Apunte Ingles I - Ingenieria Quimica 2015
Apunte Ingles I - Ingenieria Quimica 2015
Apunte Ingles I - Ingenieria Quimica 2015
INGLES I
Seleccin de Material y Ejercitacin
2014
INTRODUCCIN
Esta recopilacin y ejercitacin no est pensada como una autogua de estudio, sino como soporte de clases
presenciales. Busca colaborar con el desarrollo de tus propias habilidades lectoras e interpretativas de textos
escritos en idioma ingls que versen sobre cuestiones relacionadas a tu opcin de estudios universitarios, es decir,
la Qumica en general y la Ingeniera Qumica en particular.
Los textos que se incluyen son, en su mayora, originales, por ello se cita la fuente informtica de la cual se
obtuvieron. La ejercitacin es gradual y orientativa, dirigida a que internalices estrategias que te permitan inferir el
significado de palabras, de frases o de estructuras opacas para un hispano-parlante, minimizando el uso del
diccionario, es decir, promoviendo su utilizacin como ltimo recurso, abordando eventualmente las bsquedas de
un modo inteligente y efectivo.
Nos apoyaremos en tu Weltanshauung, tu Cosmovisin de alumno universitario argentino, de habla hispana, que
a tu edad ya ha tenido una virtual sobreexposicin meditica a la lengua inglesa desde la infancia.
Recurriremos a la Gramtica, ciencia que estudia los elementos de una lengua y sus combinaciones y a la
Gramtica Comparada, para establecer relaciones entre ambas lenguas, haciendo permanentes anlisis lexicos,
semnticos y sintcticos a partir de tus propios conocimientos y de los nuevos conceptos que vayas adquiriendo.
Te invito a compartir dos mdulos de aprendizaje, en los que reforzars tus capacidades de lector autnomo y
competente y desarrollars tus habilidades intelectuales superiores: reconocimiento, comprensin, aplicacin y
anlisis, sntesis y evaluacin de informacin relevante en idioma extranjero, en un ambiente de respeto y
cordialidad, para que la instancia alica resulte satisfactoria para todos quienes participan.
Te invito a que compruebes cuntas cosas no sabas que sabas
Downloaded from Digital Engineering Library @ McGraw-Hill (www.digitalengineeringlibrary.com) Copyright 2004 The McGraw-Hill
Companies. All rights reserved. Any use is subject to the Terms of Use as given at the website.
Gas Laws
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Gases behave differently from the other two commonly studied states of matter, solids and
liquids, so we have different methods for treating and understanding how gases behave
under certain conditions. Gases, unlike solids and liquids, have neither fixed volume nor
shape. They are molded entirely by the container in which they are held. We have three
variables by which we measure gases: pressure, volume, and temperature. Pressure is
measured as force per area. The standard SI unit for pressure is the pascal (Pa). However
atmospheres (atm) and several other units are commonly used. The table below shows the
conversions between these units.
Units of Pressure
1 pascal (Pa)
1 N*m-2 = 1 kg*m-1*s-2
1 atmosphere (atm)
1.01325*105 Pa
1 atmosphere (atm)
760 torr
1 bar
105 Pa
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Volume is related between all gases by Avogadro's hypothesis, which states: Equal
volumes of gases at the same temperature and pressure contain equal numbers of
molecules. From this, we derive the molar volume of a gas (volume/moles of gas). This
value, at 1 atm, and 0 C is shown below.
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The Ideal Gas Law assumes several factors about the molecules of gas. The volume of the
molecules is considered negligible compared to the volume of the container in which they
are held. We also assume that gas molecules move randomly, and collide in completely
elastic collisions. Attractive and repulsive forces between the molecules are therefore
considered negligible.
Previously, we considered only ideal gases, those that fit the assumptions of the ideal gas
law. Gases, however, are never perfectly in the ideal state. All atoms of every gas have
mass and volume. When pressure is low and temperature is low, gases behave similarly to
gases in the ideal state. When pressure and temperature increase, gases deviate farther
from the ideal state. We have to assume new standards, and consider new variables to
account for these changes. A common equation used to better represent a gas that is not
near ideal conditions is the Van der Waals equation, seen below.
