z1 0.42 0.42 2.263157895 -0.05052632 LOF1
0.42 0
mLOF2 bLOF2
z2 0.18 0.18 -2.33333333 0.6 LOF2
0.18 0
mLOI bLOI
xB 0.04 0.04 1.114035088 0.112105263 LOS
0.04 0

LOI

N
0.04 0.04
0.04 0.268
0.139937008 0.268 1
0.139937008 0.486
0.335622047 0.486 1
0.335622047 0.583
0.429 0.583 1
0.429 0.624
0.552 0.624 1
0.552 0.672
0.672 0.672 1
D11. A mixture of methanol and water is being separated in a distillation column with open steam. The
feed is 100.0 kmol/h. Feed is 60.0 mol% methanol and is at 40°C. The column is at 1.0 atm. The
steam is pure steam (yM = 0) and is a saturated vapor. The distillate product is 99.0 mol%
methanol and leaves as a saturated liquid. The bottoms is 2.0 mol% methanol and since it leaves
an equilibrium stage must be a saturated liquid. The column is adiabatic. The column has a total
condenser. External reflux ratio is L/D = 2.3. Assume CMO is valid. Equilibrium data are in
Table 2-7. Data for water and methanol are available in Problem 3.E1.
a. Estimate q.
b. Find optimum feed stage and total number of equilibrium stages (step off stages from top down). Use a McCabe-Thiele di
c. Find (L/D)min. Use a McCabe-Thiele diagram.

MetOH-W
x y F 100 yS 0
0 0 z 0.6 xD 0.99
0.02 0.134 P 1 atm xB 0.02
0.04 0.23 TF 40 °C
0.06 0.304
0.08 0.365 L/D 2.3
0.1 0.418
0.15 0.517 S 50
0.2 0.579
0.3 0.665 F S D B
0.4 0.729 MetOH 60 0 58.18 1.82
0.5 0.779 W 40 50 0.59 89.41
0.6 0.825 100 50 58.76 91.24
0.7 0.87
0.8 0.915 F S D B
0.9 0.958 100 50 58.7628866 91.2371134
0.95 0.979 Ln Vn Lm Vm
1 1 135.1546392 193.9175258 91.24 50
xD 0.99 0.99
0.99 0

z 0.6 0.6 mLOF bLOF LOF


0.6 0 0.305157593 0.416905444

xB 0.02 0.02 mLOR bLOR LOR


0.02 0 0.696969697 0.3

mLOS bLOS LOS


1.824742268 -0.03649485

N 10 Nf
0.99 0.99 8
0.975 0.99
0.975 0.979545455 1 1
0.951 0.979545455
0.951 0.962818182 1 0.9
0.911 0.962818182
0.8
0.911 0.934939394 1
0.845 0.934939394 0.7
0.845 0.888939394 1
0.743 0.888939394 0.6
0.743 0.817848485 1
0.582 0.817848485 0.5
0.582 0.705636364 1
0.4
0.36 0.705636364
0.36 0.550909091 1 0.3
0.172 0.550909091
0.172 0.277360825 1 0.2
0.05 0.277360825
0.05 0.054742268 1 0.1
0.01 0.054742268
0
0.01 0 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Rmin
1
mLOF bLOF
0.305157593 0.416905444 0.9

0.8
LOF 0.6 0.6
0 0.416905444
0.7

Rmin 0.6

0.5

0.4
0.7

0.6
1.65
LORmin 0.5
0.99 0.99
0.4
0 0.373584906
0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

D26. A distillation column with a partial condenser and a total reboiler is separating acetone and
ethanol. There are two feeds. One feed is 50.0 mol% acetone, flows at 100.0 mol/min, and is a
superheated vapor where approximately 1 mole of liquid will vaporize on the feed stage for each
20 moles of feed. The other feed is a saturated liquid, flows at 150.0 mol/min and is 35.0 mol%
acetone. We desire a distillate product that is yD = 0.85 mole fraction acetone and a bottoms
product that is xB = 0.10 mole fraction acetone. The column has a partial condenser and a total
reboiler. Boilup is returned as a saturated vapor. Column operates at a pressure of 1.0 atm.
Assume CMO and use a McCabe-Thiele diagram. VLE data are given in Problem 4.D7.
a. Find ( Vm/B)min. (Plot both feed lines to decide which one to use.)
b. Operate at Vm/B = 3 × ( Vm/B)min. The partial condenser is an equilibrium contact. If the stages
each have a Murphree liquid efficiency of 0.75, find optimum feed locations for each feed and
total number of real stages. (It is easiest to start at top and step down.)
columna de destilación a una razón de
benceno, si la alimentación se encuentra
1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2

Chart Title
1
Chart Title
1

0.9

0.8

0.7

0.6
Chart Title
0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


Chart Title
1

Rb
0.664489796 0.5

0
.4 .3 .2 .1 16 0.
1
0.
2
0.
3
0.
4
0.85 -0 -0 -0 -0 E-
6
0.287162162 51
462
02 -0.5
223
0.25 10
.1
-1
0.525540541
-1

-1.5
1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0.5

0.4

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0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6
1

0.9

0.8

0.7

0.6

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0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9
Analitico Ki
0.1 0.262 2.62
0.15 0.348 2.32 0.8

0.7
0.9

0.8
0.2 0.417 2.085
0.25 0.478 1.912
0.3 0.524 1.746666667
0.7
0.35 0.566 1.617142857
0.4 0.605 1.5125
0.5 0.674 1.348
0.6 0.739 1.231666667 0.6
0.7 0.802 1.145714286
0.8 0.865 1.08125
0.9 0.929 1.032222222 0.5

1.637680225
L/V 0.8
0.4
EMV V/L 1.25
0.75 S 2.047100281

0.3
Eo 0.809018613

Nreal 11.12458953
0.2

0.1

0
0 0.1 0.2 0.3 0.4

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xB
0.04

0.9

0.8

0.7

0.6
0.66 0.66
0.42 0.58 0.5

0.42 0.42 0.4

0.42 0.58
0.3

0.18 0.18 0.2


0.141526718 0.269770992
0.1
0.04 0.04
0.141526718 0.269770992 0
01 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0

0.141526718 0.269770992
0.42 0.58
0.9

0.8

0.7

0.6

0.5

0.4

0.3
0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4

Use a McCabe-Thiele diagram.

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2
z yS xD xB
0.6 0 0.99 0.02 0.1
0.4 1 0.01 0.98 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

R q
2.3 -0.43917526
0.6 0.6
0.298371191 0.507955679

0.99 0.99
0 0.3

0.02 0
0.298371191 0.507955679

N
xy
x=y
xD z xB
LOF LOR LOS

4 0.5 0.6 0.7 0.8 0.9 1

xy
x=y
xD z xB
LOF
LORmin
xy
x=y
xD z xB
LOF
LORmin

0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

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0.6

0.5

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0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1

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0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Chart Title
Chart Title

0.4 0.5 0.6 0.7 0.8 0.9 1

Chart Title

1 2 3 4 5 6 7 8 9 1
0. 0. 0. 0. 0. 0. 0. 0. 0.
8 0.9 1
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9 1
0.9 1

0.7 0.8 0.9 1


0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

xy 0.4
x=y
0.3

0.2

0.1

0.6 0.7 0.8 0.9 1 0


0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6
1

0.9

0.8

0.7

0.6

0.5

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0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
1

N
xy
x=y
xD z xB
LOF LOR LOS

0.8 0.9 1
xy
x=y
xD z xB
LOF LOR LOS

0.4 0.5 0.6 0.7 0.8 0.9 1


E5. A distillation column is separating a feed that is 30 mol% acetone and 70 mol% ethanol. The
column has a partial condenser. Operation is at p = 1 atm. The feed flow rate is 1000 kmol/day,
the feed is a saturated liquid, and feed is input at the optimum location. We desire a distillate that
is 90 mol% acetone and a bottoms that is 10 mol% acetone. Use a boilup ratio of Vm/B = 1.25. On
the fourth stage above the partial reboiler, a vapor sidestream with flow rate S = 200 kmol/day is
withdrawn and then condensed to a saturated liquid, which is returned to the column as feed at the
optimum location. Assume CMO. Find the mole fraction of vapor side stream ys, optimum feed
location, optimum location to input saturated liquid from intermediate condenser, and total number
of equilibrium stages.

z xD xB F D B
Ace 0.3 0.9 0.1 300 225.00 75.00
EtOH 0.7 0.1 0.9 700 25.00 675.00
1000 250.00 750.00

Vm 937.5 mLOS bLOS


Lm 1687.50 1.8 -0.08

LOS 0.1 0.1


N 0.05 0.05 0.3 0.46
0.05 0.12
0.111111111 0.12 q1 1
0.111111111 0.286 Lm 1687.50 Li2 687.5
0.203333333 0.286 Vm 937.5 Vi2 937.5
0.203333333 0.415 F 1000
0.275 0.415
0.275 0.5
0.322222222 0.5
0.322222222 0.495
0.319444444 0.495
Vm/Lm 0.855 Lm 134.1002103 Vn 114.6556798
Ln/Vn 0.5 Vm 114.6556798 Ln 57.32783991
q 1 B 19.44453049 D 57.32783991
z 0.545
N 3 xD 0.835

Lm/Vm 1.169590643
F D B z xD xB
54.5 47.86874632 6.631253679 0.545 0.835 0.1554
45.5 9.459093584 36.04090642 0.455 0.165 0.8446
100 57.32783991 42.67216009

mLOR bLOR mLOS bLOS


0.5 0.42 1.378593429 -0.05883342
0.725377025
0.545 0.545 0.835 0.835 Lm/Vm
0.545 1 0 0.42 1.169590643
0.855

F 204 Comp z xD xB F
z 0.6 Bz 0.6 0.95 0.05 122.40
xD 0.95 Tol 0.4 0.05 0.95 81.60
xB 0.05 204

V/F D/F 0.611111111 q 0.388888889


alfa 2.5
xy xD 0.95 0.95
0 0.00 0.95 0
0.1 0.22
0.2 0.38 z 0.6 0.6
0.3 0.52 0.6 0
0.4 0.63
0.5 0.71 xB 0.05 0.05
0.6 0.79 0.05 0
0.7 0.85
0.8 0.91
0.9 0.96
1 1.00

Nmin 6.43
1.00

0.90

0.80

0.70
1.00
0.95 0.95 0.90
0.88372093 0.95
0.80
0.88372093 0.88372093
0.752475248 0.88372093 0.70
0.752475248 0.752475248 0.60
0.548736462 0.752475248 0.50
0.548736462 0.548736462
0.40
0.548736462 0.548736462
0.327233584 0.548736462 0.30
0.327233584 0.327233584 0.20
0.327233584 0.327233584
0.10
0.162871685 0.327233584
0.162871685 0.162871685 0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.072204738 0.162871685
0.072204738 0.072204738
0.030189803 0.072204738
0.030189803 0.030189803

Rmin

q mLOF bLOF 1.00


0.388888889 -0.63636364 0.981818182
0.90

LOF 0.6 0.6


0.80
0 0.981818182
0.70
LORmin
0.60

Rmin 1.3 0.50

LORmin 0.95 0.95 0.40


0 0.413043478
0.30

0.20

R/Rmin 1.3 0.10

0.00
R 1.69 0 0.1 0.2

F D B R q Ln
204 124.6666667 79.33333333 1.69 0.388888889 210.6866667

mLOR bLOR mLOS bLOS mLOF


0.628252788 0.353159851 1.37654653 -0.01882733 -0.63636364

LOR LOS
0.95 0.497113843 0.05 0.497113843
0.95 0.665473009 0.05 0.665473009

N
0.95 0.95
0.88372093 0.95
0.88372093 0.90835999 1
0.798586304 0.90835999
0.798586304 0.854873923 1
0.702046124 0.854873923 y3 0.854873923
0.702046124 0.794222286 1
0.606894303 0.794222286
0.606894303 0.734442889 1
0.525226458 0.734442889
0.525226458 0.683134838 1
0.463048792 0.683134838
0.463048792 0.618580881 1
0.393467081 0.618580881
0.393467081 0.522798418 1
0.304696174 0.522798418
0.304696174 0.400601135 1
0.210942812 0.400601135 y3 0.400601135
0.210942812 0.271545269 1
0.129759446 0.271545269
0.129759446 0.159792588 1
0.070694953 0.159792588
0.070694953 0.078487566 1
0.032946564 0.078487566
0.032946564 0.026525151 1

N 12

Nr 18
1

0.9

0.8

0.7

0.6

0.5

0.4
1
0.3
0.9
0.2
0.8

0.7 0.1

0
0.6 0 0.1 0.2

0.5
LOF 0.3 0.46 0.4
0.3 0.3
0.3

0.2
Li1 Ln
Vi1 Vn 0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

x1 y1 x2 y2
0 0 1 1
0.1 0.314 0.9 0.686
0.2 0.508 0.8 0.492
0.3 0.64 0.7 0.36
0.4 0.734 0.6 0.266
0.5 0.806 0.5 0.194
0.6 0.862 0.4 0.138
0.7 0.905 0.3 0.095
0.8 0.943 0.2 0.057
1 1 0 0
1

0.9

0.8

F 76.7723704 N 0.7

100 0.835 0.835 0.6


1.30255194 0.55037044 0.835 0.5
mLOR bLOR 0.55037044 0.69518522
0.4
0.5 0.4175 0.355524025 0.69518522
0.3
mLOS bLOS 0.355524025 0.431289666
1.169590643 -0.05783624 0.155000198 0.431289666 0.2
0.155000198 0.154848836 0.1

0
LOR 0 0.4175 0 0.1
0.835 0.835

LOS 0.1554 0.1554


0.545 0.6925

D B
118.43 3.97
6.23 75.37
124.67 79.33

1.00

0.90

0.80

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
.7 0.8 0.9 1

.00

.90

.80

.70

.60

.50

.40

.30

.20

.10

.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Vn Lm Vm
335.3533333 290.02 210.6866667

bLOF 1.00

0.90

0.80
1.00
0.981818182
0.90

0.80
0.497113843
0.665473009 0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1

.9

.8

.7

.6

.5

.4

.3

.2

.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.6 0.7 0.8 0.9 1

K1 K2
#DIV/0! 1 0
3.14 0.762222222 4.119533528 0.314771396
2.54 0.615 4.130081301 0.508255339
2.133333333 0.514285714 4.148148148 0.639229346
1.835 0.443333333 4.139097744 0.733773629
1.612 0.388 4.154639175 0.80523159
1.436666667 0.345 4.164251208 0.861139159
1.292857143 0.316666667 4.082706767 0.906074241
1.17875 0.285 4.135964912 0.942978392
1 #DIV/0! 1
4.134302848
1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.8 0.9 1
1.00

0.90

0.80

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
A B C Tb
METHANOL 18.5875 3626.55 -34.29 337.8
WATER 18.3036 3816.44 -46.13 373.2

x y T x1 x2 T Psat1
0 0 100 0 1 100 3.497240278
0.02 0.134 96.4 0.02 0.98 96.4 3.117572209
0.04 0.23 93.5 0.04 0.96 93.5 2.836780983
0.06 0.304 91.2 0.06 0.94 91.2 2.629079666
0.08 0.365 89.3 0.08 0.92 89.3 2.467036174
0.1 0.418 87.7 0.1 0.9 87.7 2.337008446
0.15 0.517 84.4 0.15 0.85 84.4 2.08653147
0.2 0.579 81.7 0.2 0.8 81.7 1.898398936
0.3 0.665 78 0.3 0.7 78 1.663470447
0.4 0.729 75.3 0.4 0.6 75.3 1.507633772
0.5 0.779 73.1 0.5 0.5 73.1 1.389763354
0.6 0.825 71.2 0.6 0.4 71.2 1.294205478
0.7 0.87 69.3 0.7 0.3 69.3 1.204159766
0.8 0.915 67.6 0.8 0.2 67.6 1.128060936
0.9 0.958 66 0.9 0.1 66 1.060131902
0.95 0.979 65 0.95 0.05 65 1.019430792
1 1 64.5 1 0 64.5 0.999573272
Mezcla Methanol + Water
A12 A21
#N/A #N/A

Psat2 g1 g2 K1 K2 y1 y2 Sy
0.999925016
0.878114611
0.789192889
0.72411506
0.673786248
0.633699729
0.557284399
0.500644563
0.430927248
0.385366396
0.351305681
0.323966123
0.298443968
0.27706881
0.258148086
0.246887308
0.241414781
DATA
NUMBER COMPONENT MOLE WT FREEZE BOILING
POINT POINT
K K
(TFP) (TB)
0 1 2 3 4

