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Atacamite

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Atacamite
Atacamite prisms from Chile
General
CategoryHalide mineral
Formula
(repeating unit)
Cu2Cl(OH)3
Strunz classification03.DA.10a
Crystal systemOrthorhombic
Space groupOrthorhombic dipyramidal
H-M symbol: (2/m 2/m 2/m)
Space group: Pmcn
Unit cella = 6.03 Å, b = 9.12 Å, c = 6.865 Å; Z = 4
Identification
ColorBright green, dark emerald-green to blackish green
Crystal habitSlender prismatic crystals, fibrous, granular to compact, massive
TwinningContact and penetration with complex twinned groupings
CleavagePerfect on {010}, fair on {101}
FractureConchoidal
TenacityBrittle
Mohs scale hardness3 - 3.5
LusterAdamantine to vitreous
StreakApple green
DiaphaneityTransparent to translucent
Specific gravity3.745 – 3.776
Optical propertiesBiaxial (-)
Refractive indexnα = 1.831 nβ = 1.861 nγ = 1.880
Birefringenceδ = 0.049
PleochroismX = pale green; Y = yellow-green; Z = grass-green
2V angleCalculated: 74°
Dispersionr < v, strong
References[1][2][3]

Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3.

It was first described for deposits in the Atacama Desert of Chile in 1801.[1]

Atacamite is polymorphous with botallackite, clinoatacamite, and paratacamite.[1] Atacamite is a comparatively rare mineral, formed from primary copper minerals in the oxidation or weathering zone of arid climates. It has also been reported from fumarole deposits, as sulfide alteration products in black smokers and as alteration of ancient bronze and copper artefacts.[2] It occurs in association with cuprite, brochantite, linarite, caledonite, malachite, chrysocolla and its polymorphs.[2]

Atacamite from Mt. Gunson, South Australia
File:Atacamit, Madagaskar.jpg
Atacamite from Madagascar

References