Air gasification of palm empty fruit bunch in a fluidized bed gasifier using various bed materials

Pooya Lahijani1, Ghasem D. Najafpour2,*, Zainal Alimuddin Zainal1, Maedeh Mohammadi2

School of Mechanical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia 2 Faculty of Chemical Engineering, Noushirvani University of technology, 47147 Babol, Iran Corresponding author: Fax: +98 111 321 0975, E-mail address: [email protected]

Abstract: Use of lignocellulosic biomass as an alternative, renewable and sustainable source of energy has fulfilled part of the growing demand for energy in developed countries. Amongst various technologies applied to convert biomass wastes to biofuel and bioenergy, biomass gasification has attracted considerable attention. In this work, gasification of palm empty fruit bunch as a potential lignocellulosic waste was investigated in a pilot scale air-blown fluidized bed. Silica sand and dolomite were used as bed material. The bed temperature was varied in the range of 650 to 1050 oC. The quality of the producer gas (H 2 , CO, CO 2 and CH 4 ) and gasification performance was assessed in terms of heating value, carbon conversion efficiency, dry gas yield and cold gas efficiency. It was concluded that high temperatures improved the quality of producer gas; maximum heating value of 5.3 and 5.5 MJ/Nm3 were achieved using silica sand and dolomite. Maximum dry gas yield of 1.84 and 1.79 (Nm3gas/kg biomass), carbon conversion of 91 a nd 85% and cold gas efficiency of 69 a nd 65% were obtained for silica sand and dolomite, respectively. Although the quality of the produced gas was considerably improved at high temperatures, however formation of the bed agglomerates was the major concern at temperatures above 800 and 850 oC for silica sand and sawdust.
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Keywords: Biomass gasification, Fluidized bed, Gas producer, Palm empty fruit bunch
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1. Introduction
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In recent years, rapid development of modern industry has greatly increased the demand for energy. Today, fossil fuels are the most common energy sources in the world. Most countries which use such conventional fuels are facing major air pollution problems as it has been estimated that the worlds oil reserves will get depleted by 2050 [1]. Besides, significant amount of pollutants including CO 2 , NO x and SO x are emitted from fossil fuels into the atmosphere. Meanwhile, the cost of fossil fuel is globally increasing [1, 2]. Considering theses issues, boosts the importance of finding and exploring alternative, renewable and sustainable energy resources.
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Lignocellulosic biomass is one of the potential renewable energy resources which is receiving great worldwide attentions. Malaysia as the largest producer of palm oil generates a large amount of lignocellulosic residues including palm empty fruit bunch (EFB), palm shell and mesocarp [3]. These lignocellulosic biomass feedstocks can be efficiently utilized in various thermo-chemical conversion processes to yield energy and fuels. Among various biomass conversion technologies, special attention has been paid to biomass gasification due to its high conversion efficiency [4-6].
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A survey of literature reveals successful application of lignocellulosic biomass in various types of gasifiers including fixed beds [7], entrained flow [8] and fluidized beds [9-13]. However, amongst different categories of gasifiers, fluidized beds have offered advantages such as efficient mixing of gas and solid, improved reaction rate and conversion, and low tar content of the producer gas. Various gasifying agents including air, steam, oxygen-steam, airsteam, O 2 -enriched air and oxygen-air-steam have been utilized in fluidized beds [6, 8, 14, 15]. Although a very high quality producer gas is not attainable through air gasification, however is boosts the feasibility of the biomass gasification for industrial application. Although various biomass feedstocks have been gasified in fluidized beds, little data has been published on g asification of EFB in catalytic fluidized beds. Current research aims to investigate the gasification of EFB in a pilot-scale air blown bubbling fluidized bed. Calcined dolomite and silica sand were used as bed material and their effect on the quality of the producer gas was investigated. 2. Methodology 2.1. Biomass feedstock and its characterization The biomass used in the current study was palm empty fruit bunch which was obtained from a local palm oil mill factory. The raw feed containing high amount of moisture was air dried for 2 days. The dried feed was then crashed and ground to the fibers with the mean length of 2-6 mm. Ultimate and proximate analysis was conducted on a sample of EFB to determine the elemental composition of the biomass. The heating value of EFB was measured by a bomb calorimeter. The obtained results and data analysis are presented in Table 1.
Table 1. Ultimate and proximate analysis of EFB

Ultimate analysis (wt %) Carbon Hydrogen Oxygen Nitrogen Sulfur Proximate analysis (wt %) Moisture Volatiles Ash Fixed carbon HHV, MJ/kg (dry basis) 7.80 79.34 4.50 8.36 15.22 43.52 5.72 48.90 1.20 0.66

