Chapter 3 Thermodynamics
Chapter 3 Thermodynamics
Chapter 3 Thermodynamics
)... (3-1)
c = heat capaci t y ( 179 cal / or 179 cal / K or as 749J/ K)
= heat absor b/ l oses
I = Temper at ur e di f f er ence/ change
I
)... (3-2)
c = heat speci i c ( r ef er t abl e 3-1)
m = moss o tc ob]cct
= heat absor b/ l oses
I = Temper at ur e di f f er ence/ change
I
)
= 0.452 180 ( 1265 300)
= 78521.4 k[
HEATS OF TRANSFORM ATION
When ener gy i s absor bed as heat by a sol i d or l i qui d, t he sampl e may change f r om one phase, or st at e,
t o anot her .
When ener gy i s r eleased as heat by a gas or l i qui d, t he sampl e may al so change f r om one phase, or
st at e, t o anot her . Ref er di agr am as show n by f i gur e 3-4.
Figure 3-4: Sampl e/ syst em s st at e t r ansf or mat i on.
The amount of ener gy per uni t mass t hat must be t r ansf er r ed as heat w hen a sampl e compl et el y
under goes a phase change i s cal l ed t he heat of t r ansf or mat i on, L. Thus w hen a sampl e of mass, m
compl et el y under goes a phase change, t he t ot al ener gy t r ansf er r ed i s
Q=Lm...(3-3)
Exampl e 3-3
When 5.0 kg of w at er f r eezes at 0C, how much ener gy i s r el ease?
Q= mL
= (5.0 kg) x (3.33 x 10
5
J/ kg)
= 1.67 x 10
6
J ener gy i s r el eased
HEAT TRANSFER M ECHANISM E
Ther e ar e t hr ee heat t r ansf er mechani sme: conduct ion, convect ion, and radiat ion.
1) Conduct ion
Conduct i on heat t r ansf er exi st s i n mat er i al due t o t he pr esence of t emper at ur e di f f er eces
w i t hi n t he mat er i al. It can exi st i n al l subst ances but i s most of t enassoci at ed w i t h sol i ds.
(See f i gur e 3-5)
It i s expr essed mat hemat i call y by Four i er s Law of heat t r ansf er , w hi ch f or a one
di mensi onal pl ane w all t akes t he f or m
Figure 3-5: Ther mal conduct i on
= kA
1
L
(3-4)
=
A
R
I....(3-5)
=
A
R
totuI
I =
10 3
2.5
40 = 480w
2) Convect ion
Convect i on occur s w hen heat f l ow s by t he mass movement of mol ecul es f r om one pl ace t o
anot her . It may be nat ur al or f or ced; bot h t hese exampl es ar e nat ur al convect i on. (See
f i gur e 3-6)
Figure 3-6: Exampl e of Convect i on heat t r ansf er
Convect i on i s expr essed i n t er ms of t he t emper at ur e di f f er ence bet w een t he bul k f l ui d
t emper at ur e, I
=
c
A( I
s
I
) (3-5)
Exampl e 3-5
The heat t r ansf er f r om a 2 met er -di amet er spher e t o a 25C ai r st r eam over a t i me i nt er val of
one hour i s 3000 kJ. Est i mat e t he sur f ace t emper at ur e of t he spher e i f t he heat t r ansf er
coef f i ci ent i s 10W/ mK.
Solut ion:
The heat t r ansf er equat i on i s
=
c
A( I
s
I
)
Inser t al l val ue i n t he equat i on
3 10
6
= 10 4n 1
2
( I
s
25
) 3600
The sur f ace t emper at ur e i s cal cul at ed t o be
I
s
=
3 10
6
10 4n 1
2
3600
+ 25
I
s
= 31.6
3) Radiat ion
Radiat ion i s energy t r ansf er r ed as phot ons. It can be t r ansf er r ed t hr ough a per f ect vacuum
or t hr ough t r anspar ent subst ances such as ai r . It i s cal cul at ed usi ng t he St ef an-Bol t zmann
Law and account sf or t he ener gy emi t t ed and t he ener gy absor bed f r om t he sur r oundi ngs:
= eoA( I
4
I
su
4
) .(3-6)
o= St ef an-Bol t zmann ( 5.67 10
-8
w/ m
2
. K
4
)
e= Emi si vit y (a number bet w een 0 and 1, w here =1 i s f or bl ackbody)
I
su
=Temperat ure of t he sur roundi ng
Not e t hat ever y obj ect w hose t emper at ur e i s above 0 K, i ncl udi ng you emi t s t her mal r adi at i on.
