Chapter 3 First Law Thermodynamics
Chapter 3 First Law Thermodynamics
Chapter 3 First Law Thermodynamics
CHAPTER
MEC 451
Thermodynamics
Lecture Notes:
MOHD HAFIZ MOHD NOH
HAZRAN HUSAIN & MOHD SUHAIRIL
First Law of
Thermodynamics
For students EM 220 and EM 221 only
Heat
Closed
System
Work
z
Reference Plane, z = 0
or
E U KE PE
The first law of thermodynamics for closed systems then can be
written as
Qnet Wnet U KE PE
5
If the system does not move with a velocity and has no change in
elevation, the conservation of energy equation is reduced to
Qnet Wnet U
The first law of thermodynamics can be in the form of
qnet wnet
V2 V1
g ( z 2 z1 )
u 2 u1
2000
1000
V2 V1
g ( z 2 z1 )
Q net W net m u2 u1
2000
1000
V2 V1
g ( z 2 z1 )
Q net W net m u2 u1
2000
1000
2
2
V2 V1
g ( z 2 z1 )
Q net m u2 u1
2000
1000
(kJ / kg )
( kJ )
Q net W net
V2 V1
g ( z 2 z1 )
m u2 u1
2000
1000
V2 V1
g ( z 2 z1 )
Q net P (V2 V1 ) m u2 u1
2000
1000
Q net
V2 V1
g ( z 2 z1 )
m u2 u1 P(V2 V1 )
2000
1000
V2 V1
g ( z 2 z1 )
h2 h1
2000
1000
2
Q net m
Rigid tank
Piston cylinder
8
Example 3.1
A closed system of mass 2 kg
undergoes an adiabatic process.
The work done on the system is
30 kJ. The velocity of the system
changes from 3 m/s to 15 m/s.
During the process, the elevation
of the system increases 45 meters.
Determine the change in internal
energy of the system.
V2 2 V12 g ( z2 z1 )
Qnet W net m u2 u1
2000
1000
V2 2 V12 g ( z2 z1 )
Wnet m u2 u1
2000
1000
9.81 45
152 32
30 2u 2
2000
1000
u 14.451 kJ Ans..
Solution:
Energy balance,
Q net W net
V V1
g ( z 2 z1 )
m u2 u1 2
2000
1000
Example 3.2
Solution:
State1
at P1 1100 kPa, x1 0.92
v1 v f 1 x1v fg1
0.00113 0.92 0.17753 0.001133
0.1634 mkg
u1 u f 1 x1u fg1
780.09 0.92 1806.3
2441.9 kL
kg
s1 s f 1 x1 s fg1
2.1792 0.92 4.3744
6.204 kgkJ.K
10
State2
superheated
0.15122
2945.9
7.1292
0.1634
u2
s2
0.17568
3116.9
7.4337
0.1634 0.15122
3116.9 2945.9
0.17568 0.15122
u2 2945.9
3030.42 kJ
kg
0.1634 0.15122
7.4337 7.1292
0.17568
0.15122
s2 7.1292
7.2790 kgkJ. K
11
Q m u2 u1
s s2 s1
7.2790 6.204
1.075 kgkJ.K
12
Example 3.3
Solution:
State1
Comp. liquid 3
m
v1 v f @ 25oC 0.001003 kg
P1 200 kPa,
T1 25o C
initial volume of half resevoir
V1 mv
5 0.001003
; 0.005 m3
Vresevoir 2 0.005
0.01 m3
13
u1 u f @ 25oC 104.88 kJ
kg
State 2
v 0.001003 m
f
kg
T2 25 C
o
u2 u f x2 u fg
0.01
3
0.002 mkg
5
check region !
v2
vg 43.34 mkg
x2
v2 v f
v fg
2.3 105
5
u2 104.88
2304.9
104.83 2.3 10 (2304.3)
v f v vg saturated mixture
104.88 kJ
104.93
kg
Then :
The heat transfer for this process
Qnet Wnet m u ke Pe
Qnet Wnet m u ke Pe
Qnet mu m u2 u1
(104.88-104.83)
Qnet 5 104.93
104.88
0.25 kJ
Supplementary Problems 1
1.
2.
Supplementary Problems 1
3.
4.
5.