1 1,1,1-TRIFLOUROETHANE 84.041 161.9 225.5


2 1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE 203.831 298.0 364.7
3 1,1,2-TRICHLOROETHANE 133.405 236.5 386.9
4 1,1,2-TRIMETHYLCLOPENTANE 112.216 0.0 386.9
5 1,1,3-TRIMETHYLCLOPENTANE 112.216 0.0 378.0
6 1,1-DICHLORO-1,2,2,2-TETRAFLUOROETHANE 170.922 179.0 277.0
7 1,1-DICHLOROETHANE 98.960 176.2 330.4
8 1,1-DIFLOUROETHANE 66.051 156.2 248.4
9 1,1-DIFLUOROETHYLENE 64.035 0.0 0.0
10 1,1-DIMETHYLCYCLOHEXANE 112.216 239.7 392.7
11 1,1-DIMETHYLCYCLOPENTANE 98.189 203.4 361.0
12 1,2,2-TRICHLORO-1,1,2TRIFLUOROETHANE 187.380 238.2 320.7
13 1,2,3,4-TETRAHYDRONAPHTHALENE 132.206 242.0 480.7
14 1,2,3-TRICHLOROPROPANE 147.432 258.5 429.0
15 1,2,3-TRIMETHYLBENZENE 120.195 247.7 449.2
16 1,2,4,5-TETRAMETHYLBEENZENE 134.222 352.0 470.0
17 1,2,4-TRIMETHYLBENZENE 120.195 227.0 442.5
18 1,2-BUTADIENE 54.092 137.0 284.0
19 1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE 170.922 179.3 276.9
20 1,2-DICHLOROETHANE 98.960 237.5 356.6
21 1,2-DICHLOROPROPANE 112.987 172.7 369.5
22 1,2-DIMETHOXYETHANE 90.123 202.0 358.6
23 1,2-PENTADIENE 68.119 135.9 318.0
24 1,2-PROPANEDIOL 76.096 213.0 460.5
25 1,3,5-TRIMETHYLBENZENE 120.195 228.4 437.9
26 1,3-BUTADIENE 54.092 164.3 268.7
27 1,3-PROPANEDIOL 76.096 246.4 487.6
28 1,4 DIOXANE 88.107 285.0 374.5
29 1,4-DIETHYLBENZENE 134.222 231.0 456.9
30 1,4-PENTADIENE 68.119 124.9 299.1
31 1,5 HEXADIENE 82.146 132.0 332.6
32 1-BUTENE 56.108 87.8 266.9
33 1-BUTYNE 54.092 147.4 281.2
34 1-CHLORO-1,1-DIFLUOROETHANE 100.496 142.0 263.4
35 1-CHLOROBUTANE 92.569 150.1 351.6
36 1-DECANOL 158.285 280.1 503.4
37 1-DECENE 140.270 206.9 443.7
38 1-DODECENE 168.324 238.0 486.5
39 1-EICOSANOL 298.555 339.0 629.0
40 1-HEPTANOL 116.204 239.2 449.5
41 1-HEPTENE 98.189 154.3 366.8
42 1-HEXADECENE 224.432 277.3 558.0
43 1-HEXANOL 102.177 229.2 430.2
44 1-HEXENE 84.162 133.3 336.6
45 1-METHYL-1-ETHYLCYCLOPENTANE 112.216 0.0 394.7
46 1-METHYL-2-ETHYLBENZENE 120.195 192.3 438.3
47 1-METHYL-2-ISOPROPYLBENZENE 134.222 0.0 451.5
48 1-METHYL-2-ISOPROPYLBENZENE 134.222 0.0 448.3
49 1-METHYL-3-ETHYLBENZENE 120.195 177.6 434.5
50 1-METHYL-4-ETHYLBENZENE 120.195 210.8 435.2
51 1-METHYL-4-ISOPROPYLBENZENE 134.222 200.0 450.3
52 1-METHYLNAPHTHALENE 142.201 242.7 517.8
53 1-NONENE 126.243 191.8 420.0
54 1-OCTADECANOL 270.501 331.0 608.0
55 1-OCTADECENE 252.486 290.8 588.0
56 1-OCTANOL 130.231 257.7 468.4
57 1-OCTENE 112.216 171.4 394.4
58 1-PENTADECENE 210.405 269.4 541.5
59 1-PENTANOL 88.150 195.0 411.0
60 1-PENTENE 70.135 107.9 303.1
61 1-PENTYNE 68.119 167.5 313.3
62 1-PROPANOL 60.096 146.9 370.4
63 1-TERADECENE 196.378 260.3 524.3
64 1-TRANS-3-PENTADIENE 68.119 185.7 315.2
65 1-TRIDECENE 182.351 250.1 505.9
66 1-UNDECENE 154.297 224.0 465.8
67 2,2 DIMETHYL BUTANE 86.178 173.3 322.9
68 2,2,3 TRIMETHYLPETANE 114.232 160.9 383.0
69 2,2,3,3-TETRAMETHYLHEPTANE 142.286 0.0 433.5
70 2,2,3,3-TETRAMETHYLPENTANE 128.259 0.0 413.4
71 2,2,3,4-TETRAMETHYLPENTANE 128.259 0.0 406.2
72 2,2,3-TRIMETHYLBUTANE 100.205 248.3 354.0
73 2,2,3-TRIMETHYLHEXANE 128.259 0.0 406.8
74 2,2,4 TRIMETHYLPENTANE 114.232 165.8 372.4
75 2,2,4,4-TETRAMETHYLPENTANE 128.259 206.0 395.4
76 2,2,4-TRIMETHYLHEXANE 128.259 153.0 399.7
77 2,2,5,5-TETRAMETHYLHEPTANE 142.286 0.0 410.6
78 2,2,5-TRIMETHYLHEXANE 128.259 167.4 397.3
79 2,2-DIMETHYL PROPANE 72.151 256.6 282.6
80 2,2-DIMETHYL-1-PROPANOL 88.150 327.0 386.3
81 2,2-DIMETHYLHEXANE 114.232 152.0 382.0
82 2,2-DIMETHYLPENTANE 100.205 149.4 352.4
83 2,3 DIMETHYL BUTANE 86.178 144.6 331.2
84 2,3,3 TRIMETHYLPENTANE 114.232 172.5 387.9
85 2,3,3,4-TETRAMETHYLPENTANE 128.259 0.0 414.7
86 2,3,3-TRIMETHYL-1-BUTENE 98.189 163.3 351.0
87 2,3,4 TRIMETHYLPENTANE 114.232 163.9 386.6
88 2,3-DIMETHYL-1-BUTENE 84.162 115.9 328.8
89 2,3-DIMETHYL-2-BUTENE 84.162 198.9 346.4
90 2,3-DIMETHYLHEXANE 114.232 0.0 388.8
91 2,3-DIMETHYLPENTANE 100.205 0.0 362.9
92 2,3-DIMETHYLPYRIDINE 107.156 0.0 434.0
93 2,3-XYLENOL 122.167 348.0 490.1
94 2,4-DIMETHYLHEXANE 114.232 0.0 382.6
95 2,4-DIMETHYLPENTANE 100.205 154.0 353.7
96 2,4-XYLENOL 122.167 298.0 484.0
97 2,5-DIMETHYLHEXANE 114.232 181.9 382.3
98 2,5-DIMETHYLPYRIDINE 107.156 0.0 430.2
99 2,5-XYLENOL 122.167 348.0 484.3
100 2,6-XYLENOL 122.167 322.0 474.1
101 2-BUTANOL 74.123 158.5 372.7
102 2-BUTYNE 54.092 240.9 300.2
103 2-CHLOROBUTANE 92.569 141.8 341.4
104 2-ETHYLHEXANOL 130.231 203.2 457.8
105 2-METHYL BUTANE 72.151 113.3 301.0
106 2-METHYL PENTANE 86.178 119.5 333.4
107 2-METHYL-1,3-BUTADIENE 68.119 127.2 307.2
108 2-METHYL-1-BUTANOL 88.150 203.0 409.1
109 2-METHYL-1-BUTENE 70.135 135.6 304.3
110 2-METHYL-2-BUTENE 70.135 139.4 311.7
111 2-METHYL-2-PENTENE 84.162 138.1 340.5
112 2-METHYL-3-ETHYLPENTANE 114.232 158.2 388.8
113 2-METHYLHEPTANE 114.232 164.0 390.8
114 2-METHYLHEXANE 100.205 154.9 363.2
115 2-METHYLNAPHTHALENE 142.201 307.7 514.2
116 2-OCTANOL 130.231 241.2 452.9
117 3,3,5-TRIMETHYLHEPTANE 142.286 0.0 428.8
118 3,3-DIETHYLPENTANE 128.259 0.0 419.3
119 3,3-DIMETHYL-1-BUTENE 84.162 158.0 314.4
120 3,3-DIMETHYLHEXANE 114.232 147.0 385.1
121 3,3-DIMETHYLPENTANE 100.205 138.7 359.2
122 3,4 DIMETHYLHEXANE 114.232 0.0 390.9
123 3,4-DIMETHYLPYRIDINE 107.156 0.0 452.3
124 3,4-XYLENOL 122.167 328.0 500.0
125 3,5-DIMETHYLPYRIDINE 107.156 0.0 445.1
126 3,5-XYLENOL 122.167 337.0 494.8
127 3-ETHYLHEXANE 114.232 0.0 391.7
128 3-ETHYLPENTANE 100.205 154.6 366.6
129 3-METHYL PENTANE 86.178 155.0 336.4
130 3-METHYL-1,2-BUTADIENE 68.119 159.5 314.0
131 3-METHYL-1-BUTANOL 88.150 156.0 404.4
132 3-METHYL-1-BUTENE 70.135 104.7 293.3
133 3-METHYL-2-BUTANOL 88.150 264.4 375.2
134 3-METHYL-3-ETHYLPENTANE 114.232 182.3 391.4
135 3-METHYL-CIS-2-PENTENE 84.162 138.3 340.9
136 3-METHYLHEPTANE 114.232 152.7 392.1
137 3-METHYLHEXANE 100.205 100.0 365.0
138 3-METHYL-TRANS-2-PENTENE 84.162 134.7 343.6
139 4- METHYL PYRIDINE 93.129 276.9 418.5
140 4-METHYL-CIS-2-PENTENE 84.162 139.0 329.6
141 4-METHYLHEPTANE 114.232 152.2 390.9
142 4-METHYL-TRANS-2-PENTENE 84.162 132.0 331.7
143 ACETALDEHYDE 44.054 150.2 293.6
144 ACETIC ACID 60.052 289.8 391.1
145 ACETIC ANHYDRIDE 102.089 199.0 412.0
146 ACETONE 58.080 178.2 329.4
147 ACETONITRILE 41.053 229.3 354.8
148 ACETYL CHLORIDE 78.498 160.2 323.9
149 ACETYLENE 26.038 192.4 189.2
150 ACROLEIN 56.064 186.0 326.0
151 ACRYLIC ACID 72.064 285.0 414.0
152 ACRYLONITRILE 53.064 189.5 350.5
153 ALLYL ALCOHOL 58.080 144.0 370.0
154 ALLYL CHLORIDE 76.526 138.7 318.3
155 ALLYL CYANIDE 67.091 186.7 392.0
156 ALPHA-METHYL STYRENE 118.179 0.0 438.5
157 AMMONIA 17.031 195.4 239.7
158 ANILINE 93.129 267.0 457.5
159 ANTHRACENE 178.234 489.7 614.4
160 ARGON 39.948 83.8 87.3
161 BENZALDEHYDE 106.124 216.0 452.0
162 BENZENE 78.114 278.7 353.3
163 BENZOIC ACID 122.124 395.6 523.0
164 BENZONITRILE 103.124 260.0 464.0
165 BENZYL ALCOHOL 108.140 257.8 478.6
166 BORON TRICHLORIDE 117.169 165.9 285.7
167 BORON TRIFLUORIDE 67.805 146.5 173.3
168 BROMINE 159.808 266.0 331.9
169 BROMOBENZENE 157.010 242.3 429.3
170 BUTYL BENZOATE 178.232 251.0 523.0
171 BUTYL ETHER 130.231 175.3 415.6
172 BUTYRONITRILE 69.107 161.0 391.0
173 C,C,T-1,2,4-TRIMETHYLCYCLOPENTANE 112.216 0.0 391.0
174 C,T,C-1,2,4-TRIMETHYLCYCLOPENTANE 112.216 0.0 382.4
175 CAPRYLONITRILE 153.269 255.3 516.0
176 CARBON DIOXIDE 44.010 216.6 194.7
177 CARBON DISULFIDE 76.131 161.3 319.4
178 CARBON MONOXIDE 28.018 68.1 81.7
179 CARBON TETRACHLORIDE 153.823 250.0 349.7
180 CARBON TETRAFLUORIDE 88.005 86.4 145.2
181 CARBONYL SULFIDE 60.070 134.3 222.9
182 CHLORINE 70.906 172.2 238.7
183 CHLOROBENZENE 112.559 227.6 404.9
184 CHLORODIFLUOROMETHANE 86.469 113.0 232.4
185 CHLOROFORM 119.378 209.6 334.3
186 CHLOROPENTAFLUOROETHANE 154.467 167.0 234.0
187 CHLOROTRIFLUOROMETHANE 104.459 92.0 191.7
188 CIS-1,2-DIMETHYLCYCLOHEXANE 112.216 223.1 402.9
189 CIS-1,2-DIMETHYLCYCLOPENTANE 98.189 219.3 372.7
190 CIS-1,3-DIMETHYLCYCLOHEXANE 112.216 197.6 393.3
191 CIS-1,4-DIMETHYLCYCLOHEXANE 112.216 185.7 397.5
192 CIS-2-BUTENE 56.108 134.3 276.9
193 CIS-2-HEXENE 84.162 132.0 342.0
194 CIS-2-PENTENE 70.135 121.8 310.1
195 CIS-3-HEXENE 84.162 135.3 339.6
196 CIS-DECALIN 138.254 230.0 468.9
197 CYANOGEN 52.035 245.3 252.5
198 CYCLOBUTANE 56.108 182.4 285.7
199 CYCLOHEPTANE 98.189 265.0 391.9
200 CYCLOHEXANE 84.162 279.7 353.9
201 CYCLOHEXANOL 100.161 298.0 434.3
202 CYCLOHEXANONE 95.145 242.0 428.8
203 CYCLOHEXENE 82.146 169.7 356.1
204 CYCLOPENTANE 70.135 179.3 322.4
205 CYCLOPENTANONE 84.118 222.5 403.9
206 CYCLOPENTENE 68.119 138.1 317.4
207 CYCLOPROPANE 42.081 145.7 240.4
208 DEUTERIUM 4.032 18.7 23.7
209 DEUTERIUM OXIDE 20.031 277.0 374.6
210 DIBROMOMETHANE 173.835 220.6 370.0
211 DIBUTYLAMINE 129.247 211.0 432.8
212 DIBUTYL-O-PHTHALATE 278.350 238.0 608.0
213 DICHLORODIFLUOROMETHANE 120.914 115.4 243.4
214 DICHLOROMETHANE 84.933 178.1 313.0
215 DICHLOROMONOFLUOROMETHANE 102.923 138.0 282.0
216 DIETHYL AMINE 45.085 181.0 280.0
217 DIETHYL AMINE 73.139 223.4 328.6
218 DIETHYL DISULFIDE 122.244 171.7 427.2
219 DIETHYL KETONE 86.134 234.2 375.1
220 DIETHYL SULFIDE 90.180 169.2 365.3
221 DIETHYLENE GLYCOL 106.122 265.0 519.0
222 DIHEXYL ETHER 186.339 230.0 499.6
223 DIISOPROPYL ETHER 102.177 187.7 341.5
224 DIMETHYL ETHER 46.069 131.7 248.3
225 DIMETHYL OXALATE 118.090 327.0 436.6
226 DIMETHYL SULFIDE 62.130 174.9 310.5
227 DIPHENYL 154.212 342.4 528.4
228 DIPHENYL ETHER 170.211 300.0 531.2
229 DIPHENYLMETHANE 168.239 30537.5 767.0
230 DIPROPYLAMINE 101.193 210.0 382.4
231 DODECANOL 186.339 297.1 533.1
232 ETHANE 30.070 89.9 184.5
233 ETHANOL 46.069 159.1 351.5
234 ETHYL ACETATE 88.107 189.6 350.3
235 ETHYL ACRYLATE 100.118 201.0 373.0
236 ETHYL AMINE 45.085 192.0 289.7
237 ETHYL BENZOATE 150.178 238.3 485.9
238 ETHYL BROMIDE 108.966 154.6 311.5
239 ETHYL BUTYL ETHER 102.177 170.0 365.4
240 ETHYL BUTYRATE 116.160 180.0 394.0
241 ETHYL CHLORIDE 64.515 136.8 285.4
242 ETHYL ETHER 74.123 156.9 307.7
243 ETHYL FLUORIDE 48.060 129.9 235.4
244 ETHYL FORMATE 74.080 193.8 327.4
245 ETHYL ISOBUTYRATE 116.160 185.0 384.2
246 ETHYL MERCAPTAN 62.134 125.3 308.2
247 ETHYL PROPIONATE 102.134 199.3 273.0
248 ETHYL PROPYL ETHER 88.150 146.4 336.8
249 ETHYLBENZENE 106.168 178.2 409.3
250 ETHYLCYCLOHEXANE 112.216 161.8 404.9
251 ETHYLCYCLOPENTANE 98.189 134.7 376.6
252 ETHYLENE 28.054 104.0 169.4
253 ETHYLENE GLYCOL 62.069 260.2 470.4
254 ETHYLENE IMINE 43.069 195.0 329.8
255 ETHYLENE OXIDE 44.054 161.0 283.5
256 ETHYLENEDIAMINE 60.099 284.0 390.4
257 FLUORINE 37.997 53.5 85.0
258 FLUOROBENZENE 96.104 234.0 358.5
259 FORMALDEHYDE 30.026 156.0 254.0
260 FORMIC ACID 46.025 281.5 373.8
261 FURAN 68.075 187.5 304.5
262 GLYCEROL 92.095 291.0 563.0
263 HELIUM-4 4.003 0.0 4.2
264 HEPTADECANOL 256.474 327.0 597.0
265 HYDRAZINE 32.045 274.7 386.7
266 HYDROGEN 2.016 14.0 20.4
267 HYDROGEN BROMIDE 80.912 187.1 206.1
268 HYDROGEN CHLORIDE 36.461 159.0 188.1
269 HYDROGEN CYANIDE 27.026 259.9 298.9
270 HYDROGEN FLUORIDE 20.006 190.0 292.7
271 HYDROGEN IODIDE 127.912 222.4 237.6
272 HYDROGEN SULFIDE 34.080 187.6 212.8
273 IODINE 253.808 386.8 457.5
274 IODOBENZENE 204.011 241.8 461.4
275 ISOBUTANE 58.124 113.6 261.3
276 ISOBUTANOL 74.123 165.2 381.0
277 ISOBUTYL ACETATE 116.160 174.3 390.0
278 ISOBUTYL AMINE 73.139 188.0 340.6
279 ISOBUTYL FORMATE 102.134 178.0 371.6
280 ISOBUTYLBENZENE 134.222 221.7 445.9
281 ISOBUTYLCYCLOHEXANE 140.270 0.0 444.5
282 ISOBUTYLENE 56.108 132.8 266.3
283 ISOBUTYRALDEHYDE 72.107 208.2 337.0
284 ISOBUTYRIC ACID 88.107 227.2 427.9
285 ISOPROPYL ALCOHOL 60.096 184.7 355.4
286 ISOPROPYL AMINE 59.112 177.9 305.6
287 ISOPROPYL CHLORIDE 78.542 156.0 308.9
288 ISOPROPYLBENZENE 120.195 177.1 425.6
289 ISOPROPYLCYCLOHEXANE 126.243 183.4 427.7
290 ISOPROPYLCYCLOPENTANE 112.216 160.5 399.6
291 KETENE 42.038 138.0 232.0
292 KRYPTON 83.800 115.8 119.8
293 MALEIC ANHYDRIDE 98.058 326.0 472.8
294 M-CRESOL 108.140 285.4 475.4
295 M-DICHLOROBENZENE 147.004 248.4 446.0
296 METHANE 16.043 90.7 111.7
297 METHANOL 32.042 175.5 337.8
298 METHYCYCLOPENTANE 84.162 130.7 345.0
299 METHYL ACETATE 74.080 175.0 330.1
300 METHYL ACETYLENE 40.065 170.5 250.0
301 METHYL ACRYLATE 86.091 196.7 353.5
302 METHYL AMINE 31.058 179.7 266.8
303 METHYL BENZOATE 136.151 260.8 472.2
304 METHYL BROMIDE 94.939 179.5 276.7
305 METHYL BUTYRATE 102.134 188.4 275.8
306 METHYL CHLORIDE 50.488 175.4 248.9
307 METHYL ETHYL ETHER 60.096 134.0 280.5
308 METHYL ETHYL KETONE 72.107 186.5 352.8
309 METHYL ETHYL SULFIDE 76.157 167.2 339.8
310 METHYL FLUORIDE 34.033 131.4 194.8
311 METHYL FORMATE 60.052 174.2 304.9
312 METHYL HYDRAZINE 46.072 0.0 364.0
313 METHYL IODIDE 141.939 206.7 315.6
314 METHYL ISOBUTYL KETONE 100.161 189.0 389.6
315 METHYL ISOBUTYRATE 102.134 185.4 365.4
316 METHYL ISOCYANATE 57.052 0.0 312.0
317 METHYL ISOPROPYL KETONE 86.134 181.0 367.4
318 METHYL MERCAPTAN 48.107 150.0 279.1
319 METHYL N-PROPYL KETONE 86.134 196.0 375.5
320 METHYL PHENYL ETHER 108.140 235.7 426.8
321 METHYL PHENYL KETONE 120.151 292.8 474.9
322 METHYL PROPIONATE 88.107 185.7 353.0
323 METHYLAL 76.096 168.0 315.0
324 METHYLCYCLOHEXANE 98.189 146.6 374.1
325 M-ETHYLPHENOL 122.167 269.0 491.6
326 METHYLPHENYLAMINE 107.156 216.0 469.1
327 MONOETHANOLAMINE 61.084 283.5 443.5
328 MORPHOLINE 87.122 268.4 401.4
329 M-TERPHENYL 230.310 360.0 638.0
330 M-TOLUIDINE 107.156 242.8 476.5
331 M-XYLENE 106.168 225.3 412.3
332 N,N-DIMETHYLANILINE 121.183 275.6 466.7
333 NAPHTHALENE 128.174 353.5 491.1
334 N-BUTANE 58.124 134.8 272.7
335 N-BUTANOL 74.123 183.9 390.9
336 N-BUTYL AMINE 73.139 224.1 350.6
337 N-BUTYL-ACETATE 116.161 189.0 389.6
338 N-BUTYLANILINE 149.236 259.0 513.9
339 N-BUTYLBENZENE 134.222 185.2 456.4
340 N-BUTYLCYCLOHEXANE 140.270 198.4 454.1
341 N-BUTYRALDEHYDE 72.107 176.8 348.0
342 N-BUTYRIC ACID 88.107 267.9 436.4
343 N-DECANE 142.286 243.5 447.3
344 N-DECYCLCYCLOPENTANE 210.405 0.0 552.5
345 N-DECYCYCLOHEXANE 224.432 0.0 570.8
346 N-DODECENE 170.340 263.6 489.5
347 N-DODECYCLOPENTANE 238.459 0.0 584.1
348 N-EICOSANE 282.556 310.0 617.0
349 NEON 20.183 24.5 27.0
350 N-HEPTADECANE 240.475 295.0 575.2
351 N-HEPTANE 100.205 182.6 371.6
352 N-HEPTYLCYCLOPENTANE 168.324 0.0 497.3
353 N-HEXADECANE 226.448 291.0 560.0
354 N-HEXADECYLCYCLOPENTANE 294.567 0.0 637.0
355 N-HEXANE 86.178 177.8 341.9
356 N-HEXYLCYCLOPENTANE 154.297 0.0 476.3
357 NITRIC OXIDE 30.006 109.5 121.4
358 NITROGEN 28.013 63.3 77.4
359 NITROGEN DIOXIDE 46.006 261.9 294.3
360 NITROGEN TRIFLUORIDE 71.002 66.4 144.1
361 NITROMETHANE 61.041 244.6 374.4
362 NITROSYL CHLORIDE 65.459 213.5 2667.7
363 NITROUS OXIDE 44.013 182.3 184.7
364 N-NONADECANE 268.529 305.0 603.1
365 N-NONANE 128.259 219.7 424.0
366 N-NONYCLYCLOPENTANE 196.378 0.0 535.3
367 N-OCTADECANE 254.502 301.3 589.5
368 N-OCTANE 114.232 216.4 398.8
369 N-OCTYLCYCLOPENTANE 182.351 0.0 516.9
370 N-PENTADECANE 212.421 283.0 543.8
371 N-PENTADECYLCYCLOPENTANE 280.540 0.0 625.0
372 N-PENTANE 72.151 143.4 309.2
373 N-PROPYL ACETATE 102.134 178.0 374.8
374 N-PROPYL AMINE 59.112 190.0 321.8
375 N-PROPYL FORMATE 88.107 180.3 353.7
376 N-PROPYL PROPIONATE 116.161 197.3 395.7
377 N-PROPYLBENZENE 120.195 173.7 432.4
378 N-PROPYLCYCLOHEXANE 126.243 178.7 429.9
379 N-PROPYLCYCLOPENTANE 112.216 155.8 404.1
380 N-TETRADECANE 198.394 279.0 526.7
381 N-TETRADECYCLOPENT 266.513 0.0 599.0
382 N-TRIDECANE 184.367 267.8 508.6
383 N-TRIDECYLCYCLOPENTANE 252.486 0.0 598.6
384 N-UNDECENE 156.313 247.6 469.1
385 N-VALERIC ACID 102.134 239.0 458.7
386 O-CRESOL 108.140 304.1 464.2
387 O-DICHLOROBENZENE 147.004 256.1 453.6
388 O-ETHYLPHENOL 122.167 269.8 477.7
389 O-TERPHENYL 230.310 330.0 605.0
390 O-TOLUIDINE 107.156 258.4 473.3
391 OXYGEN 31.999 54.4 90.2
392 O-XYLENE 106.168 248.0 417.6
393 OZONE 47.998 80.5 161.3
394 P-CRESOL 108.140 307.9 475.1
395 P-DICLOROBENZENE 147.004 326.3 447.3
396 PERFLUOROBENZENE 186.056 0.0 353.4
397 PERFLUOROCYCLOHEXANE 300.047 0.0 325.7
398 PERFLUOROETHANE 100.016 130.7 197.5
399 PERFLUOROETHANE 138.012 172.4 194.9
400 PERFLUOROMETHYLCYCLOHEXANE 350.055 0.0 349.5
401 PERFLUORO-N-HEPTANE 388.051 195.0 355.7
402 PERFLUORO-N-HEXANE 338.044 186.0 330.3
403 P-ETHYLPHENOL 122.167 318.0 491.0
404 PHENANTHRENE 178.234 373.7 612.6
405 PHENETOLE 122.167 243.0 443.0
406 PHENOL 94.113 314.0 455.0
407 PHOSGENE 98.916 145.0 280.8
408 PHOSPHORUS TRICHLORIDE 137.333 161.0 349.0
409 PHTHALIC ANHYDRIDE 148.118 404.0 560.0
410 PIPERIDINE 85.150 262.7 379.7
411 PROPADIENE 40.065 136.9 238.7
412 PROPANE 44.097 85.5 231.1
413 PROPIONALDEHYDE 58.080 193.0 321.0
414 PROPIONIC ACID 74.080 252.5 414.0
415 PROPIONITRILE 55.080 180.3 370.5
416 PROPYL CHLORIDE 78.542 150.4 319.6
417 PROPYLENE 42.081 87.9 225.4
418 PROPYLENE OXIDE 58.080 161.0 307.5
419 P-TERPHENYL 230.310 485.0 649.0
420 P-TOLUIDINE 107.156 316.9 473.8
421 P-XYLENE 106.168 286.4 411.5
422 PYRIDINE 79.102 231.5 388.5
423 PYRROLE 67.091 0.0 403.0
424 PYRROLIDINE 71.123 0.0 359.7
425 SEC-BUTYLBENZENE 134.222 197.7 446.5
426 SEC-BUTYLCYCLOHEXANE 140.270 0.0 452.5
427 SILICON TETRACHLORIDE 169.898 204.3 330.4
428 SILICON TETRAFLUORIDE 104.080 183.0 187.0
429 STYRENE 104.152 242.5 418.3
430 SUCCINIC ACID 118.090 456.0 508.0
431 SULFUR DIOXIDE 64.063 197.7 263.0
432 SULFUR HEXAFLUORIDE 146.050 222.5 209.3
433 SULFUR TRIOXIDE 80.058 290.0 318.0
434 TERT-BUTANOL 74.123 298.8 355.6
435 TERT-BUTYL CHLORIDE 92.569 247.8 324.0
436 TERT-BUTYLBENZENE 134.222 215.3 442.3
437 TERT-BUTYLCYCLOHEXANE 140.270 232.0 444.7
438 TETRACHLOROETHYLENE 165.834 251.0 394.3
439 TETRAHYDROFURAN 72.107 164.7 339.1
440 THIOPHENE 84.136 234.9 357.3
441 TOLUENE 92.141 178.0 383.8
442 TRANS-1,2-DIMETHYLCYCLOHEXANE 112.216 185.0 396.6
443 TRANS-1,2-DIMETHYLCYCLOPENTANE 98.189 155.6 365.0
444 TRANS-1,3-DIMETHYLCYCLOHEXANE 112.216 183.0 397.6
445 TRANS-1,4-DIMETHYLCYCLOHEXANE 112.216 236.2 392.5
446 TRANS-2-BUTENE 56.108 167.6 274.0
447 TRANS-2-HEXENE 84.162 140.0 341.0
448 TRANS-2-OCTENE 112.216 185.4 398.1
449 TRANS-2-PENTENE 70.135 132.9 309.5
450 TRANS-3-HEXENE 84.162 159.7 340.3
451 TRANS-DECALIN 138.254 242.8 460.4
452 TRIBUTYLAMINE 185.355 0.0 486.6
453 TRICHLOROETHYLENE 131.389 186.8 360.4
454 TRICHLOROFLUOROMETHANE 37.368 162.0 297.0
455 TRIETHYLAMINE 101.193 158.4 362.7
456 TRIFLUOROACETIC ACID 114.024 257.9 345.6
457 TRIFLUOROBROMOMETHANE 148.910 0.0 214.0
458 TRIMETHYL AMINE 59.112 156.0 276.1
459 VALERALDEHYDE 86.134 182.0 376.0
460 VINYL ACETATE 86.091 173.0 346.0
461 VINYL CHLORIDE 62.499 119.4 259.8
462 VINYL ETHYL ETHER 72.107 157.9 308.8
463 VINYL FLUORIDE 46.044 130.0 235.5
464 VINYL FORMATE 72.064 215.5 319.6
465 VINYL METHYL ETHER 58.080 151.5 278.0
466 VINYLACETYLENE 52.076 227.6 278.1
467 WATER 18.015 273.2 373.2
468 XENON 131.300 161.3 165.0

Component-1 Component-2 Binary Mixtur A12


1-Propanol Water 1-Propanol + 906.5256
Acetone Chloroform Acetone + Chl 116.1171
Acetone Methanol Acetone + Met -114.4047
Acetone Water Acetone + Wat 344.3346
Acetone Toluene Acetone + Tol 809.1
Acetone IsopropylalcohAcetone + Isop 548.028
Acetone n-Hexane Acetone + n-H 956.23
Acetonitrile Water Acetonitrile + 328.86
Benzene Toluene Benzene + Tol 794.407
CCL4 Benzene CCL4 + Benzen 7.0459
Chloroform Methanol Chloroform + -361.7944
Dichloromethane Methanol Dichlorometha -243.987
Dichloromethane Ethylacetate Dichlorometha -174.549
Ethanol Benzene Ethanol + Ben 1264.4318
Ethanol Water Ethanol + Wat 325.0757
Ethylacetate Ethanol Ethylacetate + 58.8869
Ethylacetate Water Ethylacetate 1147.4
Ethylacetate Aceticacid Ethylacetate + -997.893
Methanol Benzene Methanol + B 1666.441
Methanol Ethylacetate Methanol + Et 982.2689
Methanol Water Methanol + W 82.9876
Methanol IsopropylalcohMethanol + Is -38.4124
Methanol Acetonitrile Methanol + Ace 667.303
Methanol Toluene Methanol + To 1753.94
Methylacetate Methanol Methylacetate -93.89
Methylacetate Ethylacetate Methylacetate 37.5877
Methylacetate Acetic acid Methylacetate -208.93
Methylacetate Water Methylacetate 887.37
N-Hexane Ethanol N-Hexane + Et 320.3611
THF Water THF + Water 1475.2583
Water Aceticacid Water + Acetic 813.1
Water N-Butanol Water + N-But 1549.66
Water Formic Acid Water + Formi -310.106
Water Toluene Water + Tolue 13433
Water Morpholine Water + Morph 1713.5
Water Pyridine Water + Pyridi 951.702
Water MIBK Water + MIBK 2561.13
CRITICAL CRITICAL CRITICAL CRITICAL ACENTRIC LIQ DEN REF T FOR DIPOLE
TEMP PRESSURE VOLUME COMPRESS FACTOR @TDEN LIQDEN MOMENT
K ATM CC/G-MOL G/CC K DEBYES
(TC) (PC) (VC) (ZC) (OMEGA) (LIQDEN) (TDEN) (DIPM)
5 6 7 8 9 10 11 12