(See f i gur e 3-7)
Figure 3-7: Col or s of t her mogr am r eveal s t he r at e at w hi ch ener gy i s r adi at ed.
Exampl e 3-6
Est i mat e t he r at e of heat t r ansf er f r om a 200C spher e w hi ch has an emi ssi vi t y of 0.8 i f i t i s
suspended i n a col d vol ume mai nt ai ned at -20C. The spher e has a di amet er of 20cm.
Solut ion:
The r at e of heat t r ansf er i s gi ven by
= eoA( I
4
I
su
4
)
= 0.8 5.67 10
-8
4n 0.1
2
( 473
4
253
4
)
= 262 [ s
3. 1. 3 THE ZEROTH LAW OF THERM ODYNAM I CS
The Zer ot h Law of Ther modynami c says:
If bodi es A and B ar e each i n t her mal equi li br i um wi t h a t hi r d body T, t hen t hey ar e i n t her mal
equi l i bri um wi t h each ot her .
Figure3-5(a)
Fi gur e 3-5(a) show s body T (a t her moscope) and body A ar e i n a t her mal equi li br i um. (Body S i s a
t her mal l y i nsul at i ng scr een)
Figure3-5(b)
Fi gur e 3-5(b) show s body T and body B ar e al so i n t her mal equil i br i um, at t he same r eadi ng of t he
t her moscope.
Figure3-5(c)
Fi gur e 3-5 (c) show s i f (a) and (b) ar e t r ue t he Zer ot h Law of t her modynami cs st at es t hat body A and B
ar e al so i n t her mal equi li br i um.
The message f r om Zer ot h Law i s: Ever y body has a pr oper t y cal l ed t emper at ur e. When t w o bodi es ar e
i n t her mal equi li br i um, t hei r t emper at ur es ar e equal . And vi ce ver sa.
3. 1. 3 THE FI RST LAW OF THERM ODYNAM I CS
The Fi r st Law of Ther modynami cs says:
The change i n i nt er nal ener gy (F
|nt
) of a cl osed syst em w i l l be equal t o t he ener gy (Q) added t o t he
syst em mi nus t he w or k (W ) done by t he syst em on i t s sur r oundi ngs.
Equat i on 3-7 i s t he Fi r st Law of t her modynami cs:
E
nt
= w..(3-7)
Exampl e 3-7
Let 1.00kg of l i qui d w at er at 100C be conver t ed t o st eam at 100C by boi l i ng at st andar d at mospher i c
pr essur e (w hi ch i s 1.00 at m or 1.01 10
5
Po) i n t he ar r angement of Fi g. 3-6. The vol ume of w at er
changes f r om an i ni t i al val ue of 1.00 10
-3
m
3
as a l i qui d t o 1.671 m
3
as st eam.
a) How much w or k i s done by t he syst em dur i ng t he pr ocess?
Solut ion:
w = pJI = p JI = p( I
]
I
)
v]
v
v]
v
= ( 1.01 10
5
Po) ( 1.671 m
3
1.00 10
-3
)
= 1.69 10
5
[ = 169k[
b) How much ener gy i s t r ansf er r ed sas heat dur i ng t he pr ocess?
Solut ion:
Ref er t o t abl e 3-2, Heat of vapor i zat i on, Lv=2256kJ/ kg
Q =Lvm =(2256kJ/ kg)(1.00kg)
= 2256kg
2260kJ
c) What i s t he changei n t he syst em s i nt er nal ener gy dur i ng t he pr ocess?
Solut ion:
E
nt
= w
=2256kJ- 169kJ
2090 k[ = 2.09 M J
3. 1. 4 THE SECOND LAW OF THERM ODYNAM I CS
The Second Law of Ther modynami cs may be def i ned in many w ays but t he t w o common st at ement s ar e
accor di ng t o Kel vi n-Pl anck and Cl ausi us ar e as f ol l ow s:
Kel vi n-Pl ank st at ement :
It i s i mpossi bl e t o const ruct an engi ne wor ki ng on a cycl i c process, w hose sole purpose i s t o conver t heat
ener gy f r om a singl e t her mal r eservoi r int o an equi val ent amount of w or k .
