Membrane Bioreactor

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The document discusses membrane bioreactors (MBR) for wastewater treatment, including basics of the technology, case studies of full-scale MBR plants, and promising areas of research. Key advantages of MBRs include high effluent quality, no sludge settling required, and reduced space requirements, while challenges include membrane fouling and higher operational costs.

Some of the main advantages of MBR technology for wastewater treatment are high effluent quality, no requirement for sludge settling, and reduced space/volume requirements. The main disadvantages are membrane fouling and increased operational costs due to more intensive treatment requirements.

Promising areas of research to reduce membrane fouling include modeling biofilm development and fouling mechanisms, examining the effects of additives on fouling, and deriving relationships between operating conditions and biomass characteristics to predict long-term fouling.

The Potential of Membrane Bioreactors for

Wastewater Treatment
S. Malamis1, A. Andreadakis1 & D. Mamais1
Laboratory of Sanitary Engineering
School of Civil Engineering
National Technical University of Athens
1

1st International Conference on Sustainable


Urban Wastewater Treatment and Reuse
Nicosia 15-16th September 2005

Presentation Aim & Layout

Aims
To assess the feasibility of Membrane
Bioreactors (MBR) in Greece
To examine state-of-the-art research in the
field of secondary treatment of municipal
wastewater using MBR technology

Layout

Basics on MBR for wastewater treatment


Examination of two full-scale MBR applications
Adoption of MBR technology in Greece
State-of-the-art research

Basics on MBR

Employ biological reactor and


membrane filtration as a unified
system for the secondary treatment
of wastewater
Membranes perform the separation
of the final effluent from the biomass
through filtration
Filtration takes place by the
application of a pressure gradient

Process Basics
DN

discharge

SCT

SS
conventional technology
membrane technology
effluent
SS
Deni

Nitri

UF not
Sec. Clarif.

Process Basics

sludge floc
water
dis. solids

bacteria
viruses

membrane

suction
kinet. energy

Submerged MBR System


Module
Feed

Permeate

Back pulse

Cleaning
chemicals

ZeeWee
d
aeration Aeration

effluent

BP Tank

Re-circulation

SS

Assessment of MBR Technology

Advantages
High effluent quality
No sludge settling problems
Reduced volume requirements

Disadvantages
Membrane fouling
Increased operational costs

Full-Scale WWTP in Germany (1)

P.E. = 80,000 Largest


MBR full-scale
installation in the world
4 parallel biological
reactors:
Anoxic zone
Swing zone
Aerobic zone with
immersed membranes

SRT = 25 days
MLSS = 10-15 g/l
192 cassettes (8 parallel
trains)
Total filtration area =
84,480m2

Full-Scale WWTP in Germany (2)

Parameter
SS (mg/l)

Final Effluent
Non detectable

COD (mg/l)

15-20

BOD5 (mg/l)

<3

NH4+-N (mg/l)

<1

TN (mg/l)
TP (mg/l)

5-10
0.7

Total Coliforms / 100 ml


Fecal Coliforms /2000 ml

<100
<500

Salmonella /1000 ml

Final Effluent disposed to a sensitive river

Full-Scale WWTP in Italy (1)

Consists of 3 parallel lines


Lines A & C: Conventional Lines
Line B: Upgraded from conventional to MBR system

Total P.E. = 380,000


Upgrading of Line B to MBR increased its capacity from 12,200 m 3/d to 42,000 m3/d within the same
space
MLSS = 6.5-10 g/l
SRT > 20 d

Full-Scale WWTP in Italy (2)


Parameter

MBR Effluent
mg/l (%)

Conventional
Effluent
mg/l (%)

SS (mg/l)

<2 (99)

25 (73.2)

BOD5 (mg/l)

4 (95.8)

19 (82.3)

COD (mg/l)

27 (88.5)

66 (77.2)

TN (mg/l)

9.2 (73.7)

15.9 (54.5)

TP (mg/l)

2.4 (36.1)

