Rule 1090 Hazardous Materials

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REPORT AND CHILL

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ARJONA BARQUERO BUENDIA


REPORTFLIX HOME TV SHOWS MOVIES MY LIST

RULE 1090.
Hazards are anything in the workplace that can be potential
sources of harm to the health and safety of an employee this
can include any activity or substance that increases the
chance for employee, contractor or general public injury or
property damage.

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RULE 1090
HAZARDOUS MATERIALS

1:47:02
Definitions
• “Hazardous materials or substances” mean substances in solid, liquid or
gaseous forms known to constitute poison, fire, explosion or health hazard.
• “Corrosive” when referred to the action on inanimate surface such as metal,
glass or wood means that a substance will cause the wearing away, or the
gradual changing or destroying of the texture or substance of such materials.
• “Hot” means that a material or substance possesses or is characterized by a
relatively high temperature.
• “Gases” means normally aeroform fluid, which have neither shape nor specific
volume but tend to expand indefinitely and which can be changed to the liquid
or solid state by the effect of increased pressure or decreased temperature.
Definitions
• “Fumes” means suspended solid particles, which are generated by
condensation from gaseous state, generally after volatilisations from
molten metals.
• “Vapor” means gaseous form of substances which are normally in the
liquid or solid state, and which can be changed to these states either
by increasing the pressure or decreasing the temperature.
• “Mists” means suspended liquid droplets generated by condensation
from the gaseous to the liquid state or by breaking up of a liquid into a
dispersed state, such as by atomizing, foaming or splashing.
Definitions
• “Fibers” means any tough solid substance composed of thread-like tissue,
whether of mineral, vegetable or animal origin.
• “Dust” means solid particles capable of being blown about or suspended
in the air generated by handling, crushing, cutting, drilling, grinding, rapid
impact, spraying, detonations, or disintegration of inorganic or organic
materials and are of a composition similar to the substance or substances
from which derived.
• “Toxic” means acting or likely to act as a poison, or may chemically
produce injurious or deadly effect.
• ”Irritating” means causing undue sensitiveness of an organ or part of the
body.
1093:

GENERAL RULES
Reduction of Hazards
• When practicable, harmless substances
shall be substituted for hazardous
substances or the process shall be
revised to reduce worker exposure to the
hazards.
Control of Processes
1. Hazardous processes shall be carried on in separate rooms or building with a
minimum number workers equipped with suitable protective equipment
and trained thoroughly in safety prac- tices for daily operations and for
emergencies.
2. The process or operation shall be carried out in an air-tight enclosure to
prevent personal contact with the harmful substances and the escape of
dusts, fibers, fumes, gases, mists, or vapors into the air or room in which
persons work.
3. Where airtight enclosures or apparatus cannot be used, harmful dusts,
fibers, fumes, gases, mists, or vapors shall be removed at or near their point
or origin by means of fume chambers or suction hoods properly connected
to efficient exhaust system, and
4. Control by general ventilation to provide a continual inflow of fresh air to
keep the concentration of contaminants within safe limits.
Use of Personal Protective Equipment
1. Workers shall be provided with, and shall use
personal protective clothing and equipment in
accordance with the requirements of Rule
1080.
2. Personal protective equipment shall also be
used to supplement control methods when
such measures cannot adequately eliminate
the hazard or when other measures are not
possible.
Marking of Containers
(1) Specific Labelling Requirements:
a. symbol of the relevant category of hazard of the substance contained;
categories of hazards shall be explosive, flammable, oxidizing, toxic,
corrosive and radioactive
b. trade name may be used in addition to the chemical name of the
substance;
c. a description of the principal risk or risks;
d. a statement of the necessary precautions to be taken; and
e. if necessary, a statement of the first-aid or other simple measures to be
taken in case of injury or emergency
Marking of Containers
(2) Other Aspects of Labelling
a. Shape of labels - warning labels shall be in rectangular shapes;
b. size of symbols - the height of the danger symbol shall be in
relation to the size of the package or container upon which the
label will be placed.
c. text on the labels shall be adequate in sizes to be clear and
legible, and
d. in black on a white background.
Marking of Containers
(3) Marking of Labels: All required markings shall be either
lithographed or press-printed or engraved upon a paper
label securely attached or applied to the outside surface of
the container. Receptacles of over 18.92 liters (5 gallons)
capacity may be marked with letters stencilled, stamped, or
uniformly printed not less than 2.54 cm. (1 in.) in height.
Marking shall not be defaced or obliterated by rain or other
weather elements.
Marking of Containers
(4) Responsibility for Labelling:
a. The primary responsibility for the correct labelling of pack of packages and containers of hazardous
substances manufactured locally shall fall upon the manufacturers. For hazardous substances imported
from foreign countries for purposes of distribution and retail to local users, responsibility for correct
labelling of containers shall be the importer, distributor or retailer.
b. When hazardous substances in a factory undergo a series of distribution or repacking processes over
which the manufacturer has no contact, responsibility for labelling shall fall upon the distributors,
wholesalers or retailers.
c. The employer shall be responsible for labelling hazardous substances for use in his workplace other than
those supplied by manufacturers or distributors;
d. In case of transfer of hazardous substances from original containers to other containers, the employer
shall be responsible for the proper labelling and identification of such substances; and
e. Unlabelled hazardous substances received by the employer shall be properly labelled and identified by
him.
Marking of Containers

