Beta Analytic Presentation About Biogenic CO2

Quantification of Carbon-Neutral
Greenhouse Gas Emissions

Using ASTM D6866
Mauricio Larenas
Verification of Biogenic Carbon / Carbon-neutral CO2
Carbon Neutral CO2
(Biogenic CO2)
 Recently respired CO2
 Plants recently removed it from the air
 A by-product of biomass incineration
 Can be subtracted from GHG inventories
 Has value in the trading markets

Carbon-14
Naturally occurring
in all biomass,
absent in fossil fuels
ASTM D6866 measures it.

Carbon-14 is ubiquitous in all living things.
But it doesn’t stick around.
It slowly and gradually decays away after

death, so that by 50,000 years
there’s none left.
Coal and fossil-derived materials do not have any

carbon-14 whereas biomass does.

Take a good look, Identical?
Carbon-14
 Biomass CO2
Coal CO2
No Carbon-14
They’re NOT the same!

The Radiocarbon Cycle
STEP 1: Ongoing formation and decay of radiocarbon within the atmosphere
Nitrogen ( 14N ) + cosmic neutrons Radiocarbon (14C)
Radiocarbon immediately oxidizes Carbon dioxide (14CO2)
The radiocarbon immediately starts to decay (T1/2 = 5730 years)
14
N+n 14
C
“Constant” amount of radiocarbon

in the atmosphere as CO2
C Decay
14
CO2
14
STEP 2: Radiocarbon is removed from the atmosphere by plants
STEP 3: Disequilibrium begins upon “death”

100% renewable
0 50,000 yrs
The Radiocarbon Decay Curve
0% renewable
Conventional biomass – CO2 inventory accounting
(Stationary Combustion Sources – e.g. Cement, Co-firing, Biomass, Waste, etc.)
Complicated
physical
characterization
of the feed stock
T
O
N Sorting, cutting,
S sectioning, and
weighing raw
fuel
Labor intensive,
expensive,
CO2 burdensome
ASTM D6866 biomass – CO2 inventory accounting
Measure CO2 in the stack effluent
Complicated
)
ic physical
$
en
og
l (b
i
characterization
ra
ut of the feed stock
T ne
O on
rb
Ca
N
S
Sorting, cutting,
sectioning, and
G ) weighing raw
(GH
s sil fuel
Fo
Labor intensive,
expensive,
CO2 burdensome
ASTM-D6866 is a standardization of
radiocarbon dating methods used by
archaeologists to determine the age of fossils.
Methods that have been in use for

60 years
(mature technology)
and being a mature industry . . .
 Expertise
 Laboratories
 Well known sources of error
 Supply Lines
 Venders
 Instrumentation
 Raw materials
Complete pre-existing infrastructure

Carbon-14 and Atmospheric Monitoring
Used for atmospheric monitoring for 3 decades
Nothing to invent
Nothing to test
Commercially available with results in 3-4 days
Gives the relative fossil CO2 in gas sample

C14 Dating is an internationally recognized
method for verification
ASTM (American Society for Testing and Materials)
CEN (European Committee for Standardization)
US EPA (Environmental Protection Agency)
ARB (California Air Resources Board)
TCR (The Climate Registry)
WCI (Western Climate Initiative)
Australia (National Greenhouse and Energy Reporting Protocol)
EU-ETS (European Union Emission Trading Scheme)
ROCs (Renewable Obligation program UK ) *Currently being Approved

Status of ASTM-D6866 in the USA
California Air Resources Board (CARB) & AB 32
“Fuels like biomass and municipal solid waste (MSW) are so varied that
fuel analysis is impractical.”
“The proposed regulation requires emissions from biomass-derived

fuels to be reported separately from fossil fuels.”
“Municipal solid waste facilities are required to use ASTM Method

D6866 . . . ”
All stationary combustion facilities which co-fire a fossil fuel with a

biomass-derived fuel are recommended to use ASTM Method D6866.
California Air Resources Board (CARB) & AB 32
January 1, 2008 : Establish a statewide GHG emissions cap

for 2020 based on 1990 emissions
January 1, 2009 : Adopt mandatory reporting rules for

significant sources of GHG
January 1, 2010 : Adopt a plan indicating how emission reductions

will be achieved
January 1, 2011 : Adopt regulations to achieve the maximum

technologically feasible and cost-effective
reductions in GHG
Status of ASTM-D6866 in the US
The Western Climate Initiative

Essential Requirements of Mandatory Reporting, Third Draft
released January 6, 2009:
ASTM D6866 has been identified as the analytical method for biogenic
CO2 emissions for general stationary fuel combustion sources.
The Climate Registry – North American GHG Protocol
Adoption of ASTM D6866 for biomass CO2 emissions monitoring
General Reporting Protocol Version 1.1 May 2008 identified ASTM

D6866 as one of the methods to use when quantifying emissions from
waste fuels and biomass.
EPA Proposed Mandatory Greenhouse Gas Reporting Rule
“Carbon dioxide emissions from the combustion of biogenic fuels shall

be excluded from the calculations.”
“For a unit that combusts MSW, the owner or operator shall use, for
each quarter, ASTM Methods D6866 and D7459 … to determine the
relative proportions of biogenic and non-biogenic CO2 emissions
when MSW is combusted.
“The owner or operator shall separate total CO2 emissions from MSW
combustion into biogenic emissions and non-biogenic emissions,
using the average proportion of biogenic emissions of all samples
analyzed during the reporting year.”
ASTM D6866 and CEN 15747
~ ASTM D6866 is part of the mandatory reporting requirements of