2.2. System description and operation An air blown bubbling fluidized bed gasifier with the height of 1050 mm and internal diameter of 150 mm was operated for EFB gasification. Air was introduced into the gasifier
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using a 0.75kW blower. Silica sand and calcined dolomite with mean size of 600 m were used as bed material. The biomass was continuously fed into the reactor through a screw feeder conveyer equipped with an inverter. The temperature of different operating zones of the gasifier was monitored by several type K thermocouples. The operated experimental setup is represented in Fig. 1. At start up, t he system was heated up t o the desired temperature of 500 oC. There was a heating chamber supplied by LPG below the distributer plate to provide the necessary heat. As the temperature of reactor reached to 500 oC, air was introduced and the biomass feeding was started. To avoid the pyrolysis of biomass inside the screw feeder, there was a cooling jacket surrounding the conveyor and cooling water always passed during the process.

Fig. 1. Schematic representation of the pilot-scale BFB gasifier: 1. Mass flow controller; 2. Blower; 3. Variable frequency driver; 4. Feeding hopper; 5. Water cooled screw feeding system; 6. Fluidized bed reactor; 7. Particle holder; 8. Cyclone; 9. Temperature monitoring unit; 10. Condensers; 11. Fiber filter; 12. Silica gel; 13. Gas chromatograph

2.3. Gas sampling and analysis The gasifier was operated at atmospheric pressure. The gasifier was equipped with a cyclone and the dirty outlet gas containing ash, char, tar and dust particles entered the cyclone separator. The cyclone removed ash and chars from the hot gas and derived them into the bin connected to the cyclone. Producer gas was exited from the cyclone to the incinerating device while a part of it was sent to the gas sampling unit. The gas samples were collected in several gas sampling Tedlar bags for further analysis using Gas Chromatograph (GC). The GC (Agilent Technology, 4890) was equipped with a thermal conductivity detector (TCD). A packed Carboxene 1000 (Supelco, USA) column (15 ft 1/8 in, 80/100 mesh) was used to measure the mole fraction of permanent gases. External standard method obtained from 6 tanks of simulation gas was used to calculate the composition of the producer gas. Temperature programmed GC analysis was carried out with initial oven temperature set at 35 C, then it was gradually increased to 210 C at a rate of 20 C/min. The injector and detector temperatures were 150 and 220 C, respectively. Helium was applied as carrier gas at a rate of 35 ml/min.

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3. Results and Discussions 3.1. Producer gas composition In order to investigate the effect of temperature and bed material on the composition of producer gas, the bed temperature was varied in the range of 650 to1050 oC. The results are depicted in Fig. 2 (a) to (d). As observed in Fig. 2 (a) increasing the bed temperature from 650 to 1050 oC improved the H 2 content of the producer gas from 7.3 to 12.4% and 11.1 to 16.8% for silica sand and dolomite, respectively. Such increase in the H 2 level of the producer gas was due to the improvement of the endothermic reactions (1-3) involved in the gasification process: CH 4 + H 2 O CO + 3H 2 CH 4 + 2H 2 O CO 2 + 4H 2 CH 4 + CO 2 2CO + 2H 2 H= +206 kJ/mol H= +165 kJ/mol H= +247 kJ/mol (1) (2) (3)

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Fig 2. Effect of bed temperature and bed material on producer gas composition

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Beside the contribution of the endothermic reforming reactions in increasing the H 2 concentration, the remarkable higher H 2 concentration obtained using dolomite in comparison to sand was confidently related to the improved tar cracking reactions (4-6): C n H m (tar) + nH 2 O (n + m/2) H 2 + nCO C n H m (tar) + nCO 2 (m/2) H 2 + 2nCO C n H m (tar) (m/2) H 2 + nC H > 0 H > 0 H > 0 (4) (5) (6)

The variation of CO level of the producer gas with respect to the bed temperature is presented in Fig. 2 (b). The obtained result revealed the positive effect of the bed temperature on CO content. As the bed temperature was raised from 650 to 1050 oC, the CO level increased from 11.5 to 19.8% and 16.2 to 18.7 for silica sand and dolomite, respectively. It was inferred that improved char gasification reactions (7 and 8) as well as methane reforming reactions (1-3) were the main cause of such increase at high temperatures [12]: C + H 2 O CO + H 2 C + CO 2 2CO H= +131 kJ/mol H= +172 kJ/mol (7) (8)

