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Material Safety Data Sheet

Diallyl Phthalate MSDS
Section 1: Chemical Product and Company Identification
Product Name: Diallyl Phthalate Catalog Codes: SLD2632 CAS#: 131-17-9 RTECS: Not available. TSCA: TSCA 8(b) inventory: Diallyl Phthalate CI#: Not available. Synonym: Chemical Name: 1,2-Benzenedicarboxylic Acid, Di-2propyl Ether Chemical Formula: C14-H14-O4 Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com

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Fire Re a c t iv it y P e rs o n a l P ro t e c t io n

CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition: Name Diallyl Phthalate CAS # 131-17-9 % by Weight 100

Toxicological Data on Ingredients: Diallyl Phthalate: ORAL (LD50): Acute: 656 mg/kg [Rat]. 1700 mg/kg [Rabbit]. DERMAL (LD50): Acute: 3300 mg/kg [Rabbit]. VAPOR (LC50): Acute: 5200 mg/m 1 hours [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator), of eye contact (irritant). Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact: p. 1

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention if irritation occurs. Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious Inhalation: Not available. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature. Auto-Ignition Temperature: Not available. Flash Points: CLOSED CUP: 166C (330.8F). Flammable Limits: Not available. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions: p. 2

Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/ spray. Avoid contact with skin. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection: Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid. (Oily liquid.) Odor: mild Taste: Not available. Molecular Weight: 246.26 g/mole Color: almost colorless pH (1% soln/water): Not available. Boiling Point: 158C (316.4F) Melting Point: -70C (-94F) Critical Temperature: Not available. Specific Gravity: 1.12 (Water = 1) Vapor Pressure: Not available. Vapor Density: 8.3(Air = 1) Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 3.2 Ionicity (in Water): Not available. Dispersion Properties: Not available. Solubility: Very slightly soluble in cold water. Soluble in most organic liquids. Soluble in gasoline, mineral oil, glycerin, certain amines. Solubility in water: 182 mg/liter water.

Section 10: Stability and Reactivity Data

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Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Heat, incompatible materials. It will polymerize with heat and catalyst. Incompatibility with various substances: Reactive with oxidizing agents. Corrosivity: Not available. Special Remarks on Reactivity: Not available. Special Remarks on Corrosivity: Not available. Polymerization: Yes.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Toxicity to Animals: WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 656 mg/kg [Rat]. Acute dermal toxicity (LD50): 3300 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 5200 mg/m 1 hours [Rat]. 3 Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/ or yeast. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator). Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: May affect genetic material. May cause cancer based on animal data. Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Causes skin irritation. Irritation may be moderate. Eyes: Causes eye irritation. Irritation may be mild. Lachrymator. Inhalation: May cause respiratory tract and mucous membrane irritation. It may affect respiration (dyspnea), and gastrointestinal tract. Ingestion: May cause digestive tract disturbances. May be harmful if swallowed. It may affect behavior, respiration, and liver. Chronic Potential Health Effects: Ingestion: Prolonged or repeated ingestion may affect the liver, respiration and gastrointestinal tract.

Section 12: Ecological Information

Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: Not available. Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

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Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States). Identification: Not applicable. Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: Pennsylvania RTK: Diallyl Phthalate Massachusetts RTK: Diallyl Phthalate TSCA 8(b) inventory: Diallyl Phthalate TSCA 8(d) H and S data reporting: Diallyl Phthalate: 12/19/95 Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. Other Classifications: WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): R20/22- Harmful by inhalation and if swallowed. R38- Irritating to skin. R40- Possible risks of irreversible effects. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S2- Keep out of the reach of children. S24/25- Avoid contact with skin and eyes. S36/37- Wear suitable protective clothing and gloves. S46- If swallowed, seek medical advice immediately and show this container or label. S60- This material and its container must be disposed of as hazardous waste. S61- Avoid release to the environment. Refer to special instructions/Safety data sheets. HMIS (U.S.A.): Health Hazard: 2 Fire Hazard: 1 Reactivity: 0 Personal Protection: g National Fire Protection Association (U.S.A.): Health: 2 Flammability: 1 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available. Other Special Considerations: Not available. Created: 10/09/2005 05:06 PM Last Updated: 11/01/2010 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume p. 5

no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages.

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