346.2 37.1 221.0 0.289 0.257 0.000 0.0 2.3


551.0 0.0 0.0 0.000 0.000 1.645 298.0 0.0
602.0 41.0 294.0 0.240 0.220 1.441 293.0 1.7
579.5 29.0 0.0 0.000 0.252 0.000 0.0 0.0
569.5 27.9 0.0 0.000 0.211 0.000 0.0 0.0
418.6 32.6 294.0 0.279 0.000 1.455 298.0 0.0
523.0 50.0 240.0 0.280 0.248 1.168 298.0 2.0
386.6 44.4 181.0 0.253 0.266 0.000 0.0 2.3
302.8 44.0 154.0 0.273 0.000 0.000 0.0 1.4
591.0 29.3 416.0 0.250 0.238 0.785 289.0 0.0
547.0 34.0 360.0 0.270 0.273 0.759 289.0 0.0
487.2 33.7 304.0 0.256 0.252 1.580 289.0 0.0
719.0 34.7 0.0 0.000 0.303 0.973 293.0 0.0
651.0 39.0 348.0 0.250 0.310 1.389 293.0 0.0
664.5 34.1 430.0 0.270 0.390 0.894 293.0 0.6
675.0 29.0 480.0 0.250 0.426 0.838 354.0 0.0
649.1 31.9 430.0 0.258 0.390 0.880 289.0 0.3
443.7 44.4 219.0 0.267 0.255 0.652 293.0 0.4
418.9 32.2 293.0 0.275 0.255 1.480 277.0 0.5
561.0 53.0 220.0 0.250 0.286 1.250 289.0 1.8
577.0 44.0 226.0 0.210 0.240 1.150 293.0 1.9
536.0 38.2 271.0 0.235 0.371 0.867 293.0 0.0
503.0 40.2 276.0 0.269 0.173 0.693 293.0 0.0
625.0 60.0 237.0 0.280 0.000 1.036 293.0 3.6
637.3 30.9 433.0 0.260 0.398 0.865 293.0 0.1
425.0 42.7 221.0 0.270 0.195 0.621 293.0 0.0
658.0 59.0 241.0 0.260 0.000 1.053 293.0 3.7
587.0 51.4 238.0 0.254 0.288 1.033 293.0 0.4
657.9 27.7 480.0 0.250 0.403 0.862 293.0 0.1
478.0 37.4 276.0 0.263 0.104 0.661 293.0 0.4
507.0 34.0 328.0 0.260 0.160 0.692 293.0 0.0
419.6 39.7 240.0 0.277 0.187 0.595 293.0 0.3
463.7 46.5 220.0 0.270 0.050 0.650 289.0 0.8
410.2 40.7 231.0 0.279 0.000 1.100 303.0 2.1
542.0 36.4 312.0 0.255 0.218 0.886 293.0 2.0
700.0 22.0 600.0 0.230 0.000 0.830 293.0 1.8
615.0 21.8 650.0 0.280 0.491 0.741 293.0 0.0
657.0 18.3 0.0 0.000 0.558 0.758 293.0 0.0
770.0 12.0 0.0 0.000 0.000 0.000 0.0 0.0
633.0 30.0 435.0 0.250 0.560 0.822 293.0 1.7
537.2 28.0 440.0 0.280 0.358 0.697 293.0 0.3
717.0 13.2 0.0 0.000 0.721 0.788 283.0 0.0
610.0 40.0 381.0 0.300 0.560 0.819 293.0 1.8
504.0 31.3 350.0 0.260 0.285 0.673 293.0 0.4
592.0 29.5 0.0 0.000 0.250 0.000 0.0 0.0
651.0 30.0 460.0 0.260 0.294 0.881 293.0 0.0
670.0 28.6 0.0 0.000 0.277 0.876 293.0 0.0
666.0 29.0 0.0 0.000 0.279 0.861 293.0 0.0
637.0 28.0 490.0 0.260 0.360 0.865 293.0 0.0
640.0 29.0 470.0 0.260 0.322 0.861 293.0 0.0
653.0 27.9 0.0 0.000 0.371 0.857 293.0 0.0
772.0 35.2 445.0 0.250 0.334 1.020 293.0 0.5
592.0 23.1 580.0 0.280 0.430 0.745 273.0 0.0
747.0 14.0 0.0 0.000 0.000 0.812 332.0 1.7
739.0 11.2 0.0 0.000 0.807 0.789 293.0 0.0
58.0 34.0 490.0 0.310 0.530 0.826 293.0 2.0
566.6 25.9 464.0 0.260 0.386 0.715 293.0 0.3
704.0 14.4 0.0 0.000 0.682 0.791 273.0 0.0
586.0 38.0 326.0 0.260 0.580 0.815 293.0 1.7
464.7 40.0 300.0 0.310 0.245 0.640 293.0 0.4
493.4 40.0 278.0 0.275 0.164 0.690 293.0 0.9
536.7 51.0 218.5 0.253 0.624 0.804 293.0 1.7
689.0 15.4 0.0 0.000 0.644 0.786 273.0 0.0
496.0 39.4 275.0 0.266 0.175 0.676 293.0 0.7
674.0 16.8 0.0 0.000 0.598 0.766 293.0 0.0
637.0 19.7 0.0 0.000 0.518 0.751 293.0 0.0
488.7 30.4 359.0 0.272 0.231 0.649 293.0 0.0
563.4 26.9 436.0 0.254 0.297 0.716 293.0 0.0
623.1 24.8 0.0 0.000 0.360 0.000 0.0 0.0
607.6 27.0 0.0 0.000 0.279 0.000 0.0 0.0
592.7 25.7 0.0 0.000 0.311 0.000 0.0 0.0
531.1 29.2 398.0 0.267 0.251 0.690 293.0 0.0
588.0 24.6 0.0 0.000 0.332 0.000 0.0 0.0
543.9 25.3 468.0 0.266 0.303 0.692 293.0 0.0
574.7 24.5 0.0 0.000 0.315 0.719 293.0 0.0
573.7 23.4 0.0 0.000 0.321 0.720 289.0 0.0
581.5 21.6 0.0 0.000 0.374 0.000 0.0 0.0
568.0 23.0 519.0 0.260 0.357 0.717 289.0 0.0
433.8 31.6 303.0 0.269 0.197 0.591 293.0 0.0
549.0 39.0 319.0 0.280 0.000 0.783 327.0 0.0
549.8 25.0 478.0 0.264 0.338 0.695 293.0 0.0
520.4 27.4 416.0 0.267 0.289 0.674 293.0 0.0
499.9 30.9 358.0 0.270 0.247 0.662 293.0 0.0
573.5 27.8 455.0 0.269 0.290 0.726 293.0 0.0
607.6 26.8 0.0 0.000 0.299 0.000 0.0 0.0
533.0 28.6 400.0 0.260 0.192 0.705 293.0 0.0
56.3 26.9 461.0 0.267 0.317 0.719 293.0 0.0
501.0 32.0 343.0 0.270 0.221 0.678 293.0 0.0
524.0 33.2 351.0 0.270 0.239 0.708 293.0 0.0
563.4 25.9 468.0 0.262 0.346 0.712 293.0 0.0
537.3 28.7 393.0 0.256 0.299 0.695 293.0 0.0
655.4 0.0 0.0 0.000 0.000 0.942 298.0 2.2
722.8 0.0 0.0 0.000 0.000 0.000 0.0 0.0
553.5 25.2 472.0 0.262 0.343 0.700 293.0 0.0
519.7 27.0 418.0 0.265 0.306 0.673 293.0 0.0
707.6 0.0 0.0 0.000 0.000 0.000 0.0 2.0
550.0 24.5 42.0 0.262 0.352 0.693 293.0 0.0
644.2 0.0 0.0 0.000 0.000 0.938 273.0 2.2
723.0 0.0 0.0 0.000 0.000 0.000 0.0 1.5
701.0 0.0 0.0 0.000 0.000 0.000 0.0 0.0
536.0 41.4 268.0 0.252 0.576 0.807 293.0 1.7
488.6 50.2 221.0 0.277 0.124 0.691 293.0 0.8
520.6 39.0 305.0 0.280 0.300 0.873 293.0 2.1
613.0 27.2 494.0 0.267 0.000 0.833 293.0 1.8
460.4 33.4 306.0 0.271 0.227 0.620 293.0 0.1
497.5 29.7 367.0 0.267 0.279 0.653 293.0 0.0
484.0 38.0 276.0 0.264 0.164 0.681 293.0 0.3
571.0 38.0 322.0 0.260 0.700 0.819 293.0 0.0
465.0 34.0 294.0 0.262 0.232 0.650 293.0 0.5
470.0 34.0 318.0 0.280 0.285 0.662 293.0 0.0
518.0 32.4 351.0 0.270 0.229 0.691 289.0 0.0
567.0 26.7 443.0 0.254 0.330 0.719 293.0 0.0
559.6 24.5 488.0 0.260 0.378 0.702 289.0 0.0
530.3 27.0 421.0 0.261 0.330 0.679 293.0 0.0
761.0 34.6 462.0 0.260 0.382 0.990 313.0 0.4
637.0 27.0 494.0 0.260 0.520 0.821 293.0 1.6
609.6 22.9 0.0 0.000 0.388 0.000 0.0 0.0
610.0 26.4 0.0 0.000 0.338 0.752 293.0 0.0
490.0 32.1 340.0 0.270 0.121 0.653 293.0 0.0
562.0 26.2 443.0 0.252 0.321 0.710 293.0 0.0
536.3 29.1 414.0 0.274 0.270 0.693 293.0 0.0
568.8 26.6 466.0 0.265 0.338 0.719 293.0 0.0
683.8 0.0 0.0 0.000 0.000 0.954 298.0 1.9
729.8 0.0 0.0 0.000 0.000 0.000 0.0 1.7
667.2 0.0 0.0 0.000 0.000 0.939 298.0 2.6
715.6 0.0 0.0 0.000 0.000 0.000 0.0 1.8
565.4 25.7 455.0 0.252 0.361 0.718 289.0 0.0
540.6 28.5 416.0 0.267 0.310 0.698 0.3 0.0
504.4 30.8 367.0 0.273 0.275 0.664 293.0 0.0
496.0 40.6 267.0 0.266 0.160 0.686 293.0 0.0
579.5 38.0 329.0 0.260 0.580 0.810 293.0 1.8
450.0 34.7 300.0 0.282 0.209 0.627 293.0 0.0
545.0 39.0 319.0 0.280 0.500 0.809 293.0 1.9
576.6 27.7 455.0 0.267 0.304 0.727 293.0 0.0
518.0 32.4 351.0 0.270 0.269 0.694 293.0 0.0
563.6 25.1 464.0 0.252 0.369 0.706 293.0 0.0
535.2 27.8 404.0 0.256 0.324 0.687 293.0 0.0
521.0 32.5 350.0 0.270 0.207 0.698 293.0 0.0
646.0 44.0 311.0 0.260 0.270 0.955 293.0 0.0
490.0 30.0 360.0 0.270 0.290 0.669 293.0 0.0
561.7 25.1 476.0 0.259 0.369 0.705 293.0 0.0
493.0 30.0 360.0 0.270 0.290 0.669 293.0 0.0
461.0 55.0 154.0 0.220 0.303 0.778 293.0 2.5
594.4 57.1 171.0 0.200 0.454 1.049 293.0 1.3
569.0 46.2 290.0 0.287 0.000 1.087 293.0 3.0
508.1 46.4 209.0 0.232 0.309 0.790 293.0 2.9
548.0 47.7 173.0 0.184 0.321 0.782 293.0 3.5
508.0 58.0 204.0 0.280 0.344 1.104 293.0 2.4
308.3 60.6 113.0 0.271 0.184 0.615 189.0 0.0
506.0 51.0 0.0 0.000 0.330 0.839 293.0 2.9
615.0 56.0 210.0 0.230 0.560 1.051 293.0 0.0
536.0 45.0 210.0 0.210 0.350 0.806 293.0 3.5
545.0 56.4 203.0 0.256 0.630 0.855 288.0 0.0
514.0 47.0 234.0 0.260 0.130 0.937 293.0 2.0
585.0 39.0 265.0 0.220 0.390 0.835 293.0 3.4
654.0 33.6 397.0 0.250 0.000 0.911 293.0 0.0
405.6 111.3 72.5 0.242 0.250 0.639 273.2 1.5
699.0 52.4 270.0 0.247 0.382 1.022 293.0 1.6
883.0 0.0 0.0 0.000 0.000 0.000 0.0 0.0
150.8 48.1 74.9 0.291 -0.004 1.373 90.0 0.0
695.0 46.0 0.0 0.000 0.320 1.045 293.0 2.8
562.1 48.3 259.0 0.271 0.212 0.885 289.0 0.0
752.0 45.0 341.0 0.250 0.620 1.075 403.0 1.7
699.4 41.6 0.0 0.000 0.360 1.010 288.0 3.5
677.0 46.0 334.0 0.280 0.710 1.041 298.0 1.7
452.0 38.2 0.0 0.000 0.150 1.350 284.0 0.0
260.8 49.2 0.0 0.000 0.420 0.000 0.0 0.0
584.0 102.0 127.0 0.270 0.132 3.119 293.0 0.2
670.0 44.6 324.0 0.263 0.249 1.495 293.0 1.5
723.0 26.0 561.0 0.250 0.580 1.006 293.0 0.0
580.0 25.0 500.0 0.260 0.500 0.768 293.0 1.2
582.2 37.4 285.0 0.223 0.371 0.792 293.0 3.8
579.0 284.0 0.0 0.000 0.277 0.000 0.0 0.0
571.0 27.7 0.0 0.000 0.246 0.000 0.0 0.0
622.0 32.1 0.0 0.000 0.000 0.820 293.0 0.0
304.2 72.8 94.0 0.274 0.225 0.777 293.0 0.0
552.0 78.0 170.0 0.293 0.115 1.293 273.0 0.0
32.9 34.5 93.1 0.295 0.049 0.803 81.0 0.1
556.4 45.0 276.0 0.272 0.194 1.584 298.0 0.0
227.6 36.9 140.0 0.277 0.191 0.000 0.0 0.0
375.0 58.0 140.0 0.260 0.099 1.274 173.7 0.7
417.0 76.0 124.0 0.275 0.073 1.563 239.1 0.2
632.4 44.6 308.0 0.265 0.249 1.106 293.0 1.6
369.2 49.1 165.0 0.267 0.215 1.230 289.0 0.0
536.4 54.0 239.0 0.293 0.216 1.489 293.0 1.1
353.2 31.2 252.0 0.271 0.253 0.000 0.0 0.3
302.0 38.7 180.0 0.282 0.180 0.000 0.0 0.5
606.0 29.3 0.0 0.000 0.236 0.796 293.0 0.0
564.8 34.0 368.0 0.270 0.269 0.777 289.0 0.0
591.0 29.3 0.0 0.000 0.224 0.766 293.0 0.0
598.0 29.3 0.0 0.000 0.234 0.783 293.0 0.0
435.6 41.5 234.0 0.272 0.202 0.621 293.0 0.3
518.0 32.4 351.0 0.270 0.256 0.687 293.0 0.0
476.0 36.0 300.0 0.280 0.240 0.656 293.0 0.0
517.0 32.4 350.0 0.270 0.225 0.680 293.0 0.3
702.2 31.0 0.0 0.000 0.230 0.897 293.0 0.0
400.0 59.0 0.0 0.000 0.240 0.000 0.0 0.2
459.9 49.2 210.0 0.274 0.209 0.694 293.0 0.0
589.0 36.7 390.0 0.300 0.336 0.810 293.0 0.0
553.4 40.2 308.0 0.273 0.213 0.779 293.0 0.3
625.0 37.0 327.0 0.240 0.550 0.942 303.0 1.7
629.0 38.0 312.0 0.230 0.443 0.951 288.0 3.1
560.4 42.9 292.0 0.270 0.210 0.816 289.0 0.6
511.6 44.5 260.0 0.276 0.192 0.745 293.0 0.0
626.0 53.0 268.0 0.280 0.350 0.950 293.0 3.0
506.0 0.0 0.0 0.000 0.000 0.772 293.0 0.9
397.8 54.2 170.0 0.282 0.264 0.563 288.0 0.0
38.4 16.4 60.3 0.314 -0.130 0.165 22.7 0.0
644.0 213.8 55.6 0.225 0.000 1.105 293.0 1.9
583.0 71.0 0.0 0.000 0.000 2.500 293.0 1.9
596.0 25.0 517.0 0.260 0.590 0.767 293.0 1.1
0.0 0.0 0.0 0.000 0.000 1.047 293.0 0.0
385.0 40.7 217.0 0.280 0.176 1.750 158.0 0.5
510.0 60.0 193.0 0.277 0.193 1.317 298.0 1.8
451.6 51.0 197.0 0.272 0.202 1.380 282.0 1.3
437.6 52.4 187.0 0.272 0.288 0.656 293.0 0.0
496.6 36.6 301.0 0.270 0.299 0.707 293.0 1.1
642.0 0.0 0.0 0.000 0.000 0.998 293.0 2.0
561.0 36.9 336.0 0.269 0.347 0.814 293.0 2.7
557.0 39.1 318.0 0.272 0.300 0.837 293.0 1.6
681.0 6.0 316.0 0.260 0.000 1.116 293.0 0.0
657.0 18.0 720.0 0.240 0.700 0.794 293.0 0.0
500.0 28.4 386.0 0.267 0.340 0.724 293.0 1.2
400.0 53.0 178.0 0.287 0.192 0.667 293.0 1.3
628.0 39.3 0.0 0.000 0.000 1.150 288.0 0.0
503.0 54.6 201.0 0.266 0.190 0.848 293.0 1.5
789.0 38.0 502.0 0.295 0.364 0.990 347.0 0.0
766.0 31.0 0.0 0.000 0.440 1.066 303.0 1.1
29.4 0.0 0.0 0.000 0.471 1.006 293.0 0.4
550.0 31.0 407.0 0.280 0.455 0.738 293.0 1.0
679.0 19.0 718.0 0.240 0.000 0.835 293.0 1.6
305.4 48.2 148.0 0.285 0.098 0.548 183.0 0.0
516.2 63.0 167.0 0.248 0.635 0.789 293.0 1.7
523.2 37.8 286.0 0.252 0.363 0.901 293.0 1.9
552.0 37.0 320.0 0.261 0.400 0.921 293.0 0.0
456.0 55.5 178.0 0.264 0.284 0.683 293.0 1.3
697.0 32.0 451.0 0.250 0.480 1.046 293.0 1.9
503.8 61.5 215.0 0.320 0.254 1.451 298.0 2.0
531.0 30.0 390.0 0.270 0.400 0.749 293.0 1.2
566.0 31.0 395.0 0.260 0.470 0.879 293.0 1.8
460.4 52.0 199.0 0.274 0.190 0.896 293.0 2.0
466.7 35.9 280.0 0.262 0.281 0.713 293.0 1.3
375.3 49.6 169.0 0.272 0.238 0.000 0.0 2.0
508.4 46.8 229.0 0.257 0.283 0.927 289.0 2.0
553.0 30.0 410.0 0.270 0.427 0.869 293.0 2.1
499.0 54.2 207.0 0.274 0.190 0.839 293.0 1.5
546.0 33.2 345.0 0.256 0.395 0.895 289.0 1.8
500.6 32.1 0.0 0.000 0.331 0.733 293.0 1.2
617.1 35.6 374.0 0.263 0.301 0.867 293.0 0.4
609.0 29.9 450.0 0.270 0.243 0.788 293.0 0.0
569.5 33.5 375.0 0.269 0.283 0.771 289.0 0.0
282.4 49.7 129.0 0.276 0.085 0.577 163.0 0.0
645.0 76.0 186.0 0.270 0.000 1.114 293.0 2.2
0.0 0.0 0.0 0.000 0.000 0.833 298.0 1.9
469.0 71.0 140.0 0.258 0.200 0.899 273.0 1.9
593.0 62.0 206.0 0.260 0.510 0.896 293.0 1.9
144.3 51.5 66.2 0.288 0.048 1.510 85.0 0.0
560.1 44.9 271.0 0.265 0.245 1.024 293.0 1.4
408.0 65.0 0.0 0.000 0.253 0.815 253.0 2.3
580.0 0.0 0.0 0.000 0.000 1.226 288.0 1.5
490.2 54.3 218.0 0.294 0.204 0.938 293.0 0.7
726.0 66.0 255.0 0.280 0.000 1.261 293.0 3.0
5.2 2.2 57.3 0.301 -0.387 0.123 4.3 0.0
736.0 14.0 0.0 0.000 0.000 0.848 327.0 0.0
653.0 145.0 96.1 0.260 0.328 1.008 293.0 3.0
33.2 12.8 65.0 0.305 -0.220 0.071 20.0 0.0
363.2 84.4 100.0 0.283 0.063 2.160 216.0 0.8
324.6 82.0 81.0 0.249 0.120 1.193 188.1 1.1
456.8 53.2 139.0 0.197 0.407 0.688 293.0 3.0
461.0 64.0 69.0 0.120 0.372 0.967 293.0 0.0
424.0 82.0 131.0 0.309 0.050 2.803 237.0 0.5
373.2 88.2 98.5 0.284 0.100 0.993 213.6 0.9
819.0 115.0 155.0 0.265 0.299 3.740 453.2 1.3
721.0 44.6 351.0 0.265 0.246 1.855 277.0 1.4
408.1 36.0 263.0 0.283 0.176 0.557 293.0 0.1
547.7 42.4 273.0 0.257 0.588 0.802 293.0 1.7
561.0 30.0 414.0 0.270 0.479 0.875 293.0 1.9
516.0 42.0 284.0 0.280 0.000 0.000 0.0 1.2
551.0 38.3 350.0 0.296 0.390 0.885 293.0 1.9
650.0 31.0 480.0 0.280 0.378 0.853 293.0 0.3
659.0 30.8 0.0 0.000 0.319 0.795 293.0 0.0
417.9 39.5 239.0 0.275 0.190 0.594 293.0 0.5
513.0 41.0 274.0 0.270 0.350 0.789 293.0 0.0
609.0 40.0 292.0 0.230 0.610 0.968 293.0 1.3
508.3 47.0 220.0 0.248 0.000 0.786 293.0 1.7
476.0 50.0 229.0 0.290 0.297 0.688 293.0 0.0
485.0 46.6 230.0 0.269 0.232 0.862 293.0 2.1
631.0 31.7 428.0 0.260 0.335 0.862 293.0 0.4
640.0 28.0 0.0 0.000 0.237 0.802 293.0 0.0
601.0 29.0 0.0 0.000 0.240 0.776 293.0 0.0
380.0 64.0 145.0 0.300 0.207 0.000 0.0 1.4
209.4 54.3 91.2 0.288 -0.002 2.420 120.0 0.0
0.0 0.0 0.0 0.000 0.000 1.310 333.0 4.0
705.8 45.0 310.0 0.241 0.464 1.034 293.0 1.8
684.0 38.0 359.0 0.240 0.260 1.288 293.0 1.4
190.6 45.4 99.0 0.288 0.008 0.425 111.7 0.0
512.6 79.9 118.0 0.224 0.559 0.791 293.0 1.7
532.7 37.4 319.0 0.273 0.239 0.754 289.0 0.0
506.8 46.3 228.0 0.254 0.324 0.934 293.0 1.7
402.4 55.5 164.0 0.276 0.218 0.706 223.0 0.7
536.0 42.0 265.0 0.250 0.350 0.956 293.0 0.0
430.0 73.6 140.0 0.292 0.275 0.703 259.6 1.3
692.0 36.0 396.0 0.250 0.430 1.086 293.0 1.9
464.0 85.0 0.0 0.000 0.273 1.737 268.0 1.8
554.4 34.3 340.0 0.257 0.382 0.898 293.0 1.7
416.3 65.9 139.0 0.268 0.156 0.915 293.0 1.9
437.8 43.4 221.0 0.267 0.236 0.700 293.0 1.2
535.6 41.0 267.0 0.249 0.329 0.805 293.0 3.3
533.0 42.0 0.0 0.000 0.000 0.837 293.0 0.0
317.8 58.0 124.0 0.275 0.190 0.843 213.0 1.8
487.2 59.2 172.0 0.255 0.252 0.974 293.0 1.8
567.0 79.3 271.0 0.462 0.000 0.000 0.0 1.7
528.0 65.0 190.0 0.285 0.172 2.279 293.0 1.6
571.0 32.3 371.0 0.260 0.400 0.801 293.0 2.8
540.8 33.9 339.0 0.259 0.367 0.891 293.0 2.0
491.0 55.0 0.0 0.000 0.278 0.958 293.0 0.0
553.4 38.0 310.0 0.259 0.349 0.803 293.0 2.8
470.0 71.4 145.0 0.268 0.155 0.866 293.0 1.3
564.0 38.4 301.0 0.250 0.348 0.806 293.0 2.5
641.0 41.2 0.0 0.000 0.000 0.996 293.0 1.2
701.0 38.0 376.0 0.250 0.420 1.032 288.0 3.0
530.6 39.5 282.0 0.256 0.352 0.915 293.0 1.7
497.0 0.0 0.0 0.000 0.000 0.888 291.0 1.0
572.1 34.3 368.0 0.269 0.233 0.774 289.0 0.0
716.4 0.0 0.0 0.000 0.000 1.025 273.0 0.0
701.0 51.3 0.0 0.000 0.000 0.989 293.0 1.7
614.0 44.0 196.0 0.170 0.000 1.016 293.0 2.6
618.0 54.0 253.0 0.270 0.370 1.000 293.0 1.5
924.8 34.6 784.0 0.358 0.000 0.000 0.0 0.0
709.0 41.0 343.0 0.240 0.406 0.989 293.0 1.5
617.0 35.0 376.0 0.260 0.331 0.864 293.0 0.3
687.0 35.8 0.0 0.000 0.000 0.956 293.0 1.6
748.4 40.0 410.0 0.267 0.302 0.971 363.0 0.0
425.2 37.5 255.0 0.274 0.193 0.579 293.0 0.0
562.9 43.6 274.0 0.259 0.590 0.810 293.0 1.8
524.0 41.0 288.0 0.270 0.396 0.739 293.0 1.3
571.0 32.3 371.0 0.260 0.400 0.801 293.0 2.8
721.0 28.0 518.0 0.250 0.000 0.932 293.0 0.0
660.5 28.5 497.0 0.261 0.392 0.860 293.0 0.4
667.0 31.1 0.0 0.000 0.362 0.799 293.0 0.0
524.0 40.0 278.0 0.260 0.352 0.802 293.0 2.6
628.0 52.0 292.0 0.295 0.670 0.958 293.0 1.5
617.6 20.8 603.0 0.247 0.490 0.730 293.0 0.0
723.8 15.0 0.0 0.000 0.654 0.000 0.0 0.0
750.0 13.4 0.0 0.000 0.583 0.000 0.0 0.0
658.3 18.0 713.0 0.240 0.562 0.748 293.0 0.0
750.0 12.8 0.0 0.000 0.719 0.000 0.0 0.0
767.0 11.0 0.0 0.000 0.907 0.775 313.0 0.0
44.4 27.2 41.7 0.311 0.000 1.204 27.0 0.0
733.0 13.0 1000.0 0.220 0.770 0.778 293.0 0.0
540.2 27.0 432.0 0.263 0.351 0.684 293.0 0.0
679.0 19.2 0.0 0.000 0.515 0.000 0.0 0.0
717.0 14.0 0.0 0.000 0.742 0.773 293.0 0.0
791.0 9.6 0.0 0.000 0.861 0.000 0.0 0.0
507.4 29.3 370.0 0.260 0.296 0.659 293.0 0.0
660.1 21.1 0.0 0.000 0.476 0.000 0.0 0.0
180.0 64.0 58.0 0.250 0.607 1.280 121.0 0.2
126.2 33.5 89.5 0.290 0.040 0.804 78.1 0.0
431.4 100.0 170.0 0.480 0.860 1.447 292.9 0.4
234.0 44.7 0.0 0.000 0.132 1.537 144.0 0.2
588.0 62.3 173.0 0.224 0.346 1.138 293.0 3.1
440.0 90.0 139.0 0.350 0.318 1.420 261.0 1.8
309.6 71.5 97.4 0.274 0.160 1.226 183.6 0.2
756.0 11.0 0.0 0.000 0.827 0.789 305.0 0.0
594.6 22.8 548.0 0.260 0.444 0.718 293.0 0.0
710.5 16.3 0.0 0.000 0.610 0.000 0.0 0.0
745.0 11.9 0.0 0.000 0.790 0.777 301.0 0.0
568.8 24.5 492.0 0.259 0.394 0.703 293.0 0.0
694.0 17.7 0.0 0.000 0.564 0.000 0.0 0.0
707.0 15.0 880.0 0.230 0.706 0.769 293.0 0.0
780.0 10.1 0.0 0.000 0.833 0.000 0.0 0.0
469.6 33.3 304.0 0.262 0.251 0.626 293.0 0.0
549.4 32.9 345.0 0.252 0.392 0.887 293.0 1.8
497.0 46.8 233.0 0.267 0.229 0.717 293.0 1.3
538.0 40.1 285.0 0.259 0.315 0.911 289.0 1.9
578.0 0.0 0.0 0.000 0.000 0.881 293.0 1.8
638.3 31.6 440.0 0.265 0.344 0.862 293.0 0.4
639.0 27.7 0.0 0.000 0.258 0.793 293.0 0.0
603.0 29.6 425.0 0.250 0.335 0.781 289.0 0.0
694.0 16.0 830.0 0.230 0.679 0.763 293.0 0.0
772.0 11.1 0.0 0.000 0.789 0.000 0.0 0.0
675.8 17.0 780.0 0.240 0.623 0.756 293.0 0.0
761.0 11.9 0.0 0.000 0.755 0.000 0.0 0.0
638.8 19.4 660.0 0.240 0.535 0.740 293.0 0.0
651.0 38.0 340.0 0.240 0.616 0.939 293.0 0.0
697.6 49.4 282.0 0.240 0.443 1.028 313.0 1.6
697.3 40.5 360.0 0.225 0.272 1.306 293.0 2.3
703.0 0.0 0.0 0.000 0.000 1.037 273.0 0.0
891.0 38.5 769.0 0.405 0.000 0.000 0.0 0.0
694.0 37.0 343.0 0.260 0.435 0.998 293.0 1.6
154.6 49.8 73.4 0.288 0.021 1.149 90.0 0.0
630.2 36.8 369.0 0.263 0.314 0.880 293.0 0.5
261.0 55.0 88.9 0.288 0.215 1.356 161.3 0.6
704.6 50.8 0.0 0.000 0.515 1.019 313.0 1.6
685.0 39.0 372.0 0.260 0.270 1.248 328.0 0.0
516.7 32.6 0.0 0.000 0.400 0.000 0.0 0.0
457.2 24.0 0.0 0.000 0.000 0.000 0.0 0.0
306.4 38.9 175.0 0.271 0.226 1.519 197.0 0.0
292.8 0.0 224.0 0.000 0.000 1.590 195.0 0.0
486.8 23.0 0.0 0.000 0.482 0.000 0.0 0.0
474.8 16.0 664.0 0.273 0.560 1.733 293.0 0.0
451.7 18.8 442.0 0.224 0.730 0.000 0.0 0.0
716.4 0.0 0.0 0.000 0.000 0.000 0.0 0.0
878.0 0.0 0.0 0.000 0.000 0.000 0.0 0.0
647.0 33.8 0.0 0.000 0.000 0.979 277.0 1.2
694.2 60.5 229.0 0.240 0.440 1.059 313.0 1.6
455.0 56.0 190.0 0.280 0.204 1.381 293.0 1.1
563.0 0.0 260.0 0.000 0.000 1.574 294.0 0.9
810.0 47.0 368.0 0.260 0.000 0.000 0.0 5.3
594.0 47.0 289.0 0.280 0.250 0.862 293.0 1.2
393.0 54.0 162.0 0.271 0.313 0.658 238.0 0.2
369.8 41.9 203.0 0.281 0.152 0.582 231.0 0.0
496.0 47.0 223.0 0.260 0.313 0.797 293.0 2.7
612.0 53.0 230.0 0.242 0.536 0.993 293.0 1.5
564.4 41.3 230.0 0.205 0.318 0.782 293.0 3.7
503.0 45.2 254.0 0.278 0.230 0.891 293.0 2.0
365.0 45.6 181.0 0.275 0.148 0.612 223.0 0.4
482.2 48.6 186.0 0.228 0.269 0.829 293.0 2.0
926.0 32.8 779.0 0.336 0.000 0.000 0.0 0.7
667.0 0.0 0.0 0.000 0.000 0.964 323.0 1.6
616.2 34.7 379.0 0.260 0.324 0.861 293.0 0.1
620.0 55.6 254.0 0.277 0.240 0.983 293.0 2.3
640.0 0.0 0.0 0.000 0.000 0.967 294.0 1.8
568.6 55.4 249.0 0.296 0.000 0.852 295.0 1.6
664.0 29.1 0.0 0.000 0.274 0.862 293.0 0.4
669.0 26.4 0.0 0.000 0.264 0.813 293.0 0.0
507.0 37.0 326.0 0.290 0.264 1.480 293.0 0.0
259.0 36.7 0.0 0.000 0.000 1.660 178.0 0.0
647.0 39.4 0.0 0.000 0.257 0.906 293.0 0.1
0.0 0.0 0.0 0.000 0.000 0.000 0.0 2.2
430.8 77.8 122.0 0.268 0.251 1.455 263.0 1.6
318.7 37.1 198.0 0.281 0.286 1.830 223.0 0.0
491.0 81.0 130.0 0.260 0.410 1.780 318.0 0.0
506.2 39.2 275.0 0.259 0.618 0.787 293.0 1.7
507.0 39.0 295.0 0.280 0.190 0.842 293.0 2.1
660.0 29.3 0.0 0.000 0.265 0.867 293.0 0.5
659.0 26.3 0.0 0.000 0.252 0.813 293.0 0.0
620.0 44.0 290.0 0.250 0.000 1.620 293.0 0.0
540.2 51.2 224.0 0.259 0.000 0.889 293.0 1.7
579.4 56.2 219.0 0.259 0.200 1.071 289.0 0.5
591.7 40.6 316.0 0.264 0.257 0.867 293.0 0.4
596.0 29.3 0.0 0.000 0.242 0.776 293.0 0.0
553.2 34.0 362.0 0.270 0.269 0.756 289.0 0.0
598.0 29.3 0.0 0.000 0.189 0.785 293.0 0.0
590.0 29.3 0.0 0.000 0.242 0.763 293.0 0.0
428.6 40.5 238.0 0.274 0.214 0.604 293.0 0.0
516.0 32.3 351.0 0.270 0.242 0.678 293.0 0.0
580.0 27.3 0.0 0.000 0.350 0.720 293.0 0.0
475.0 36.1 300.0 0.280 0.237 0.649 293.0 0.0
519.9 32.1 350.0 0.260 0.227 0.677 293.0 0.0
690.0 31.0 0.0 0.000 0.270 0.870 293.0 0.0
643.0 18.0 0.0 0.000 0.000 0.779 293.0 0.8
571.0 48.5 256.0 0.265 0.213 1.462 293.0 0.9
471.2 43.5 248.0 0.279 0.188 0.000 0.0 0.5
535.0 30.0 390.0 0.270 0.329 0.728 293.0 0.9
491.3 32.2 0.0 0.000 0.000 1.535 273.0 2.3
340.2 39.2 200.0 0.280 0.000 0.000 0.0 0.7
433.2 40.2 254.0 0.287 0.195 0.633 293.0 0.6
554.0 35.0 333.0 0.260 0.400 0.810 293.0 2.6
525.0 43.0 265.0 0.260 0.340 0.932 293.0 1.7
429.7 55.3 169.0 0.265 0.122 0.969 259.0 1.5
475.0 40.2 260.0 0.270 0.000 0.793 293.0 1.3
327.8 51.7 144.0 0.277 0.000 0.000 0.0 1.4
475.0 57.0 210.0 0.310 0.550 0.963 293.0 0.0
436.0 47.0 205.0 0.270 0.340 0.750 293.0 0.0
455.0 49.0 202.0 0.260 0.092 0.710 273.0 0.0
647.3 217.6 56.0 0.229 0.344 0.998 293.0 1.8
289.7 57.6 118.0 0.286 0.002 3.060 165.0 0.0