DEFINITIONS
Analytical Spectroscopy
Chromatography
Forensic Chemistry
Instrumental Analysis
Quantitative Analysis
Statistics in Analytical Chemistry
Software for Analytical Chemistry Biochemistry
Biochemistry
1.
2.
3.
4.
Biochemistry Laboratory
Inorganic Biochemistry
Models for Biochemistry
Software for Biochemistry
http://www.umsl.edu/~chemist/books/texts.html
CONSIGNAS
6. Definiciones: analice las definiciones. Cules son las estructuras que se repiten? Son
transparentes?
7. Qu contiene una Table of Contents?
8. Cules palabras son sustantivos? Cules son adjetivos?
9. Que inferencia puedes hacer en relacin a la sintaxis de la frase sustantiva ms simple
(sustantivo + modificadores)
10. Cules son las funciones de la lengua que encontramos en los textos de esta unidad?
States of Matter
Gases, liquids and solids are all made up of microscopic particles, but the behaviors of these
particles differ in the three phases. The following figure illustrates the microscopic differences.
Note that:
Particles in a:
o gas are well separated with no regular arrangement.
o liquid are close together with no regular arrangement.
o solid are tightly packed, usually in a regular pattern.
Particles in a:
o gas vibrate and move freely at high speeds.
o liquid vibrate, move about, and slide past each other.
o solid vibrate (jiggle) but generally do not move from place to place.
Liquids and solids are often referred to as condensed phases because the particles are very close
together. The following table summarizes properties of gases, liquids, and solids and identifies
the microscopic behavior responsible for each property.
Characteristics of Gases, Liquids and Solids, Microscopic Explanation for the Behavior
gas
liquid
solid
Its compressible
There is a lot of free space
between particles
CONSIGNAS
11. Analice las definiciones. Cules son las expresiones utilizadas?
12. Subraye los verbos, y las expresiones verbales.
13. Identifique los verbos en presente simple. Identifique el verbo auxiliar utilizado en este
tiempo verbal.
14. Cules palabras terminadas en s son sustantivos en plural? Cules son verbos
en 3. persona singular del tiempo presente simple?
15. Indique cmo se formaron las oraciones negativas.
The area of this research covers studies aiming to create seeds for innovative technologies based
on creative ideas on living matter concerning techniques for measurements and analyses based
on new principles and methods necessary for the elucidation of life phenomena.
More concretely, it covers new techniques for measurements and analyses of various chemical
processes in cells and for the elucidation of life phenomena of cells, living matter, and ecological
systems ranging from a micro-scale to a macro-scale. It covers studies expected to trigger the
creation of new methodologies and technological development that aim to obtain unique results in
life science technologies. It also includes environmental measurements associated with life
phenomena. In the field of life science, studies in biomolecular science such as structural biology,
which are closely associated with the structures and functions of biomolecules, are actively carried
out. Needless to say, this research area undoubtedly has the molecular science of life phenomena
within its view. It is becoming clearer that the area of chemistry is shifting from "chemistry of
biomolecules" to "chemistry of life phenomena (chemical biology)", which aims at the chemical
elucidation of life phenomena. However, a leaping development in technology for measurements
and analyses related to life phenomena is essential for the progress from science of biomolecules
to that of life phenomena. The science of life phenomena can not make progress without unique
techniques for measurements and analyses of interactions of biomolecules in living matter and cell
or at levels of living matter, cell, individual, and, further, ecology. Studies that are positive for the
development of advanced methods for measurements and analyses based on new concepts by
taking advantage of physical, chemical, and biological phenomena are welcome for the purpose of
elucidating life phenomena including various complex chemical processes. This research area
includes studies on measurements and analyses covering environment related to life phenomena.
de http://www.seimei.jst.go.jp/en/ryoiki/index.html
CONSIGNAS
1. Subraye todas las palabras que considere que estn en plural.
2. Identifique los plurales Griegos y Latinos. Cules son las formas ms utilizadas en este
texto? Cules son las formas singulares de esos mismos trminos?
