Tugas Atk 1: Oleh: Kelompok 6 Anton Algrinov 1507114913 Yogie Aldi 1507113030 Zamri Fadilah 1507123635
Tugas Atk 1: Oleh: Kelompok 6 Anton Algrinov 1507114913 Yogie Aldi 1507113030 Zamri Fadilah 1507123635
Tugas Atk 1: Oleh: Kelompok 6 Anton Algrinov 1507114913 Yogie Aldi 1507113030 Zamri Fadilah 1507123635
Methyl iodide can be produced by reacting hydriodic acid with anexcess of met
hanol via the reaction :
HI + CH3OH CH2I + H2O
A typical process for large – scale production of methyl iodide is indicated in fig
ure P. 3.17 the process conditions are :
1. The feed to the reactor contains 2 mol CH3OH per 1 mol HI
2. 50% conversion of HI is obtained in the reactor
3. 90% of the H2O entering the first separator leaves in stream 5
4. All compositions are on a molar basis
How many moles of CH3I are produced per mole of fresh HI feed?
FLO
W D
IAGR
AM
D
O
F
SEPARATOR SEPARATOR
DOF OVERALL MIXER REACTOR
1 2
SPLITTER PROCESS
Stream
Variable
8+1 5 7+1 8 7 6 21
Independent
Balance 2 2 4 3 3 2 13
Composition 2 1 1 - 2 - 3
Subsidiary 2 - 1 - 1 - 2
Flow - - - - - - -
SR 1 - - - - 1 1
Conversion 1 - 1 - - - 1
Reactor
Neraca Massa Total (basis N2 = 100) • H2O
N2 + N3 + r = N4 N2*X2H2O + N3*X3H2O + r1 = N4*X4H2O
100 + N3 + r = N4
100*0,05 + 0 + r = N4*X4H2O
5 + 47,5 = N4*X4H2O
Neraca Massa Komponen X = r/input
0,5 = r/95 N4*X4H2O = 52,5
• HI • CH3OH
N2*X2HI + N3*X3HI + r1 = N4*X4HI r = 47,5
Karena mol CH3OH adalah 2 x mol HI,
100*0,95 – r1 = N4*X4HI maka
47,5 = 337,5*X4CH3I
X4CH3I = 0,140
Mixer
Neraca Massa Total : Pada separator 1, H2O melewati aliran 5 sebanyak 90% dan 10% melewati
aliran 8, maka mol HI pada N8 adalah
N1 + N10 = N2
N4*X4HI = N8*X8HI
N1 + N10 = 100
47,5 = N8*X8HI
N8*XHI = 47,5 mol
• HI
N1*X1HI + N10*X10HI = N2*X2HI Kemudian 10% H2O pada aliran 4 masuk ke aliran 8, maka didapat:
• Mol CH3I N7
N7*X7CH3I = 47,5 mol
• Fresh HI N1
N1*X1HI = 47,25 mol