Scribd Logo
Upload

Welcome to Scribd!

  • 40 views

    11 - Reaksi Polimerisasi

    Uploaded by

    Jhonson
    This document compares and contrasts step-growth polymerization and chain-growth polymerization. It also describes different types of polymerization reactions including bulk, solution, suspension, and emulsion polymerization. The key steps in radical chain polymerization including initiation, propagation, termination, and chain transfer are outlined. Anionic and condensation polymerization processes are also summarized.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd

    11 - Reaksi Polimerisasi

    Uploaded by

    Jhonson
    40 views17 pages
    This document compares and contrasts step-growth polymerization and chain-growth polymerization. It also describes different types of polymerization reactions including bulk, solution, suspension, and emulsion polymerization. The key steps in radical chain polymerization including initiation, propagation, termination, and chain transfer are outlined. Anionic and condensation polymerization processes are also summarized.

    Original Title

    11_REAKSI POLIMERISASI

    Copyright

    © © All Rights Reserved

    Available Formats

    PPTX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document compares and contrasts step-growth polymerization and chain-growth polymerization. It also describes different types of polymerization reactions including bulk, solution, suspension, and emulsion polymerization. The key steps in radical chain polymerization including initiation, propagation, termination, and chain transfer are outlined. Anionic and condensation polymerization processes are also summarized.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    40 views17 pages

    11 - Reaksi Polimerisasi

    Uploaded by

    Jhonson
    This document compares and contrasts step-growth polymerization and chain-growth polymerization. It also describes different types of polymerization reactions including bulk, solution, suspension, and emulsion polymerization. The key steps in radical chain polymerization including initiation, propagation, termination, and chain transfer are outlined. Anionic and condensation polymerization processes are also summarized.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 17

    REACTION OF POLYMER

    REACTION OF POLYMER

    Addition Polymerization
    (Chain Growth)

    Step Growth Polymerization


    (Condensation)
    D I F F E R E N CE S B E T W E E N
    S T E P - G R O W T H P O LY M E R IZ AT I O N A N D
    C H AI N - G R O W T H P OLY M ER I Z AT I O N

    Step-growth polymerization Chain-growth polymerization


    Growth throughout matrix Growth by addition of monomer only at one end of
    chain
    Rapid loss of monomer early in the reaction Some monomer remains even at long reaction times

    Same mechanism throughout Different mechanisms operate at different stages of


    reaction (i.e. Initiation, propagation and
    termination)
    Average molecular weight increases slowly at low Molar mass of backbone chain increases rapidly at
    conversion and high extents of reaction are required early stage and remains approximately the same
    to obtain high chain length throughout the polymerization
    Ends remain active (no termination) Chains not active after termination
    No initiator necessary Initiator required
    STEP OF RADICAL CHAIN POLYMERIZATION

    Propagatio Terminatio
    Initiation
    n n
    INITIATION

    Dissosiation

    Assosiation
    PROPAGATION
    TERMINATION
    CHAIN TRANSFER REACTION
    IONIC CHAIN POLYMERIZATION

    Using catalyst, not initiator


    Highest reaction rate
    Termination step is just disproportionation
    Environment must be pure
    Reaction occurs in the cold
    Anionic Polymerization=Living Polymerization

    If the starting reagents are pure and the polimerization reactor is purged of all
    oxygen and traces of water, polimerization can proceed until all monomer is
    consumed.
    CONDENSATION POLYMERIZATION

    Inisiator required
    Minumum two functional groups required
    Usually linear
    Molecular weight increases slowly at low conversion
    High extents of reaction are required to obtain high
    chain length
    BULK POLYMERIZATION

    • The simplest technique

    • It gives the highest-purity polymer

    Ingredients : monomer, monomer-soluble initiator, perhaps a chain transfer agent

    Advantages Disadvantages
    High yield per reactor volume Difficult of removing the lost traces of monomer

    Easy polymer recovery Dissipating heat produced during the


    polimerization

    Final product form


    SOLUTION POLYMERIZATION

    • Heat can be removed by conducting the polymerization in an organic solvent or water

    • Initiator or monomer must be soluble in solvent

    • Solvents have acceptable chain-transfer characteristics

    • Solvents have suitable melting or boiling points for the conditions of polymerization

    Advantages Disadvantages Ingredients :


    Temperature control is easy Small yield per reactor volume
    monomer , initiator, solvent
    Easy removed Solvent recovery
    SUSPENTION POLYMERIZATION

    • Coalescense of sticky droplets is prevented by PVA

    • Near the end of polymerization, the particles harder and they can be removed by

    filtration, then washing  Ingredients :


    water-insoluble monomer,
    Advantages (according to bulk
    Disadvantages water-insoluble initiator,
    polymerization)
    sometimes chain transfer agent
    Forming process not using Polymer purity is low
    suspention medium (water usually)
    Stirring is easy Reactor capital costs are higher
    than for solution polymerization

    Separation process is easy


    EMULSION POLYMERIZATION

    • Particles are formed monosize with emulsion polymerization

    • Polymerization is initiated when the water-soluble radical enters a monomer-containing


    micelles.

     Ingredients : water-insoluble monomer,


    water-soluble initiator,
    chain transfer agent,
    dispersing medium (water),
    fatty acid,
    surfactant such as sodium salt of a long chain

    You might also like