3. Subraye los verbos, y las expresiones verbales. Cual es el tiempo que predomina?
4. Qu funciones de la lengua predominan?
Laws of Chemistry
Summary of Major Chemistry Laws
By Anne Marie Helmenstine, Ph.D., About.com
Avogadro's Law
Equal volumes of gases under identical temperature and pressure conditions contain equal
numbers of particles (atoms, ion, molecules, electrons, etc.).
Boyle's Law
At constant temperature, the volume of a confined gas is inversely proportional to the pressure
to which it is subjected.
Charles' Law
At constant pressure, the volume of a confined gas is directly proportional to the absolute
temperature.
Dalton's Law
The pressure of a mixture of gases is equal to the sum of the partial pressures of the
component gases.
Faraday's Law
The weight of any element liberated during electrolysis is proportional to the quantity of
electricity passing through the cell and also to the equivalent weight of the element.
Gay-Lussac's Law
The ratio between the combining volumes of gases and the product (if gaseous) can be
expressed in small whole numbers.
Graham's Law
The rate of diffusion or effusion of a gas is inversely proportional to the square root of its
molecular mass.
Henry's Law
The solubility of a gas (unless it is highly soluble) is directly proportional to the pressure applied
to the gas.
Chemistry (from Egyptian kme (chem), meaning "earth") is the science concerned
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with the composition, structure, and properties of matter, as well as the changes it
undergoes during chemical reactions. Historically, modern chemistry evolved out of
alchemy following the chemical revolution (1773). Chemistry is a physical science related
to studies of various atoms, molecules, crystals and other aggregates of matter whether in
isolation or combination, which incorporates the concepts of energy and entropy in
relation to the spontaneity of chemical processes.
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Disciplines within chemistry are traditionally grouped by the type of matter being studied
or the kind of study. These include inorganic chemistry, the study of inorganic matter;
organic chemistry, the study of organic matter; biochemistry, the study of substances
found in biological organisms; physical chemistry, the energy related studies of chemical
systems at macro, molecular and submolecular scales; analytical chemistry, the analysis of
material samples to gain an understanding of their chemical composition and structure.
Many more specialized disciplines have emerged in recent years, e.g. neurochemistry the
chemical study of the nervous system
http://en.wikipedia.org/wiki/Chemistry#Etymology
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Element
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The most convenient presentation of the chemical elements is in the periodic table of the
chemical elements, which groups elements by atomic number. Due to its ingenious
arrangement, groups, or columns, and periods, or rows, of elements in the table either
share several chemical properties, or follow a certain trend in characteristics such as
atomic radius, electronegativity, etc. Lists of the elements by name, by symbol, and by
atomic number are also available.
CONSIGNAS
1. Cmo se forma la voz pasiva en Ingls? Y en Castellano?
2. Identifique los verbos y la Voz en que se encuentran.
3. En general, Cundo se prefiere la Voz Pasiva a la Voz Activa en textos tcnicos?
4. Que funcin cumple el Complemento Agente?
5. Identifica en los textos los complementos agente y distnguelos de otras expresiones
introducidas por by.
6. Cuales son las formas ms utilizadas en este texto? Cules son las formas
singulares de esos mismos trminos?
7. Qu funciones de la lengua predominan en estos textos?
El tipo de materia bajo estudio es lo que diferencia las disciplinas dentro de la qumica
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CAUSA / RAZN
Because / of
On account of
Owing to
o
As a result
As a consequence
Then
Thus
Or else
Otherwise
Provided / providing
As / So long as
Should (sintaxis invertida)
Have / Be (sintaxis invertida)
Earlier
Next
Before
Later / on
Ultimately
Meanwhile
From to
As
For
Since
In view of
Due to
So
And so
Therefore
Hence
In addition / to
Besides
Moreover
Both and
As well / as well as
Furthermore
For instance
Namely
Such as
That is
Likewise
Unlike
To summarize
But
However
In contrast
Instead
Conversely
Nevertheless
Yet
While
On the other hand
In spite of
Neither nor
Whether or
Particularly
In particular
In fact
Actually
Indeed
Really
REPETICIN O ENFASIS:
Above all
In other words
Most importantly
In summary
For + ~ ing
In order to + infinitivo
So as to
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Despite the increasing signicance of precious metals secondary sources, the bulk are still
recovered by tradicional mining processes.