In ot her w or ds, no act ual heat engi ne, w or ki ng on a cycl i c pr ocess, can conver t w hol e of t he heat
suppl i ed t o i t , i nt o mechani cal w or k. It means t hat t her e i s a degr adat i on of ener gy i n t he pr ocess of
pr oduci ng mechani cal w or k f r om t he heat suppl i ed. Thus i t i s somet imes know n as Law of Degr adat i on
of Ener gy.
A heat engi ne w hi ch vi ol at es t hi s st at ement of t he second l aw of t her modynami c (i .e. a heat engi ne
w hi ch conver t s w hol e of t he heat ener gy i nt o mechani cal w or k) i s know n as per pet ual mot i on machi ne
of t he second ki nd or 100% ef f i ci ent machi ne w hi ch is i mpossi bl e t o obt ai n i n act ual pr act i ce, because
no machi ne can conver t w hol e of t he heat ener gy suppl i ed t o i t , i nt o i t s equi val ent amount of w or k.
Thus f or t he sat i sf act or y oper at i on of heat engi ne w hi ch i s a devi ce used f or conver t i ng heat ener gy i nt o
mechani cal w or k, t her e shoul d be at l east r eser voi r s of heat , one at a hi gher t emper at ur e and t he ot her
at l ow er t emper at ur e as show n i n f i gur e 3-6.
Figure 3-6: Heat Engi ne
In t hi s case, consi der t hat heat energy (Q1) f r om t he hi gh t emper at ur e r eservoi r (or sour ce) at
t emper at ur e T1 i s suppli ed t o t he engi ne. A par t of t hi s heat ener gy i s r ej ect ed t o t he l ow r eser voi r (or
si nk) at t emper at ur e T2. If Q2 i s t he heat r ej ect ed t o t he si nk, t hen t he r emai ni ng heat (i .e Q1-Q2) i s
conver t ed i nt o mechani cal w or k. The r at i o of t he maximum mechani cal w or k obt ai ned t o t he t ot al heat
suppl i ed t o t he engi ne i s know n as maxi mum t her mal ef f i ci ency (p
mux
) of t he engi ne. M at hemat i cal ly,
p
mux
=
Hox work obtoincJ
Iotol cot supplicJ
=
1-
1
=
I
1-
I
2
I
1
= 1
1
= 1
I
2
I
1
Not e: For a r ever si bl e engi ne,
1
I
1
=
2
I
2
Exampl e 3-8
A r ever si bl e engi ne i s suppli ed wi t h heat f r om t w o const ant t emper at ur e sour ces at 900 K and 600 K and
r ej ect s heat at t o a const ant t emper at ur e si nk at 300 K. The engi ne devel ops w or k equival ent t o 90 kJ/ s
and r ej ect heat s at t he r at e of 56kJ/ s.
Figure 3-7
a) Est i mat e heat suppl i ed by each sour ce.
Solut ion:
Gi ven: I
1
= 900 K; I
3
= 600 K; I
2
= I
4
= 300 K; w
L
= 90k J/ s;
2
+
4
= 56k J/ s
Q1 = Heat suppl i ed by t he f i r st sour ce
Q2 = Heat suppl i ed by t he second sour ce
We know t hat ef f i ci ency of t he engi ne w hen t he heat i s suppl i ed f r om t he f i r st sour ce
p
1
=
work obtoincJ
Iotol cot supplicJ
=
1-
1
=
I
1-
I
2
I
1
=
900 300
900
= 0.67
Wor k obt ai ned by t he engi ne f r om t he i r st sour ce,
p
1
=
1
2
1
= 0.67
w
1
=
1
2
= 0.67
1
And heat r ej ect ed t o t he si nk,
2
=
1
w
1
=
1
0.67
1
Si mil ar ly, ef f i ci ency of t he engi ne w hen t he heat i s suppl i ed f r om t he second sour ce
p
2
=
work obtoincJ
Iotol cot supplicJ
=
w
2
3
=
3-
3
=
I
3-
I
4
I
3
=
600 300
600
= 0.5
Wor k obt ai ned by t he engi ne f r om t he i r st sour ce,
p
2
=
3
4
3
= 0.5
w
2
=
3
4
= 0.5
3
And heat r ej ect ed t o t he si nk,
4
=
3
w
2
=
3
0.5
3
= 0.5
3
We know t hat t ot al w or k obt ai ned f r om t he engi ne (WE),
90 = W1 + W2 = 0.67Q1 + 0.5 Q3...(i )
And t ot al heat r ej ect ed t o t he si nk,
56 =
2
+
4
= 0.33
1
0.5
3
(i i )
Sol ve equat i on (i ) and (i i )
Q1 = 100kJ/ s
Q2 = 46kJ/ s
b) Cal cul at e t her mal ef f i ci ency of t he engi ne.