A21
1396.6398
-506.8519
545.2942
1482.2133
-345.07
113.562
374.78
1689.3
-550.89
59.6233
1694.0241
1902.66
-212.107
266.6118
953.2792
570.0349
2084
2738.13
227.2126
-172.9317
520.6458
176.318
42.5767
307.37
847.4348
-40.9238
269.707
1966.7
2189.2896
1844.7926
-180.84
2050.2569
1180.804
3708.3
-1341.7
1143.85
1874.96
VAPOR HEAT CAPACITY LIQUID VISCOSITY STD HEAT STD ENERGY
CP=A+(B*T)+(C*T^2)+(D*T^3) LOG(V)=B*(1/T-1/C) FORM FORM
CAL/G-MOLE-K T AS K AND V AS CP KCAL/G-MOLE KCAL/G-MOLE
(A) (B) (C) (D) B C DELHG DELGF
13 14 15 16 17 18 19 20

1.3720 7.502E-02 -6.203E-05 2.010E-08 0.00 0.00 -178.2 -162.23


0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 0 0
1.5100 8.194E-02 -7.064E-05 2.339E-08 346.72 304.43 -33.1 -18.52
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 0 0
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 0 0
9.6620 7.830E-02 6.572E-05 1.868E-08 0.00 0.00 0 0
2.9790 6.439E-02 -4.896E-05 1.505E-08 412.27 239.10 -31.05 -17.47
2.0720 5.722E-02 -3.480E-05 8.107E-09 319.27 186.56 -118 -104.26
0.7340 5.839E-02 -5.014E-05 1.677E-08 0.00 0.00 -82.5 -76.84
-17.1220 2.149E-01 -1.199E-04 2.461E-08 0.00 0.00 -43.26 8.42
-13.8270 1.832E-01 -1.075E-04 2.413E-08 0.00 0.00 -33.05 9.33
14.6030 6.865E-02 -5.780E-05 1.649E-08 0.00 0.00 -178.1 0
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 6.6 39.9
6.4210 8.651E-02 -6.656E-05 2.099E-08 818.63 342.88 -44.4 -23.37
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4.3750 6.123E-02 -1.675E-05 -2.147E-09 259.01 153.30 -2.67 15.05
-7.8640 1.655E-01 -1.342E-04 4.788E-08 344.33 197.95 -12.88 18.27
-3.0620 1.799E-01 -1.061E-04 2.509E-08 427.64 240.32 -22.59 22.15
0.4650 9.988E-02 -5.201E-05 1.052E-08 349.33 176.62 -7.59 16.71
-1.0360 1.316E-01 -7.840E-05 1.922E-08 344.33 197.95 -13.01 18.55
-23.3280 2.495E-01 -1.308E-04 2.145E-08 702.27 339.66 -43.57 17.55
1.9090 2.861E+00 -1.000E+00 -1.601E+00 -4.00 3.46 -8 889.06
7.2070 5.462E-05 -5.324E-05 1.696E-08 145.60 196.60 -1.4 4.75
9.7890 3.893E-02 -3.383E-05 9.903E-09 0.00 0.00 -68 -58.64
-4.4020 1.709E-01 -1.049E-04 2.609E-08 355.52 214.48 -23.8 26.36
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 0 0
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 -155.1 -148.8
-1.9600 9.486E-02 -5.299E-05 1.104E-08 0.00 0.00 -5.7 23.64
3.4010 1.034E-01 -5.033E-05 7.553E-09 521.30 252.03 -54.45 -25.88
3.6210 6.676E-02 -2.103E-05 -3.965E-09 457.89 235.35 -75.5 0
1.4210 4.823E-02 -3.669E-05 1.140E-08 276.90 167.04 8.4 12.31
4.1270 7.729E-02 -3.514E-05 5.134E-09 349.95 189.02 -33.5 0
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 0 0
6.6430 4.392E-02 -8.502E-06 -5.577E-08 428.40 224.83 0 0
3.7330 5.592E-02 -2.316E-05 2.537E-09 318.41 180.98 0 0
1.6140 6.785E-02 -5.410E-05 1.782E-08 0.00 0.00 72.8 73.13
7.7010 4.595E-04 2.521E-06 -8.590E-10 658.25 283.16 -57.8 -54.64
0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00 0 0
ANTOINE VAPOR PRESSURE EQN VAP PRESS VAP PRESS HARLACHER VAPOR PRESSURE EQN
LN(P)=A-B/(T+C) MAX TEMP MIN TEMP LN(PVP)=A+B/T+C*LN(T)+(D*PVP/(T^2))
P AS mmHg AND T AS K K K PVP AS mmHg AND T AS K
A B C TMX TMN A B C
21 22 23 24 25 26 27 28