A pesar de
Hydrometallurgical schemes deal with the fundamental chemistry of the precious metals as
well as extraction mechanisms.
asi como
tambin
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In spite of the positive aspects, there are still some drawbacks to secondary source
precious metal recovery.
The material on thermochemistry (Chapter 14) has been expanded to include energy
changes at constant volume as well as at constant pressure.
In order to write the formula, enter through the keyboard the power to which you wish to
raise the number
When homework assignments are returned and you find some problems marked wrong (in
spite of your efforts), do something about it soon.
The number need not be an integer, plus it may be less than one as well as larger than one.
The mathematics used in general chemistry is elementary, involving only arithmetic and
simple algebra. Nevertheless, if you don't understand it, you can expect troubles before
long. Actually, before you can really get into chemistry, you need to master the
mathematical operations in the first six chapters.
Throughout this chapter, we talked as though every number we wish to use with a
calculator must be entered through the keyboard. Frequently, however, we wish to use the
result of a just-performed calculation (i.e. a number which is still visible in the lighted
display) as part of the next calculation step.
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comperative
superlative
positive
comperative
superlative
strong
stronger than
The strongest
big
bigger than
The biggest
small
smaller than
The smallest
thin
thinner than
The thinnest
late
later than
The latest
fat
fatter than
The fattest
nice
nicer than
The nicest
white
whiter than
The whitest
positive
comperative
superlative
careful
expensive
difficult
tired
terrible
Irregular forms
positive
comperative
superlative
positive
comperative superlative
good
better
The best
many
more
The most
bad
worse
The worst
little
less
The least
much
more
The most
Gold is likely the earliest metal known to humanity because it can be found in its
native form and is easier to work (softer) than copper, which is also found in its
native form. Gold is the least active of the metals.
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CONSIGNAS
1.
2.
Today, the industry has two new words to get acquainted with, words that may be even
more important since they affect not just construction but the very quality of life in our
communities: depollution and photocatalysis.
Depollution is the opposite of pollution and means the removal of contaminants and
impurities from the environment. The newest tool for achieving depollution is a
photocatalyst, a material that uses solar energy to accelerate chemical reactions without
being consumed or depleted in the process. As new as these words are, they are rapidly
entering the vocabulary of designers and builders around the world.
2. Definicin: Photocatalyst
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ZINC
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Zinc is crystalline (hexagonal), moderately hard and brittle, and has a bluish-white
color. Its vapor density corresponds with the formula Zn. It readily burns in air
when the turnings are heated in a flame, or the metal is heated strongly in a
crucible, producing a white cloud of oxide which settles out in the form of woolly
flocks. These were called Philosophers wool, nix alba or pompholyx by the
alchemists. A tassel of thin sheet of zinc tipped with a little burning sulphur burns
brilliantly in oxygen. The metal oxidizes in moist air forming a greyish-white crust
of the basic carbonate, and is attacked and dissolved by soft water, especially that
containing peat acids, or sea water.
Zinc is more resistant to moist air than iron, and is used as a protection for this
metal. The iron sheets or wire are cleaned by a sand-blast and pickling in dilute
hydrochloric acid, and are dipped into molten zinc where an adherent coating of
the latter is formed. This process is known as galvanizing and the product as
galvanized iron. Iron particles may also be coated with zinc by spraying or by
heating them in zinc dust (sherardizing). The zinc dissolves before iron in
presence of oxygen and moisture, since it is more electropositive than iron. The
metal is also used for the negative electrodes of the voltaic cell.
Zinc dissolves in dilute acid evolving hydrogen (except before nitric acid) and
producing zinc salts containing the cations Zn. It also dissolves readily in hot
solutions of potassium or sodium hydroxides (magnesium is insoluble), evolving
hydrogen and forming solutions of zincates.
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3. RESOLVER
a. En la lnea 16 hay una comparacin. Diga si es de igualdad, superioridad o de
inferioridad y qu se compara.
b. Qu es el hierro galvanizado?