(5) Samples of Labels:


Marking of Containers
(6) Condensing of Labels: Where small containers present a problem in
labelling for lack of adequate space, the following shall be applied:
a. retain the symbol and the name of the product;
b. retain the statement of hazards;
c. consider omission of precautionary measures if they are clearly
indicated in the symbol and in the statement of hazards; and
d. include precautionary measures for any additional hazards, which
may be present because of the characteristic of the container, the
nature of its use, and the train- ing and experience of the user.
Testing of Atmosphere
The atmosphere of workrooms shall be tested
periodically at such intervals as may be necessary but
not longer than annually, to ensure that the
concentration of irritating or toxic dusts, fibers,
fumes, gases, mists or vapors are kept within the
threshold limit values specified in Rule 1070.

Ventilation and Exhaust Equipment


Ventilation and exhaust equipment shall be inspected
and tested periodically for safe and efficient
operational performance.
Prevention of Dust Accumulation
(1) All parts of structure or equipment in which harmful dust is liberated shall
be designed and installed so that the surfaces on which dust can accumulate
are reduced to a minimum and shall be frequently cleaned.
(2) In rooms where materials producing flammable dusts are processed,
handled and stored;
a. dusts shall be removed daily from floors, equipment and other
horizontal surfaces, preferably by means of appropriate vacuum
apparatus; and
b. all fixtures, ledges, projections, bearings, sidewalks, ceilings and other
parts shall be cleaned and freed of dusts at least once a week.
(3) Floors: Where practicable, floors or rooms in which harmful dust is liberated
shall:
a. be smooth, impervious and easy to clean; and
b. not be covered with loose sheets, metal or other materials under which
dust can accumulate.
Cleaning
 Where toxic and irritating substances are being handled,
manufactured or used, the floors, walls, structural surfaces,
work benches, tables and equipment shall be thoroughly
cleaned daily by means of vacuum cleaning, wet brushing
or sweeping, outside of working hours.
Precautionary Measures for Emergencies
(1) Warning Devices: In all workplaces where hazardous substances
are manufactured, handled or used, suitable warning device
shall be installed wherever possible, to alert the personnel in
case of the liberation of dangerous quantities of said substances.
(2) Training of Personnel: Workers shall be trained on procedures to
control the liberation of hazardous substances, eliminate
pollution, and to evacuate from the affected area in an orderly
manner.
Working Clothing
All personnel exposed to irritating or toxic substances
shall be provided with appropriate protective clothing
including head covering, which shall:
(1) be removed before eating or leaving the premises
and kept in places provided for the purpose;
(2) not be taken out of the factory by the users for any
purpose; and
(3) be maintained in good condition and washed or
cleaned at least once a week.
Spillage – Spillage of irritating or toxic substances shall be
removed as quickly as possible by the best technical and
scientific means possible. and available.
Instruction on Health Hazards – All workers shall be
thoroughly informed of the health hazards connected with
their work and the measures to be taken to protect
themselves there from.
Meals – The introduction, preparation and consumption of
food, drink and tobacco in the workroom shall be
prohibited.
Personal Cleanliness – All workers exposed to toxic
substances which enter the body through ingestion, shall be
required to wash their faces and hands thoroughly before
eating, drinking, smoking or before leaving the premises.
Time for Use of Washrooms
A time allowance for the use of the washroom before the meal period and for
the use of the shower bath at the end of the days’ work shall be allotted to
each worker employed in the manufacture or handling of the following:
(1) irritating or toxic dry mineral or organic substances such as arsenic,
chrome, lead, manganese, mercury, phosphorus, zinc and their
compounds;
(2) Superphosphates and their compounds;
(3) Dust-producing toxic dyestuffs and pigments;
(4) Dust-producing and coal-tar products such as pitch and soot; and
(5) Radioactive substances.
Medical Aid
All workers exposed to irritating or toxic
substances shall be required to report promptly
any physical complaints.

