Maillard Reaction Functional Foods

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Lecture 11

Maillard
Reaction
Functional foods
1912

Maillard Maillard
published a paper
describing the

reaction reaction between


amino acids and
sugars at elevated

discover temperatures.

ed 1953

recently
Chemist John E.
Hodge, with the U.S.
Department of
Agriculture,
established a
mechanism for the
Maillard reaction
The Maillard
Reaction
• Reaction between carbohydrates and proteins
under heating

• Reducing sugars and amino acids (proteins)


produce glycosides which are red-brown to very
dark brown colours and caramel-like aromas

• Results in browning during the:


- grilling of meats
- formation of crusts on breads
- boiling of maple syrup
- roasting of coffee and cocoa beans
- roasting of nuts
Classic
example of
Maillard
reaction
Examples of
Maillard Reaction
Maillard
browning
process

First step is a condensation


reaction between an amino
group on an amino acid or
protein and a reducing sugar
(glucose or lactose)
Why do milk
products brown
so quickly?

Milk based products


contain high levels of
lysine which has two
amino groups to react
with the lactose – milk
sugar
Maillard
Reaction
The Maillard reaction
produces hundreds
of products – some
contribute to flavour
and aroma
https://www.youtube.com/watch?v=meUEXukFM-o
Caramelisatio
n
• Occurs when sugars are heated over their
melting points
• Sucrose melts at  160ºC
• Continuation of heating pulls water out of the
sugar molecule (condensation) to form furfural
derivatives which undergo further reactions
(polymerisation) to form brown coloured
compounds
Chemistry of
caramelisatio Pyrolitic
Caramelans (C24 H36 O18)
n Brown colour
(caramelisation) is
produced by three Caramelens (C36 H50 O25)
Basically the groups of polymers:

browning of sugar Volatile chemicals Caramelins (C125 H188


such as diacetyl are
during cooking 80)
O

released = caramel
flavour
Typically
cooking Maillard reaction
involves both starts at 140 to 165°C
Maillard and
caramelisatio Caramelisation from
n around 160°C
reactions
Enzymatic
browning
Occurs in fruits and vegetables -
enzyme polyphenoloxidase
When cut or damage occurs the
enzyme in conjunction with oxygen
causes brown pigmentation
Prevention of
enzymatic browning

• Use of additives - ascorbates and


citric acid
• Chilling
• Heating
• Modified atmosphere
Function
al foods
A food claimed to

Function have an additional


function other than

al food for refuelling the body

definitio
n Normally related to
health-promotion or
disease prevention
Good
Good
working
working
IFT
definitio
definitio
definition
nn
Good
working
definition

“Foods or dietary components that may provide a health benefit


beyond basic nutrition”
The International Food Information Council (IFIC)
Removing a compound/component – lactose free

Replacing an element of the food – alternative

Functionali sweeteners

ty Concentrating – Increasing protein


achieved
by Adding – fortifying with vitamins and minerals

Increasing the bioavailability of a food component


Conventional foods – Prebiotic foods

Enriched foods – folate enriched breads

Functional Fortified foods – iodised salt


food
categories Enhanced foods – formulated with bioactive compounds
probiotic, energy and protein

Medical foods – Phenylketonuria (PKU) formulas free


of phenylalanine

Special dietary use - Infant formulae, weight lose foods ,


gluten free, lactose free
Good examples of fortification
B1 and B3 enriched flour for pellagra and beriberi

Iodine in salt for goitre

Vitamin D enriched milk for rickets

Vitamin C for scurvy

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