Sol ut i on:
p
mux
=
work obtoincJ
Iotol cot supplicJ
=
w
L
1
+
3
=
90
100 + 46
= 0.616 or 61.6%
Cl ausi us st at ement :
It i s i mpossi bl e f or a sel f act i ng machi ne, w or ki ng i n a cycl i c pr ocess, t o t r ansf er heat f r om a body at
l ow er t emper at ur e t o a body at a hi gher t emper at ur e w i t hout t he ai d of an ext er nal agency.
In ot her w or ds, heat cannot f l ow i t sel f f r om a col d body t o a hot body w i t hout t he hel p of an ext er nal
agency (i .e wi t hout t he expendi t ur e of mechani cal w or k).
Devi ce (such as r ef r i gerat or or a heat pump), as show n i n f i g 3-8 (a), vi olat es t he Cl ausi us st at ement
because no i nput w or k i s suppl i ed t o t he devi ce t o t r ansf er heat f r om a col d body t o a hot body. Such a
devi ce i s cal l ed per pet ual mot i on machi ne of t he second ki nd.
Figure 3-8
In or der t o achi eve t he obj ect of t r ansf er r i ng heat f r om a col d body t o a hot body, t he r ef r i ger at or and a
heat pump, w hi l e oper at i ng i n a cycl i c pr ocess, r equi r e an i nput w or k, as show i n f i gur e 3-7(b) and (c)
r espect i vel y. A r ef ri ger at or w or ks bet ween t he col d body t emper at ur e and t he at mospher i c
t emper at ur e w her eas a heat pump oper at es bet w een t he hot body t emper at ur e and t he at mospher i c
t emper at ur e.
The per f or mance of r ef r i ger at or and heat pump i s measur ed by Coef f i ci ent of Per f or mance (COP)
Coef f i ci ent of Per f or mance f or r ef r i ger at or ,
C0P
R
=
2
w
R
=
2
1
2
=
I
2
I
1
I
2
Coef f i ci ent of Per f or mance f or heat pump,
C0P
P
=
1
w
P
=
1
1
2
=
I
1
I
1
I
2
=
I
2
I
1
I
2
+ 1 = C0P
R
+ 1
Exampl e 3-9
A col d st or age i s t o mai nt ai ned at -5C w hi l e t he sur r oundi ngs ar e at 35C. The heat l eakage f r om t he
sur r oundi ngs i nt o t he col d st or age i s est i mat ed t o be 29kW. The act ual COP of t he r ef r i ger at i on pl ant i s
one-t hi r d of an i deal pl ant w or ki ng bet w een t he same t emper at ur es. Fi nd t he pow er r equi r ed t o dr i ve
t he pl ant .
Figure 3-9
Solut ion:
Gi ven:
I
2
= 5 = 5 + 273 = 268 K; I
1
= 35 = 35+ 273 = 308 K;
2
= 29kw; ( C0P)
uctuuI
=
1
3
( C0P)
dcuI
The r ef r i ger at i ng pl ant oper at i ng bet w een t he t emperat ur es I
1
and I
2
i s show n i n f i gur e 3-9.
Let w
R
= w or k or pow er r equi r ed t o dr i ve t he pl ant .
We know t hat t he coef f i ci ent of per f or mance of an i deal r ef r i ger at i ng pl ant ,
( C0P)
dcuI
=
I
2
I
1
I
2
=
268
308 268
= 6.7
Act ual coef i ci ent of per f or mance,
( C0P)
uctuuI
=
1
3
( C0P)
dcuI
=
1
3
6.7 = 2.233
We al so know t hat C0P =
2
w
R
w
R
=
2
( C0P)
uctuuI
=
29
2.233
= 12.987kw