Exposure Records
The employer shall maintain accurate record of
employee exposure to potentially toxic materials
which are required to be measured or monitored.
This record shall be open to authorized agents
and the workers exposed to such hazards.
1094:

HOT AND CORROSIVE SUBSTANCES


Protection of Structure & Equipment
• In all workplaces where corrosive gases,
fumes, mists or vapors are generated
and liberated, adequate measures shall
be taken to prevent damage to structural
parts and factory equipment by
corrosion.
Handling
(1) Corrosive or hot liquids should be handled in bulk by gravity system or
pressure pump system, extending to the point or points of use so as to
eliminate transporting in small container.
(2) Emptying receptacles containing corrosives or hot liquids not provided with
drain cock shall be by pumps, tipping appliances or other suitable apparatus.
(3) Where portable receptacles are used for corrosive liquids, transport inside
factories shall be effected without the escape of fumes or mists and
preferably by mechanical means.
(4) Receptacles shall be kept securely closed except during extraction of the
contents.
Spillage of Acids and Alkalies
(1) Floors in rooms where corrosive liquids are
manufactured, handled or used shall be kept as dry
as possible.
(2) Spillage should be avoided. Spilled corrosive liquid
shall be guarded until removed to prevent workers
from stepping or getting into contact with it.
(3) Spilled or escaping corrosive acid shall not be
absorbed by sawdust, waste cloth or other organic
materials but shall be flushed out with water or
neutralized with chalk or lime.
Diluting Acids
When diluting acid with water, the acid shall be poured slowly
into the water, with constant stirring of the mixture. Water shall
never be poured into acid.

Physical Contact With Corrosive Substances


(1) Workers exposed to physical contact with corrosive or hot liquids
or to caustic compounds of calcium, potassium, sodium or their
dusts, shall be provided with and shall use protective clothing
and equipment conforming to the requirements of Rule 1080.
(2) In workrooms where corrosive liquids are manufactured,
handled or used, clean running water, and quick operating eye
fountains and shower baths shall be installed and maintained in
or adjacent to such workrooms readily accessible to all workers.
1095:

STORAGE
Vats and Tanks
(1) Vats, pans, and open tanks containing hot corrosive or toxic liquids shall, when the opening or
top is less than 1 m (3.3 ft) above the floor or working level, be either:
a. raised so the top will not be less than 1 m(3.3 ft.) from the floor or working level, or
b. guarded on all sides by enclosures or by standard railings and when the top is less than
15 cm. (6 in.) above the floor shall be provided with standard toe- boards.
The provisions of a. and b. shall apply to every vat, pan or tank irrespective of the nature of the
liquid it may contain.
(2) Where vats, pans or open tanks containing hot, corrosive or toxic liquids adjoin, the space
shall be fenced.
(3) Vats, pans, or open tanks containing hot, corrosive or toxic liquids shall be provided with pipes
or drains of sufficient capacity to carry off the contents without spilling or their backing up on the
floor.
Vats and Tanks
(4) Above-ground tanks containing hot, corrosive or poisonous liquids shall be:
a. surrounded by pits, catch basins or depressions of sufficient size to hold the entire
contents in case of rupture; and
b. provided with overflow pipes leading to tanks or to safe places outside the
building.
(5) Walkways shall not cross over open vats, pans or tanks containing hot, corrosive or
toxic liquids. Where it is necessary to install service walkways for access to agitator drives
or valves or for taking samples, such walkways shall be:
c. not less than 50 cm (20 in.) in width;
d. provided on both sides with standard railings and toeboards; and
e. kept clean and dry at all times.
Storage Tanks for Non-Flammable Hazardous Liquids

(1) Tanks used for storage of non-flammable hazardous liquids shall be:
a. located above ground or floor level;
b. supported so that leakage from any part of the tank will be noticeable;
c. surrounded with pits, catch basins or depressions of sufficient size to hold the
entire contents of the largest tank in the event of rupture;
d. covered with protective paint to prevent corrosion from moisture or fumes; and
e. provided with stairways or permanent ladders and platforms, where necessary,
for convenient and safe access to all parts of the tank and with floors or
platforms preferably of metal grating.
(2) Tanks used for storing non-flammable hazardous liquids shall not be placed above
passageways.
Storage Tanks for Non-Flammable Hazardous Liquids