16
Boundary Works
P
2
3
4
1
V
18
According to a law of
P V n constant
No
Value of n
isochoric
isobaric
isothermal
constant temperature
(T1 = T2)
1<n<
polytropic
-none-
Process
isentropic
Description
Result of IGL
P1 P2
T1 T2
V1 V2
T1 T2
P1V1 P2V2
P1 V2
P2 V1
T1
T2
n
n 1
19
Boundary Work
isochoric
W12 P(V2 V1 ) 0
isobaric
W12 P(V2 V1 )
isothermal
polytropic
isentropic
W12 P1V1 ln
V2
V1
P2V2 P1V1
W12
1 n
20
Example 3.4
Sketch a P-V diagram showing the following processes in a cycle
Process 1-2:
21
Solution:
V3
W23 PV
ln
2 2
V2
P3
0.028
0.103
140 0.103 ln
18.78 kJ
22
23
Example 3.5
A fluid at 4.15 bar is expanded reversibly according to a law PV = constant to
a pressure of 1.15 bar until it has a specific volume of 0.12 m 3/kg. It is then
cooled reversibly at a constant pressure, then is cooled at constant volume
until the pressure is 0.62 bar; and is then allowed to compress reversibly
according to a law PVn = constant back to the initial conditions. The work
done in the constant pressure is 0.525 kJ, and the mass of fluid present is 0.22
kg. Calculate the value of n in the fourth process, the net work of the cycle and
sketch the cycle on a P-V diagram.
24
Solution:
0.00732 m3
V2
W12 PV
ln
1 1
V1
V1
415 0.00732 ln
0.0264
0.00732
3.895 kJ
25
Section 2 3 isobaric
W23 P V3 V2 0.525 kJ
0.525
0.0264
115
0.03097 m3
V3
Section 3 4 isochoric
W34 0
Section 4 1 PolytroPic
P4 V1
P1 V4
62 0.00732
415 0.03097
ln 0.1494 n ln 0.2364
n 1.3182
W41
PV
1 1 PV
4 4
1 n
415 0.0072 62 0.03097
1 1.3182
3.5124 kJ
26
Supplementary Problems 2
1.
A mass of 0.15 kg of air is initially exists at 2 MPa and 350 oC. The air
is first expanded isothermally to 500 kPa, then compressed
polytropically with a polytropic exponent of 1.2 to the initial state.
Determine the boundary work for each process and the net work of the
cycle.
2.
0.078 kg of a carbon monoxide initially exists at 130 kPa and 120 oC. The
gas is then expanded polytropically to a state of 100 kPa and 100 oC.
Sketch the P-V diagram for this process. Also determine the value of n
(index) and the boundary work done during this process.
[1.248,1.855 kJ]
27
3.
4.
28
29
Conservation of Mass
Conservation of mass is one of the most fundamental
principles in nature. We are all familiar with this
principle, and it is not difficult to understand it!
For closed system, the conservation of mass principle is
implicitly used since the mass of the system remain
constant during a process.
However, for control volume, mass can cross the
boundaries. So the amount of mass entering and leaving
the control volume must be considered.
30
m V .dA
If the fluid density and velocity are constant over the flow crosssectional area, the mass flow rate is
AV
m AV
1
where
m&in m&out
(kg/s)
32
As the fluid upstream pushes mass across the control volume, work
done on that unit of mass is
W flow
w flow
A
F dL F dL PdV Pv m
A
W flow
Pv
m
33
V2
V2
energy u P 2 gz h 2 gz
The first law for a control volume can be written as
.
Vout
Vin
34
V2 V1
g ( z 2 z1 )
h2 h1
2000
1000
qnet wnet
V2 V1
g ( z 2 z1 )
h2 h1
2000
1000
2
Q net W net m
Q net W net
V2 V1
g ( z 2 z1 )
m h2 h1
2000
1000
(kJ / kg )
( kJ )
(kW )
35
36
Q in W in min
in
.
.
.
Vin
Vout
hin
gzin Q out W out mout hout
gzout
2
2
out
Vin
min hin
2
V1
h1
mout hout
Vout
V2
h2
2
38
Example 3.6
State1
V12
V2 2
h1
h2
2
2
State1
P1 0.4 MPa h1 3067.1 kJ
kg
State 2
P1 0.4 MPa
P2 0.2 MPa
T1 300o C
x2 0.9
V1 ; 0
P2 0.2 MPa h2 h f x2 h fg
x2 0.9 h2 2486.1 kJ
kg
Exit velocity:
V2
1078 m / s
39
Example 3.7
State1
State 2
P1 80 kPa
V2 ; 0
T1 10o C
V1 200m / s
A1 0.4 m 2
Solution:
V
V
2
h1 h2
2
2
2
1
RT1
3
1.015 mkg
P1
40
1
m& V1 A1
v1
1
200 0.4
1.015
78.8 kgs
V12
h2 h1
2000
2002
284.42
2000
304.42 kJ
kg
T2
Enthalpy at state 1
h1 C pT1 1.005 283
284.42 kJ
kg
h2
Cp
304.42
1.005
302.9 K
41
Vin
Vout
Q in W in min hin
gzin Q out W out mout hout
gzout
2
2
in
out
W out m h1 h2
43
Q in W in min
in
.
