FL101
FL101
FL101
Unit
mg litre metre
Dimension
mass volume length
Conversion of Units
To convert a quantity inits terms of one unit to 2 to 2 Convert 23 Ib .ft/min equivalent in kg.cm/s m an equivalent in new units 1. Convert one unit to an equivalent new unit Multiply by a conversion factor (a ratio of 2. Multiplyquantities) by a conversion factor equivalent 4. Units & values raised 3.2808 ft to same power
1m 3. Old units cancel out
2
30.48 cm 1 ft
0.088 kg.cm s2
60 s
Conversion Factors
Mass Length Volume 1 kg = 1000g = 0.001 metric ton = 2.20462 Ibm =35.27392 oz 1 m = 100 cm = 1000 mm = 39.37 in = 3.2808 ft = 1.0936 yd = 0.0006214 mile 1 m3 = 1000 liters =106 cm3 = 35.3145 ft3 = 220.83 imperial gallons = 264.17 gal 1 N = 1 kg.m/s2 = 105 dynes = 105 g.cm/s2 = 0.22481 Ibf
Force
Pressure 1 atm = 1.01325 x 105 N/m2(Pa) = 101.325 kPa = 1.01325 bars = 760 mm Hg at 0oC = 14.696 Ibf/in2 (psi) Energy Power 1 J = 1 N.m = 2.778 x 10-7 kW.h = 0.23901 cal = 107 dyne.cm 1 W = 1 J/s = 0.23901 cal/s = 9.486 x 10-4 Btu/s = 0.7376 ft. Ibf/s = 1.341 x 10-3 hp
Group Assignments
Convert
(a) 1 cm/s2 to km/y2
(b)
(c)
(d)
120 hp to kJ/min
Systems of Units
SI (Systeme Internationale dUnites) cgs Engineering (American, English, fps)
Systems Base units SI Multiples Derived N,Pa,J,W kg,m,s,K,A powers of 10 - k,c,m
cgs
Eng.
g,cm
same as SI
dyne, erg
kg.m/s2 = Newton(N) g.cm/s2 = 1 dyne The force exerted on the object by Ibm .ft/s2 = 1 Ibf gravitational attraction,g
mg W= gc 2 2 2 lb .ft/s m kg.m/s g.cm/s gc = a constant = 1 =1 = 32.174 lbf N dyne g (at sea level & 45o latitude) = acceleration of gravity = 9.8066 m/s2 = 980.66 cm/s2 = 32.174 ft/s2
Group Assignments
Calculate the weight in
(a) Ibf of a 10 Ibm object
(b)
(c)
N of a 10 kg object
Ibf of a 4539 g object
(d)
Process
Any operation or series of operations that causes a physical or chemical change in a substance or mixture of substances
Steam 3160C
90 % H2 S
BOILER
3990C
Air
1st CONVERTER
Feedwater
Water
288oC
Sulfur Feedwater
SULFUR CONDENSER
SULFUR SCRUBBER
Process Unit
An apparatus in which one of the operation that constitute a process is carried out. Each process unit has a set of input and output process stream
Output or product
Input or feed
Process Variables
Properties and conditions of the materials that enter and leave each process unit Examples: Mass, volume and density Flow rate
Chemical composition
Concentration Pressure Temperature
Mass, Volume and Density Calculate the density of mercury (specific gravity at 20oC = 12.546) in Ibm/ft3 and calculate the volume in ft3 occupied by 215g of mercury. Solution:
62.43 Ibm/ft3
Hg = 13.536 (62.43 Ibm/ft3) = 845.7 Ibm/ft3 215 kg 1 Ibm 1 ft3 = 0.560 ft3
V=
Group Assignments
A liquid has a specific gravity of 0.50. What is (a) its density in g/cm3 and in Ibm/ft3? (b)
(c)
(d)
Flow Rate
rate at which material is transported through a process line Mass flow rate = mass (kg) time (s)
Volumetric flow rate = volume (m3) time (s) = m V can be used to convert a known flow rate of a process stream to the mass flow rate of that stream or vice versa
Flow Rate The specific gravity of nitrobenzene is 1.20. Calculate the volumetric flow rate in ml/min corresponding to a mass flow rate of 30 Ibm/h nitrobenzene. Solution:
62.43 Ibm/ft3
= 188.99 ml/min
If the molecular weight of a substance is M, then there are M kg/kmol,M g/mol, and M Ibm/Ib-mole of this substance
Moles & Molecular Weight Example (a) For ammonia,NH3, 1 mol NH3 contains 17g (M=17) Therefore, 34 kg NH3 = 34 kg NH3 1 kmol NH3 17 kg NH3 = 2 kmol NH3 (b) If 4 Ib-moles of NH3/h flows through a pipeline, the mass flow rate of NH3 is 4 Ib-moles NH3 17 Ibm NH3 = 68 Ibm NH3/h h 1 Ib-mole NH3
Group Assignments
How many of each of the following are contained in 100 g of CO2 (M = 44.01)? (a) mol CO2
(b)
(c)
Ib-moles CO2
mol O
(d)
mol O2
Composition
Composition fractions : Mass fraction, xA = mass of A (kg A) total mass (kg total)
=1
all components