Hardly
Cooled
Weakly
The former
After
Cold
5. CONECTORES Diga que tipo de relacin establece y complete las funciones lgicas.
When (l.3)
Since (l.16)
6. Que expresan?
a. By soft water
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CONSIGNAS
1. Identifique los verbos, la Voz y el Tiempo en que se encuentran.
2. Cuales verbos indican FUTURIDAD?
3. Identifique todos los verbos en INFINITIVO
4. Que funcin cumple el el infinitivo en cada caso? (Sujeto de la oracin, completa el
significado de otro verbo, indica prpsito, complemento indispensable del
predicado)
5. Qu otra forma de indicar propsito encuentra en el texto?
6. Qu funciones de la lengua predominan en este texto?
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Cual es la motivacin que tiene A.M. Torres para dedicarse al tratamiento de aguas?
2.
3.
4.
Qu influencia tiene el tamao del poro del oxido de aluminio que se tutiliza en el tratamiento de aguas?
5.
REFERENCIA (A qu remiten?)
1.
2.
3.
4.
5.
6.
her (l. 2)
our (l. 5)
they (l.16)
them (l. 19)
it (l. 25)
my (l. 31)
5.
Torres tiene fuertes motivaciones personales y familiares para participar de los proyectos
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Las palabras terminadas en ing pueden traducirse de diversas maneras, segn la funcin que
desempeen dentro de la oracin:
1. Como SUSTANTIVO
Decanting and centrifuging are two very important processes in Chemistry.
Reading is a rewarding habit.
2. Como ADJETIVO
The decanting bottle must be duly cleansed before filling it with a different solvent..
I forgot my reading glasses home.
Traveling is sometimes boring without a good deal of reading material.
3. Como gerundio, indicando el MODO en que algo sucede o se realiza
The molecules of the gas inside the pump are in constant motion, bumping into one
another and into the walls of the pump.
Immiscible liquids (such as water and cooking oil) can be separated by using a
separating funnel.
4. Como gerundio, indicando el MTODO de realizacin
The molecules of the gas inside the pump are in constant motion. They can be
compressed by gently pushing down the piston.
You can separate a solution simply by letting the solvent evaporate.
Pollutants can be hidden from sight by covering the dumping area with soil.
5. Como gerundio, en los tiempos verbales CONTINUOS
The engineer cannot be disturbed. He is currently working on the restricted area of
the manufacturing plant.
I was working hard on my new paper when the people from a nearby construction
started making a terrible noise.
They are not working now, but they were working on that last week.
6. Como INFINITIVO, indicando propsito
Mixtures containing a solid and a solvent can be separated by using a decanter, and
then simply pouring the liquid off.
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EJERCICIO
Ahora, para ejercitar estos nuevos conceptos sobre usos y traducciones de las palabras
terminadas en -ing, vuelva al texto Students investigate methods to remove arsenic and
fluoride from water de la pgina 16. Identifique de qu uso se trata.
Traduzca cada frase en el contexto que le da sentido.
USOS DE LA -ING
1.
2.
3.
4.
5.
6.
7.
8.
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Gases are fluids which have no definite shape and no definite volume. They differ
from liquids in possessing the power of expanding until they fill completely any
vessel in which they are placed.
Gases and liquids are classed together as FLUIDS, on account of their ability to
flow under the influence of very small forces. Thus, gases (which were former
described as ELASTIC FLUIDS) will flow under the influence of their own elasticity
until the space in which they are confined is filled completely. Liquids will flow
under gravity, but viscous liquids flow only slowly. PLASTIC SOLIDS, such as
lead or sodium, can be made to flow under pressure, e.g. by squirting through a
nozzle; but this flow does not take place until a minimum limiting pressure is
applied.
The behavior of gases is generally much simpler than that of solids and liquids.
Thus, while the physical properties of liquids and solids vary widely from
substance to substance, and have to be studied individually, it is often possible to
state a simple rule which will describe the properties or behavior of all gases, e.g.
their combination by volume (Chapter III) and their behavior on compression or on
change of temperature. For this reason, it is convenient to begin the study of
physical chemistry by considering the properties of gases.
