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We might expect the peaks to occur where the sine function
reaches the value 1.
Grating Spectrographs Diffraction gratings are widely used to measure the spectrum of light emitted by a source, a process called spectroscopy or spectrometry. Light incident on a grating of known spacing is dispersed into a spectrum. The angles of deviation of the maxima are then measured, and Eq.
is used to compute the wavelength. With a grating that has many
slits, very sharp maxima are produced, and the angle of deviation (and hence the wavelength) can be measured very precisely. schematic diagram of a diffraction-grating spectrograph for use in astronomy. Note that the light does not strike the grating normal to its surface, so the intensity maxima are given by a somewhat different expression. In the case of electromagnetic waves, the wave induces an oscillating electric dipole moment in each scatterer. These dipoles act like little antennas, emitting scattered waves. The resulting interference pattern is the superposition of all these scattered waves. The situation is different from that with a diffraction grating, in which the waves from all the slits are emitted in phase (for a plane wave at normal incidence). Here the scattered waves are not all in phase because their distances from the source are different. To compute the interference pattern, we have to consider the total path differences for the scattered waves, including the distances from source to scatterer and from scatterer to observer. (1) Strong reflection (constructive interference) occurs at angles such that the incident and scattered angles are equal and Eq. (1) is satisfied. Since sin can never be greater than 1, Eq. (1) says that to have constructive interference the quantity m must be less than 2d and so must be less than 2d/m. For example, the value of d in an NaCl crystal is only 0.282 nm. Hence to have the mth-order, maximum present in the diffraction pattern, must be less than 2(0.282 nm) /m; that is, 0.564 nm for m = 1, 0.282 nm for m= 2, 0.188 nm for m = 3, and so on. These are all x-ray wavelengths, which is why x rays are used for studying crystal structure.