all components
Solution:
Basis : 100 g of the mixture For O2, amount of moles, nO2 =
Step 4 1 & 3 2
Molar fraction Assume Amount of a moles basis of calculation each components component in 100g of the mixture
mol O2 = mol total mol CO = yCO = mol total mol CO2 = yCO2 = mol total mol N2 = yN2 = mol total
yO2 =
CO2
N2
0.5 = 0.15 3.279 0.143 = 0.044 3.279 0.386 = 0.12 3.279 2.25 = 0.69 3.279
Check : yi = 1.00
Solution:
Given :
yN2 = 0.79, yO2 = 0.21 xN2 = 0.767, xO2 = 0.233
1. M = yN2MN2 + yO2MO2
0.79 kmol N2 28 kg N2 0.21 kmol O2 32 kg O2 = kmol kmol N2 + kmol kmol O2 = 29 kg / kmol
Group Assignments
1. An industrial-strength drain cleaner contains 5.0 kg of water and 5.0 kg of NaOH. What are the mass fraction and mole fraction of each component in the drain cleaner container? 2. A gas has the following molar composition: CH4 80% C2H4 10% C2H6 10% What is the average molecular weight of the mixture? What is the mass fraction of each of the components in the mixture? 3. A mixture of gases contains equimolar amounts of ethylene, ethane, and propane. Calculate the mass fractions of the components in the mixture and the average molecular weight? 4. A gas contains 28 mole% CO, 17 mole % CO2 and 55 mole % CH4 . Determine the mass fractionf of CO, CO2 and CH4 in the gas.
Concentration
Concentrations are based on volume
Can be used to convert mass or mass flow rates (moles or molar flow rates) to total volume or volumetric flow rates
Mass concentration = mass kg volume m3
(2) If a stream of this solution flows at a rate of 2 liters/min, the molar flow rate of NaOH is 2 liters 0.02 mol NaOH = 0.04 mol NaOH/min min liter
Pressure
Atmospheric Pressure =pressure, force, Patm. F N the hydrostatic area pressure the forceon acts, the A surface m2 of the earth at sea level = 1 atm = 2) Po (N/m 14.696 psi = 760mm Hg = 101.325 kPa Gauge pressure, Pgauge Fluid density pressure relative to atmospheric pressure Absolute pressure, Pabs. relative to a perfect P vacuum is given = Po + which (g / g c) h a pressure of zero Pabs. = Pgauge + Patm.
P(mm Hg) = Po(mm Hg) + h (mm Hg)
h (m) P (N/m2) (kg/m3) A (m2)
Temperature
Absolute The degree temperature of hotness scales or coldness is scales of that a substance began at absolute measured zero on some definite scale Conversion between temperature units Fahrenheit Kelvin (K) (oF)
0K = -273.15oC 0oC = 273.15 K Most common o T(K) = T( C) + 273.15 temperature scales o o oF = 459.67oR oo o 0 RT( = -459.67 FoF) +0459.67 Rankine Celsius (( C) R) R) = T(
Process Classification
Batch Process
Feed is charged into the system at the begining of the process and product is removed all at once at sometime later
Continuous Process
Input and outputs flow continuously throughout the duration of the process
Semibatch Process
Any process continuous that is neither batch nor
Material Balances
Law of Conservation of Mass : Mass can neither be created nor destroyed (except in nuclear reactions) General balance equation:
Input + Generation Output Consumption = Accumulation
3.
4.
5.
Solution :
Step 2 1
Label chart Flow unknown with known values variables
450 kg B/h
1000 kg/hr of mixture contains 50% benzene
q1 kg T/h
3 4 Step 5
Basis of Material Solve unknowns Calculation Balance
Benzene balance:
0.5(1000) kg B/h = 450 kg B/h + q2
q2 = 50kg B/h
Toluene balance:
475 kg T/h q2 kg B/h
Checking: Total Mass Balance: 1000kg/h = (450 +q1 + q2+475) kg/h 1000kg/h = 1000 kg/h
3 4 Step 5
Basis of Material Solve unknowns Calculation Balance Qg x g CH3OH/g (1-x) g H2O/g Basis: Given feed flow rates Input = Output
Q = 350 g
Methanol balance: 200 g 0.4 g CH3OH 150g 0.7 g CH3OH + g g = 350 g x g CH3OH g x = 0.529 g CH3OH/g
Group Assignments
1. 1000 kg of a mixture of 10 wt. % ethanol and 90 wt. % water are distilled in a column. The weight of the distillate which contains 60 wt. % water is 1/10 of the feed. Calculate the composition of the bottoms and the mass of the alcohol in the bottoms.
