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    Redox Reactions - Transfer of Electrons Between Species

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    Rovinda Hadi
    1. I2 akan bereaksi dengan Nal menghasilkan Na+ dan I- karena I2 lebih kuat oksidator daripada Nal. Reaksinya adalah: I2 + 2e- → 2I- 2. E°Mg = -2.37 V, E°Ag = 0.80 V Reaksi: Mg → Mg2+ + 2e-, Ag+ + e- → Ag Emf = E°katoda - E°anoda = 0.80 - (-2.37) = 3.17 V 3. E°Cd = -0.40 V, E°Cr =

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    Redox Reactions - Transfer of Electrons Between Species

    Uploaded by

    Rovinda Hadi
    89 views9 pages
    1. I2 akan bereaksi dengan Nal menghasilkan Na+ dan I- karena I2 lebih kuat oksidator daripada Nal. Reaksinya adalah: I2 + 2e- → 2I- 2. E°Mg = -2.37 V, E°Ag = 0.80 V Reaksi: Mg → Mg2+ + 2e-, Ag+ + e- → Ag Emf = E°katoda - E°anoda = 0.80 - (-2.37) = 3.17 V 3. E°Cd = -0.40 V, E°Cr =

    Original Title

    Redox reaction

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    1. I2 akan bereaksi dengan Nal menghasilkan Na+ dan I- karena I2 lebih kuat oksidator daripada Nal. Reaksinya adalah: I2 + 2e- → 2I- 2. E°Mg = -2.37 V, E°Ag = 0.80 V Reaksi: Mg → Mg2+ + 2e-, Ag+ + e- → Ag Emf = E°katoda - E°anoda = 0.80 - (-2.37) = 3.17 V 3. E°Cd = -0.40 V, E°Cr =

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    89 views9 pages

    Redox Reactions - Transfer of Electrons Between Species

    Uploaded by

    Rovinda Hadi
    1. I2 akan bereaksi dengan Nal menghasilkan Na+ dan I- karena I2 lebih kuat oksidator daripada Nal. Reaksinya adalah: I2 + 2e- → 2I- 2. E°Mg = -2.37 V, E°Ag = 0.80 V Reaksi: Mg → Mg2+ + 2e-, Ag+ + e- → Ag Emf = E°katoda - E°anoda = 0.80 - (-2.37) = 3.17 V 3. E°Cd = -0.40 V, E°Cr =

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 9

    Redox reactions - transfer of electrons between species.

    All the redox reactions have two parts:

    Oxidation Reduction
    Balancing Redox
    Equations
    Fe2+ + MnO4- + H+ Mn2+ + Fe3+ + H2O
    1. Assign oxidation numbers to each atom.
    2. Determine the elements that get oxidized and reduced.
    3. Split the equation into half-reactions.
    4. Balance all atoms in each half-reaction, except H and O.
    5. Balance O atoms using H2O.
    6. Balance H atoms using H+.
    7. Balance charge using electrons.
    8. Sum together the two half-reactions, so that: e- lost = e- gained
    9. If the solution is basic, add a number of OH- ions to each side of
    the equation equal to the number of H+ ions shown in the
    overall equation. Note that H+ + OH-  H2O
    Example

    Fe2+ + MnO4- + H+ Mn2+ + Fe3+ + H2O

    MnO4- Mn2+ Reduction half reaction


    (+7) (+2)

    Fe2+ Fe3+ Oxidation half reaction

    MnO4- + 8H+ + 5e Mn2+ + 4H2O

    5Fe2+ 5Fe3+ +5e

    5Fe2+ + MnO4- + 8H+ Mn2+ + 5Fe3+ + 4H2O


    Latihan 11
    Setarakan persamaan redoks berikut dengan
    metode ion-elektron:
    1. H2O2 + Fe2+  Fe3+ + H2O (larutan asam)
    2. Cu + HNO3  Cu2+ + NO + H2O (larutan asam)
    3. CN- + MnO4-  CNO- + MnO2 (larutan basa)
    4. Br2  BrO3- + Br- (larutan basa)
    5. S2O32- + I2  I- + S4O62- (larutan asam)
    6. Mn2+ + H2O2  MnO2 + H2O(larutan basa)
    7. Bi(OH)3 + SnO22-  SnO32- + Bi (larutan basa)
    8. Cr2O72- + C2O42-  Cr3+ + CO2 (larutan asam)
    9. ClO3- + Cl-  Cl2 + ClO2 (larutan asam)
    Hydrogen Electrode
    • consists of a platinum
    electrode covered
    with a fine powder of
    platinum around
    which H2(g) is
    bubbled. Its potential
    is defined as zero
    volts.
    Hydrogen Half-Cell
    H2(g) = 2 H+(aq) + 2 e-
    reversible reaction
    Galvanic Cell
    -
    What is the standard emf of an electrochemical cell made
    of a Cd electrode in a 1.0 M Cd(NO3)2 solution and a Cr
    electrode in a 1.0 M Cr(NO3)3 solution?

    Cd is the stronger
    Cd2+ (aq) + 2e- Cd (s) E0 = -0.40 V
    oxidizer
    Cr3+ (aq) + 3e- Cr (s) E0 = -0.74 V Cd will oxidize Cr
    Anode (oxidation): Cr (s) Cr3+ (1 M) + 3e- x 2
    Cathode (reduction): 2e- + Cd2+ (1 M) Cd (s) x3
    2Cr (s) + 3Cd2+ (1 M) 3Cd (s) + 2Cr3+ (1 M)

    Ecell
    0
    = E0cathode - Eanode
    0

    Ecell
    0
    = -0.40 – (-0.74)
    Ecell
    0
    = 0.34 V
    19.3
    Latihan 12
    1. Pada keadaan standar ditambahkan I2 ke dalam
    larutan Nal dan NaCl. Ramalkan reaksi yg terjadi.
    2. Sel Volta terdiri atas elektroda Mg dalam larutan 1 M
    Mg(NO3)2 dan elektroda Ag dalam larutan 1 M
    AgNO3. Hitung emf standar selnya jika suhu 250C.
    3. Hitung emf standar suatu sel elektrokimia yg terdiri
    atas elektroda Cd dalam larutan 1 M Cd(NO3)2 dan
    elektroda Cr dalam larutan 1 M Cr(NO3)3

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