Carboxylic Acid: Ruiz Sumagaysay Toledo Vergara

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CARBOXYLIC

ACID
Ruiz
Sumagaysay
Toledo
Vergara
CARBOXYLIC ACID
• are used in the production of polymers, pharmaceuticals,
solvents, and food additives.
• in addition to its use as a disinfectant, formic acid, the
simplest carboxylic acid, is employed in textile treatment
and as an acid reducing agent.
• Acetic acid is extensively used in the production of
cellulose plastics and esters.
• any of a class of organic compounds in which a carbon (C)
atom is bonded to an oxygen (O) atom by a double bond
and to a hydroxyl group (―OH) by a single bond.
CARBOXYLIC ACID
• GENERAL STRUCTURE:

• The carboxyl (COOH) group is so-named because of the carbonyl group


(C=O) and hydroxyl group.
• For example, in addition to its use as a disinfectant, formic acid, the
simplest carboxylic acid, is employed in textile treatment and as an acid
reducing agent.
• Acetic acid - production of cellulose plastics and esters.
• Aspirin, the ester of salicylic acid, is prepared from acetic acid.
• Palmitic acid and stearic acid - manufacture of soaps, cosmetics,
pharmaceuticals, candles, and protective coatings.
• Stearic acid also is used in rubber manufacture.
• Acrylic acid is employed as an ester in the production of polymers (long-
chain molecules) known as acrylates.
• Methacrylic acid serves as an ester and is polymerized to form Lucite.
• Oleic acid - manufacture of soaps and detergents and of textiles.
PROPERTIES OF CARBOXYLIC
ACID

ACIDITY SOLUBILITY

BOILING POINT ODOUR


PROPERTIES OF CARBOXYLIC
ACID

ACIDITY SOLUBILITY

BOILING POINT ODOUR


PROPERTIES OF CARBOXYLIC
ACID

ACIDITY SOLUBILITY

BOILING POINT ODOUR


PROPERTIES OF CARBOXYLIC
ACID

ACIDITY SOLUBILITY

BOILING POINT ODOUR


STRUCTURE COMMO IUPAC NAME STRUCTURE COMMON IUPAC
N NAME NAME NAME

Carbonic Carbonic Valeric Pentanoic


Acid acid Acid acid

Formic Methanoic Caproic Hexanoic


Acid acid Acid acid

Acetic Enanthic Heptanoic


Ethanoic acid
Acid Acid acid

Propionic Propanoic Caprylic Octanoic


-
Acid acid Acid acid

Butyric Butanoic Pelargonic


Acid acid - Acid Nonanoic
acid
NOMENCLATURE
• The IUPAC name of a carboxylic acid is derived
from the longest carbon chain that contains the
carboxyl group by dropping the final -e from the
name of the parent alkane and adding the suffix
-oic followed by the word “acid.”
• The chain is numbered beginning with the carbon
of the carboxyl group
• For example, the compound CH3CH2COOH has
three carbon atoms and is called propanoic acid,
STEPS IN NAMING
CARBOXYLIC ACID
1st Count the longest carbon chain that
contains the carboxylic acid and use the
base name

2nd Change the ending of the parent name


from 'e' to ‘oic acid'.

3rd Count the carbons so that the


carboxylic acid group gets the lowest
possible number.
4th Number additional substituent groups,
groups attached to the main carbon chain,
according to the carbon they branch from.
List all substituents in alphabetical order
as prefixes prior to the carboxylic acid
name.

More Complicated Acids


For molecules with two carboxylic acid groups the carbon chain in
between the two carboxyl groups (including the carboxyl carbons) is used
as the longest chain; the suffix -dioic acid is used. • For molecules with
more than two carboxylic acid groups, the carboxyl groups are named as
carboxylic acid substituents.
EXAMPLE 1
EXAMPLE 1
EXAMPLE 1
EXAMPLE 2
• 4-METHOXYBUTANOIC ACID
• 6-AMINOHEXANOIC ACID
EXAMPLE 3
BOARD WORK
BOARD WORK
• 3. 2-ethylcyclohexanecarboxylic acid
– 2-methylpropanoic acid
QUIZ
QUIZ
QUIZ
QUIZ
QUIZ
QUIZ
• 4. 3-OXOPENTANOIC ACID
• 5. 4-hydroxy-2butenoic acid

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