2. An aqueous solution of sodium hydroxide contains 20 wt. % NaOH. It is desired to produce an 8 wt. % NaOH solution by diluting a stream of the 20 wt. % solution with a stream of pure water. Determine the feed rates of the 20 wt. % solution and diluting water needed to produce 2310 Ibm/min of the 8 wt. % solution.
Group Assignments
3. Following is a labeled flowchart of an extraction process in which a solute (A) is transferred from one solvent (S) to another (T) in which it is more soluble.
W g T/min 400 g/min 0.1 g A/g 0.9 g S/g Q g/min 0.02 g A/g R g/min 0.98 g S/g 0.2 g A/g 0.8 g T/g
4. 2000 kg/h of a mixture containing 45 wt. % benzene (B) and 55 wt. % toluene (T) is fed to a distillation column. An overhead product stream of 95 wt. % B is produced and 8 % of the benzene fed to the column leaves in the bottom stream. Determine the overhead flow rate and the mass flow rates of benzene and toluene in the bottom stream.
Multiple-unit Processes
Material Most processes balances consists (boundaries) of a number can be written of interconnected around any unit subsystem processes. of the plant. Material balances can also be written for mixing points or splitters.
Feed 2
C Feed 1 B E D Unit 1 Unit 2
A Product 3
100 kg/h
0.5 kg A/kg 0.5 kg B/kg
Unit 1
Unit 2
Solution:
40 kg/h 0.900 kg A/kg 0.100 kg B/kg 30 kg/h 0.600 kg A/kg 0.400 kg B/kg
1 Q1(kg/h)
x1(kg A/kg) 1x1(kg B/kg) 30 kg/h
2 Q2(kg/h)
x2(kg A/kg) 1x2(kg B/kg) 0.300 kg A/kg 0.700 kg B/kg
Unit 2
3 Q3(kg/h)
x3(kg A/kg) 1x3(kg B/kg)
100 kg/h
Q1(kg/h)
Unit 1
Q2(kg/h)
Q3(kg/h)
Unit 2
Entire process
Overall Balance on A :
0.5(100) + 0.3(30) = 0.9(40) + 0.6(30) + x3(60) x3 = 0.0833 kg A/kg
Q2(kg/h)
60 kg/h
Unit 2
Unit 1
Mass Balance on A :
0.5(100) = 0.9(40) + x1(60) x1 = 0.233 kg A/kg
Q2 (kg/h)
60 kg/h
Unit 2
Mass Balance on A :
0.233(60) + 0.3(30) = x2(90) x2 = 0.255 kg A/kg
Group Assignments
A liquid mixture containing 30 mole % benzene, 25 mole % toluene and 45 mole % xylene is fed at a rate of 1275 kmol/h to a distillation unit consisting of two columns. The bottoms product from the first column is to contain 99 mole % xylene and no benzene, and 98% of the xylene in the feed is to be recovered in this stream. The overhead product from the first column is fed to a second column. The overhead product from the second column contains 99 mole % benzene and no xylene. The benzene recovered in this stream represents 96% of the benzene in the feed to this column. Calculate the molar flow rates (kmol/h) and component mole fractions in each product stream from both columns.
1275 kmol/h 0.3 kmol B/kmol 0.25 kmol T/kmol 0.45 kmol X/kmol
Bypass
A stream that skips one or more stages of the process and goes directly to another downstream stage. Here a fraction of the feed to a process unit is diverted around the unit and combined with the output stream from the unit.
Feed Process Unit Bypass stream Product
Solution:
Basis : 10,000 kg/h of feed
V = 8000 kg/h
0.95 kg B/kg 0.05 kg T/kg R F = 10000 kg/h 0.5 kg B/kg 0.5 kg T/kg D 0.95 kg B/kg 0.05 kg T/kg
Entire process
Solving simultaneously,
V = 8000 kg/h 0.95 kg B/kg 0.05 kg T/kg F = 10000 kg/h 0.5 kg B/kg 0.5 kg T/kg R 0.95 kg B/kg 0.05 kg T/kg
Condenser
Group Assignments
A labeled flow chart for a closed-loop system is as shown below. What is the flow rate of the recycle stream R?
R kg/h 0.286 kg V/kg 0.714 kg H2O/kg