15.8965 1814.91 -29.92 300 270 50.589 -3540.17 -5.223


0.0000 0.00 0.00 0 0 75.315 -7113.72 -8.344
16.0381 3110.79 -56.16 428 302 0.000 0.00 0.000
15.7084 3015.51 -54.59 414 279 0.000 0.00 0.000
15.6794 2938.09 -53.25 404 273 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.0842 2697.29 -45.03 352 242 56.233 -5422.68 -5.726
16.1871 2095.35 -29.16 273 238 48.591 -3837.61 -4.811
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.9647 4276.08 -52.80 480 345 0.000 0.00 0.000
15.6973 2807.94 -51.20 390 260 0.000 0.00 0.000
15.8424 2523.61 -45.67 360 250 57.097 -5249.75 -5.913
16.2805 4009.49 -64.89 500 365 0.000 0.00 0.000
16.1246 3417.27 -69.15 470 315 0.000 0.00 0.000
16.2121 3670.22 -66.07 479 329 0.000 0.00 0.000
16.3023 3850.91 -71.72 500 361 64.139 -8300.92 -6.478
16.2190 3622.58 -64.59 471 324 56.241 -7256.56 -5.459
16.1039 2397.26 -30.88 305 245 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 52.316 -4327.01 -5.350
16.1764 2927.17 -50.22 373 240 51.956 -5712.66 -4.991
16.0385 2985.07 -52.16 408 288 0.000 0.00 0.000
16.0210 2869.79 -53.15 393 262 0.000 0.00 0.000
15.9297 2544.34 -44.30 340 250 0.000 0.00 0.000
20.5324 6091.95 -22.46 483 357 0.000 0.00 0.000
16.2893 3614.19 -63.57 466 321 58.041 -7326.78 -5.706
15.7727 2142.66 -34.30 290 215 0.000 0.00 0.000
17.2917 3888.84 -123.20 525 380 0.000 0.00 0.000
16.1327 2966.88 -62.15 410 275 0.000 0.00 0.000
16.1140 3657.22 -71.18 487 335 0.000 0.00 0.000
15.7392 2344.02 -41.69 320 240 0.000 0.00 0.000
16.1351 2728.54 45.45 350 282 0.000 0.00 0.000
15.7564 2132.42 -33.15 295 190 48.333 -3996.80 -4.788
16.0605 2271.42 -40.30 300 200 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
15.9750 2826.26 -49.05 385 255 0.000 0.00 0.000
15.9395 3389.43 -139.00 503 376 0.000 0.00 0.000
16.0129 3448.18 -76.09 460 356 73.938 -8380.48 -7.950
16.0610 3729.87 -90.88 517 361 82.968 -9846.99 -9.073
15.8233 3912.10 -203.10 679 492 0.000 0.00 0.000
15.3068 2626.42 -146.60 449 333 0.000 0.00 0.000
15.8894 2895.51 -53.97 400 265 60.035 -6147.41 -6.211
357.8500 -59.23 40.99 16.2203 4245 -115.200 592.00 420.000
18.0994 4055.45 -76.49 430 308 0.000 0.00 0.000
15.8089 2654.81 -47.30 360 240 55.909 -5423.07 -5.705
15.8222 3120.66 -55.06 422 286 0.000 0.00 0.000
16.1253 3535.33 -65.85 467 321 64.337 -7662.94 -6.617
15.9809 3564.52 -70.00 481 330 0.000 0.00 0.000
15.9811 3543.79 -69.22 478 328 67.726 -8033.58 -7.076
30.2200 16.15 3521.08 -64.64 463 318.000 65.67 -7678.110
16.1135 3516.31 -64.23 463 318 61.404 -7422.59 -6.212
15.9424 3539.21 -70.10 480 329 63.225 -7800.97 -6.432
16.2008 4206.70 -78.15 551 380 0.000 0.00 0.000
16.0118 3305.03 -67.61 448 308 69.085 -7626.91 -7.339
15.6898 3757.82 -193.10 658 474 0.000 0.00 0.000
16.2221 4416.13 -127.30 623 444 0.000 0.00 0.000
15.7428 3017.81 -137.10 468 343 0.000 0.00 0.000
15.9630 3116.52 -60.39 420 288 64.487 6883.34 -6.765
347.4600 -54.31 38.97 16.1539 4103.15 -110.600 574.00 406.000
16.5270 3026.89 -105.00 411 310 0.000 0.00 0.000
15.7646 2405.96 -39.63 325 220 51.816 -4694.26 -5.202
16.0429 2515.62 -45.97 335 230 0.000 0.00 0.000
17.5439 3166.38 -80.15 400 285 101.820 -9416.25 -11.790
336.1300 -49.36 36.99 16.1643 4018.01 -102.700 557.00 392.000
15.9182 2541.69 -41.43 340 250 0.000 0.00 0.000
323.7100 -44.45 34.96 16.085 3856.23 -97.940 537.00 377.000
16.0412 3597.72 -83.41 496 345 78.295 -9105.75 -8.489
15.5536 2489.50 -43.81 350 230 51.470 -4910.28 -5.314
15.7162 2981.56 -54.73 409 277 58.179 -6218.74 -5.942
15.7598 3371.05 -64.09 463 314 0.000 0.00 0.000
15.7280 3220.55 -59.31 440 328 64.104 -7011.38 -6.731
15.7363 3167.42 -58.21 430 318 0.000 0.00 0.000
15.6398 2764.40 -47.10 379 254 52.761 -5431.67 -5.251
15.8017 3164.17 -61.66 436 297 0.000 0.00 0.000
15.6850 2896.28 -52.41 398 269 58.265 -6039.34 -5.988
15.6488 3049.98 -57.13 413 313 0.000 0.00 0.000
15.7639 3084.08 -61.94 428 291 0.000 0.00 0.000
15.8446 3172.92 -66.15 438 300 0.000 0.00 0.000
15.7445 3052.17 -62.24 420 315 0.000 0.00 0.000
15.2069 2034.15 -45.37 305 260 49.600 -4213.21 -4.977
18.1336 3694.96 -65.00 406 328 0.000 0.00 0.000
15.7431 2932.56 -58.08 405 276 61.971 -6425.90 -6.475
15.6917 2740.15 -49.85 378 254 55.514 -5590.61 -5.636
15.6802 2595.44 -44.25 354 235 51.700 -5061.44 -5.138
15.7578 3057.94 -52.77 415 280 56.436 -6186.92 -5.685
15.8029 3269.07 -58.19 425 325 0.000 0.00 0.000
15.6536 2719.47 -49.56 375 253 0.000 0.00 0.000
15.7818 3028.09 55.62 413 280 58.957 -6346.90 -6.033
15.8012 2612.69 -43.78 360 235 0.000 0.00 0.000
16.0043 2798.63 -47.71 375 250 0.000 0.00 0.000
15.8189 3029.06 -58.99 415 283 61.855 -6587.23 -6.425
15.7815 2850.64 -51.33 388 262 57.249 -5882.73 -5.843
17.1492 4219.74 -33.04 440 420 0.000 0.00 0.000
16.2424 3724.58 -102.40 500 420 0.000 0.00 0.000
15.7797 2965.44 -58.36 408 278 62.103 -6487.48 -6.482
15.7179 2744.78 -51.52 378 256 0.000 0.00 0.000
16.2456 3655.26 -103.80 500 410 0.000 0.00 0.000
15.7954 2964.06 -58.74 408 278 62.872 -6532.90 -6.590
16.3046 3545.14 -63.59 435 350 0.000 0.00 0.000
16.2368 3667.32 -102.40 490 410 0.000 0.00 0.000
16.2809 3749.35 -85.55 480 400 0.000 0.00 0.000
17.2102 3026.03 -86.65 393 298 0.000 0.00 0.000
16.2871 2536.78 -37.34 320 240 0.000 0.00 0.000
15.9907 2753.43 -47.15 375 250 0.000 0.00 0.000
15.3614 2773.46 -140.00 458 348 0.000 0.00 0.000
15.6338 2348.67 -40.05 322 216 50.428 -4565.64 -5.021
15.7476 2614.38 -46.58 370 240 55.352 -5301.22 -5.650
15.8548 2467.40 -39.64 330 250 0.000 0.00 0.000
16.2708 2752.19 -116.30 402 307 0.000 0.00 0.000
15.8260 2426.42 -40.36 325 220 60.581 -5160.84 -6.474
15.9238 2521.53 -40.31 335 226 55.255 -5010.98 -5.671
15.9423 2725.89 -47.64 370 245 0.000 0.00 0.000
15.8040 3035.08 -57.84 415 282 0.000 0.00 0.000
15.9278 3079.63 -59.46 417 285 65.685 -6865.40 -6.957
15.8261 2845.06 -53.60 390 264 60.131 -6074.01 -6.244
16.2758 4237.37 -74.75 548 377 0.000 0.00 0.000
14.7108 2441.66 -150.70 453 345 0.000 0.00 0.000
15.7848 3305.20 -67.66 458 313 0.000 0.00 0.000
15.8709 3341.62 -57.57 440 350 0.000 0.00 0.000
15.3755 2326.80 -48.24 340 225 0.000 0.00 0.000
15.7755 3011.51 -55.71 411 279 59.518 -6352.78 -6.118
15.7190 2829.10 -47.83 385 260 54.572 -5634.72 -5.487
15.8415 3062.52 -58.29 417 284 61.319 -6588.72 -6.344
16.9517 4237.04 -41.65 460 400 0.000 0.00 0.000
16.3004 3733.53 -113.90 520 430 0.000 0.00 0.000
16.8850 4106.95 -44.45 460 400 0.000 0.00 0.000
16.4192 3775.91 -109.00 500 410 0.000 0.00 0.000
15.8671 3057.57 -60.55 418 286 0.000 0.00 0.000
15.8317 2882.44 -53.26 392 266 0.000 0.00 0.000
15.7701 2653.43 -46.02 365 240 54.479 -5323.33 -5.509
15.9880 2541.83 -42.26 335 250 0.000 0.00 0.000
16.7127 3026.43 -104.10 426 298 0.000 0.00 0.000
15.7179 2333.61 -36.33 315 210 0.000 0.00 0.000
15.0113 1988.08 -137.80 375 298 0.000 0.00 0.000
15.8126 3102.06 53.47 418 283 0.000 0.00 0.000
15.9124 2731.79 -46.47 364 248 0.000 0.00 0.000
15.8865 3065.96 -60.74 418 286 64.371 -6817.44 -6.763
15.8133 2855.66 -53.93 390 265 59.325 -6059.25 -6.123
15.9484 2750.50 -48.33 366 250 0.000 0.00 0.000
16.2143 3409.40 -62.65 460 300 0.000 0.00 0.000
15.7527 2580.52 -46.56 352 218 0.000 0.00 0.000
15.8893 3057.05 -60.59 417 285 64.394 -6799.54 -6.769
15.8425 2631.57 -46.00 354 240 0.000 0.00 0.000
16.2481 2465.15 -37.15 320 210 0.000 0.00 0.000
16.8080 3405.57 -56.34 430 290 57.834 -6841.98 -5.647
16.3982 3287.56 -75.11 437 308 0.000 0.00 0.000
16.6513 2940.46 -35.93 350 241 0.000 0.00 0.000
16.2874 2945.47 -49.15 390 260 47.394 -5392.43 -4.357
15.7514 2447.33 -55.33 355 237 0.000 0.00 0.000
16.3481 1637.18 -19.77 202 194 46.122 -2891.04 -4.162
15.9057 2606.53 -45.15 360 235 0.000 0.00 0.000
16.5617 3319.18 -80.15 450 315 0.000 0.00 0.000
15.9253 2782.21 -51.15 385 255 0.000 0.00 0.000
16.9066 2928.20 -85.15 400 286 0.000 0.00 0.000
15.9772 2531.92 -47.15 350 230 0.000 0.00 0.000
16.0019 3128.75 -58.15 430 400 0.000 0.00 0.000
16.3308 3644.30 -67.15 493 348 0.000 0.00 0.000
16.9481 2132.50 -32.98 261 179 51.947 -4104.67 -5.146
16.6748 3857.52 -73.15 500 340 65.881 -8442.37 -6.662
405.8100 53.70 0.00 17.6701 6492.44 -26.130 655.00 490.000
15.2330 700.51 -5.84 94 81 31.173 -1039.64 -2.382
16.3501 3748.62 -66.12 460 300 0.000 0.00 0.000
15.9008 2788.51 -52.36 377 280 52.100 -5557.61 -5.072
17.1634 4190.70 -125.20 560 405 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 59.774 -7912.31 -5.881
17.4582 4384.81 -73.15 603 385 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 52.723 -4443.16 -5.404
0.0000 0.00 0.00 0 0 67.758 -3748.59 -2.819
15.8441 2582.32 -51.56 354 259 0.000 0.00 0.000
15.7972 3313.00 -67.71 450 320 56.566 -7005.23 -5.548
16.3363 4158.47 -94.15 570 390 0.000 0.00 0.000
16.0778 3296.15 -66.15 455 305 0.000 0.00 0.000
16.2092 3202.21 -56.16 433 307 56.605 -6476.68 -5.599
15.7543 3073.95 54.20 418 283 0.000 0.00 0.000
15.7756 3009.70 53.23 417 282 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
22.5898 3103.39 -0.16 204 154 52.730 -3146.64 -3.572
15.9844 2690.83 -31.62 342 223 37.410 -4233.99 -3.072
14.3686 530.22 -13.15 108 63 32.981 -997.18 -3.216
15.8742 2808.19 -45.99 374 253 351.009 -5386.51 -0.953
16.0543 1244.55 -13.06 148 93 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 41.853 -3137.78 -3.914
15.9610 1978.32 -27.01 264 172 42.217 -3412.28 -3.894
16.0676 3295.12 -55.60 420 320 57.251 -6684.47 -5.686
15.5602 1704.80 -41.30 240 223 52.663 -3763.03 -3.474
15.9732 2696.79 -46.16 370 260 52.872 -5359.56 -5.200
15.7343 1848.90 -30.88 230 175 15.878 -3659.53 -5.433
0.0000 0.00 0.00 0 0 44.255 -2769.96 -4.415
15.6535 3043.34 -55.30 420 283 52.143 -6026.09 -5.055
15.7729 2922.30 -52.94 400 270 0.000 0.00 0.000
15.7470 3081.95 -55.08 420 284 0.000 0.00 0.000
15.7333 3098.39 -57.00 425 287 53.571 -6219.26 -5.233
15.8171 2210.71 -36.15 305 200 49.609 -4217.05 -4.938
16.2057 2897.97 -39.30 370 245 0.000 0.00 0.000
15.8251 2459.05 -42.56 330 220 55.199 -4985.30 -5.668
15.8384 2680.52 -48.40 365 245 0.000 0.00 0.000
15.8312 3671.61 -69.74 495 368 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 58.323 -4390.80 -6.185
15.9254 2359.09 -31.78 290 200 0.000 0.00 0.000
15.7818 3066.05 -56.80 435 330 0.000 0.00 0.000
15.7527 2766.63 -50.50 380 280 53.451 -5562.12 -5.303
0.0000 0.00 0.00 0 0 86.548 -9573.09 -9.539
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
15.8243 2813.53 -49.98 360 300 0.000 0.00 0.000
15.8574 2588.48 -41.79 345 230 0.000 0.00 0.000
16.0897 3193.92 -66.15 440 300 0.000 0.00 0.000
15.9356 2583.07 -39.87 378 244 0.000 0.00 0.000
15.8599 1971.04 -26.65 245 180 0.000 0.00 0.000
13.2954 157.89 0.00 25 19 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.7307 3721.90 -64.15 459 322 0.000 0.00 0.000
336.2400 0.00 0.00 16.9539 4852.47 -138.100 657.00 469.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.3029 2622.44 -41.70 332 229 53.767 -5110.20 5.364
0.0000 0.00 0.00 0 0 54.563 -4629.02 -5.590
16.2653 2358.77 -35.15 310 218 67.611 -5350.44 -7.435
16.0545 2595.01 -53.15 350 242 64.890 -5912.65 -6.955
16.0607 3421.57 -64.19 455 312 0.000 0.00 0.000
16.8138 3410.51 -40.15 400 275 111.200 -9773.63 -13.260
15.9531 2896.27 -54.49 390 260 0.000 0.00 0.000
17.0326 4122.52 -122.50 560 402 0.000 0.00 0.000
16.3372 3982.78 -89.15 545 373 0.000 0.00 0.000
16.3417 2895.73 -43.15 364 249 0.000 0.00 0.000
16.8467 2361.44 -17.10 265 179 48.857 -3840.19 -4.856
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.0001 2511.56 -42.35 331 226 0.000 0.00 0.000
16.6832 4602.23 -70.42 545 343 0.000 0.00 0.000
16.3459 4310.25 -87.31 598 418 0.000 0.00 0.000
14.4856 2902.44 -167.90 563 473 0.000 0.00 0.000
16.5939 3259.08 -55.15 422 302 0.000 0.00 0.000
398.8900 -105.84 -20.81 15.2638 3242.04 -157.100 580.00 407.000
15.6637 1511.42 -17.16 199 130 38.759 -2464.42 -3.601
18.9119 3803.98 -41.68 369 270 83.319 -7994.90 -9.201
16.1516 2790.50 -57.15 385 260 65.669 -6394.77 -6.965
16.0890 2974.94 -58.15 409 274 0.000 0.00 0.000
17.0073 2618.73 -37.30 316 215 64.056 -5352.01 -6.875
16.2065 3845.09 -84.15 531 361 0.000 0.00 0.000
15.9338 2511.68 -41.44 333 226 37.985 -4246.27 -3.090
16.0477 2921.52 -55.15 400 265 0.000 0.00 0.000
15.9987 3127.60 -60.15 432 288 0.000 0.00 0.000
15.9800 2332.01 -36.48 310 200 48.665 -4364.03 -4.733
16.0828 2511.29 -41.95 30 225 57.260 -5105.90 -3.945
16.0686 1966.89 -27.00 252 170 0.000 0.00 0.000
16.1611 2603.30 -54.15 360 240 60.604 -5724.26 -6.305
0.0000 0.00 0.00 0 0 74.336 -7477.19 -8.108
16.0077 2497.23 -41.77 330 224 51.954 -4900.34 -5.139
16.1620 2935.11 -64.17 396 276 67.631 -6869.83 -7.193
15.4539 2423.41 -62.28 360 246 58.911 -5663.85 -6.100
16.0195 3279.47 -59.95 450 300 58.100 -6792.54 -5.802
15.8125 3183.25 -58.15 433 293 0.000 0.00 0.000
15.8581 2990.13 -52.47 402 270 0.000 0.00 0.000
15.5368 1347.01 -18.15 182 120 38.961 -2282.37 -3.678
20.2501 6022.18 -28.25 494 364 0.000 0.00 0.000
16.4227 2610.44 -63.15 359 248 0.000 0.00 0.000
16.7400 2567.61 -29.01 310 200 0.000 0.00 0.000
16.4082 3108.49 -72.15 425 292 0.000 0.00 0.000
15.6700 714.10 -6.00 91 59 30.772 -1040.27 -2.683
16.5487 3181.78 -37.59 370 250 55.141 -5819.21 -5.489
16.4775 2204.13 -30.15 271 185 45.118 -3873.26 -4.200
16.9882 3599.58 -26.09 409 271 0.000 0.00 0.000
16.0612 2442.70 -45.41 363 238 0.000 0.00 0.000
17.2392 4487.04 -140.20 600 440 0.000 0.00 0.000
12.2514 33.73 1.79 4.3 3.7 8.622 -12.23 0.433
15.6161 3672.62 -188.10 656 464 0.000 0.00 0.000
17.9899 3877.65 -45.15 343 288 56.096 -6951.84 -5.286
13.6333 164.90 3.19 25 14 12.050 -114.95 0.048
14.4687 1242.53 -47.86 221 184 28.102 -2394.35 -1.843
16.5040 1714.25 -14.45 200 137 38.614 -2626.67 -3.443
16.5138 2585.80 -37.15 330 234 37.742 -4183.37 3.004
17.6958 3404.49 15.06 313 206 26.160 -3496.52 -1.338
12.9149 957.96 -85.06 256 215 33.884 -3013.08 -2.673
16.1040 1768.69 -26.06 230 190 42.687 -3132.31 -3.985
16.1597 3709.23 -68.16 487 383 0.000 0.00 0.000
16.1454 3776.53 -64.38 470 290 57.691 -7589.50 -5.646
15.5381 2032.73 -33.15 280 187 46.141 -3771.21 -4.509
16.8712 2874.73 -100.30 388 293 0.000 0.00 0.000
16.1714 3092.83 -66.15 427 289 0.000 0.00 0.000
16.1419 2704.16 -56.15 373 251 0.000 0.00 0.000
16.2292 2980.47 -64.15 409 278 58.420 -6314.51 -5.879
15.9524 3512.47 -69.03 476 326 0.000 0.00 0.000
15.8141 3437.99 -69.99 455 355 0.000 0.00 0.000
15.7528 2125.75 -33.15 290 190 50.832 -4104.56 -5.157
15.9888 2676.98 -51.15 370 247 0.000 0.00 0.000
16.7792 3385.49 -94.15 465 330 82.657 -9222.72 -8.986
18.6929 3640.20 -53.54 374 273 0.000 0.00 0.000
16.3637 2582.35 -40.15 337 239 0.000 0.00 0.000
16.0384 2490.48 -43.15 340 225 0.000 0.00 0.000
15.9722 3363.60 -63.37 454 311 46.941 -6285.25 -4.227
15.8260 3346.12 -63.71 440 330 0.000 0.00 0.000
15.8561 3176.22 -55.18 427 289 0.000 0.00 0.000
16.0197 1849.21 -35.15 255 170 0.000 0.00 0.000
15.2677 958.75 -8.71 129 113 30.717 -1408.77 -2.579
16.2747 3765.65 -82.15 516 352 0.000 0.00 0.000
17.2878 4274.42 -74.09 480 370 79.796 -9855.80 -8.509
16.8173 4104.13 -43.15 475 326 0.000 0.00 0.000
15.2243 897.84 -7.16 120 93 30.175 -1300.61 -2.641
18.5875 3626.55 -34.29 364 257 72.268 -7064.20 -7.680
15.8023 2731.00 -47.11 375 250 0.000 0.00 0.000
16.1295 2601.92 -56.15 360 245 61.268 -5840.56 -6.374
15.6227 1850.66 -44.07 267 183 0.000 0.00 0.000
16.1088 2788.43 -59.15 390 260 0.000 0.00 0.000
17.2622 2484.83 -32.92 311 212 62.306 -4954.32 -6.642
16.2272 3751.83 -81.51 516 350 0.000 0.00 0.000
16.0252 2271.71 -34.83 326 215 55.295 -4467.46 -5.788
0.0000 0.00 0.00 0 0 65.898 -6819.11 -6.941
16.1052 2077.97 -29.55 266 180 43.660 -3642.21 -4.064
13.5435 1161.63 -112.40 310 205 74.838 -5631.77 -8.549
16.5986 3150.42 -36.65 376 257 47.683 -5328.22 -4.426
15.9765 2722.95 -48.37 360 250 0.000 0.00 0.000
16.3428 1704.41 -19.27 209 141 43.063 -2890.54 -4.102
16.5104 2590.87 -42.60 324 225 57.840 -5258.90 -5.939
15.1424 2319.84 -91.70 400 270 0.000 0.00 0.000
16.0905 2639.55 -36.50 325 260 47.781 -4686.90 -4.577
15.7165 2893.66 -70.75 425 285 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 66.160 -6637.51 -7.016
16.3258 2480.37 -56.31 340 230 0.000 0.00 0.000
14.1779 1993.12 -103.20 406 271 0.000 0.00 0.000
16.1909 2338.38 -34.44 300 200 46.610 -4233.88 -4.408
16.0031 2934.87 -62.25 410 275 0.000 0.00 0.000
16.2394 3430.82 -69.58 440 370 0.000 0.00 0.000
16.2384 3781.07 -81.15 520 350 0.000 0.00 0.000
16.1693 2804.06 -58.92 385 260 65.367 -6419.79 -6.915
15.8237 2415.92 -52.58 315 270 0.000 0.00 0.000
15.7105 2926.04 -51.75 400 270 52.902 -5797.19 -5.199
17.1955 4272.77 -86.08 500 370 0.000 0.00 0.000
16.3066 3756.28 -80.71 480 320 0.000 0.00 0.000
17.8174 3988.33 -86.93 477 344 0.000 0.00 0.000
16.2364 3171.35 -71.15 440 300 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.7498 4080.32 -73.15 500 355 0.000 0.00 0.000
16.1390 3366.99 -58.04 440 300 55.493 -6666.23 -5.436
16.9647 4276.08 -52.80 480 345 0.000 0.00 0.000
16.1426 3992.01 -71.29 525 360 0.000 0.00 0.000
15.6782 2154.90 -34.42 290 195 48.334 -4065.57 -4.781
17.2160 3137.02 -94.43 404 288 0.000 0.00 0.000
16.6085 3012.70 -48.96 373 259 0.000 0.00 0.000
16.1836 3151.09 -69.15 435 295 0.000 0.00 0.000
16.3994 4079.72 -96.15 560 385 0.000 0.00 0.000
16.0793 3633.40 -71.77 486 335 0.000 0.00 0.000
15.9116 3542.57 -72.32 485 332 0.000 0.00 0.000
16.1668 2839.09 -50.15 380 255 0.000 0.00 0.000
17.9240 4130.93 -70.55 470 335 73.806 -9015.33 -7.651
16.0114 3456.80 -78.67 476 330 75.475 -8563.64 -8.149
368.3000 -69.78 26.73 16.1261 4203.94 -109.700 586.00 413.000
378.6900 0.00 0.00 16.1627 4373.37 -111.800 573.00 463.000
16.1134 3774.56 -91.31 520 364 84.248 -10012.50 -9.236
16.1915 4395.87 -124.20 619 441 0.000 0.00 0.000
16.4685 4680.46 -141.10 652 471 0.000 0.00 0.000
14.0099 180.47 -2.61 29 24 26.181 -295.44 -2.645
16.1510 4294.55 -124.00 610 434 0.000 0.00 0.000
15.8737 2911.32 -56.51 400 270 61.276 -6303.87 -6.373
16.0589 3850.38 -88.75 529 368 0.000 0.00 0.000
16.1841 4214.91 -118.70 594 423 95.680 -12411.30 -10.580
16.3553 4715.69 -152.10 674 488 0.000 0.00 0.000
15.8366 2697.55 -48.78 370 245 57.279 -5587.42 -5.885
16.0140 3702.56 -81.55 507 351 0.000 0.00 0.000
20.1314 1572.52 -4.88 140 95 61.514 -2465.78 -7.211
14.9342 588.72 -6.60 90 54 31.927 -924.86 -3.075
20.5324 4141.29 3.65 320 230 61.862 -6073.34 -6.094
15.6107 1155.69 -15.37 155 103 39.219 -1971.37 -3.810
16.2193 2972.64 -64.15 409 278 50.133 -5996.30 -4.641
166.9505 2520.70 -23.46 285 210 36.380 -3748.59 -2.819
16.1271 1506.49 -25.99 200 144 46.444 -2867.98 -4.655
16.1533 4450.44 -135.60 639 456 0.000 0.00 0.000
15.9671 3291.45 -71.33 452 312 73.133 -7969.42 7.890
357.7400 -64.85 24.72 16.1089 4096.3 -103.000 569.00 400.000
16.1232 4361.79 -129.90 625 445 0.000 0.00 0.000
15.9426 3120.29 -63.63 425 292 66.639 -7100.69 -7.053
346.1900 -59.92 22.72 16.0941 3983.01 -95.850 549.00 385.000
355.9200 -84.31 17.98 16.1724 4121.51 -111.800 577.00 408.000
16.3092 4642.01 -145.10 661 476 0.000 0.00 0.000
15.8333 2477.07 -39.94 330 220 56.682 -4827.08 -5.313
16.2291 2980.47 -64.15 410 280 69.656 -7028.88 -7.475
15.9957 2551.72 -49.15 350 235 0.000 0.00 0.000
15.7671 2593.95 -69.69 360 280 63.318 -6292.56 -6.635
16.8641 3558.18 -47.86 420 292 0.000 0.00 0.000
16.0062 3433.84 -66.01 461 316 0.000 0.00 0.000
15.8567 3363.62 -65.21 459 313 0.000 0.00 0.000
15.8969 3187.67 -59.99 431 294 0.000 0.00 0.000
344.2100 -79.38 15.97 16.148 4008.52 -105.400 560.00 394.000
16.2632 4439.38 -138.10 648 465 0.000 0.00 0.000
332.1000 -74.45 13.97 16.1355 3892.91 -98.930 540.00 380.000
16.2270 4483.13 -131.30 634 453 0.000 0.00 0.000
16.0541 3614.07 -85.45 498 348 80.121 -9305.80 -8.729
17.6306 4092.15 -86.55 495 350 0.000 0.00 0.000
15.9148 3305.37 -108.00 480 370 75.616 -9341.59 -7.959
16.2799 3798.23 -59.84 483 331 0.000 0.00 0.000
17.9610 4928.36 -45.75 500 350 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.7834 4072.58 -72.15 500 375 0.000 0.00 0.000
15.4075 734.55 -6.45 100 63 31.041 -1082.52 -2.761
16.1156 3395.57 -59.46 445 305 61.763 -7149.21 -6.302
15.7427 1272.18 -22.16 174 109 0.000 0.00 0.000
16.1989 3479.39 -111.30 480 370 64.083 -8825.19 -6.316
16.1135 3626.83 -64.64 477 326 0.000 0.00 0.000
16.1940 2827.53 -57.66 390 270 74.686 -6815.04 -8.318
13.9087 1374.07 -136.80 400 280 119.200 -8611.09 -14.890
15.8800 1574.60 -27.22 210 140 51.903 -3165.74 -5.537
15.6422 1512.94 -26.94 200 170 48.373 -2969.90 -5.032
15.7130 2610.57 -61.93 385 290 51.689 -5514.04 -5.004
15.9747 2719.68 -64.50 390 270 83.896 -7348.95 -9.644
15.8307 2488.59 -59.73 330 270 90.505 -7074.74 -10.780
19.0905 5579.62 -44.15 500 370 0.000 0.00 0.000
0.0000 48.40 0.00 16.7187 5477.94 -69.390 655.00 450.000
16.1673 3473.20 -78.66 460 385 0.000 0.00 0.000
16.4270 3490.89 -98.59 481 345 72.558 -9072.60 7.516
15.7565 2167.31 -43.15 341 213 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
15.9984 4467.01 -83.15 615 409 0.000 0.00 0.000
16.1004 3015.46 -61.15 416 280 0.000 0.00 0.000
13.1563 1054.72 -77.08 257 174 0.000 0.00 0.000
15.7260 1872.46 -25.16 249 164 43.492 -3266.92 -4.179
16.2315 2659.02 -44.15 350 235 0.000 0.00 0.000
17.3789 3723.42 -67.48 450 315 76.490 -8619.48 -8.139
15.9571 2940.86 -55.15 405 270 53.398 -5937.37 -5.200
15.9594 2581.48 -42.95 350 230 0.000 0.00 0.000
15.7027 1807.53 -26.15 240 160 44.794 -3260.31 -4.379
15.3227 2107.58 -64.87 340 225 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.6968 4041.04 -72.15 500 350 0.000 0.00 0.000
16.0963 3346.65 -57.84 440 300 56.175 -6673.70 -5.543
16.0910 3095.13 -61.15 425 285 0.000 0.00 0.000
16.7966 3457.47 -62.73 440 330 0.000 0.00 0.000
15.9444 2717.03 -67.90 400 300 0.000 0.00 0.000
15.9999 3544.19 -68.10 476 325 0.000 0.00 0.000
15.8670 3524.57 -70.78 470 360 0.000 0.00 0.000
15.8019 2634.16 -43.15 364 238 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.0193 3328.57 -63.72 460 305 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.7680 2302.35 -35.97 280 195 55.502 -4552.50 -5.666
19.3785 2524.78 -11.16 220 159 0.000 0.00 0.000
20.8403 3995.70 -36.66 332 290 139.560 -10420.10 -17.380
16.8548 2658.29 -95.50 376 293 0.000 0.00 0.000
15.8121 2567.15 -44.15 360 235 0.000 0.00 0.000
15.9300 3462.28 -69.87 472 323 0.000 0.00 0.000
15.7884 3457.85 -67.04 450 357 0.000 0.00 0.000
16.1642 3259.29 -52.15 460 307 0.000 0.00 0.000
16.1069 2768.38 -46.90 370 270 0.000 0.00 0.000
16.0243 2869.07 -51.80 380 260 0.000 0.00 0.000
16.0137 3096.52 -53.67 410 280 56.785 -6283.50 -5.681
15.7337 3117.43 -54.02 424 286 53.523 -6162.66 -5.245
15.7594 2861.53 -51.46 390 260 0.000 0.00 0.000
15.7371 3093.95 -57.76 425 288 56.097 -6271.67 -5.615
15.6984 3063.44 -54.57 420 283 52.909 -6071.72 -5.163
15.8177 2212.32 -33.15 300 200 50.137 -4174.56 -5.041
15.8727 2701.72 -48.62 365 245 60.438 -5734.51 -6.348
15.8554 3134.97 -58.00 425 289 0.000 0.00 0.000
15.9011 2495.97 -40.18 330 220 56.420 -5028.79 -5.853
15.9288 2718.68 -47.77 365 245 0.000 0.00 0.000
15.7989 3610.66 -66.49 470 363 0.000 0.00 0.000
312.4800 0.00 0.00 16.2878 3865.58 -86.150 531.00 362.000
16.1827 3028.13 -43.15 400 260 53.482 -5776.65 -5.295
15.8516 2401.61 -36.30 300 240 48.709 -4464.14 -4.753
15.8853 2882.38 -51.15 400 260 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.0499 2230.51 -39.15 305 215 50.869 -4261.51 -5.127
16.1623 3030.20 -58.15 412 277 0.000 0.00 0.000
16.1003 2744.68 -56.15 379 255 0.000 0.00 0.000
14.9601 1803.84 -43.15 290 185 48.672 -3955.89 -4.823
15.8911 2449.26 -44.15 340 225 0.000 0.00 0.000
0.0000 0.00 0.00 0 0 0.000 0.00 0.000
16.6531 2569.68 -63.15 350 240 0.000 0.00 0.000
14.4602 1950.22 -25.15 315 190 0.000 0.00 0.000
16.0100 2203.57 -43.15 305 200 0.000 0.00 0.000
18.3036 3816.44 -46.13 441 284 55.336 -6869.50 -5.115
15.2958 1303.92 -14.50 178 158 31.429 -1951.76 -2.544
HEAT VAPOR
NORMAL BP
CAL/G-MOLE
D HV
30 31