(3) Tanks used for storing non-flammable hazardous liquids stored in pits below ground level:
a. the pits shall be of concrete or masonry with sufficient space between the walls and
the tanks to permit the passage of any person at any point; and
b. the tanks shall be mounted 38 to 45 cm. (15 to 18 in.) above the bottom of the pit.
(4) Pits containing sunken tanks used for storing non-flammable hazardous liquids shall be
provided with covers and fixed ladders for safe access.
(5) All control-valves for sunken tanks used for storing non-flammable hazardous liquids shall
be:
c. situated or of such design that they can be turned without any person entering the
pit; and
d. provided with locking devices operated from the outlets of the pit
Storage Tanks for Non-Flammable Hazardous Liquids

(6) Workers entering storage tanks and pits containing hazardous liquids shall
be provided with personal protective clothing and equipment conforming to
the requirements of Rule 1080.
(7) Tanks used for storing corrosive or caustic liquids shall be provided with:
a. a permanent open wet pipe not less than 5 cm. (2 in.) in diameter at
the highest point in the tank; and
b. a drain connection at the lowest point in the tank discharging into a
safe place.
(8) Tanks used for storing corrosive or caustic liquids shall have the filling
connections at the top and the discharge pipes 15 cm. (6 in.) above the
bottom.
Carboys for Acids
(1) Carboys containing acids shall be encased singly in baskets or in boxes cushioned with noncombustible
packing material.
(2) Carboys containing acids shall be stored in separate store rooms or buildings with concrete floors having
anti-acid protection or with brick floors properly drained to catch basins, dry and protected from dampness,
extreme heat or sudden change in temperature.
(3) Carboys containing acids shall not be piled one on top of another but should be placed in suitable storage
racks or on wooden strips laid on the floor.
(4) Special handling equipment such as two-wheeled carboy trucks shall be provided for transporting carboys
containing acids to and from storage.
(5) Adequate equipment shall be provided and used for the emptying of carboys.
(6) Empty acid carboys shall be stored apart from filled carboys.
(7) Empty carboys shall be thoroughly washed out by turning them upside down over and upward with stream
of water and drained before they are stored.
(8) Carboys together with their baskets or boxes shall be examined as to their condition before they are filled
with acid.
1096:

USE OF LEAD AND ITS COMPOUNDS


Definitions
 “Lead Compounds” means any organic or inorganic
derivatives of lead.

Control Measures
(1) A substitute substance or agent less injurious or
harmful shall be used instead of lead such as zinc
oxide or titanium oxide instead of white lead in paint
manufacture.
(2) Processes involving the use of lead and its
compounds shall be enclosed and mechanical
handling methods should be used or employed.
Storage and Handling
 Stocks of lead materials shall be kept in special storage rooms
outside the workrooms. Workrooms in which lead materials
are handled shall be located in relation to other parts of the
shop of factory in as small an area as possible to confine the
lead and to concentrate control measures in that area.

Local Exhaust System


 Properly designed exhaust systems, capable of carrying or
drawing of air contaminants to maintain or control the
threshold limit value of lead in the atmosphere, shall be
provided for all processes which generate lead, fumes or
dusts. The contaminants removed shall not be allowed to re-
enter the workrooms or to pollute other parts of the
workplace or the surrounding areas.
Personal Protective Equipment
Appropriate protective equipment and clothing
such as overalls, head covering, goggles, gloves,
aprons and respirators shall be issued free of
charge to lead workers by the employer who
shall see to their proper use and maintenance.
Smoking or Eating
Smoking, chewing, eating and the keeping of
food in workrooms where lead or its
compounds are used and handled shall not be
allowed.
Storage Lockers
Suitable storage lockers for street and work-clothes shall be
issued to each worker exposed to lead and its compounds.
Adequate washing facilities shall be provided.

Physical Examination
Workers exposed to lead shall be subjected to periodic
physical examination and laboratory examination at
intervals of not more than six (6) months and where the
degree of contamination rises above the threshold limit
value, such physical examination shall be conducted at least
once every three (3) months and a record of such
examinations shall be open to authorized agents and to the
exposed workers.
Reporters: Justine Arjona, Mitzi Joy Buendia, Dwight Kelly Barquero

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