Scribd Logo
Upload

Welcome to Scribd!

  • 43 views

    Zagreb-Solid State Tamnija

    Uploaded by

    Jelena Zdravkovic
    This document analyzes the thermal degradation kinetics of a copper(II) complex, [Cu2(bipy)2(pht)2]·4H2O. Thermogravimetric analysis showed two main degradation steps: dehydration from 30-100°C and degradation from 100-420°C. Kinetic parameters like activation energy and frequency factor were calculated using non-isothermal methods at various heating rates. The second and third degradation steps were deconvoluted and each step's kinetic triplet of activation energy, frequency factor, and reaction model were determined.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd

    Zagreb-Solid State Tamnija

    Uploaded by

    Jelena Zdravkovic
    43 views1 page
    This document analyzes the thermal degradation kinetics of a copper(II) complex, [Cu2(bipy)2(pht)2]·4H2O. Thermogravimetric analysis showed two main degradation steps: dehydration from 30-100°C and degradation from 100-420°C. Kinetic parameters like activation energy and frequency factor were calculated using non-isothermal methods at various heating rates. The second and third degradation steps were deconvoluted and each step's kinetic triplet of activation energy, frequency factor, and reaction model were determined.

    Original Description:

    Conference presentation

    Copyright

    © © All Rights Reserved

    Available Formats

    PPTX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document analyzes the thermal degradation kinetics of a copper(II) complex, [Cu2(bipy)2(pht)2]·4H2O. Thermogravimetric analysis showed two main degradation steps: dehydration from 30-100°C and degradation from 100-420°C. Kinetic parameters like activation energy and frequency factor were calculated using non-isothermal methods at various heating rates. The second and third degradation steps were deconvoluted and each step's kinetic triplet of activation energy, frequency factor, and reaction model were determined.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    43 views1 page

    Zagreb-Solid State Tamnija

    Uploaded by

    Jelena Zdravkovic
    This document analyzes the thermal degradation kinetics of a copper(II) complex, [Cu2(bipy)2(pht)2]·4H2O. Thermogravimetric analysis showed two main degradation steps: dehydration from 30-100°C and degradation from 100-420°C. Kinetic parameters like activation energy and frequency factor were calculated using non-isothermal methods at various heating rates. The second and third degradation steps were deconvoluted and each step's kinetic triplet of activation energy, frequency factor, and reaction model were determined.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 1

    THERMAL DEGRADATION AND KINETICS OF 0D COPPER (II) COMPLEX

    J. D. Zdravković 1, D. D. Poleti 2, J. R. Rogan 2, P. J. Vulić 3, D. M. Minić 4


    1 Innovation Centre - Faculty of Technology and Metallurgy, University of Belgrade, Serbia
    2 Faculty of Technology and Metallurgy, University of Belgrade, Serbia
    3 Faculty of Mining and Geology, University of Belgrade, Serbia
    4 Faculty of Physical Chemistry, University of Belgrade, Serbia

    Table 1. Thermodynamic (for β = 15 °C min–1) and overall


    kinetic parameters (Ea and A) for [Cu2(bipy)2(pht)2]·4H2O .
    Thermolysis of coordination
    compounds as precursors can be used Process Dehydration Degradation
    for production of metals, metal oxides, Temperature range
    metal sulfides or other nanosized 30-100 100-420
    (oC)
    materials. Therefore we prepared
    dimeric [Cu2(bipy)2(pht)2]·4H2O (bipy = DSC peak minimum 218.7
    81.5
    2,2’-bipyridine, pht = dianion of (oC) 233.7
    phthalic acid), whose degradation Mass loss (%),
    process is practically finished up to 8.6 (8.6) 59.2 (57.4)
    (calc. (%) )
    280°C. The mechanism of all CO2 + C8H4O3 + 2 CO
    degradation steps has been analyzed Fragment loss 4H2O
    + C10H8N2 + C5H4N
    under non-isothermal conditions in
    H (kJmol-1) 133.3 52.4
    nitrogen atmosphere at following
    heating rates: 5, 10 and 15 ºC min–1. 151.5 ± 12.2; 151.6 ±
    Ea (kJ mol–1), 84.0 ± 8.0;
    The second and the third degradation 10.2
    (Kissinger; Ozawa) 85.3 ± 8.0
    steps are highly overlapped and were 101.7 ± 8.2; 104.4 ± 8.9
    deconvoluted (Fig. 3) using Fraser- ln A (min–1), 29.4 ± 10.3; 37.3 ± 17.5; 37.4 ± 13.3
    Suzuki function as recommended for (Kissinger; Ozawa) 29.4 ± 9.3 24.0 ± 11.1; 24.9 ± 9.0
    Fig. 1. TG-DTG curves for [Cu2(bipy)2(pht)2]·4H2O. this type of processes. 27.0
    ∆S# (J mol–1 K–1) -4.4
    -83.8

    Fig. 2. XRPD pattern of residue obtained at 330 °C. Fig. 3. Deconvolution using Fraiser-Suzuki function Fig. 4. Ea versus α for individual degradation
    at β = 10 °C min–1. steps using Ortega isoconversional method.

    Fig. 5. Màlek curves y(α) and z(α) for individual degradation steps.

    Table 2. The kinetic triplets of individual degradation steps.


    Individual
    Ea (kJ mol–1) ln A (min–1) f(α) = αm (1- α) n
    step
    Step 1 111.1 ± 4.6 26.4 ± 10.6 α0.52(1 - α)1.10
    Step 2 127.6 ± 11.2 31.3 ± 13.1 α0.58(1 - α)0.94
    Step 3 87.9 ± 6.8 20.2 ± 10.9 α0.42(1 - α)1.30

    You might also like