4.2 (4.1) Periodic Table & Periodic Trends

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THE PERIODIC TABLE &

PERIODIC TRENDS.

Specific objectives:

4.1. Explain the basis of the


arrangement of elements in
the Periodic Table;
Page 28
The Periodic Table
I II III IV V VI VII 0
Groups

Transition elements
The Periodic Table

1
2
3
Period

4
5
6
7

■ The elements are arranged in order of increasing proton


(atomic) number.
■ There are 7 horizontal rows called “Periods”.
Trends in the Periodic Table
Some of the properties of elements which can be
compared are:
- Atomic radius – A measure of the size of an
atom
- Ease of Ionization – a measure of the ability of
an atom to lose electrons to form positive ions.
- Electronegativity – a measure of the ease of an
atom to gain electrons to form negative ions.
- Other physical properties, e.g. melting point,
boiling point and electrical conductivity.
- Reactivity.
For each of these properties, there can be group
trends and period trends.
Trends in the Periodic Table
Some of the properties of elements which can be
compared are:
- Atomic radius – A measure of the size of an atom
- Ease of Ionization – a measure of the ability of
an atom to lose electrons to form positive ions.
-Ionization Energy- a measure of the amount of energy
that is required to remove one electron
- Electronegativity – a measure of the ease of an
atom to gain electrons to form negative ions.
- Other physical properties, e.g. melting point,
boiling point and electrical conductivity.
- Reactivity.
For each of these properties, there can be group trends
GROUPS
The Periodic Table contains 8 groups numbered I-
VIII. Group VIII is sometimes called Group 0. Some
general trends include:
■All the elements have the same number of electrons
in the outermost shell. This number is the same as
the group number. All the elements in a group must
therefore lose or gain the same number of electrons
to form a stable electronic configuration. Therefore
they tend to have the same common oxidation number
and valency.
■Elements in a group show similar chemical
properties.
GROUPS

■ ATOMIC RADIUS increases down a group.


Down the group each element has one more
electron shell than the previous element. The
inner electron shells “shield” the outer shells
from the full charge of the nucleus. The atomic
radii therefore increase as shells move further
away from the nucleus than they should.
GROUPS

■ The EASE OF IONIZATION increases down the


group since outer electrons are further from the
nucleus and are therefore more weakly held. This
also means that there is an increase in metallic
character down a group.
■ ELECTRONEGATIVITY decreases down the
group. As the nucleus becomes increasingly
shielded by inner electron shells, the power of the
nucleus to draw electrons to itself lessens.
These points can be further illustrated by
examining Group II and VII.
ELECTRONEGATIVITY DECREASES
TRENDS IN
GROUPS

METALLIC CHARACTER
INCREASES
EASE OF IONIZATION INCREASES
ATOMIC RADIUS INCREASES

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