Ejemplo 4.3 Smith & Vann Ness
Ejemplo 4.3 Smith & Vann Ness
Ejemplo 4.3 Smith & Vann Ness
To =
A=
B=
C=
D=
R=
DeltaH =
Iteracin
1
2
3
4
5
6
B
C
D
T0 1 T0 2 2 1
2
3
T0 2
533.15 K
3.578
0.00302
0
-18600
8.314 J /mol K
37218 J /mol
T/K
1250
1250.24095
1250.19854
1250.206
1250.20469
1250.20492
tau
2.34455594
2.34500787
2.34492833
2.34494233
2.34493987
2.3449403
H
T0
CP H
MCPH
B
T0 1
2
(B/2)*To*(t+1)
2.6925565
2.692920331
2.692856294
2.692867564
2.692865581
2.69286593
T0 2
-0.02790959
-0.02790422
-0.02790516
-0.027905
-0.02790502
-0.02790502
MCPH
6.24264691
6.24301612
6.24295113
6.24296257
6.24296056
6.24296091
CP
R
H
T0
CP H
Cp
B
C
D 1
dT AT0 1 T0 2 2 1 T03 3 1
T0 R
2
3
T0
ICPH
MCPH
CP
T/K
1250.24095
1250.19854
1250.206
1250.20469
1250.20492
1250.20488
H R
T0
Cp
dT
R
T
tau
ATo*(t-1)
(B/2)*To^2*(t^2-1)
1249.88555 2.34434127 2564.47979
1929.727087
celda variable
Restriccin :
T0 2 2 1
C 3 3
D 1
T0 1
3
T0
(D/To)*(t-1)/t
-20.00562983
T > To = 533
To =
A=
B=
C=
D=
R=
DeltaH =
ICPH
4476.54559
delta H
37218
533.15 K
3.578
0.00302
0
-18600
8.314 J /mol K
37218 J /mol
Diferencia
-5.1731E-07
celda objetivo