Lowry and Cavell. Intermediate Chemistry. Macmillan and Co. London, p.453
1. De ejemplos de
a. Fluidos
b. Fluidos Elsticos
c. Solidos Plsticos
2. REFERENCIA (A qu/quin remiten los trminos?)
a. they (l.1)
b. their (l.4)
c. their (l.6)
d. That (l. 12)
e. their (l. 16)
3. USOS DE LA TERMINACIN -ING (Diga de qu uso se trata y traduzca los conceptos
que dan sentido al uso)
a. In posessing (l.2)
b. By squirting (l.9)
c. Limiting (l.10)
d. By considering (l.18)
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having
Because of
forced
broadly
performance
variation
appropriate
5. CONECTORES Diga que tipo de relacin establece y complete las funciones lgicas.
Until (l.2)
On account of
(l.4)
thus (l.5)
e.g. (l.9)
e.g. (l.15)
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Un Verbo Modal (modal, modal auxiliary verb, modal auxiliary) es un tipo especial de verbo
auxiliar que se usa para imprimir modalidad al verbo principal al cual acompaa (posibilidad,
habilidad, permiso, obligacin, necesidad). Componen una clase diferente de verbos en el
idioma ingls.
Los verbos modales, en general, comparten ciertas caractersticas gramaticales entre s:
1.
Son verbos auxiliares como be, do, y have, es decir, que acompaan a un verbo
principal, portador del sentido principal, pero a diferencia de stos, imprimen al verbo
principal una modalidad, modificando el sentido funcional.
2.
Como auxiliares, permiten la inversin necesaria para armar interrogaciones, y
aceptan la forma de negaciones (la partcula negativa not)
3.
Son verbos defectivos, y como tales, no son conjugables en tiempos distintos. Existen,
no obstante, expresiones modales sinnimas que pueden ser usadas en todos los
tiempos conjugados, e incluso aceptan ser acompaados por verbos modales.
I am able to go to New York now (posibilidad fsica)
I was able to go to New York last summer
I will be able to go to New York next summer
I have not been able to go back to New York since I lost my passport
I might have been able to visit NY if I had attended the congress
I have to go to New York (obligacin)
I had to go to New York, but I couldnt.
I will have to go to New York if I want to attend the congress
I could have to go to New York next summer
4.
Van siempre acompaados del verbo principal en forma de infinitivo sin la partcula to,
salvo el modal ought to que la contiene.
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EJERCICIOS
1.
Observa qu tipo de modalidad imprime cada uno de los verbos modales marcados en el texto.
2.
Determina si se trata de modalidad sobre el eje del Poder / Deber / Necesidad, y la subcategora.
3.
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Solar power remains the ultimate Olympic gold-medal dream of a clean, efficient
and sustainable source of energy. The problem has been that in order to replace
fossil fuels, we need to get a lot more proficient at harvesting sunlight and
converting it into energy. Nature has solved this problem through
photosynthesis; all we have to do is emulate it. But first we need a much better
understanding of how photosynthesis works at the molecular and electronic
levels.
"After working on the problem for about 3 billion years, nature has achieved an
energy transfer efficiency of approximately 97 percent," says Graham Fleming,
director of Berkeley Lab's Physical Biosciences Division and an internationally
acclaimed leader in spectroscopic studies of photosynthetic processes. "If we
can get a complete understanding as to how this is done, creating artificial
versions of photosynthesis should be possible." ...
"If we can follow the steps in transferring energy from donor to acceptor
molecules, we might be able to design new and much more effective strategies
for synthetic light harvesters," Fleming says.
Because the extra energy being transferred from one molecule to the next
changes the way each molecule absorbs and emits light, the flow of energy can
be spectroscopically followed. To do this, however, Fleming and his
experimental research team need to know what spectroscopic signals they
should be looking for.
de http://www.lbl.gov/Science-Articles
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A chemical bond is the physical process responsible for the attractive interactions
between atoms and molecules, and that which confers stability to diatomic and
polyatomic chemical compounds. The explanation of the attractive forces is a complex
area that is described by the laws of quantum electrodynamics. In practice, however,
chemists usually rely on quantum theory or qualitative descriptions that are less
rigorous but more easily explained to describe chemical bonding. In general, strong
chemical bonding is associated with the sharing or transfer of electrons between the
participating atoms. Molecules, crystals, and diatomic gases, indeed most of the
physical environment around us, are held together by chemical bonds, which dictate
the structure of matter.