.
.
Vin
Vout
hin
gzin Q out W out mout hout
gzout
2
2
out
W in m h2 h1
44
Example 3.8
The power output of an adiabatic steam turbine is 5 MW. Compare
the magnitudes of h, ke, and pe. Then determine the work done
per unit mass of the steam flowing through the turbine and calculate
the mass flow rate of the steam.
Data
45
Solution:
3248.4 kJ
T1 400o C h1 3247.6
kg
State 2
P2 15 kPa
sat. mixture
x2 0.9
h2 h f 2 x2 h fg 2
Vin 2
Qin W in min hin
gzin
2
in
.
.
.
Vout 2
Q out W out mout hout
gzout
2
out
h2 h1 -887.39
885.87 kJ
kg
V2 2 V12
KE
14.95 kJ
kg
2000
g z2 z1
PE
0.04 kJ
kg
1000
46
g z1 z2
V12 V2 2
Wout h1 h2
2000
1000
887.39 14.95 0.04
885.87
kJ
870.96
872.48 kg
W&out
5000
5.73 kgs
m&
5.74
Wout 870.96
872.48
47
Solution:
Example 3.9
Air at 100 kPa and 280 K is
compressed steadily to 600
kPa and 400 K. The mass
flow rate of the air is 0.02
kg/s, and a heat loss of 16
kJ/kg occurs during the
process.
Assuming
the
changes in kinetic and
potential
energies
are
negligible, determine the
necessary power input to the
compressor.
& out
m& h2 h1 mq
State1
air
P1 100 kPa
air
Thus
49
Throttling Valve
50
Example 3.10
State 1
P1 8000 kPa sup erheated
o
T1 300 C h1 2786.5 kJkg
State 2
P2 1600 kPa
h2 h1
P kPa
vf
1500
198.29
1600
T2
1750
205.72
vg
0.001154 0.131710
vf 2
vg 2
0.001166 0.113440
hf
hg
844.55
2791
hf 2
hg 2
878.16
2795.2
51
T2 Tsat 201.3o C
Getting the quality at state 2
x2
v2 v f 2 x2v fg 2
0.0011588
0.997 0.124402 0.0011588
0.1240
h2 h f 2
m3
kg
hg 2 h f 2
2786.5 857.994
2792.68 857.994
0.997
52
Mixing Chamber
53
Mixing Chamber
Energy Balance:
&1h1 m
&2 h2 m
&3h3
m
&1h1 m
&3 m
&1 h2 m
&3 h3
m
&1 h1 h2 m
&3 h3 h2
m
h3 h2
&1 m
&3
m
h
2
1
54
Heat Exchanger
Example 3.11
Solution:
Assume a sat.
vapor state to
obtain the max.
allowable exiting
enthalpy.
56
m&w
ms C p , s T1s T2 s
h2 w h1w
100 1.25 450 350
2794.2 88.61
4.62 kgs
57
Supplementary Problems 3
1.
Air flows through the supersonic nozzle . The inlet conditions are 7 kPa
and 420C. The nozzle exit diameter is adjusted such that the exiting
velocity is 700 m/s. Calculate ( a ) the exit temperature, ( b )the mass flux,
and ( c ) the exit diameter. Assume an adiabatic quasiequilibrium flow.
2.
3.
Steam enters a turbine at 4000 kPa and 500 oC and leaves as shown in Fig
A below. For an inlet velocity of 200 m/s, calculate the turbine power
output. ( a )Neglect any heat transfer and kinetic energy change ( b )Show
that the kinetic energy change is negligible.
58
Figure A
4.
Consider an ordinary shower where hot water at 60C is mixed with cold
water at 10C. If it is desired that a steady stream of warm water at 45C
be supplied, determine the ratio of the mass flow rates of the hot to cold
water. Assume the heat losses from the mixing chamber to be negligible
and the mixing to take place at a pressure of 150 kPa.
5.
59