1.790 4580
4.950 0
0.000 7960
0.000 7790
0.000 7570
0.000 0
3.170 6860
1.870 5100
0.000 0
0.000 0
0.000 7240
3.910 6570
0.000 9490
0.000 9180
0.000 9570
8.800 10880
7.270 9380
0.000 5800
3.020 5560
3.300 7650
0.000 7500
0.000 7510
0.000 6590
0.000 12940
7.220 9330
0.000 5370
0.000 13500
0.000 8690
0.000 9410
0.000 6010
0.000 6561
2.460 5238
0.000 5970
0.000 0
0.000 7170
0.000 12000
9.900 9240
13.100 10270
0.000 15600
0.000 11500
5.700 7430
105.900 -13117
0.000 11600
4.540 6760
0.000 8040
7.180 9290
0.000 0
8.390 9110
-6.815 7.2
7.230 9180
8.410 0
0.000 11000
8.380 8680
0.000 0
0.000 12970
0.000 12100
6.980 8070
98.920 -12205.3
0.000 10600
3.420 6022
0.000 0
3.130 9980
92.474 -11329.2
0.000 6460
88.010 -10609.4
11.460 9770
4.323 6287
6.540 7650
0.000 8690
8.460 8430
0.000 8190
5.370 6919
0.000 8310
6.480 7411
0.000 7850
0.000 8130
0.000 8430
0.000 8070
3.310 5438
0.000 10300
6.720 7710
5.490 6970
4.472 6520
6.560 7730
0.000 8350
0.000 6900
6.610 7823
0.000 6550
0.000 7083
6.790 7936
5.580 7263
0.000 0
0.000 11300
6.740 7790
0.000 7050
0.000 11260
6.840 7800
0.000 0
0.000 11200
0.000 10600
0.000 9750
0.000 6370
0.000 6980
0.000 11300
3.550 5900
4.911 6640
0.000 6230
0.000 10800
3.470 6094
3.710 6287
0.000 6930
0.000 7879
7.120 8080
5.790 7330
0.000 11000
0.000 10600
0.000 8760
0.000 8600
0.000 6130
6.690 7760
5.490 7086
6.760 7953
0.000 0
0.000 11900
0.000 0
0.000 11800
0.000 8033
0.000 7399
4.579 6710
0.000 6510
0.000 10540
0.000 5760
0.000 9700
0.000 7838
0.000 6890
7.020 8100
5.720 7360
0.000 7000
0.000 8950
0.000 6590
6.980 8100
0.000 6680
0.000 6150
3.440 5660
0.000 9850
0.000 6960
3.490 7500
0.000 6850
0.863 4050
0.000 6770
0.000 11000
0.000 7800
0.000 9550
0.000 6475
0.000 8200
0.000 9150
0.820 5580
5.180 10000
0.000 0
0.264 1560
0.000 10200
3.610 7352
0.000 12100
6.530 0
0.000 12070
2.970 0
1.200 6140
0.000 7210
5.590 0
0.000 11700
0.000 8900
5.030 8220
0.000 7900
0.000 7900
0.000 0
0.703 4100
2.210 6390
0.284 1444
3.820 7170
0.000 2860
1.300 0
1.270 4880
4.980 8735
1.530 4826
2.960 7100
2.250 4650
1.300 3706
6.200 7790
0.000 7576
0.000 7840
6.290 8070
2.580 5580
0.000 6960
3.510 6240
0.000 6860
0.000 9400
1.510 0
0.000 5780
0.000 7900
4.220 7160
5.860 10870
0.000 9500
0.000 7280
0.000 6524
0.000 8740
0.000 6450
0.000 4790
0.000 292
0.000 9880
0.000 0
0.000 9500
0.000 0
0.000 4772
2.410 6690
2.220 5960
2.030 6330
3.730 6650
0.000 9010
4.730 8060
0.000 7590
0.000 13670
0.000 10900
0.000 7010
1.710 5140
0.000 0
0.000 6440
0.000 10900
0.000 11260
0.000 0
0.000 8840
0.000 0
1.073 3515
2.350 9260
4.010 7700
0.000 7950
2.080 6700
0.000 10700
2.290 6330
0.000 7600
0.000 8200
2.260 5900
3.400 6380
0.000 0
3.070 7200
5.660 8365
2.550 6400
4.980 8180
4.330 7290
5.750 8500
0.000 8200
0.000 7715
0.881 3237
0.000 12550
0.000 7660
0.000 6120
0.000 10000
0.210 1560
3.880 0
3.410 5500
0.000 5240
0.000 6474
0.000 14600
0.007 22
0.000 14500
1.630 10700
0.048 216
0.871 4220
0.717 3860
2.180 6027
1.840 1600
1.230 4724
0.871 4460
0.000 10000
6.460 9440
2.570 5090
0.000 10050
0.000 8568
0.000 7400
4.410 8170
0.000 9040
0.000 0
2.460 5286
0.000 7500
5.150 9830
0.000 9520
0.000 6500
0.000 6280
6.860 8970
0.000 0
0.000 8150
0.000 4930
0.448 2309
0.000 0
6.140 11330
0.000 9230
0.442 1955
1.860 8426
0.000 6950
3.080 7200
0.000 5290
0.000 7650
1.400 6210
0.000 10300
2.350 5715
4.980 8145
1.460 5120
2.450 5900
3.880 7460
0.000 7050
0.906 0
2.230 6740
0.000 0
2.840 6500
0.000 8500
4.790 7974
0.000 7070
0.000 7320
1.710 5870
0.000 8000
0.000 0
0.000 0
3.980 7780
0.000 0
5.230 7440
0.000 12140
0.000 0
0.000 12000
0.000 9000
0.000 0
0.000 10900
6.080 8690
0.000 0
0.000 10340
2.680 5352
0.000 10300
0.000 7670
0.000 8600
0.000 11690
0.000 9380
0.000 9200
0.000 7530
4.220 10040
10.200 9388
0.000 0
0.000 0
13.370 10430
0.000 12570
0.000 13740
0.041 440
0.000 12640
6.000 7576
0.000 10360
20.270 12240
0.000 14180
4.778 6896
0.000 9840
0.279 3300
0.264 1333
1.040 4555
0.679 0
3.080 8225
1.200 6140
0.743 3955
0.000 13390
8.690 8823
0.000 0
0.000 13020
7.310 8225
0.000 0
95.000 -11995.6
0.000 13780
3.680 61.6
5.100 8170
0.000 7100
4.010 7760
0.000 8690
0.000 9140
0.000 8620
0.000 8152
91.172 -11322.9
0.000 13380
0.000 0
0.000 12980
11.750 9920
0.000 11900
5.470 10800
0.000 9480
0.000 11490
0.000 0
0.000 10835
0.265 1630
6.110 8800
0.000 2670
5.420 11340
0.000 9270
5.310 0
6.040 0
1.340 0
1.530 3860
5.470 0
7.820 0
7.330 0
0.000 12100
0.000 0
0.000 0
4.420 10900
0.000 5830
0.000 0
0.000 11850
0.000 8180
0.000 4450
1.810 4487
0.000 6760
3.930 7700
4.280 7710
0.000 6510
1.630 4400
0.000 6450
0.000 0
0.000 10700
6.190 8600
0.000 8400
0.000 0
0.000 0
0.000 9070
0.000 0
0.000 6580
0.000 0
0.000 8800
0.000 0
1.320 5955
0.000 0
1.600 9716
0.000 9330
0.000 6550
0.000 8990
0.000 0
0.000 8300
0.000 7070
0.000 7520
4.840 7930
6.380 7860
0.000 7375
6.290 8090
6.200 7790
2.660 5439
4.730 6910
0.000 8200
3.620 6230
0.000 6920
0.000 9200
0.000 0
3.700 7500
2.850 5920
0.000 7500
0.000 0
0.000 0
2.590 5760
0.000 8040
0.000 0
1.850 5321
0.000 6330
0.000 0
0.000 7680
0.000 4550
0.000 5850
1.050 9717
0.804 3108
% 10°C 15°C 20°C 25°C
0 0.99973 0.99973 0.99913 0.99913 0.99823 0.99823 0.99708
1 785 0.99785 725 0.99725 636 0.99636 520
2 602 0.99602 542 0.99542 453 0.99453 336
3 426 0.99426 365 0.99365 275 0.99275 157
4 258 0.99258 195 0.99195 103 0.99103 0.98984
5 98 0.99098 32 0.99032 0.98938 0.98938 817
6 0.98946 0.98946 0.98877 0.98877 780 0.9878 656
7 801 0.98801 729 0.98729 627 0.98627 500
8 660 0.9866 584 0.98584 478 0.98478 346
9 524 0.98524 442 0.98442 331 0.98331 193
10 393 0.98393 304 0.98304 187 0.98187 43
11 267 0.98267 171 0.98171 47 0.98047 0.97897
12 145 0.98145 41 0.98041 0.9791 0.9791 753
13 26 0.98026 0.97914 0.97914 775 0.97775 611
14 0.97911 0.97911 790 0.9779 643 0.97643 472
15 800 0.978 669 0.97669 514 0.97514 334
16 692 0.97692 552 0.97552 387 0.97387 199
17 583 0.97583 433 0.97433 259 0.97259 62
18 473 0.97473 313 0.97313 129 0.97129 0.96923
19 363 0.97363 191 0.97191 0.96997 0.96997 782
20 252 0.97252 68 0.97068 864 0.96864 639
21 139 0.97139 0.96944 0.96944 729 0.96729 495
22 24 0.97024 818 0.96818 592 0.96592 348
23 0.96907 0.96907 689 0.96689 453 0.96453 199
24 787 0.96787 558 0.96558 312 0.96312 48
25 665 0.96665 424 0.96424 168 0.96168 0.95895
26 539 0.96539 287 0.96287 20 0.9602 738
27 406 0.96406 144 0.96144 0.95867 0.95867 576
28 268 0.96268 0.95996 0.95996 710 0.9571 410
29 125 0.96125 844 0.95844 548 0.95548 241
30 0.95977 0.95977 686 0.95686 382 0.95382 67
31 823 0.95823 524 0.95524 212 0.95212 0.9489
32 665 0.95665 357 0.95357 38 0.95038 709
33 502 0.95502 186 0.95186 0.9486 0.9486 525
34 334 0.95334 11 0.95011 679 0.94679 337
35 162 0.95162 0.94832 0.94832 494 0.94494 146
36 0.94986 0.94986 650 0.9465 306 0.94306 0.93952
37 805 0.94805 464 0.94464 114 0.94114 756
38 620 0.9462 273 0.94273 0.93919 0.93919 556
39 431 0.94431 79 0.94079 720 0.9372 353
40 238 0.94238 0.93882 0.93882 518 0.93518 148
41 42 0.94042 682 0.93682 314 0.93314 0.9294
42 0.93842 0.93842 478 0.93478 107 0.93107 729
43 639 0.93639 271 0.93271 0.92897 0.92897 516
44 433 0.93433 62 0.93062 685 0.92685 301
45 226 0.93226 0.92852 0.92852 472 0.92472 85
46 17 0.93017 640 0.9264 257 0.92257 0.91868
47 0.92806 0.92806 426 0.92426 41 0.92041 649
48 593 0.92593 211 0.92211 0.91823 0.91823 429
49 379 0.92379 0.91995 0.91995 604 208
50 0.92126 0.92126 0.91776 0.91776 0.91384 0.91384 0.90985
51 0.91943 0.91943 555 0.91555 160 0.9116 760
52 723 0.91723 333 0.91333 0.90936 0.90936 534
53 502 0.91502 110 0.9111 711 0.90711 307
54 279 0.91279 0.90885 0.90885 485 0.90485 79
55 55 0.91055 659 0.90659 258 0.90258 0.8985
56 0.90831 0.90831 433 0.90433 31 0.90031 621
57 607 0.90607 207 0.90207 0.89803 0.89803 392
58 381 0.90381 0.8998 0.8998 574 0.89574 162
59 154 0.90154 752 0.89752 344 0.89344 0.88931
60 0.89927 0.89927 523 0.89523 113 0.89113 699
61 698 0.89698 293 0.89293 0.88882 0.88882 446
62 468 0.89468 62 0.89062 650 0.8865 233
63 237 0.89237 0.8883 0.8883 417 0.88417 0.87998
64 6 0.89006 597 0.88597 183 0.88183 763
65 0.88774 0.88774 364 0.88364 0.87948 0.87948 527
66 541 0.88541 130 0.8813 713 0.87713 291
67 308 0.88308 0.87895 0.87895 477 0.87477 54
68 74 0.88074 660 0.8766 241 0.87241 0.86817
69 0.87839 0.87839 424 0.87424 4 0.87004 579
70 602 0.87602 187 0.87187 0.86766 0.86766 340
71 365 0.87365 0.86949 0.86949 527 0.86527 100
72 127 0.87127 710 0.8671 287 0.86287 0.85859
73 0.86888 0.86888 470 0.8647 47 0.86047 618
74 648 0.86648 229 0.86229 0.85806 0.85806 376
75 408 0.86408 0.85988 0.85988 564 0.85564 134
76 168 0.86168 747 0.85747 322 0.85322 0.84891
77 0.85927 0.85927 505 0.85505 79 0.85079 647
78 685 0.85685 262 0.85262 0.84835 0.84835 403
79 442 0.85442 18 0.85018 590 0.8459 158
80 197 0.85197 0.84772 0.84772 344 0.84344 0.83911
81 0.8495 0.8495 525 0.84525 96 0.84096 664
82 702 0.84702 277 0.84277 0.83848 0.83848 415
83 453 0.84453 28 0.84028 599 0.83599 164
84 203 0.84203 0.83777 0.83777 348 0.83348 0.82913
85 0.83951 0.83951 525 0.83525 95 0.83095 660
86 697 0.83697 271 0.83271 0.8284 0.8284 405
87 441 0.83441 14 0.83014 583 0.82583 148
88 181 0.83181 0.82754 0.82754 323 0.82323 0.81888
89 0.82919 0.82919 492 0.82492 62 0.82062 626
90 654 0.82654 227 0.82227 0.81797 0.81797 362
91 386 0.82386 0.81959 0.81959 529 0.81529 94
92 114 0.82114 688 0.81688 257 0.81257 0.80823
93 0.81839 0.81839 413 0.81413 0.80983 0.80983 549
94 561 0.81561 134 0.81134 705 0.80705 272
95 278 0.81278 0.80852 0.80852 424 0.80424 0.79991
96 0.80991 0.80991 566 0.80566 138 0.80138 706
97 698 0.80698 274 0.80274 0.79846 0.79846 415
98 399 0.80399 0.79975 0.79975 547 0.79547 117
99 94 0.80094 670 0.7967 243 0.79243 0.78814
100 0.79784 0.79784 360 0.7936 0.78934 0.78934 506
30°C 35°C 40°C
0.99708 0.99568 0.99568 0.99406 0.99406 0.99225 0.99225
0.9952 379 0.99379 217 0.99217 34 0.99034
0.99336 194 0.99194 31 0.99031 0.98846 0.98846
0.99157 14 0.99014 0.98849 0.98849 663 0.98663
0.98984 0.98839 0.98839 672 0.98672 485 0.98485
0.98817 670 0.9867 501 0.98501 311 0.98311
0.98656 507 0.98507 335 0.98335 142 0.98142
0.985 347 0.98347 172 0.98172 0.97975 0.97975
0.98346 189 0.98189 9 0.98009 808 0.97808
0.98193 31 0.98031 0.97846 0.97846 641 0.97641
0.98043 0.97875 0.97875 685 0.97685 475 0.97475
0.97897 723 0.97723 527 0.97527 312 0.97312
0.97753 573 0.97573 371 0.97371 150 0.9715
0.97611 424 0.97424 216 0.97216 0.96989 0.96989
0.97472 278 0.97278 63 0.97063 829 0.96829
0.97334 133 0.97133 0.96911 0.96911 670 0.9667
0.97199 0.9699 0.9699 760 0.9676 512 0.96512
0.97062 844 0.96844 607 0.96607 352 0.96352
0.96923 697 0.96697 452 0.96452 189 0.96189
0.96782 547 0.96547 294 0.96294 23 0.96023
0.96639 395 0.96395 134 0.96134 0.95856 0.95856
0.96495 242 0.96242 0.95973 0.95973 687 0.95687
0.96348 87 0.96087 809 0.95809 516 0.95516
0.96199 0.95929 0.95929 643 0.95643 343 0.95343
0.96048 769 0.95769 476 0.95476 168 0.95168
0.95895 607 0.95607 306 0.95306 0.94991 0.94991
0.95738 442 0.95442 133 0.95133 810 0.9481
0.95576 272 0.95272 0.94955 0.94955 625 0.94625
0.9541 98 0.95098 774 0.94774 438 0.94438
0.95241 0.94922 0.94922 590 0.9459 248 0.94248
0.95067 741 0.94741 403 0.94403 55 0.94055
0.9489 557 0.94557 214 0.94214 0.9386 0.9386
0.94709 370 0.9437 21 0.94021 662 0.93662
0.94525 180 0.9418 0.93825 0.93825 461 0.93461
0.94337 0.93986 0.93986 626 0.93626 257 0.93257
0.94146 790 0.9379 425 0.93425 51 0.93051
0.93952 591 0.93591 221 0.93221 0.92843 0.92843
0.93756 390 0.9339 16 0.93016 634 0.92634
0.93556 186 0.93186 0.92808 0.92808 422 0.92422
0.93353 0.92979 0.92979 597 0.92597 208 0.92208
0.93148 770 0.9277 385 0.92385 0.91992 0.91992
0.9294 558 0.92558 170 0.9217 774 0.91774
0.92729 344 0.92344 0.91952 0.91952 554 0.91554
0.92516 128 0.92128 733 0.91733 332 0.91332
0.92301 0.9191 0.9191 513 0.91513 108 0.91108
0.92085 692 0.91692 291 0.91291 0.90884 0.90884
0.91868 472 0.91472 69 0.91069 660 0.9066
0.91649 250 0.9125 0.90845 0.90845 434 0.90434
0.91429 28 0.91028 621 0.90621 207 0.90207
0.91208 0.90805 0.90805 396 0.90396 0.89979 0.89979
0.90985 0.9058 0.9058 0.90168 0.90168 0.8975 0.8975
0.9076 353 0.90353 0.8994 0.8994 519 0.89519
0.90534 125 0.90125 710 0.8971 288 0.89288
0.90307 0.89896 0.89896 479 0.89479 56 0.89056
0.90079 667 0.89667 248 0.89248 0.88823 0.88823
0.8985 437 0.89437 16 0.89016 589 0.88589
0.89621 206 0.89206 0.88784 0.88784 356 0.88356
0.89392 0.88975 0.88975 552 0.88552 122 0.88122
0.89162 744 0.88744 319 0.88319 0.87888 0.87888
0.88931 512 0.88512 85 0.88085 653 0.87653
0.88699 278 0.88278 0.87851 0.87851 417 0.87417
0.88446 44 0.88044 615 0.87615 180 0.8718
0.88233 0.87809 0.87809 379 0.87379 0.86943 0.86943
0.87998 574 0.87574 142 0.87142 705 0.86705
0.87763 337 0.87337 0.86905 0.86905 466 0.86466
0.87527 100 0.871 667 0.86667 227 0.86227
0.87291 0.86863 0.86863 429 0.86429 0.85987 0.85987
0.87054 625 0.86625 190 0.8619 747 0.85747
0.86817 387 0.86387 0.8595 0.8595 407 0.85407
0.86579 148 0.86148 710 0.8571 266 0.85266
0.8634 0.85908 0.85908 470 0.8547 25 0.85025
0.861 667 0.85667 228 0.85228 0.84783 0.84783
0.85859 426 0.85426 0.84986 0.84986 540 0.8454
0.85618 184 0.85184 743 0.84743 297 0.84297
0.85376 0.84941 0.84941 500 0.845 53 0.84053
0.85134 698 0.84698 257 0.84257 0.83809 0.83809
0.84891 455 0.84455 13 0.84013 564 0.83564
0.84647 211 0.84211 0.83768 0.83768 319 0.83319
0.84403 0.83966 0.83966 523 0.83523 74 0.83074
0.84158 720 0.8372 277 0.83277 0.82827 0.82827
0.83911 473 0.83473 29 0.83029 578 0.82578
0.83664 224 0.83224 0.8278 0.8278 329 0.82329
0.83415 0.82974 0.82974 530 0.8253 79 0.82079
0.83164 724 0.82724 279 0.82279 0.81828 0.81828
0.82913 473 0.82473 27 0.82027 576 0.81576
0.8266 220 0.8222 0.81774 0.81774 322 0.81322
0.82405 0.81965 0.81965 519 0.81519 67 0.81067
0.82148 708 0.81708 262 0.81262 0.80811 0.80811
0.81888 448 0.81448 3 0.81003 552 0.80552
0.81626 186 0.81186 0.80742 0.80742 291 0.80291
0.81362 0.80922 0.80922 478 0.80478 28 0.80028
0.81094 655 0.80655 211 0.80211 0.79761 0.79761
0.80823 384 0.80384 0.79941 0.79941 491 0.79491
0.80549 111 0.80111 669 0.79669 220 0.7922
0.80272 0.79835 0.79835 393 0.79393 0.78947 0.78947
0.79991 555 0.79555 114 0.79114 670
0.79706 271 0.79271 0.78831 0.78831 388
0.79415 0.78981 0.78981 542 100
0.79117 684 247 0.77806 0.77806
0.78814 382 0.77946 0.77946 507
75 641 203
15°C 20°C 25°C 30°C 35°C 40°C
0.91776 0.91384 0.90985 0.9058 0.90168 0.8975
555 160 760 353 0.8994 519
333 0.90936 534 125 710 288
110 711 307 0.89896 479 56
0.90885 485 79 667 248 0.88823
659 258 0.8985 437 16 589
433 31 621 206 0.88784 356
207 0.89803 392 0.88975 552 122
0.8998 574 162 744 319 0.87888
752 344 0.88931 512 85 653
523 113 699 278 0.87851 417
293 0.88882 446 44 615 180
62 650 233 0.87809 379 0.86943
0.8883 417 0.87998 574 142 705
1.2
597 183 763 337 0.86905 466
364 0.87948 527 100 667 227
1
130 713 291 0.86863 429 0.85987
0.87895 477 54 625 190 747
0.8
660 241 0.86817 387 0.8595 407
424 4 579 148 710 266
187 0.86766 0.6 340 0.85908 470 25
0.86949 527 100 667 228 0.84783
710 287 0.4 0.85859 426 0.84986 540
470 47 618 184 743 297
229 0.85806 0.2 376 0.84941 500 53
0.85988 564 134 698 257 0.83809
747 322 0 0.84891 455 13 564
0 20 40 60 80 100 120
505 79 647 211 0.83768 319
262 0.84835 403 0.83966 523 74
18 590 158 720 277 0.82827
0.84772 344 0.83911 473 29 578
525 96 664 224 0.8278 329
277 0.83848 415 0.82974 530 79
28 599 164 724 279 0.81828
0.83777 348 0.82913 473 27 576
525 95 660 220 0.81774 322
271 0.8284 405 0.81965 519 67
14 583 148 708 262 0.80811
0.82754 323 0.81888 448 3 552
492 62 626 186 0.80742 291
227 0.81797 362 0.80922 478 28
0.81959 529 94 655 211 0.79761
688 257 0.80823 384 0.79941 491
413 0.80983 549 111 669 220
134 705 272 0.79835 393 0.78947
0.80852 424 0.79991 555 114 670
566 138 706 271 0.78831 388
274 0.79846 415 0.78981 542 100
0.79975 547 117 684 247 0.77806
670 243 0.78814 382 0.77946 507
360 0.78934 506 75 641 203
100 120
AJUSTE van Laar
A B C A
ETHANOL 18.9119 3803.98 -41.68 ln  1 
 x
WATER 18.3036 3816.44 -46.13
1 
 x

P A12 A21 ln  2 
760 1.677638831 0.908474813  x
1 

x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 100 1695.628333 759.9430125 5.352901932 1 11.9428055
0.019 0.981 95.5 1447.895348 645.7493081 4.776835506 1.00108384 9.100470929
0.0721 0.9279 89 1143.554379 506.2459246 3.607526471 1.01440781 5.42816144
0.0966 0.9034
Chart Title
86.7 1049.522117 463.3508815 3.221900875 1.025010953 4.44928451
0.1238 0.8762
1.2 85.3 995.5050447 438.7604024 2.872482883 1.039666138 3.762593685
0.1661 0.8339 84.1 951.0680201 418.5606944 2.451450343 1.067901277 3.067757927
0.2337 0.7663 82.7 901.3280763 395.9838679 1.986879173 1.125153985 2.356355241
0.2608 0.7392 82.3 887.5224056 389.7240297 1.849795312 1.15186862 2.160177349
1
0.3273 0.6727f(x) = 0.999289227219007
81.5 860.4403571
x 377.4528707 1.592750786 1.225659365 1.803246125
0.3965 0.6035R² = 0.999962955890422
80.7 834.0522099 365.5072841 1.408437293 1.313892794 1.545671364
0.5198 0.4802 79.7 802.0214891 351.0227067 1.205068178 1.497240645 1.271698125
0.5732 0.8
0.4268 79.3 789.5006013 345.3653606 1.148574545 1.586275007 1.193158282
0.6765 0.3235 78.74 772.2464187 337.5738147 1.07355717 1.773905754 1.090856157
0.7472 0.2528 78.41 762.2273782 333.0518868 1.041043664 1.913462812 1.044094714
0.8943 0.1057
0.6 78.15 754.4104331 329.5250895 1.006088962 2.231035234 0.998689486
1 0 78.3 758.9119752 331.5559306 1 2.480536365 0.998568388

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1
A12
ln  1  2
 x1 A12 
1  
1.59161691 0.964660414 0.002154181

 x 2 A21 
1.596483324 0.964187815 0.002078768
1.587113105 0.931186687 0.001516951
A21 1.689568789 0.93696514 0.001037034
ln  2  2 1.677638831 0.908474813 0.000226553
 x 2 A21 
1  
 x1 A12 

K2 y1 y2 Sy y error
0.999925016 0 0.999925016 0.999925016 0 0
0.850591049 0.172908948 0.834429819 1.007338767 0.17 8.46198E-06
0.675710289 0.39137044 0.626991577 1.018362017 0.3891 5.1549E-06
0.624920696 0.429800884 0.564553357 0.99435424 0.4375 5.92764E-05
0.600216228 0.465809098 0.525909459 0.991718557 0.4704 2.10764E-05
0.588133553 0.509554592 0.49044457 0.999999161 0.5089 4.2849E-07
0.586240562 0.55068022 0.449236143 0.999916362 0.5445 3.81951E-05
0.590672211 0.563374252 0.436624898 0.999999151 0.558 2.88826E-05
0.608721903 0.590202457 0.409487224 0.999689681 0.5826 5.77973E-05
0.631891299 0.612858696 0.381346399 0.994205095 0.6122 4.3388E-07
0.691533505 0.661028685 0.332074389 0.993103074 0.6599 1.27393E-06
0.720847947 0.683918327 0.307657904 0.991576231 0.6841 3.3005E-08
0.78792649 0.73796419 0.254894219 0.99285841 0.7385 2.87092E-07
0.838529474 0.78014757 0.211980251 0.992127821 0.7815 1.82907E-06
0.967344849 0.893128008 0.102248351 0.995376358 0.8943 1.37357E-06
1.082153346 0.998568388 0 0.998568388 1 2.04951E-06
15.96911833 0.000226553
16

1 1.2
100

95

90

85

80

75

70
0 0.2 0.4 0.6 0.8 1 1.2
Ejemplo 9.1 Un destilador disconttnuo SC carga con 100 kmol de un líquido que contiene
una mezcla binaria de 50 moles ‘L de benceno cn tolueno. Constrúyanse representaciones
gráficas, en funcicín del tiempo, de (a) la temperatura de la caldera, (b) la composición instantánea
del vapor, (c) la composición del líquido de la caldera del destilador, y (d) la composición
media total del destilado. Supongase una velocidad dc vaporización constante de
10 kmol/h y una volatilidad relativa constante dc 2.41 para una presión de 101.3 kPa (1 atm).
Soluc~ión. Inicialmente, W,, = 100. x,, = 0.5. Obteniendo W a partir de (9-5) para valores
de .Y desde 0.5, a incrementos dc 0.05. y determinando los correspondientes valores del
tiempo a partir de t = (W,, - W)/lO, sc genera la siguiente tabla
1. h 2.12 3 75 5 . 0 4 h.OX 6 . 9 4 7.66 x.7x x.x3 9 . 3 5
W. kmot 7X.X( hl.5 I 49.59 Nlfl 3O.FY 3 3 . 3 8 17.19 II.69 6.52
x 0.4s 0 . 4 0 0 . 3 5 0 . 3 0 0.25 0.20 0.15 0.10 0.05
123456789
1.00
Tiempo, horas
0.90

alfa 2.5 xW0 0.5 0.5 0.80

xy 0.5 0 0.70
0 0.00 0.60
0.1 0.22 0.50
0.2 0.38 0.40
0.3 0.52
0.30
0.4 0.63
0.20
0.5 0.71
0.6 0.79 0.10

0.7 0.85 0.00


0 0.1 0.2 0.3
0.8 0.91
0.9 0.96 xy

1 1.00

yD 0.7 0.7 0.6 0.6


0.4827586 0.7 0.375 0.6
0.4827586 0.4827586 0.375 0.375

y x f
0.5
0.7 0.4827586 4.6031746
0.6 0.375 4.4444444
0.5 0.2857143 4.6666667
0.4 0.2105263 5.2777778
0.3 0.1463415 6.5079365
0.2 0.0909091 9.1666667
0.114 0.048948 15.372328
13.2. Differential distillation.
A mixture of 40 mol% isopropanol in water is distilled at 1 atm by x
differential distillation until 70 mol% of the charge has been vaporized 0
(equilibrium data are given in Exercise 7.33). What is the composition 0.0118
of the liquid residue in the still-pot and of the collected distillate? 0.0841
0.1978
xW0 0.4 0.3496
Recup 70% 0.4525
W0 100 0.6794
0.6854
xW0 0.7693
0.4 0.4 0.9442
0.4 0 1

0.57 0.57 0.5 0.5 0.45 0.45 0.4


0.35 0.57 0.13 0.5 0.075 0.45 0.057
0.35 0 0.13 0 0.075 0 0.057
0.35 0.35 0.3 0.3 0.25 0.25 0.2
0.042 0.35 0.0275 0.3 0.018 0.25 0.0087
0.042 0 0.0275 0 0.018 0 0.0087

0.15 0.15 0.12 0.12


0.004 0.15 0.0037 0.12
0.004 0 0.0037 0

yD x 1/(y-x) I W D xD d
100
0.57 0.35 4.5454545 -0.797297 45.054501 54.945499 0.535 29.395842
0.5 0.13 2.7027027 -0.147658 38.869708 6.184793 0.475 2.9377767
0.45 0.075 2.6666667 -0.050239 36.965172 1.9045362 0.425 0.8094279
0.4 0.057 2.9154519 -0.046217 35.295646 1.6695253 0.375 0.626072
0.35 0.042 3.2467532 -0.050144 33.569407 1.726239 0.325 0.5610277
0.3 0.0275 3.6697248 -0.037905 32.320763 1.2486448 0.275 0.3433773
0.25 0.018 4.3103448 -0.04435 30.918644 1.402119 0.225 0.3154768
0.2 0.0087 5.2273915 -0.02838 30.053499 0.8651446 0.175 0.1514003
0.15 0.004 6.8493151 -0.002317 29.983941 0.0695583 0.135 0.0093904
0.12 0.0037 8.5984523
70.016059 35.149791 xD

13.9. Batch rectification at constant reflux ratio.


Repeat Exercise 13.2 for the case of batch distillation carried out
in a two-stage column with L/V =0.9.
N 2
W0 100
xW0 0.4
D 70
L/V 0.9
D/V 0.1

R 9

xD xD xD xD xD
0.63 0.6 0.55 0.5 0.45
mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.9 0.063 0.9 0.06 0.9 0.055 0.9 0.05 0.9 0.045

0.63 0.63 0.6 0.6 0.55 0.55 0.5 0.5 0.45 0.45
0 0.063 0 0.06 0 0.055 0 0.05 0 0.045
0.63 0.63 0.6 0.6 0.55 0.55 0.5 0.5 0.45 0.45
0.55 0.63 0.48 0.6 0.28 0.55 0.13 0.5 0.075 0.45
0.55 0.558 0.48 0.492 0.28 0.307 0.13 0.167 0.075 0.1125
0.32 0.558 0.11 0.492 0.03 0.307 0.006 0.167 0.002 0.1125
0.32 0.351 0.11 0.159 0.03 0.082 0.006 0.0554 0.002 0.0468

yD x 1/(y-x) I W D xD d
100
0.63 0.32 3.2258065 -0.552995 57.522421 42.477579 0.615 26.123711
0.6 0.11 2.0408163 -0.158556 49.088219 8.4342017 0.575 4.849666
0.55 0.03 1.9230769 -0.047368 46.817199 2.2710195 0.525 1.1922852
0.5 0.006 2.0242915 -0.008513 46.420342 0.3968571 0.475 0.1885071
0.45 0.002 2.2321429 -0.002369 46.310493 0.1098491 0.425 0.0466859
0.4 0.001 2.5062657 -0.000269 46.298059 0.0124345 0.375 0.0046629
0.35 0.0009 2.8645087
53.689507 32.400856

13.13. Batch rectification at constant composition.


An acetone–ethanol mixture of 0.5 mole fraction acetone is to be 0 0
separated by batch distillation at 101 kPa. 0.05 0.16
Vapor–liquid equilibrium data at 101 kPa are as follows: 0.1 0.25
Mole Fraction Acetone 0.2 0.42
y 0.16 0.25 0.42 0.51 0.60 0.67 0.72 0.79 0.87 0.93 0.3 0.51
x 0.05 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 0.4 0.6
(a) Assuming an L/D of 1.5 times the minimum, how many stages 0.5 0.67
should this column have if the desired composition of the distillate 0.6 0.72
is 0.90 mole fraction acetone when the residue contains 0.1 mole 0.7 0.79
fraction acetone? 0.8 0.87
0.9 0.93
xD 0.9 0.9 1 1
0.9 0 1

