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    Ignition of The Precipitate

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    asep wandi nugraha
    This document describes the thermo gravimetric analysis method for analyzing precipitates. It discusses the different types of water that can be present in precipitates and the importance of bringing the precipitate to a constant composition before weighing. The treatment involves either drying the precipitate until 200-250°C or igniting it up to 1200°C. It provides detailed steps for incinerating the filter paper and igniting the precipitate, including slowly burning off the carbon and heating to constant weight between weighings.

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    Ignition of The Precipitate

    Uploaded by

    asep wandi nugraha
    2K views12 pages
    This document describes the thermo gravimetric analysis method for analyzing precipitates. It discusses the different types of water that can be present in precipitates and the importance of bringing the precipitate to a constant composition before weighing. The treatment involves either drying the precipitate until 200-250°C or igniting it up to 1200°C. It provides detailed steps for incinerating the filter paper and igniting the precipitate, including slowly burning off the carbon and heating to constant weight between weighings.

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    kimia analitik Ignition of the Precipitate gravimetri kimia analisis pemijaran endapan

    Original Title

    Ignition of the Precipitate

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    This document describes the thermo gravimetric analysis method for analyzing precipitates. It discusses the different types of water that can be present in precipitates and the importance of bringing the precipitate to a constant composition before weighing. The treatment involves either drying the precipitate until 200-250°C or igniting it up to 1200°C. It provides detailed steps for incinerating the filter paper and igniting the precipitate, including slowly burning off the carbon and heating to constant weight between weighings.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF or read online from Scribd
    Download as ppt or pdf
    2K views12 pages

    Ignition of The Precipitate

    Uploaded by

    asep wandi nugraha
    This document describes the thermo gravimetric analysis method for analyzing precipitates. It discusses the different types of water that can be present in precipitates and the importance of bringing the precipitate to a constant composition before weighing. The treatment involves either drying the precipitate until 200-250°C or igniting it up to 1200°C. It provides detailed steps for incinerating the filter paper and igniting the precipitate, including slowly burning off the carbon and heating to constant weight between weighings.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF or read online from Scribd
    Download as ppt or pdf
    of 12

    IGNITION OF THE

    PRECIPITATE:

    THERMOGRAVIMETRIC
    METHOD OF ANALYSIS
    Water in precipitate :
    (a)adsorbed water, present on al1 solid surfaces in amount
    dependent on the humidity of the atmosphere;
    (b)occluded water, present in solid solution or in cavities
    within crystals;
    (c)sorbed water, associated with substances having a large
    interna1 surface development, e.g. hydrous oxides; and
    (d)essential water, present as water of hydration or
    crystallisation [e.g.CaC204,H20 or Mg(NH4)P04,6H20] or
    as water of constitution
    [the water is not present as such but is formed on
    heating, e.g.
    Ca(OH), +Ca0 + H20].
    Direction of ignition :

    •To bring the precipitate


    to a constant composition
    before it can be weighed.
    Treatment :
    • The treatment consists in drying or
    igniting the precipitate

    • The further treatment will depend both


    upon the nature of the precipitate and
    upon that of the filtering medium;

    • Drying : untill 200 -250 degree Celcius


    • Ignition : up to 1200 degree Celcius
    Remember…..

    • Precipitates that are to be dried should be


    collected on filter paper, or in sintered-
    glass or porcelain filtering crucibles.

    • Precipitates that are to be ignited are


    collected on filter paper, porcelain filtering
    crucibles, or silica filtering crucibles.
    Incineration of the filter
    paper

    • A silica crucible is first ignited to


    constant weight (i.e. to within 0.0002
    g) at the same temperature to which
    the precipitate is ultimately heated.
    • The well drained filter paper and
    precipitate are carefully detached from
    the funnel;
    • The filter paper is folded to enclose the
    precipitate completely
    • The packet is placed point-down in the
    weighed crucible, which is supported on a
    silica triangle resting on a ring stand.
    • The crucible is slightly inclined, and
    partially covered with the lid, which should
    rest partly on the triangle.
    • A very small flame is then placed under
    the crucible lid; drying thus proceeds
    quickly and without undue risk
    • When the moisture has been
    expelled, the flame is increased
    slightly so as to carbonize the paper
    slowly.
    • The paper should not be allowed to
    inflame, as this may cause a
    mechanical expulsion of fine particles
    of the precipitate owing to the rapid
    escape of the products of combustion
    • If the paper does catch fire, the flame
    should be extinguished by momentarily
    placing the cover on the mouth of the
    crucible with the aid of a pair of crucible
    tongs.
    • When the paper has completely
    carbonized and vapors are no longer
    evolved, the flame is moved to the back
    (bottom) of the crucible and the carbon
    slowly burned off while the flame is
    gradually increased.*
    • After all the carbon has been burned
    away, the crucible is covered
    completely (if desired, the crucible
    may be placed in a vertical position
    for this purpose) and heated to the
    required temperature by means of a
    Bunsen burner.
    • Usually it takes about 20 minutes to
    char the paper, and 30-60 minutes to
    complete the ignition
    After ignition …..
    • When the ignition is ended, the flame is
    removed and, after 1-2 minutes,
    thecrucible and lid are placed in a
    desiccator containing a suitable desiccant
    and allowed to cool for 25-30 minute
    • The crucible and lid are then weighed.
    • The crucible and contents are then ignited
    at the same temperature for 10-20
    minutes, allowed to cool in a desiccator as
    before, and weighed again.
    • The ignition is repeated until
    constant weight is attained. Crucibles
    should always be handled with clean
    crucible tongs and preferably with
    platinum-tipped tongs.
    • It is important to note that 'heating
    to constant weight' has no real
    significance unless the periods of
    heating, cooling of the covered
    crucible, and weighing are
    duplicated.

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