California's AB 32, Western Climate Initiative, The Climate Registry
and the EPA’s GHG protocol.
~ The European Union allows the use of ASTM D6866 for

monitoring various types of heterogeneous fuels.
~ The Australian government has recommended the use of ASTM

D6866 for blended fuels.
~ The Renewable Obligation Certificate program in the United

Kingdom is also considering this method for monitoring biomass
energy production.
~ CEN 15747 is used to monitor refused derived fuels for the

European Union's Emission Trading Scheme.
ASTM
ASTM D7459
D7459
Standard Practice for Collection of Integrated Samples for the
Speciation of Biomass (Biogenic) and Fossil-Derived Carbon Dioxide
Emitted from Stationary Emissions Sources
Established for the EPA Proposed Mandatory Greenhouse Gas Reporting Rule
Written by stack testing community including The Avogadro Group
Used as basis for international ISO standard under development

Reporting
Simple Visual Report
Easy Inter-comparison
Instinctively Obvious

How much does it cost?
$595 per analysis
(Off-setting labor, liabilities and hazards

associated with feedstock characterization)
How long does it take to get a result?
One week, but as little as 2-3 days

LSC Counter Room

One of the Chemistry Line Rooms

Accelerator Mass Spectrometry Room

Company Background
- 30 years in business, considered the leader of our field

- Fast turn-around times (as little as 24 hours)
- Confidentiality of all results
- Large throughput operation [52 LSC counters, 2 mass
spectrometers, 2 accelerator mass spectrometers (4 ions
sources), 16 chemistry lines]
-18 dedicated full-time professionals, no part-time students
learning on your samples
- ISO/IEC 17025:2005 accredited

WWW.BETALABSERVICES.COM
Mauricio Larenas –
[email protected]
305-662-7760
Beta Analytic Inc. Beta Analytic Limited

4985 SW 74 Court The London BioScience
Miami, Florida 33155 Innovation Centre
USA 2 Royal College Street
London NW10NH
United Kingdom
Tel: (44) 207 617 7490

Fax: (44) 207 160 5350
[email protected]

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Quantification of Carbon-Neutral

Greenhouse Gas Emissions

 A by-product of biomass incineration

 Can be subtracted from GHG inventories

 Has value in the trading markets

Verification of Biogenic Carbon / Carbon-neutral CO2

ASTM D6866 measures it.

But it doesn’t stick around.

It slowly and gradually decays away after

Coal and fossil-derived materials do not have any

Verification of Biogenic Carbon / Carbon-neutral CO2

They’re NOT the same!

Nitrogen ( 14N ) + cosmic neutrons Radiocarbon (14C)

Radiocarbon immediately oxidizes Carbon dioxide (14CO2)

The radiocarbon immediately starts to decay (T1/2 = 5730 years)

“Constant” amount of radiocarbon

STEP 2: Radiocarbon is removed from the atmosphere by plants

STEP 3: Disequilibrium begins upon “death”

Methods that have been in use for

Complete pre-existing infrastructure

Used for atmospheric monitoring for 3 decades

Commercially available with results in 3-4 days

Gives the relative fossil CO2 in gas sample

ASTM (American Society for Testing and Materials)

CEN (European Committee for Standardization)

US EPA (Environmental Protection Agency)

ARB (California Air Resources Board)

TCR (The Climate Registry)

WCI (Western Climate Initiative)

Australia (National Greenhouse and Energy Reporting Protocol)

EU-ETS (European Union Emission Trading Scheme)

ROCs (Renewable Obligation program UK ) *Currently being Approved

Verification of Biogenic Carbon / Carbon-neutral CO2

California Air Resources Board (CARB) & AB 32

“The proposed regulation requires emissions from biomass-derived

“Municipal solid waste facilities are required to use ASTM Method

All stationary combustion facilities which co-fire a fossil fuel with a

California Air Resources Board (CARB) & AB 32

January 1, 2008 : Establish a statewide GHG emissions cap

January 1, 2009 : Adopt mandatory reporting rules for

January 1, 2010 : Adopt a plan indicating how emission reductions

January 1, 2011 : Adopt regulations to achieve the maximum

The Western Climate Initiative

The Climate Registry – North American GHG Protocol

Adoption of ASTM D6866 for biomass CO2 emissions monitoring

General Reporting Protocol Version 1.1 May 2008 identified ASTM

EPA Proposed Mandatory Greenhouse Gas Reporting Rule

“Carbon dioxide emissions from the combustion of biogenic fuels shall

~ ASTM D6866 is part of the mandatory reporting requirements of

~ The European Union allows the use of ASTM D6866 for

~ The Australian government has recommended the use of ASTM

~ The Renewable Obligation Certificate program in the United

~ CEN 15747 is used to monitor refused derived fuels for the

Written by stack testing community including The Avogadro Group

Used as basis for international ISO standard under development

Simple Visual Report

Verification of Biogenic Carbon / Carbon-neutral CO2

$595 per analysis

(Off-setting labor, liabilities and hazards