3.4 (8.6)

Conclusions from the examination


of full-scale installations (1)

Full-scale MBR provide a superior effluent quality


compared to conventional methods
The final effluent can meet the requirements of the
Urban Wastewater Directive 91/271/EEC even for
P.E. >100,000 with disposal to sensitive recipients
(TN <10 mg/l, TP < 1mg/l)
Final effluent conforms to the microbiological
requirements for bathing waters (Directive
76/160/EEC), without the need for further
disinfection with chlorine or ozone

Conclusions from the examination


of full-scale installations (1)

Enhance reuse options of secondary


effluent

However:
the stricter microbiological criteria for
agricultural reuse are not met and further
disinfection is required

Main barrier to their wider full-scale


adoption is the high operational cost and
the lack of economies of scale

Adoption of full-scale MBR in Greece

Currently there is no full-scale MBR system


It is an attractive solution for arid and semiarid regions and islands characterized by:

Water scarcity
Small/Medium P.E.
Coastal zones and seas of high aesthetic value
Limited land availability
Large seasonal changes in populations

State-of-the-art Research

MBR technology has resulted in


multidiscipline research, since it
brings together the topics of system
design and construction,
hydrodynamics, chemistry and
microbiology.
This work focuses on the topics of:
Membrane fouling
System microbiology

Membrane Fouling (1)

Biofouling is the dominant type of


membrane fouling in MBRs
Definition: the undesirable deposition
and accumulation of microorganisms,
EPS and cell debris
Main operating problem impeding the
widespread adoption of MBR to fullscale plants

Membrane Fouling (2)

Biofilm develops due to the following


mechanisms:
Adsorption of macromolecules
Adhesion of micro-molecules which are
easily attached from the liquid under
suspension to the membranes surface
Creation of colonies and growth of
micro-organisms on and within the
biofilm
Detachment mechanisms attributed
mainly to shear forces

Main Parameters Influencing Fouling (3)

Membrane parameters

Configuration
Material
Pore Size
Hydrophobicity

Operating Parameters
HRT/SRT
Aeration system
TMP and flux

Biomass
characteristics

EPS
SMP
MLSS

The degree of influence of


each biomass characteristic
varies depending on the
operating conditions and
particularly SRT
Research is often
contradictory
No universally adopted
relationships relating
fouling to its main
influencing parameters

Promising research areas related to


membrane fouling (4)
Modeling the development of biofilm (determining
thickness, concentration gradient of nutrients and
DO etc)
Derive relationships describing the degree of fouling
with respect to operating and biomass
characteristics
The ultimate goal is to model long-term fouling

Examination of the influence of certain


additives (alum, zeolite, activated carbon)
on fouling

System Microbiology (1)

Sludge Filterability

Impacts on filtration and fouling


Improved sludge filterability retards the
degree of fouling and thus prolongs the life of
the membrane

Biomass characteristics

MBR produce 20-50% less sludge than


conventional systems as they operate at higher
SRT
Floc size depends on the SRT value and on the
MBR configuration
Presence of small flocs, single cells and freeswimming bacteria
Filamentous micro-organisms are favored
(absence of FST, low F/M ratios)

System Microbiology (2)

Organic & nutrient removal


Examined extensively through pilotplants and bench-scale experiments
Innovative processes have been tested
(e.g. use of a single reactor for
simultaneous nitr-denitr by maintaining
the DO level at 1mg/l)

Promising research areas related to


microbiology (4)

Extensive analysis of the microbiology


and physiology of micro-organisms which
develop both in the liquid under
suspension and on the membrane
surface. Examination of the differences in
the microbial populations
Determine the influence of certain factors
(e.g. pH, organic loading, SRT) on
filterability

Conclusions

MBR technology is compatible with Greek


needs of wastewater treatment
Promising research themes:

Develop model that will predict long-term


fouling
Find cost effective additives which can reduce
fouling
Determine the operating factors which affect
filterability
Extensive microscopic analysis of the biomass

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