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    Light Scattering: Basics: R K T E E

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    Simo Sore
    Light scattering from polymer solutions can provide information about polymer properties and dynamics. The intensity of scattered light (Is) is related to fluctuations in the polarizability (α) of the solution components. For a dilute polymer solution, the excess scattered intensity (Iex) above the solvent is directly proportional to the mean-square fluctuation in concentration (δc). Thermodynamic expressions relate (δc)2 to compressibility and other thermodynamic derivatives. The form factor P(q) describes the spatial distribution of fluctuations and contains terms for the polymer radius of gyration Rg. The Zimm equation relates the scattering intensity to the scattering vector q, polymer molecular weight Mw, second

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    Light Scattering: Basics: R K T E E

    Uploaded by

    Simo Sore
    32 views18 pages
    Light scattering from polymer solutions can provide information about polymer properties and dynamics. The intensity of scattered light (Is) is related to fluctuations in the polarizability (α) of the solution components. For a dilute polymer solution, the excess scattered intensity (Iex) above the solvent is directly proportional to the mean-square fluctuation in concentration (δc). Thermodynamic expressions relate (δc)2 to compressibility and other thermodynamic derivatives. The form factor P(q) describes the spatial distribution of fluctuations and contains terms for the polymer radius of gyration Rg. The Zimm equation relates the scattering intensity to the scattering vector q, polymer molecular weight Mw, second

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    simonux

    Original Title

    Lesson 4 ChMP

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    Light scattering from polymer solutions can provide information about polymer properties and dynamics. The intensity of scattered light (Is) is related to fluctuations in the polarizability (α) of the solution components. For a dilute polymer solution, the excess scattered intensity (Iex) above the solvent is directly proportional to the mean-square fluctuation in concentration (δc). Thermodynamic expressions relate (δc)2 to compressibility and other thermodynamic derivatives. The form factor P(q) describes the spatial distribution of fluctuations and contains terms for the polymer radius of gyration Rg. The Zimm equation relates the scattering intensity to the scattering vector q, polymer molecular weight Mw, second

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    32 views18 pages

    Light Scattering: Basics: R K T E E

    Uploaded by

    Simo Sore
    Light scattering from polymer solutions can provide information about polymer properties and dynamics. The intensity of scattered light (Is) is related to fluctuations in the polarizability (α) of the solution components. For a dilute polymer solution, the excess scattered intensity (Iex) above the solvent is directly proportional to the mean-square fluctuation in concentration (δc). Thermodynamic expressions relate (δc)2 to compressibility and other thermodynamic derivatives. The form factor P(q) describes the spatial distribution of fluctuations and contains terms for the polymer radius of gyration Rg. The Zimm equation relates the scattering intensity to the scattering vector q, polymer molecular weight Mw, second

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 18

    Light Scattering: Basics

    E E0 cos(t k r )

    2c
    2
    0

    x
    E ( x, t ) E0 ( y, t ) cos(t kx) E0 ( y , t ) cos(2 t





    E ( x, t ) Re E0 cos(t k r ) Re E0 exp it exp ik r

    I E E E0 E0 e e e
    it it ikr ikr
    e

    E0 E0
    Light Scattering: Basics
    Refractive Index
    0
    n

    Lorentz-Lorenz

    Relates the material property, n (refractive index),


    to the molecular property, (polarizability).

    n n 2 2
    s
    4
    Light Scattering: Basics


    Ei E0 cos(t k r )


    ea
    Es 2 sin
    rc

    2
    a Ei
    e
    Light Scattering: Basics

    E E 2 2
    Is s s e a 1
    2 4 sin 2

    I 0 Ei Ei r c Ei Ei

    2
    2 4 Ei Ei sin 2

    e 2
    2 4
    e r c Ei Ei

    I s 16 4 2
    2 4 sin 2
    I0 r 0
    Light Scattering: Basics
    Is 16 4 2

    I 0 ,v r 2 40
    Is


    8 4 2 1 cos 2
    I 0 ,u r 2 40
    Scattering from a Dilute Polymer Solution

    2 2
    2 2
    2

    2 2 mean-square fluctuations
    in polarizability


    p T c
    p T ,c T p,c c T , p
    Scattering from a Dilute Polymer Solution

    I ex I ssolution I ssolvent excess scattered intensity

    I s 16 4 2

    I0 r 2 40

    I ex 16 4 1 16 4 1
    2 4 c 2
    2
    2 4
    I0 r 0 r 0 c T,p

    1 Number of cells for


    : Unit volumr
    n 2 ns2

    4
    n

    c T,p 2 c T,p

    P c dc
    2
    c
    c 2

    P c dc

    G
    P c A exp
    kT
    G 1 2G Expansion as Taylor
    G c 2
    (c ) ....
    c 2! c series

    kT
    c 2
    2G c 2 T,p

    2
    I ex 4 n n
    2 2
    kT

    I0 r 0 c
    2 4
    2G c 2 T,p
    kT kT ckT

    2G c 2 T,p
    V V 1c
    1

    VRT 1 M 2 Bc ...
    c

    c 1

    VN av 1 M 2 Bc ...

    2
    I ex 4 2 n 2 n c
    2 4
    I 0 r 0 N av c 1 M 2 Bc ...
    I ex r 2
    R Rayleigh ratio
    I0
    2
    4 2 n 2 n
    K 4
    0 N av c

    Kc
    R
    1
    2 Bc ....
    M
    The Form Factor and the Zimm Equation

    N N it N i j
    Es ,tot Es , j E0, s exp i (t i ) E0, s e e
    j 1 j 1 j 1

    2 N N

    e
    i k j
    I s E0 , s
    j 1 k 1
    The Form Factor and the Zimm Equation

    2 N N

    e
    i k j
    E0 , s N N
    1

    j 1 k 1 i k j
    P ( ) 2 e
    2 N N N
    E0 , s e i0

    j 1 k 1
    j 1 k 1


    k j q rjk

    q2 2
    P (q) 1 Rg ....
    3
    The Form Factor and the Zimm Equation

    Kc 1 1
    2 Bc
    R M P ( )

    Kc 1 q2 2
    1 Rg ..... 2 Bc ...
    R Mw 3
    c

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