0.9
xW0 0.5 0.5
0.8
0.5 0
0.7
Rmin 0.6
1.69
0.5
LORmin 0.9 0.9
0.4
0 0.3345725
0.3
R 2.535 0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xD R xD R xD R xD R xD R
0.9 2.535 0.9 3.5 0.9 4.5 0.9 5.5 0.9 6.5
mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.7171146 0.2545969 0.7777778 0.2 0.8181818 0.1636364 0.8461538 0.1384615 0.8666667 0.12

0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
0 0.2545969 0 0.2 0 0.1636364 0 0.1384615 0 0.12

0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
0.845 0.9 0.845 0.9 0.845 0.9 0.845 0.9 0.845 0.9
0.845 0.8605587 0.845 0.8572222 0.845 0.855 0.845 0.8534615 0.845 0.8523333
0.79 0.8605587 0.783 0.8572222 0.781 0.855 0.78 0.8534615 0.778 0.8523333
0.79 0.8211174 0.783 0.809 0.781 0.8026364 0.78 0.7984615 0.778 0.7942667
0.737 0.8211174 0.72 0.809 0.718 0.8026364 0.714 0.7984615 0.706 0.7942667
0.737 0.7831103 0.72 0.76 0.718 0.7510909 0.714 0.7426154 0.706 0.7318667
0.69 0.7831103 0.66 0.76 0.65 0.7510909 0.64 0.7426154 0.62 0.7318667
0.69 0.7494059 0.66 0.7133333 0.65 0.6954545 0.64 0.68 0.62 0.6573333
0.645 0.7494059 0.59 0.7133333 0.555 0.6954545 0.522 0.68 0.485 0.6573333
0.645 0.7171358 0.59 0.6588889 0.555 0.6177273 0.522 0.5801538 0.485 0.5403333
0.59 0.7171358 0.485 0.6588889 0.42 0.6177273 0.38 0.5801538 0.336 0.5403333
0.59 0.6776945 0.485 0.5772222 0.42 0.5072727 0.38 0.46 0.336 0.4112
0.51 0.6776945 0.38 0.5772222 0.3 0.5072727 0.24 0.46 0.195 0.4112
0.51 0.6203253 0.38 0.4955556 0.3 0.4090909 0.24 0.3415385 0.195 0.289
0.43 0.6203253 0.29 0.4955556 0.192 0.4090909 0.152 0.3415385 0.125 0.289
0.43 0.5629562 0.29 0.4255556 0.192 0.3207273 0.152 0.2670769 0.125 0.2283333
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xy x=y xW0 0.7

0.5 0.5 0.4 0.4 0.3 0.3 0.2


0.2857143 0.5 0.2105263 0.4 0.1463415 0.3 0.0909091
0.2857143 0.2857143 0.2105263 0.2105263 0.1463415 0.1463415 0.0909091

I W D D xD d t (h)

100 0 0
-0.536227 58.495087 41.504913 41.504913 0.4288793 17.800599 4.1504913
-0.447421 37.394444 21.100643 62.605556 0.3303571 6.9707482 2.1100643
-0.411236 24.786167 12.608277 75.213833 0.2481203 3.1283695 1.2608277
-0.416055 16.35004 8.4361271 83.64996 0.1784339 1.505291 0.8436127
-0.477884 10.138561 6.2114786 89.861439 0.1186253 0.7368384 0.6211479
-0.566325 5.7547238 4.3838372 94.245276 0.0699286 0.3065555 0.4383837

94.245276 30.448401 9.4245276


y
1
0
0.2195 0.9
0.462 0.8
0.5242 Vapor–liquid data in mole-fraction isopropanol at 101 kPa are:
0.7
0.5686 T, _x0004_C 93.00 84.02 82.12 81.25 80.62 80.16 80.28 81.51
0.5926 y 0.2195 0.4620 0.52420.6
0.5686 0.5926 0.6821 0.7421 0.9160
0.6821 x 0.0118 0.0841 0.19780.5
0.3496 0.4525 0.6794 0.7693 0.9442
0.6854 Notes: Composition of 0.4
the azeotrope is x ¼ y ¼ 0.6854. Boiling
0.7421 point of azeotrope ¼ 80.22_x0004_C.
0.3
0.916
1 0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0.4
0.4
0
0.2
0.2
0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5020247

xD xD 1
0.4 0.35 0.9
mLOR bLOR mLOR bLOR
0.8
0.9 0.04 0.9 0.035
0.7

0.4 0.4 0.35 0.35 0.6


0 0.04 0 0.035 0.5

0.4

0.3

0.2

0.1
0.7

0.6

0.5

0.4

0.4 0.4 0.35 0.35 0.3


0.055 0.4 0.04 0.35 0.2
0.055 0.0895 0.04 0.071
0.1
0.001 0.0895 0.001 0.071
0
0.001 0.0409 0.0009 0.03581 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

0.6034858

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

(b) Assume the column has eight stages and the reflux rate is varied
continuously so that the top product is maintained constant at
0.9 mole fraction acetone. Make a plot of the reflux ratio versus
the still-pot composition and the amount of liquid left in the
still-pot.
(c) Assume the same distillation is carried out at constant reflux
ratio (and varying product composition). It is desired to have a residu
containing 0.1 and an (average) product containing 0.9 mole
fraction acetone. Calculate the total vapor generated. Which method
0.7 0.8 0.9 1 of operation is more energy-intensive? Suggest operating policies
0.7 0.8 0.9 1
other than constant reflux ratio and constant distillate compositions
xD R that lead to equipment or operating cost savings.
1
0.9 8
mLOR bLOR
0.9
0.8888889 0.1

0.8
0.9 0.9
0 0.1
0.7

0.6
0.9 0.9
0.845 0.9
0.845 0.8511111 0.5

0.776 0.8511111
0.776 0.7897778 0.4

0.7 0.7897778
0.7 0.7222222 0.3

0.605 0.7222222
0.605 0.6377778 0.2
0.453 0.6377778
0.453 0.5026667 0.1
0.295 0.5026667
0.295 0.3622222 0
0 0.1 0.2 0.3 0.4 0.5 0
0.163 0.3622222
0.163 0.2448889
0.1 0.2448889
0.1 0.1888889
Chart Title
18

16

14

12

10

8
0.2 6 0.114 0.114
0.2 0.048948 0.114
4
0.0909091 0.048948 0.048948
2

0
0 0.1 0.2 0.3 0.4 0.5 0.6
0.7 0.8 0.9 1
0.5 0.6 0.7 0.8 0.9 1

he reflux rate is varied


ained constant at
e reflux ratio versus
iquid left in the

t at constant reflux
desired to have a residue
aining 0.9 mole
nerated. Which method
st operating policies
distillate compositions

0.4 0.5 0.6 0.7 0.8 0.9 1


COMPONENTES CLAVES
F D B
C3 5
iC4 15
nC4 (LK) 25 23.125 1.875
iC5 (HK) 20 3.6 16.4
C5 35

DISTRIBUCIÓN INICIAL (SUPUESTA)

F D B z xD xB
C3 5 5 0 0.05 0.1070091 0
iC4 15 15 0 0.15 0.3210273 0
nC4 (LK) 25 23.125 1.875 0.25 0.4949171 0.0351947
iC5 (HK) 20 3.6 16.4 0.2 0.0770465 0.3078367
C5 35 0 35 0.35 0 0.6569686
100 46.725 53.275 1

TIPO DE CONDENSADOR Y PRESIÓN DE OPERACIÓN


Supongo CT
RefrigerantAgua TD 120 °F

CÁLCULO DE LA PRESIÓN DE OPERACIÓN


P [psi] T [R]
94.540177 579.67 DeltaPc 5 PD
Comp xD K KixDi aD DeltaPe 0.1 PT
C3 0.1070091 2.312296 0.2474367 6.7167415 N 30 PF
iC4 0.3210273 1.0611048 0.3406436 3.0822899 PB
nC4 (LK) 0.4949171 0.7796679 0.385871 2.264774
iC5 (HK) 0.0770465 0.3442586 0.0265239 1 P
C5 0 0.2830931 0 0.8223268
1.0004752

P [psi] T [R]
102.54018 680.2142
Comp xB K KixBi aB Tc
C3 0 4.7630975 0 4.4628386 369.8 665.64
iC4 0 2.5475099 0 2.3869185 408.1 734.58
nC4 (LK) 0.0351947 2.0464796 0.0720253 1.9174724 425.2 765.36
iC5 (HK) 0.3078367 1.0672798 0.3285479 1 460.4 828.72
C5 0.6569686 0.9121453 0.5992508 0.8546449 469.6 845.28
0.999824

P [psi] T [R]
101.04018 623.64137
Comp z K KixBi aF aprom
C3 0.05 3.2393044 0.1619652 5.4948728 9.8907711 5.4816229
iC4 0.15 1.6006617 0.2400993 2.7152226 4.8874008 2.713348
nC4 (LK) 0.25 1.2280615 0.3070154 2.0831763 3.7497173 2.0836591
iC5 (HK) 0.2 0.589514 0.1179028 1 1.8 1
C5 0.35 0.4946674 0.1731336 0.8391105 1.5103989 0.8385902
1.0001162

NUMERO MÍNIMO DE ETAPAS Y SU DISTRIBUCIÓN

Comp F D B aprom Nmin (d/b)i d b


C3 5 5.4816229 2490.937 4.9979935 0.0020065
iC4 15 2.713348 52.529384 14.71978 0.2802199
nC4 (LK) 25 23.125 1.875 2.0836591 12.333333 23.125 1.875
iC5 (HK) 20 3.6 16.4 1 0.2195122 3.6 16.4
C5 35 0.8385902 0.0835456 2.6986368 32.301363
100 5.4876896 49.14141 50.85859

REFLUJO MÍNIMO
q T q1 q2 q3 q4
1 0 4.9329881 2.4613906 1.3684478 0.9252031
Comp z aF f1 f2 f3 f4
C3 0.05 5.4948728 0.488968 0.0905704 0.0665815 0.0601233
iC4 0.15 2.7152226 -0.183646 1.604539 0.3024139 0.2275301
nC4 (LK) 0.25 2.0831763 -0.182747 -1.376981 0.72866 0.4497462
iC5 (HK) 0.2 1 -0.050852 -0.136856 -0.542818 2.673909
C5 0.35 0.8391105 -0.071739 -0.181035 -0.554823 -3.411311
-1.513E-05 0.0002376 1.421E-05 -1.99E-06

DISTRIBUCION

Comp f lF d b aF (d/lF)i d (d/f)


C3 5 5 5.4948728 3.2715377 16.357688 3.2715377 CLASE II
iC4 15 15 2.7152226 1.3597164 20.395747 1.3597164 CLASE II
nC4 (LK) 25 25 23.125 1.875 2.0831763 0.925 23.125 0.925 CLASE I
iC5 (HK) 20 20 3.6 16.4 1 0.18 3.6 0.18 CLASE I
C5 35 35 0.8391105 0.0693415 2.4269524 0.0693415 CLASE I

Rmin
q3 q4
1.3684478 0.9252031
Comp d aF Lmin+D Lmin+D Lmin Rmin D B
C3 5 5.4948728 6.6581517 6.0123304 5 0
iC4 15 2.7152226 30.241387 22.753014 15 0
nC4 (LK) 23.125 2.0831763 67.401049 41.601528 23.125 1.875
iC5 (HK) 3.6 1 -9.77072 48.130362 3.6 16.4
C5 2.9366763 0.8391105 -4.655248 -28.62262 2.9366763 32.063324
49.661676 89.874619 89.874619 40.212943 0.8097379 49.661676 50.338324
0
REFLUJO

R/Rmin 1.2
R 0.9716855

NÚMERO DE ETAPAS

X 0.0821366

Y 0.568105 N 14.021451 N 15

ETAPA DE ALIMENTACIÓN

D B zLK zHK xDHK xBLK (Nr/Ns) Ns


49.661676 50.338324 0.25 0.2 0.0724905 0.037248 0.7279569 8.6807719

Comp z Ki (xD/xB)C2H5Cl 0.01


C2H4 0.05 5.1 (xD/xB)C2H6 75
HCl 0.05 3.8
C2H6 0.1 3.4
C2H5Cl 0.8 0.15

SELECCIÓN DE CLAVES
Comp z Ki ai,HK
C2H4 0.05 5.1 34
HCl 0.05 3.8 25.333333
C2H6 (LK) 0.1 3.4 22.666667
C2H5Cl (HK 0.8 0.15 1

Nmin suponer
Comp (xD/xB) ai,HK Nmin (d/b) (d/b) f b d xD
C2H4 34 57.493825 5 0.0854791 4.9145209 0.2534917
HCl 25.333333 24.79012 5 0.1938727 4.8061273 0.2479007
C2H6 (LK) 75 22.666667 18.037455 10 0.5252803 9.4747197 0.4887074
C2H5Cl (HK 0.01 1 0.002405 0.002405 80 79.808062 0.1919379 0.0099002
2.8590059 100 80.612694 19.387306

Rmin
q 1-q q1 q2 q3
1 0 30.820485 24.310077 4.3121709
Comp z ai,HK fun fun fun D F=LF (d/lF) (d/f)
C2H4 0.05 34 0.5346728 0.17544 0.0572625 5 1.4418177 1.4418177
HCl 0.05 25.333333 -0.230842 1.2378786 0.0602567 5 1.0637886 1.0637886
C2H6 (LK) 0.1 22.666667 -0.277988 -1.379245 0.1234938 9.4747197 10 0.947472 0.947472
C2H5Cl (HK 0.8 1 -0.026827 -0.03432 -0.241533 0.1919379 80 0.0023992 0.0023992
-0.000985 -0.000247 -0.00052

R 0.28434

Numero de etapas

R Rmin Nmin X Y N N
0.28434 0.18956 2.8590059 0.0737967 0.5788155 8.1622691 9

Etapa de Alimentación

D B zLK zHK xDHK xBLK (Nr/Ns) Ns


19.666658 80.333342 0.1 0.8 0.0097596 0.0065388 1.7389031 3.285987

Comp z F a D Nmin q
A 0.4 40 5
B (LK) 0.2 20 3
C (HK) 0.4 40 1
100 60 5 1

Comp F a (d/b) (d/b) b d xD xB


A 40 5 150.52725 0.2639789 39.736021 0.6622666 0.0065995
B (LK) 20 3 11.704999 1.5741836 18.425816
C (HK) 40 1 0.0481687 0.0481687 38.161795 1.8382048
100 39.999958 60.000042
T [R]
559.67
aT1 aT2 aT6 aP1 aP2 aP3 Comp
C1 -292860 0 8.2445 -0.8951 59.8465 0 C1
C2 -687248.3 0 7.90694 -0.886 49.02654 0 C2
C3 -970688.6 0 7.156059 -0.76984 0 6.90224 C3
iC4 -1166846 0 7.72668 -0.92213 0 0 iC4
nC4 -1280557 0 7.94986 -0.96455 0 0 nC4
iC5 -1481583 0 7.58071 -0.93159 0 0 iC5
C5 -1524891 0 7.33129 -0.89143 0 0 nC5

94.540177
99.540177
101.04018
102.54018

100

(d/b)i
10000

1000

100

10

0.1

0.01
0.1 1
xD xB
0.1006813 0
0.3020438 0
0.4656508 0.037248
0.0724905 0.3257955
0.0591337 0.6369565

Ns Nf Ns
8 1 6 15
xB xD/xB
0.0010604
0.002405
0.0065161 75
0.9900185 0.01

q3
4.3121709
d d b xD xB Rmin+1 Rmin
7.2090886 5 0 0.2542374 0 0.2911655
5.3189431 5 0 0.2542374 0 0.3063903
9.4747197 9.4747197 0.5252803 0.4817656 0.0065388 0.5949507
0.1919379 0.1919379 79.808062 0.0097596 0.9934612 -0.002947
19.666658 80.333342 1.18956 0.18956

Ns Nf Ns
3 1 5 9
P [psi]
200
K Comp Tc
13.046317 METHANE 190.6
2.7726152 ETHANE 305.4
1.0128361 PROPANE 369.8
0.4130212 ISOBUTANE 408.1
0.2868323 N-BUTANE 425.2
0.1242875 2-METHYL 460.4
0.1043442 N-PENTANE 469.6
(d/b)i

1 10
Un kmol de una mezcla equimolar de benceno y tolueno se introduce como alimentación
a un sistema de destilación que consta de tres etapas (incluyendo el calderín).
El liquido de reflujo está a su punto de burbuja y L/D = 4. ¿Cuál es la cantidad y composición
media del producto en el momento en que la composición instantánea del
producto es 55 moles % de benceno? Despréciese el líquido retenido en las etapas y
supóngase a = 2,5.
alfa 2.5
x y
0 0
0.1 0.2173913 xD 0.87 xD 0.8 xD 0.75 xD
0.2 0.3846154 mLOR bLOR mLOR bLOR mLOR bLOR mLOR
0.3 0.5172414 0.8 0.174 0.8 0.16 0.8 0.15 0.8
0.4 0.625
0.5 0.7142857 0.87 0.87 0.8 0.8 0.75 0.75 0.7
0.6 0.7894737 0.7280335 0.87 0.6153846 0.8 0.5454545 0.75 0.4827586
0.7 0.8536585 0.7280335 0.7564268 0.6153846 0.6523077 0.5454545 0.5863636 0.4827586
0.8 0.9090909 0.5540128 0.7564268 0.4287159 0.6523077 0.3618513 0.5863636 0.3075993
0.9 0.9574468 0.5540128 0.6172102 0.4287159 0.5029727 0.3618513 0.4394811 0.3075993
1 1 0.3920825 0.6172102 0.2881472 0.5029727 0.2387474 0.4394811 0.2009908
0.3920825 0.487666 0.2881472 0.3905177 0.2387474 0.3409979 0.2009908

x y I W D
100
0.3920825 0.87 2.0924112 -0.141613 86.795672 13.204328
0.2881472 0.8 1.9536866 -0.097742 78.713532 8.0821399
0.2387474 0.75 1.9559803 -0.098999 71.294295 7.4192379
0.2009908 0.7 2.0039711 -0.102281 64.36276 6.9315344
0.1709059 0.65 2.0872727 -0.107266 57.816201 6.546559
0.1461506 0.6 2.2033742 -0.237475 45.594821 12.221381
0.1072461 0.5 2.5461239
0.1072461 0.5 2.5461239
0.1072461 0.5
54.405179
z 0.5 0.5
0.5 0

0.7 xD 0.65 xD 0.6 xD 0.5 xD 0.5 xD


bLOR mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR mLOR
0.14 0.8 0.13 0.8 0.12 0.8 0.1 0.8 0.1 0.8

0.7 0.65 0.65 0.6 0.6 0.5 0.5 0.5 0.5 0.5
0.7 0.4262295 0.65 0.375 0.6 0.2857143 0.5 0.2857143 0.5 0.2857143
0.5262069 0.4262295 0.4709836 0.375 0.42 0.2857143 0.3285714 0.2857143 0.3285714 0.2857143
0.5262069 0.2626023 0.4709836 0.2245989 0.42 0.1637011 0.3285714 0.1637011 0.3285714 0.1637011
0.3860794 0.2626023 0.3400818 0.2245989 0.2996791 0.1637011 0.2309609 0.1637011 0.2309609 0.1637011
0.3860794 0.1709059 0.3400818 0.1461506 0.2996791 0.1072461 0.2309609 0.1072461 0.2309609 0.1072461
0.3007927 0.1709059 0.2667247 0.1461506 0.2369205 0.1072461 0.1857969 0.1072461 0.1857969 0.1072461

xD d D xD

0.835 11.025614 13.204328 0.835


0.775 6.2636584 15.58278 0.75
0.725 5.3789474 13.51004 0.65
0.675 4.6787857 6.0193879 0.55
0.625 4.0915994
0.55 6.7217593

38.160364 0.7014105 48.316536


1

0.9

0.8

0.7
0.5
0.6
bLOR
0.5
0.1
0.4
0.5 0.3
0.5
0.2
0.3285714
0.3285714 0.1

0.2309609 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.2309609
0.1857969

d D xD d

11.025614 4.0351164 0.86 3.4702001


11.687085 9.0889718 0.825 7.4984017
8.7815261 8.0896116 0.775 6.269449
3.3106633 7.4260967 0.725 5.3839201
6.9379423 0.675 4.6831111
6.552611 0.625 4.0953819
12.232679 0.55 6.7279734

34.804888 0.7203515 54.363029 38.128437 0.7013671


0.7 0.8 0.9 1
Fase acuosa Fase orgánica
W IPE H Ac W IPE H Ac
A B C A B C
0.981 0.0121 0.0069 0.005 0.9932 0.0018 0.0121
0.971 0.0149 0.0141 0.007 0.9893 0.0037 0.9932
0.955 0.0161 0.0289 0.008 0.9841 0.0079
0.917 0.0188 0.0642 0.01 0.9707 0.0193 0.0149
0.844 0.023 0.133 0.019 0.9328 0.0482 0.9893
0.711 0.034 0.255 0.039 0.847 0.114
0.589 0.044 0.367 0.069 0.715 0.216 0.0161
0.451 0.106 0.443 0.108 0.581 0.311 0.9841
0.371 0.165 0.464 0.151 0.487 0.362
0.0188
0.9707

0.023
0.9328

0.034
0.847

0.044
0.715

0.106
0.581

0.165
0.487
Refinado Extracto
CH3Cl H2O H Ac CH3Cl H2O H Ac
A B C A B C
0.9901 0.0099 0.0000 0.0084 0.9916 0
0.9185 0.0138 0.0677 0.0121 0.7369 0.251
0.8 0.0228 0.1772 0.073 0.4858 0.4412
0.7013 0.0412 0.2575 0.1511 0.3471 0.5018
0.6715 0.052 0.2765 0.1833 0.3111 0.5056
0.5999 0.0793 0.3208 0.252 0.2539 0.4941
0.5581 0.0953 0.3466 0.2885 0.2328 0.4787

SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 60 60 0 1
C 300 0 300 0.3 0
1000 60 1060

F 0 0.3
M 0.056603774 0.2830189
S 1 0

SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 70000 70000 0 1
C 300 0 300 0.3 0
1000 70000 71000

F 0 0.3
M 0.985915493 0.0042254
S 1 0

CANTIDAD DE AGUA
F S M R E xF ySmin
A 700 0 700 0.7 0
B 0 742.3 742.3 0 1
C 300 0 300 0.3 0
1000 742.3 1742.3

0 0.96
F 0 0.3 1 0
S 1 0 -0.3 0.3
0.7369 0.251
M 0.42605 0.1721862 0.0138 0.0677 0.2534919

0.05
0.9

0.05
0.82

0.051
0.742
0.052
0.675

0.054
0.611

A B C A B C 0.056
0.95 0.05 0 0.1 0.9 0 0.558
0.925 0.05 0.025 0.101 0.82 0.079
0.899 0.051 0.05 0.108 0.742 0.15 0.059
0.873 0.052 0.075 0.115 0.675 0.21 0.503
0.846 0.054 0.1 0.127 0.611 0.262
0.819 0.056 0.125 0.142 0.558 0.3 0.062
0.791 0.059 0.15 0.159 0.503 0.338 0.457
0.763 0.062 0.175 0.178 0.457 0.365
0.734 0.066 0.2 0.196 0.414 0.39 0.066
0.675 0.075 0.25 0.246 0.329 0.425 0.414
0.611 0.089 0.3 0.28 0.275 0.445
0.544 0.106 0.35 0.333 0.217 0.45 0.075
0.466 0.134 0.4 0.405 0.165 0.43 0.329
0.434 0.15 0.416 0.434 0.15 0.416
0.089
0.275

0.106
0.217

0.134
0.165

0.15
0.15

F S1 M1 R1 E1 xF yS1
A 70 0 70 59.333911 10.666089 59.333911 0.7 0
B 0 50 50 4.1512266 45.801443 4.198557 0 1
C 30 0 30 8.0877345 21.959596 8.040404 0.3 0
100 50 150 71.572872 78.427128
0.829
0.0586613
R1 S2 M2 R2 E2 0.1123387 x1 yS2
A 59.333911 0 59.333911 52.627891 6.7060193 52.627891 0.829 0
B 4.1512266 50 54.151227 3.0007131 50.774146 3.3770804 0.058 1
C 8.0877345 0 8.0877345 2.0774168 6.386685 1.7010494 0.113 0
71.572872 50 121.57287 57.706021 63.86685
0.912
0.0585221
R2 S3 M3 R3 E3 0.0294779 x2 yS3
A 52.627891 0 52.627891 46.972725 5.6551666 0.912 0
B 3.0007131 50 53.000713 2.500012 50.319442 0.052 1
C 2.0774168 0 2.0774168 0.5275025 1.7311735 0.036 0
57.706021 50 107.70602 50.000239 57.705782

E1 E2 E3 E y
10.666089 6.7060193 5.6551666 23.027275 0.1151365
45.801443 50.774146 50.319442 146.89503 0.734476
21.959596 6.386685 1.7311735 30.077454 0.1503875
199.99976
0.0121
A B C A B C 0.9932
0.981 0.0121 0.0069 0.005 0.9932 0.0018
0.971 0.0149 0.0141 0.007 0.9893 0.0037 0.0149
0.955 0.0161 0.0289 0.008 0.9841 0.0079 0.9893
0.917 0.0188 0.0642 0.01 0.9707 0.0193
0.844 0.024 0.132 0.019 0.9328 0.0482 0.0161
0.711 0.034 0.255 0.039 0.847 0.114 0.9841
0.589 0.044 0.367 0.069 0.715 0.216
0.451 0.106 0.443 0.108 0.581 0.311 0.0188
0.371 0.165 0.464 0.151 0.487 0.362 0.9707

0.024
0.9328

0.034
0.847

0.044
0.715

0.106
0.581

0.165
0.487
SOLVENTE MÍNIMO
F Smin M Rn E1 xF Ysmin
Agua 180 0 180 143.11475 36.885248 143.11475 0.6 0
IPE 0 316.6251184 316.62512 3.1111903 313.52461 3.1005064 0 1
H Acetico 120 0 120 9.3335708 110.65575 9.3442546 0.4 0
300 316.6251184 616.62512 155.55951 461.06561
1.999567

0.5

0.4

0.3

0.2

0.1

0
0 0.5 1 1.5 2

-0.1

F Smin M Rn E1 xF Ysmin
Agua 180 0 180 143.89961 36.100395 143.89961 0.6 0
IPE 0 443.2751657 443.27517 3.1282523 440.14691 3.1282523 0 1
H Acetico 120 0 120 9.3847569 110.61524 9.3847569 0.4 0
300 443.2751657 743.27517 156.41261 586.86255
2.0105328