Bonds vary widely in their strength. Generally covalent and ionic bonds are often
described as "strong", whereas hydrogen bonds and van der Waals bonds are
generally considered to be "weak". Care should be taken because the strongest of the
"weak" bonds can be stronger than the weakest of the "strong" bonds.
In the year 1927, valence bond theory was formulated which argued essentially that a
chemical bond forms when two valence electrons, in their respective atomic orbitals,
work or function to hold two nuclei together, by virtue of system energy lowering
effects. In 1931, building on this theory, chemist Linus Pauling published what some
consider one of the most important papers in the history of chemistry: On the Nature
of the Chemical Bond. In this paper, building on the works of Lewis, and the valence
bond theory (VB) of Heitler and London, and his own earlier work, he presented six
rules for the shared electron bond, the first three of which were already generally
known:
1. The electron-pair bond forms through the interaction of an unpaired electron on
each of two atoms.
2. The spins of the electrons have to be opposed.
3. Once paired, the two electrons cannot take part in additional bonds.
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
4. The electron-exchange terms for the bond involves only one wave function
from each atom.
5. The available electrons in the lowest energy level form the strongest bonds.
6. Of two orbitals in an atom, the one that can overlap the most with an orbital
from another atom will form the strongest bond, and this bond will tend to lie in
the direction of the concentrated orbital.
Building on this article, Paulings 1939 textbook: On the Nature of the Chemical Bond
would become what some have called the bible of modern chemistry. This book
helped experimental chemists to understand the impact of quantum theory on
chemistry. However, the later edition in 1959 failed to address adequately the
problems that appeared to be better understood by molecular orbital theory. The
impact of valence theory declined during the 1960s and 1970's as molecular orbital
theory grew in popularity and was implemented in many large computer programs.
Since the 1980s, the more difficult problems of implementing valence bond theory into
computer programs have been largely solved and valence bond theory has seen a
resurgence
26
el
tipo
de
27
10
15
20
II.
1.
2.
3.
4.
5.
III.
1.
2.
3.
4.
IV.
1.
2.
3.
which (l. 3)
which (l. 9)
this (l. 23)
it (l. 23)
FUNCIONES ( Diga qu se compara y de lnea de referencia ) (0.5 x 3 = 1.5 p)
Un comparativo (superioridad)
Un comparativo (inferioridad)
Un comparativo (igualdad)
28
The reason a liquid evaporates is that its molecules are all in motion in nearly random 5
directions and speeds, and the energy of that movement can be compared to the heat
needed to boil that liquid. On average, the molecules do not have enough energy to
escape from the liquid, or else the liquid would turn into vapor quickly. When the
molecules collide, they transfer energy to each other in varying degrees, based on how
they collide. Sometimes the transfer is so one-sided that one of the molecules ends up 10
with enough energy to be considered past the boiling point of the liquid. If this happens
near the surface of the liquid it may actually fly off into the gas and thus "evaporate".
Liquids that do not appear to evaporate visibly at a given temperature in a given gas
(e.g. cooking oil at room temperature) have molecules that do not tend to transfer
energy to each other in a pattern sufficient to frequently give a molecule the "escape 15
velocity" - the heat energy - necessary to turn into vapor. However, these liquids are
evaporating, it's just that the process is much slower and thus significantly less visible.
Evaporation is an essential part of the water cycle. Solar energy drives evaporation of
water from oceans, lakes, moisture in the soil, and other sources of water. In hydrology,
evaporation and transpiration (which involves evaporation within plant stomata) are 20
collectively termed evapotranspiration.
