Phosphorus oxoacid
In chemistry, phosphorus oxoacid (or phosphorus acid) is a generic name for any acid whose molecule consists of atoms of phosphorus, oxygen, and hydrogen.[1] There is a potentially infinite number of such compounds. Some of them are unstable and have not been isolated, but the derived anions and organic groups are present in stable salts and esters. The most important ones—in biology, geology, industry, and chemical research—are the phosphoric acids, whose esters and salts are the phosphates.
In general, any hydrogen atom bonded to an oxygen atom is acidic, meaning that the –OH group can lose a proton H+
leaving a negatively charged –O−
group and thus turning the acid into a phosphorus oxoanion. Each additional proton lost has an associated acid dissociation constant Ka1, Ka2 Ka3, ..., often expressed by its cologarithm (pKa1, pKa2, pKa3, ...). Hydrogen atoms bonded directly to phosphorus are generally not acidic.
Classification
[edit]The phosphorus oxoacids can be classified by the oxidation state(s) of the phosphorus atom(s), which may vary from +1 to +5. The oxygen atoms are usually in oxidation state -2, but may be in state -1 if the molecule includes peroxide groups.
Oxidation state +1
[edit]
- Hypophosphorous acid (or phosphinic acid), H
3PO
2 (or H
2PO(OH)), a monoprotic acid (meaning that only one of the hydrogen atoms is acidic). Its salts and esters are called hypophosphites or phosphinates.
Oxidation state +3
[edit]
- Phosphorous acid (or phosphonic acid), H
3PO
3 (or HPO(OH)
2), a diprotic acid (with only two acidic hydrogens). Its salts and esters are called phosphites or phosphonates.
Oxidation state +4
[edit]
- Hypophosphoric acid, H
4P
2O
6 (or (HO)
2P–P(OH)
2). All four hydrogens are acidic. Its salts and esters are hypophosphates.
Oxidation state +5
[edit]The most important members of this group are the phosphoric acids, where each phosphorus atom bonded to four oxygen atoms, one of them through a double bond, arranged as the corners of a tetrahedron. Two or more of these PO
4 tetrahedra may be connected by shared single-bonded oxygens, forming linear or branched chains, cycles, or more complex structures. The single-bonded oxygen atoms that are not shared are completed with acidic hydrogen atoms. Their generic formula is Hn−x+2PnO3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure.
These acids, and their esters and salts ("phosphates") include some of the best-known and most important compounds of phosphorus.
3PO
4.
The simplest member of this class is:
- Phosphoric acid proper (also called orthophosphoric acid or monophosphoric acid), H
3PO
4 (or OP(OH)
3), a triprotic acid. It forms orthophosphate salt and esters, commonly called phosphates.
The smallest compounds of this class with two or more phosphorus atoms are called "oligophosphoric acids", and the larger ones, with linear –P–O– backbones, are "polyphosphoric acids"; with no definite separation between the two. Some of the most important members are:
- Pyrophosphoric acid, H
4P
2O
7 (or (HO)
2P–O–P(OH)
2), with four acid hydrogens. Forms pyrophosphates. - Triphosphoric acid (or tripolyphosphoric acid), H
5P
3O
10 (or (HO)
2P–O–P(OH)–O–P(OH)
2), with five acidic hydrogens. Forms triphosphates or tripolyphosphates. - Tetraphosphoric acid, H
6P
4O
13 (or (HO)
2P(–O–P(OH))2–O–P(OH)
2), with six acidic hydrogens. Forms tetraphosphates.
The backbone may be branched, as in:
- Triphosphono phosphoric acid, H
6P
4O
13 or P(O)(–OP(O)(OH)
2)3, a branched isomer of tetrapolyphosphoric acid.
The PO
4 tetrahedra may be connected to form closed –P–O– chains, as in:
- Trimetaphosphoric acid (or cyclotriphosphoric acid), H
3P
3O
9 (or (HPO
3)
3, (–P(O)(OH)–O–)3), a cyclic molecule with three acidic hydrogens. Forms the trimetaphosphate salts and esters.
Metaphosphoric acid is a general term for phosphoric acids with a single cycle, (–P(O)(OH)–O–)n, whose elemental formula is HPO
3.
-
-
-
Tetrapolyphosphoric acid
H6P4O13 -
Trimetaphosphoric acid
H
3P
3O
9
Another compound that may be included in this class is
- Peroxomonophosphoric acid, H3PO5 (or OP(OH)2(OOH)), which can be seen as monophosphoric acid with a peroxide group replacing the oxygen atom in one of the hydroxyl groups
Mixed oxidation states
[edit]Some phosphorus oxoacids have two or more P atoms in different oxidation states. One example is
- Isohypophosphoric acid, H
4P
2O
6 (or H(OH)(O)P−O−P(O)(OH)2), a tetraprotic acid and isomer of hypophosphoric acid, containing P in oxidation state +3 and +5
P4O10
See also
[edit]References
[edit]- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
Further reading
[edit]- Schröder HC, Kurz L, Muller WE, Lorenz B (Mar 2000). "Polyphosphate in bone" (PDF). Biochemistry (Moscow). 65 (3): 296–303. PMID 10739471. Archived from the original (PDF) on 2011-08-25.
External links
[edit]- Determination of Polyphosphates Using Ion Chromatography with Suppressed Conductivity Detection, Application Note 71 by Dionex
- US 3044851, Young, Donald C., "Production of ammonium phosphates and product thereof", published 1962-07-17, assigned to Collier Carbon & Chemical Co.
- Phosphorus+Acids at the U.S. National Library of Medicine Medical Subject Headings (MeSH)
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