0.5

0.4
F Smin M Rn E1 xF Ysmin
Agua 180 0 180 150.04439 29.955607 150.04439 0.6 0
0.3

0.2
0.4

0.3
IPE 0 0 0 -458.942 474.49681 -474.4968 0 1
H Acetico 120 0 120 9.7855039 94.659717 25.340283 0.4 0
300 0 300 -299.1121
0.2 599.11213
2.0963864

0.1

0
0 0.2 0.4 0.6 0.8 1 1.2 1.
0.0069
0.0018

0.0141
0.0037

0.0289
0.5
0.0079
0.45
0.0642 0.4
0.0193
0.35

0.133 0.3

0.0482 0.25

0.2
0.255
0.15
0.114
0.1
0.367 0.05
0.216
0
0 0.2 0.4 0.6
0.443
0.311

0.464
0.362

0.0099 0
0.9916 0

0.0138 0.0677
0.7369 0.251

0.0228 0.1772
0.4858 0.4412
0.6
0.0412 0.2575
0.3471 0.5018 0.5
xM 0.6000
x y
0.6603774 0.052 0.2765
0.4
0.05660380.5000 0.3111 0.5056
0.2830189
0.3
0.4000

0.2
0.3000
0.6000

0.4
0.5000

0.3
0.4000 0.0793 0.3208
0.2539 0.4941
0.2
0.3000
0.0953 0.3466
0.2328 0.4787 0.1
0.2000

0.0
0.1000 0 0.2

0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0.6000
xM x y
0.0098592 0.5000
0.9859155
0.0042254 0.4000

0.3000

0.2000

0.1000

0.0000
xM x y 0 0.2
0.4017678 0.4017678
0.42605 0.251 0.42602
0.1721862 0.1721942

0.0642018

0
0

0.025
0.079

0.05
0.15
0.075
0.21

0.1
0.262

0.125
0.3

0.15
0.338

0.175
0.365

0.2
0.39

0.25
0.425

0.3
0.445

0.35
0.45

0.4
0.43

0.416
0.416

0.5

0.45

xM1 x1 y1 F 0 0.3
0.4
0.4666667 0.829 0.136 M1 0.3333333 0.2
0.3333333 0.058 0.584 S1 1 0
0.35
0.2 0.113 0.28
1 1 1 R1 0.058 0.113
0.3
E1 0.584 0.28
0.25

0.2

0.15
0.3

0.25
xM2 x2 y2 R1 0.058 0.113
0.4880522 0.912 0.105 M2 0.445422 0.0665258 0.2
0.445422 0.052 0.795 S2 1 0
0.0665258 0.036 0.1 0.15
R2 0.052 0.036
E2 0.795 0.1 0.1

xM3 x3 y3 R2 0.052 0.036 0.05


0.4886253 0.93945 0.098 M3 0.4920868 0.0192878
0.4920868 0.05 0.872 S3 1 0 0
0 0.1 0.2
0.0192878 0.01055 0.03
R3 0.05 0.01055
E3 0.872 0.03

0.0069
0.0018

0.0141
0.0037

0.0289
0.0079

0.0642
0.0193

0.132
0.0482

0.255
0.114

0.367
0.216

0.443
0.311

0.464
0.362
xM xN y1 F 0 0.4
0.2919116 0.92 0.08 M 0.5134807 0.1946077 -0.4 0.4
0.5134807 0.02 0.68 Smin 1 0
0.1946077 0.06 0.24
1 1 1 Rn 0.02 0.06
E1 0.68 0.24 0.2727273 0.0545455

F 0 0.4
E 0.68 0.24 -0.235294 0.4
P 1.9462069 -0.057931

R 0.02 0.06
S 1 0 -0.061224 0.0612245
P 1.9462069 -0.057931

M 0.5135135 0.1945946

-3.278E-05

1.5 2 2.5

xM xN y1 F 0 0.4
0.2421714 0.92 0.0615142 M 0.596381 0.1614476 -0.4 0.4
0.596381 0.02 0.75 S 1 0
0.1614476 0.06 0.1884858
1 1 1 Rn 0.02 0.06
M 0.596381 0.1614476 0.1760079 0.0564798
E1 0.75 0.1884858

F 0 0.4
E 0.75 0.1884858 -0.282019 0.4
P 1.5343478 -0.032715

R 0.02 0.06
S 1 0 -0.061224 0.0612245
P 1.5343478 -0.032715

xM xN y1 E1 0.75 0.1884858
0.6 -0.501633 0.05 R1 0.044 0.35 -0.228774 0.360066
0 1.5343478 0.792
0.4 -0.032715 0.158 R1 0.04 0.35
1 1 1 P 1.5343478 -0.032715

E2 0.792 0.158
R2 0.038 0.31

R2 0.038 0.31
0.8 1 1.2 1.4 1.6 1.8
P 1.5343478 -0.032715

E3 0.831 0.128
R3 0.035 0.268

R3 0.035 0.268
P 1.5343478 -0.032715

E4 0.868 0.1
R4 0.028 0.19

R4 0.028 0.19
P 1.5343478 -0.032715

E5 0.92 0.058
R5 0.024 0.145

R5 0.024 0.145
P 1.5343478 -0.032715

E6 0.95 0.036
R6 0.02 0.1

R6 0.02 0.1
P 1.5343478 -0.032715

E7 0.97 0.017
R7 0.02 0.06
0.4 0.6 0.8 1 1.2

0.6

0.5

0.4

0.3

0.2
0.4

0.3

0.2

0.1

0.0
0 0.2 0.4 0.6 0.8 1 1.2

00

00

00

00

00

00

00
0 0.2 0.4 0.6 0.8 1 1.2
0.5

0.45

0.4

0.35

0.3

0.25

0.2

0.15
0.3

0.25

0.2

0.15

0.1

0.05

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5

0.45

0.4

0.35

0.3

0.25

0.2

0.15

0.1

0.05

0
0 0.2 0.4 0.6 0.8 1 1.2
0.40

0.35

0.30

0.25

0.20
0.25

0.20

0.15

0.10

0.05

0.00
0 0.1 0.2 0.3 0.4
1 1.2
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
Fase acuosa x Fase orgánica y
W ChlorB Pyr W ChlorB Pyr
A B C A B C
0.9992 0.0008 0 0.0005 0.9995 0 0.0008 0
0.9482 0.0016 0.0502 0.0067 0.8828 0.1105 0.9995 0
0.8871 0.0024 0.1105 0.0115 0.799 0.1895
0.8072 0.0038 0.189 0.0162 0.7428 0.241 0.0016 0.0502
0.7392 0.0058 0.255 0.0225 0.6915 0.286 0.8828 0.1105
0.6205 0.0185 0.361 0.0287 0.6558 0.3155
0.5087 0.0418 0.4495 0.0395 0.61 0.3505 0.0024 0.1105
0.379 0.089 0.532 0.064 0.53 0.406 0.799 0.1895
0.132 0.378 0.49 0.132 0.378 0.49
0.0038 0.189
0.7428 0.241

0.0058 0.255
0.6915 0.286

0.0185 0.361
0.6558 0.3155

0.0418 0.4495
0.61 0.3505

0.089 0.532
0.53 0.406

0.378 0.49
0.378 0.49

SELECTIVIDAD

ChlorB Pyr KChlorB KPyr ChlorB Pyr Beta


B C B C
0.0008 0 1249.375 #DIV/0! 0.9995 0
0.0016 0.0502 551.75 2.2011952 0.8828 0.1105 250.65928
0.0024 0.1105 332.91667 1.7149321 0.799 0.1895 194.12819
0.0038 0.189 195.47368 1.2751323 0.7428 0.241 153.29679
0.0058 0.255 119.22414 1.1215686 0.6915 0.286 106.30124
0.0185 0.361 35.448649 0.8739612 0.6558 0.3155 40.560894
0.0418 0.4495 14.593301 0.7797553 0.61 0.3505 18.715233
0.089 0.532 5.9550562 0.7631579 0.53 0.406 7.8031771

F S M R E xF yS xM
A 1000 0 1000 926.33863 73.661373 0.5 0 0.0392157
B 0 23500 23500 0.946209 23497.978 0 1 0.9215686
C 1000 0 1000 18.92418 982.15164 0.5 0 0.0392157
2000 23500 25500 946.20902 24553.791 1

10.4
F S M R E xF yS xM
A 1000 0 1000 955.62779 44.372215 0.5 0 0.25
B 0 2000 2000 7.3604194 1980.1101 0 1 0.5
C 1000 0 1000 263.74836 748.78113 0.5 0 0.25
2000 2000 4000 1226.7366 2773.2634 1

R1 S M2 R2 E2 xF yS xM
A 955.62779 0 955.62779 941.18074 14.447049 0.779 0 0.3895
B 7.3604194 1226.7366 1234.097 2.0175364 1235.2227 0.006 1 0.503
C 263.74836 0 263.74836 65.569933 195.03517 0.215 0 0.1075
1226.7366 1226.7366 2453.4731 1008.7682 1444.7049 1

R1 S M2 R2 E2 xF yS xM
A 941.18074 0 941.18074 938.0025 3.17824 0.933 0 0.4665
B 2.0175364 1008.7682 1010.7857 0.9581231 1008.5615 0.002 1 0.501
C 65.569933 0 65.569933 19.162462 47.6736 0.065 0 0.0325
1008.7682 1008.7682 2017.5364 958.12308 1059.4133 1

10.5
F S M R E xF yS xM
A 4050 0 4050 3566.3389 483.66111 0.5 0 0.2810633
B 0 6309.5636 6309.5636 21.969233 6287.5945 0 1 0.4378733
C 4050 0 4050 73.230778 3976.7692 0.5 0 0.2810633
8100 6309.5636 14409.564 3661.5389 10748.025 1

F S M R E xF yS xM
A 4050 0 4050 3671.0953 378.90474 0.5 0 0.2472527
B 0 8280 8280 3.7498419 8272.7535 0 1 0.5054945
C 4050 0 4050 74.996839 3978.4998 0.5 0 0.2472527
8100 8280 16380 3749.8419 12630.158 1
F S M R E xF yS xM
A 4050 0 4050 3969.9392 80.060813 0.5 0 0.4009901
B 0 2000 2000 30.577195 3572.7138 0 1 0.1980198
C 4050 0 4050 1095.6828 1351.0262 0.5 0 0.4009901
8100 2000 10100 5096.1992 5003.8008 1

0.6
R1 S M2 R2 E2 xF yS xM
A 3969.9392 0 3969.9392 3909.9222 60.016994 0.779 0 0.3895
B 30.577195 5096.1992 5126.7764 8.3813981 5131.453 0.006 1 0.503
C 1095.6828 0 1095.6828 272.39544 810.22942 0.215 0 0.1075
5096.1992 5096.1992 10192.398 4190.699 6001.6994 0.5 1

R1 S M2 R2 E2 xF yS xM
A 3909.9222 0 3909.9222 3896.7189 13.203278 0.4 0.933 0 0.4665
B 8.3813981 4190.699 4199.0804 3.9803053 4189.8403 0.002 1 0.501
C 272.39544 0 272.39544 79.606107 198.04917 0.065 0 0.0325
4190.699 4190.699 8381.3981 3980.3053 4401.0927 1

0.3

0.2

0.1

0
0 0.2 0.4 0.6 0.8

-0.1
0.6

0.5

0.4

0.3
x y F 0 0.5

0.2
0.3

0.979 0.003 M 0.9215686 0.0392157


0.001 0.957 S 1 0
0.02 0.04 0.2
1 1 R 0.001 0.02
E 0.957 0.04

0.1
x y F 0 0.5 0.6
0.779 0.016 M 0.5 0.25
0.006 0.714 S 1 0
0.215 0.27 0.50 0 0.2 0
1 1 R 0.006 0.215
E 0.714 0.27
0.4
x y R1 0.006 0.215
0.933 0.01 M2 0.503 0.1075
0.002 0.855 S 1 0 0.3
0.065 0.135
1 1 R2 0.002 0.065
E2 0.855 0.135 0.2

x y R1 0.002 0.065
0.979 0.003 M2 0.501 0.0325 0.1
0.001 0.952 S 1 0
0.02 0.045
1 1 R2 0.001 0.02
0
E2 0.952 0.045 0 0.1 0.

x y F 0 0.5 8100
0.974 0.045 M 0.4378733 0.2810633 -6.86E-05
0.006 0.585 S 1 0 0
0.02 0.37 1
1 1 R 0.006 0.02
E 0.585 0.37 0.006
0.585
x y F 0 0.5
0.979 0.03 M 0.5054945 0.2472527 F
0.001 0.655 S 1 0 E
0.02 0.315 P
1 1 R 0.001 0.02 S
E 0.655 0.315 R
x y F 0 0.5 F
0.779 0.016 M 0.1980198 0.4009901 P
0.006 0.714 S 1 0
0.215 0.27 R1
1 1 R 0.006 0.215 E1
E 0.714 0.27
R1
x y R1 0.006 0.215 P
0.933 0.01 M2 0.503 0.1075
0.002 0.855 S 1 0 R2
0.065 0.135 E2
1 1 R2 0.002 0.065
E2 0.855 0.135 R2
P
x y R1 0.002 0.065
0.979 0.003 M2 0.501 0.0325 R3
0.001 0.952 S 1 0 E3
0.02 0.045
1 1 R2 0.001 0.02
E2 0.952 0.045

0.6 0.8 1 1.2 1.4 1.6 1.8 2


Pyridine ChlorobenzWater Pyridine ChlorobenzWater
0 99.95 0.05 0 0.08 99.92
11.05 88.28 0.67 5.02 0.16 94.82
18.95 79.9 1.15 11.05 0.24 88.71
24.1 74.28 1.62 18.9 0.38 80.72
28.6 69.15 2.25 25.5 0.58 73.92
31.55 65.58 2.87 36.1 1.85 62.05
35.05 61 3.95 44.95 4.18 50.87
40.6 53 6.4 53.2 8.9 37.9
49 37.8 13.2 49 37.8 13.2

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.2 0.4 0.6 0.8 1 1.
0.2 0.4 0.6 0.8 1 1.2

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5
0 -0.5 0.5

0.02
0.37 0.6044905 0.0163731
0.6

0 0.5
0.655 0.315 -0.282443 0.5
1.8296089 -0.01676 0.5
1 0
0.01 0.02 -0.020202 0.020202

0.4

0.3
0.5

0.4

0 0.5
1.8296089 -0.01676
0.3
0.025 0.362
0.655 0.315

0.025 0.362 0.2


1.8296089 -0.01676

0.01 0.12
0.79 0.2 0.1

0.01 0.12
1.8296089 -0.01676
0
0 0.2 0.4 0.6
0.01 0.02
0.945 0.05
1 1.2
1
0.6 0.8 1 1.2
Fase acuosa Fase orgánica
W IPE H Ac W IPE H Ac
A B C A B C
0.981 0.0121 0.0069 0.005 0.9932 0.0018 0.0121
0.971 0.0149 0.0141 0.007 0.9893 0.0037 0.9932
0.955 0.0161 0.0289 0.008 0.9841 0.0079
0.917 0.0188 0.0642 0.01 0.9707 0.0193 0.0149
0.844 0.023 0.133 0.019 0.9328 0.0482 0.9893
0.711 0.034 0.255 0.039 0.847 0.114
0.589 0.044 0.367 0.069 0.715 0.216 0.0161
0.451 0.106 0.443 0.108 0.581 0.311 0.9841
0.371 0.165 0.464 0.151 0.487 0.362
0.0188
0.9707

0.023
0.9328

0.034
0.847

0.044
0.715

0.106
0.581

0.165
0.487
Refinado Extracto
CH3Cl H2O H Ac CH3Cl H2O H Ac
A B C A B C
0.9901 0.0099 0.0000 0.0084 0.9916 0
0.9185 0.0138 0.0677 0.0121 0.7369 0.251
0.8 0.0228 0.1772 0.073 0.4858 0.4412
0.7013 0.0412 0.2575 0.1511 0.3471 0.5018
0.6715 0.052 0.2765 0.1833 0.3111 0.5056
0.5999 0.0793 0.3208 0.252 0.2539 0.4941
0.5581 0.0953 0.3466 0.2885 0.2328 0.4787

SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 60 60 0 1
C 300 0 300 0.3 0
1000 60 1060

F 0 0.3
M 0.056603774 0.2830189
S 1 0

SOLVENTE MÍNIMO
F Smin M R E xF ySmin
A 700 0 700 0.7 0
B 0 70000 70000 0 1
C 300 0 300 0.3 0
1000 70000 71000

F 0 0.3
M 0.985915493 0.0042254
S 1 0

CANTIDAD DE AGUA
F S M R E xF ySmin
A 700 0 700 0.7 0
B 0 742.3 742.3 0 1
C 300 0 300 0.3 0
1000 742.3 1742.3

0 0.96
F 0 0.3 1 0
S 1 0 -0.3 0.3
0.7369 0.251
M 0.42605 0.1721862 0.0138 0.0677 0.2534919

0.05
0.9

0.05
0.82

0.051
0.742
0.052
0.675

0.054
0.611

A B C A B C 0.056
0.95 0.05 0 0.1 0.9 0 0.558
0.925 0.05 0.025 0.101 0.82 0.079
0.899 0.051 0.05 0.108 0.742 0.15 0.059
0.873 0.052 0.075 0.115 0.675 0.21 0.503
0.846 0.054 0.1 0.127 0.611 0.262
0.819 0.056 0.125 0.142 0.558 0.3 0.062
0.791 0.059 0.15 0.159 0.503 0.338 0.457
0.763 0.062 0.175 0.178 0.457 0.365
0.734 0.066 0.2 0.196 0.414 0.39 0.066
0.675 0.075 0.25 0.246 0.329 0.425 0.414
0.611 0.089 0.3 0.28 0.275 0.445
0.544 0.106 0.35 0.333 0.217 0.45 0.075
0.466 0.134 0.4 0.405 0.165 0.43 0.329
0.434 0.15 0.416 0.434 0.15 0.416
0.089
0.275

0.106
0.217

0.134
0.165

0.15
0.15

F S1 M1 R1 E1 xF yS1
A 70 0 70 59.333911 10.666089 59.333911 0.7 0
B 0 50 50 4.1512266 45.801443 4.198557 0 1
C 30 0 30 8.0877345 21.959596 8.040404 0.3 0
100 50 150 71.572872 78.427128
0.829
0.0586613
R1 S2 M2 R2 E2 0.1123387 x1 yS2
A 59.333911 0 59.333911 52.627891 6.7060193 52.627891 0.829 0
B 4.1512266 50 54.151227 3.0007131 50.774146 3.3770804 0.058 1
C 8.0877345 0 8.0877345 2.0774168 6.386685 1.7010494 0.113 0
71.572872 50 121.57287 57.706021 63.86685
0.912
0.0585221
R2 S3 M3 R3 E3 0.0294779 x2 yS3
A 52.627891 0 52.627891 46.972725 5.6551666 0.912 0
B 3.0007131 50 53.000713 2.500012 50.319442 0.052 1
C 2.0774168 0 2.0774168 0.5275025 1.7311735 0.036 0
57.706021 50 107.70602 50.000239 57.705782

E1 E2 E3 E y
10.666089 6.7060193 5.6551666 23.027275 0.1151365
45.801443 50.774146 50.319442 146.89503 0.734476
21.959596 6.386685 1.7311735 30.077454 0.1503875
199.99976
fase acuosa fase organica 0.0081
A B C A B C 0.995
0.9919 0.0081 0 0.005 0.995 0
0.8297 0.0123 0.158 0.013 0.7 0.287 0.0123
0.7311 0.0129 0.256 0.022 0.557 0.421 0.7
0.6229 0.0171 0.36 0.044 0.429 0.527
0.456 0.051 0.493 0.103 0.284 0.613 0.0129
0.345 0.098 0.557 0.186 0.204 0.61 0.557

0.0171
0.429

0.051
0.284

0.098
0.204
SOLVENTE MÍNIMO
F Smin M Rn E1 xF Ysmin
Agua 899.748 0 899.748 1303.2268 4.6865614 895.06144 0.9 0
CLOROFOR 0 555 555 10.563135 194.4923 360.5077 0 1
ACETONA 99.972 0 99.972 6.6019597 35.14921 64.82279 0.1 0
999.72 555 1554.72 1320.3919 234.32807
12.505596

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
-2 -1 0 0.5 1 1.5

F Smin M Rn E1 xF Ysmin
Agua 899.748 0 899.748 883.03792 16.710079 883.03792 0.9 0
IPE 0 555 555 7.1573489 547.84265 7.1573489 0 1
H Acetico 99.972 0 99.972 4.4733431 95.498657 4.4733431 0.1 0
999.72 555 1554.72 894.66861 660.05139
12.337606

F Smin M Rn E1 xF Ysmin
Agua 180 0 180 168.23567 11.764331 168.23567 0.6 0
IPE 0 0 0 -104.3745 186.347 -186.347 0 1
H Acetico 120 0 120 0.8522577 37.175285 82.824715 0.4 0
300 0 300 64.713389 235.28661
2.3505508

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
-2 -1 0 0.5
0.0069
0.0018

0.0141
0.0037

0.0289
0.5
0.0079
0.45
0.0642 0.4
0.0193
0.35

0.133 0.3

0.0482 0.25

0.2
0.255
0.15
0.114
0.1
0.367 0.05
0.216
0
0 0.2 0.4 0.6
0.443
0.311

0.464
0.362

0.0099 0
0.9916 0

0.0138 0.0677
0.7369 0.251

0.0228 0.1772
0.4858 0.4412
0.6
0.0412 0.2575
0.3471 0.5018 0.5
xM 0.6000
x y
0.6603774 0.052 0.2765
0.4
0.05660380.5000 0.3111 0.5056
0.2830189
0.3
0.4000

0.2
0.3000
0.6000

0.4
0.5000

0.3
0.4000 0.0793 0.3208
0.2539 0.4941
0.2
0.3000
0.0953 0.3466
0.2328 0.4787 0.1
0.2000

0.0
0.1000 0 0.2

0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0.6000
xM x y
0.0098592 0.5000
0.9859155
0.0042254 0.4000

0.3000

0.2000

0.1000

0.0000
xM x y 0 0.2
0.4017678 0.4017678
0.42605 0.251 0.42602
0.1721862 0.1721942

0.0642018

0
0

0.025
0.079

0.05
0.15
0.075
0.21

0.1
0.262

0.125
0.3

0.15
0.338

0.175
0.365

0.2
0.39

0.25
0.425

0.3
0.445

0.35
0.45

0.4
0.43

0.416
0.416

0.5

0.45

xM1 x1 y1 F 0 0.3
0.4
0.4666667 0.829 0.136 M1 0.3333333 0.2
0.3333333 0.058 0.584 S1 1 0
0.35
0.2 0.113 0.28
1 1 1 R1 0.058 0.113
0.3
E1 0.584 0.28
0.25

0.2

0.15
0.3

0.25
xM2 x2 y2 R1 0.058 0.113
0.4880522 0.912 0.105 M2 0.445422 0.0665258 0.2
0.445422 0.052 0.795 S2 1 0
0.0665258 0.036 0.1 0.15
R2 0.052 0.036
E2 0.795 0.1 0.1

xM3 x3 y3 R2 0.052 0.036 0.05


0.4886253 0.93945 0.098 M3 0.4920868 0.0192878
0.4920868 0.05 0.872 S3 1 0 0
0 0.1 0.2
0.0192878 0.01055 0.03
R3 0.05 0.01055
E3 0.872 0.03

0
0
fase acuoosa fase organica
0.158 A B C A B C
0.287 99.19 0.81 0.5 99.5
82.97 1.23 1.3 70
0.256 73.11 1.29 2.2 55.7
0.421 62.29 1.71 4.4 42.9
45.6 5.1 10.30.7 28.4
0.36 34.5 9.8 18.6 20.4
0.6
0.527
0.5
0.493
0.613 0.4

0.557 0.3
0.61
0.2

0.1

0
0 0.2 0.4
xM xN y1 F 0 0.1
0.5787203 0.987 0.02 M 0.3569775 0.0643023 -0.1 0.1
0.3569775 0.008 0.83 Smin 1 0
0.0643023 0.005 0.15
1 1 1 Rn 0.008 0.005
E1 0.83 0.15 0.176399 0.0035888

F 0 0.1
E 0.83 0.15 0.060241 0.1
P -1.454623 0.0123721

R 0.008 0.005
S 1 0 -0.00504 0.0050403
P -1.454623 0.0123721

M 0.3488116 0.0651188
1 1.5

0.0081658

xM xN y1 F 0 0.1
0.5787203 0.987 0.0253163 M 0.3569775 0.0643023 -0.1 0.1
0.3569775 0.008 0.83 S 1 0
0.0643023 0.005 0.1446837
1 1 1 Rn 0.008 0.005
M 0.3569775 0.0643023 0.1699315 0.0036405
E1 0.83 0.1446837

F 0 0.1
E 0.83 0.1446837 0.0538357 0.1
P -1.612874 0.0131697

R 0.008 0.005
S 1 0 -0.00504 0.0050403
P -1.612874 0.0131697

xM xN y1 E1 0.83 0.1446837
0.6 2.5997042 0.05 R1 0.044 0.35 -0.261217 0.3614935
0 -1.612874 0.792
0.4 0.0131697 0.158 R1 0.04 0.35
1 1 1 P -1.612874 0.0131697

E2 0.792 0.158
R2 0.038 0.31

R2 0.038 0.31
P -1.612874 0.0131697

E3 0.831 0.128
R3 0.035 0.268
0.7

R3 0.035 0.268
0.6
P -1.612874 0.0131697

0.5
E4 0.868 0.1
R4 0.028 0.19
0.4

R4 0.028 0.19
0.3
P -1.612874 0.0131697

0.2 E5 0.92 0.058


R5 0.024 0.145
0.1

R5 0.024 0.145
0
0 0.5 1 1.5
P -1.612874 0.0131697

E6 0.95 0.036
R6 0.02 0.1

R6 0.02 0.1
P -1.612874 0.0131697

E7 0.97 0.017
R7 0.008 0.005
0.4 0.6 0.8 1 1.2

0.6

0.5

0.4

0.3

0.2
0.4

0.3

0.2

0.1

0.0
0 0.2 0.4 0.6 0.8 1 1.2

00

00

00

00

00

00

00
0 0.2 0.4 0.6 0.8 1 1.2
0.5

0.45

0.4

0.35

0.3

0.25

0.2

0.15
0.3

0.25

0.2

0.15

0.1

0.05

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.2 0.4 0.6 0.8 1 1.2


0.40

0.35

0.30

0.25

0.20
0.25

0.20

0.15

0.10

0.05

0.00
0 0.1 0.2 0.3 0.4
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1

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