For molecules of a liquid to evaporate, they must be located near the surface, be
moving in the proper direction, and have sufficient kinetic energy to overcome liquidphase intermolecular forces. Only a small proportion of the molecules meet these
criteria, so the rate of evaporation is limited. Since the kinetic energy of a molecule is 25
proportional to its temperature, evaporation proceeds more quickly at higher
temperature. As the faster-moving molecules escape, the remaining molecules have
lower average kinetic energy, and the temperature of the liquid thus decreases. This
phenomenon is also called evaporative cooling. This is why evaporating sweat cools
the human body. Evaporation also tends to proceed more quickly with higher flow rates 30
between the gaseous and liquid phase and in liquids with higher vapor pressure. For
example, laundry on a clothes line will dry (by evaporation) more rapidly on a windy day
than on a still day. Three key parts to evaporation are heat, humidity and air movement.
I.
II.
III.
IV.
when (l. 8)
e.g. (l. 13)
however (l. 16)
as (l. 26)
V.
VI.
29
its (l. 5)
they (l. 9)
they (l.22)
its (l. 25)
Matter comes in three states that are distinguished by the strength of the bonds holding the
molecules of the matter together. The three states of matter are:
Solids: The strong bonds between molecules make solids rigid and very difficult to deform.
Liquids: The relatively weak bonds between molecules allow liquids to be deformed without
effort. Liquids have a fixed volume, but their shape is determined by the shape of the container
holding them.
Gases: Virtually no bonds exist between gas molecule so that gases can spread into any
available space. The volume of a gas is determined by the size of the container holding it.
The molecules of a solid don't move around very much. They tend to stay relatively close to
each other. If a solid has molecules arranged in an orderly fashion, we say it is crystalline. If
the molecules of a solid are not arranged in any order, we call the solid amorphous. Many
polymers are crystalline solids, while others are amorphous solids.
10
The molecules of a liquid move around a lot. They're always moving relative to each other.
This is why liquids don't hold their shape and why they can be poured. But even though the
molecules of a liquid move relative to each other, they are still bound to each other through
intermolecular forces. This is why liquids hold their volume.
15
Another important difference between gases and liquids is that molecules in the liquid state
interact with each other through intermolecular forces. These forces hold liquid molecules
together. When molecules are in the gas state, they don't interact much. This is why liquids
keep their volume but gases do not. Gas molecules aren't held together strongly, so they can
spread out, filling as much space as they can.
20
Solids can melt and become liquids, and liquids can boil to become gases. Likewise, gases
can condense to become liquids, and liquids can freeze to become solids. Sometimes solids
can even become gases without ever becoming liquids. This is called subliming. But what
makes solids melt, and what makes gases condense?
25
The simple answer is heat. Heat is a form of energy. Heat is the energy of moving molecules.
Let's think about an ice cube. An ice cube is a solid, that is, its molecules aren't moving relative
to each other. They may be shaking and vibrating, but they stay put. If we heat the ice cube, its
molecules start moving around more. If we heat the ice cube enough, the molecules will start
moving around relative to each other, and when this happens, the solid ice melts and becomes
liquid water. If we keep heating the liquid water, eventually the water molecules will be moving
so fast that the liquid water becomes a gaswater vapor.
30
All this can happen backwards, too. If the water vapor gets cold enough, it will condense back
into liquid water, and if we keep cooling the water, it will freeze to become ice again.
35
30
I.
II.
III.
USOS DE LA -ING Diga de cul uso se trata. Traduzca la frase que las contiene?
a. holding (l. 8)
b. moving (l. 13)
c. filling (l. 21)
d. becoming (l. 24)
IV.
REFERENCIA (A qu remiten?)
a. their (l. 5)
b. them (l. 6)
c. it (l.8)
d. they (l. 28)
V.
CONECTORES (de qu tipo se trata? Traduzca las seguencias lgicas que completan su sentido )
VI.
a.
if (l. 11)
b.
c.
so (l.21)
d.
e.
if (l.30)
VII.
If we keep heating the liquid water, eventually the water molecules will be moving so fast that the liquid
water becomes a gas - water vapor.
31
32
PERIODIC TABLE
The integer that you find in each box of the Periodic Chart is the atomic number. The atomic number is the number of
protons in the nucleus of each atom. Another number that you can often find in the box with the symbol of the
element is not an integer. It is oversimplifying only a little to say that this number is the number of protons plus the
average number of neutrons in that element. The number is called the atomic weight or atomic mass.