Tugas Atk 1: Oleh: Kelompok 6 Anton Algrinov 1507114913 Yogie Aldi 1507113030 Zamri Fadilah 1507123635

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Anton Algrinov Yogie Aldi Zamri Fadilah TUGAS ATK 1

1507114913 1507113030 1507123635 Oleh:


KELOMPOK 6
SOAL NO 3.17

Methyl iodide can be produced by reacting hydriodic acid with anexcess of met
hanol via the reaction :
HI + CH3OH CH2I + H2O
A typical process for large – scale production of methyl iodide is indicated in fig
ure P. 3.17 the process conditions are :
1. The feed to the reactor contains 2 mol CH3OH per 1 mol HI
2. 50% conversion of HI is obtained in the reactor
3. 90% of the H2O entering the first separator leaves in stream 5
4. All compositions are on a molar basis
How many moles of CH3I are produced per mole of fresh HI feed?
FLO
W D
IAGR
AM
D
O
F
SEPARATOR SEPARATOR
DOF OVERALL MIXER REACTOR
1 2
SPLITTER PROCESS

Stream
Variable
8+1 5 7+1 8 7 6 21
Independent
Balance 2 2 4 3 3 2 13
Composition 2 1 1 - 2 - 3
Subsidiary 2 - 1 - 1 - 2
Flow - - - - - - -
SR 1 - - - - 1 1
Conversion 1 - 1 - - - 1
Reactor
Neraca Massa Total (basis N2 = 100) • H2O
N2 + N3 + r = N4 N2*X2H2O + N3*X3H2O + r1 = N4*X4H2O
100 + N3 + r = N4
100*0,05 + 0 + r = N4*X4H2O
5 + 47,5 = N4*X4H2O
Neraca Massa Komponen X = r/input
0,5 = r/95 N4*X4H2O = 52,5
• HI • CH3OH
N2*X2HI + N3*X3HI + r1 = N4*X4HI r = 47,5
Karena mol CH3OH adalah 2 x mol HI,
100*0,95 – r1 = N4*X4HI maka

95 – r1 = N4*X4HI 2*N2*X2HI = N3*X3CH3OH

N4*X4HI = 47,5 2*100*0,95 = N3*1


N3 = 190
Maka, didapat: N2 + N3 + r= N4
100 + 190 + 47,5 = N4
N4 = 337,5
N2*X2CH3OH + N3*X3CH3OH = N4*X4CH3OH Neraca Massa Komponen:
0 + 190*1 = 337,5*X4CH3OH X4HI = 0,140

X4CH3OH = 0,563 X4H2O = 0,155


• CH3I X4CH3OH = 0,563
N2*X2CH3I + N3*X3CH3I + r = N4*X4CH3I X4CH3I = 0,140
0 +0 + r = N4*X4CH3I

47,5 = 337,5*X4CH3I

X4CH3I = 0,140
Mixer
Neraca Massa Total : Pada separator 1, H2O melewati aliran 5 sebanyak 90% dan 10% melewati
aliran 8, maka mol HI pada N8 adalah
N1 + N10 = N2
N4*X4HI = N8*X8HI
N1 + N10 = 100
47,5 = N8*X8HI
 
N8*XHI = 47,5 mol
• HI

N1*X1HI + N10*X10HI = N2*X2HI Kemudian 10% H2O pada aliran 4 masuk ke aliran 8, maka didapat:

N4*X4H2O = 52,5 10% dari H2O aliran 4 =


N1*1 + N10*X10HI = 100*0,95
1,81%
N1 + N10*X10HI = 95
sehingga sisanya HI = 98,19%
 
N8*X8H2O = 10% * N4*X4H2O = 52,5 / 10 = 5,25 mol

Mol Total (N10) = 47,5 + 5,25 = 52,75 mol


N1 + N10 = N2 Separator 2
N1 + 52,75 = 100 Neraca Massa Total : N5 = N6 + N7
N1 = 47,25 N5 = N6 + N7 284,75 = N6 + 57,92
284,75 = N6 + N7 N6 = 226,82
Separator 1
Neraca Massa Total : • CH3I
N4 = N5 + N8 N5*X5CH3I = N6*X6CH3I + N7*X7CH3I
337,5 = N5 + 52,75 284,75*0,166 = N7*0,82
N5 = 284,75 N7 = 57,92
Moles of CH3I are produced per mole of fresh HI
feed

• Mol CH3I N7
N7*X7CH3I = 47,5 mol

• Fresh HI N1
N1*X1HI = 47,25 mol

Sehingga total produksi CH3I adalah 1,005 mol


=Terimakasih=

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