Fig. 2 (C) shows the CH 4 level of the producer gas at various applied bed temperatures. The maximum CH 4 level of 3.8 and 3.6% was obtained at 750 oC for silica sand and 650 oC for dolomite, respectively. The results showed that the CH 4 content of the producer gas follows a reducing trend for both silica sand and dolomite at high gasification temperatures. High temperature favors endothermic methane reforming reactions, thus reducing the CH 4 content of the producer gas. The variation of CO 2 level of the producer gas with respect to the bed temperature is presented in Fig. 2 (d).The high concentration of CO 2 was observed at low temperatures and then a drastic decrease at temperatures above 850 oC was experienced for both sand and dolomite. At low temperatures, CO 2 is produced through water-gas shift reaction (9) but high temperature promoted its evolution via methane reforming (2). However, the generated CO 2 was consumed through methane dry reforming (3), tar cracking (5) and Boudouard reaction (8) to yield more H 2 and CO and lead to a decrease in CO 2 level at temperatures above 850 o C. The lowest CO 2 content of 17.4 was achieved at 1050 oC for both sand and dolomite. CO + H 2 O CO 2 + H 2 H= - 41.98 kJ/mol (9)

3.2. Gasification performance Fig. 3 (a) illustrates the effect of bed temperature on high heating value (HHV) of the producer gas for sand and dolomite. As explained earlier, high temperatures enhanced the evolution of combustible gases especially H 2 and CO which in turn resulted in an increase in HHV of the producer gas. The HHV of the producer gas increased from 3.3 to 5.3 MJ/Nm3 and 4.9 t o 5.5 M J/Nm3 for silica sand and dolomite, as the bed temperature was increased from 650 to 1050 oC. Variations of dry gas yield with respect to bed temperature are shown in Fig. 3 (b) for silica sand and dolomite. Increase of the bed temperature improved the dry gas yield from 1.3 to 1.8 Nm3/kg and 1.5 t o 1.8 Nm3/kg for dolomite, respectively. Increase in dry gas yield may be

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originated from the promotion of initial pyrolysis rate at high temperatures which increased the gas production as well as steam cracking and reforming of tars at high temperatures. In addition, endothermic reactions of char gasification at elevated temperature (7 and 8) improved the dry gas yield [11]. The result of carbon conversion calculation is presented in Fig. 3(c) for sand and dolomite. As expected, high temperatures enhanced carbon conversion efficiency due to the improvement of water-gas and Boudouard reactions (7 and 8) through which more carbon is converted to gaseous products. However, increase of the bed temperature beyond to 850 oC did not enhance carbon conversion due to the reduction of CO 2 content despite CO production. Improvement of cold gas efficiency with increasing the bed temperature for EFB and sawdust is depicted in Fig. 4 (d). The highest cold gas efficiency of 69 and 65% was achieved at 1050 o C for sand and dolomite due to the high dry gas yield and heating value.

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Fig 3. Effect of bed temperature and bed material on gasification performance

Agglomeration of the bed material was observed as the major concern in EFB fluidized bed gasification, especially at high temperatures. Such undesired phenomenon originated from the high K 2 O content of EFB (44%) which deteriorates the sintering and agglomeration tendency of the bed materials to form low melting eutectics [16]. Increase of the bed temperature

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beyond to 800 and 850 oC for silica sand and dolomite, resulted in the growth of bed particle. However, agglomeration with dolomite was not severe and the size of agglomerates was not considerable in comparison to silica sand agglomerates. 4. Conclusions Gasification of EFB as an abundant lignocellulosic waste was studied in an air blown pilotscale bubbling fluidized bed gasifier. The effect of bed temperature and catalytic bed material on the quality of the producer gas was assessed. The achieved results proved the potential of this biomass to generate energy as the HHV of 5.5 M J/Nm3 was obtained with dolomite. However, the agglomeration evolved at high temperatures was the main concern in EFB gasification. Thus, the EFB gasification experiments should be performed at temperatures below 850 oC to ensure the avoidance of any agglomeration. References [1] R. Saxena, D. Adhikari, H. Goyal, Biomass-based energy fuel through biochemical routes: a review, Renewable and Sustainable Energy Reviews 13, 2009, pp. 167-178. [2] J. Escobar, E. Lora, O. Venturini, E. Yez, E. Castillo,O. Almazan, Biofuels: Environment, technology and food security, Renewable and Sustainable Energy Reviews 13, 2009, pp. 1275-1287. [3] S. de Souza, S. Pacca, M. de vila, J. Borges, Greenhouse gas emissions and energy balance of palm oil biofuel, Renewable Energy 35, 2010, pp. 2552-2561. [4] M. Paisley, Biomass gasification system and method. 2001, Google Patents. [5] I. Narvaez, A. Orio, M. Aznar, J. Corella, Biomass gasification with air in an atmospheric bubbling fluidized bed. Effect of six operational variables on the quality of the produced raw gas, Industrial and Engineering Chemistry Research 35, 1996, pp. 2110-2120. [6] Z.A.B.Z. Alauddin, P. Lahijani, M. Mohammadi, A.R. Mohamed, Gasification of lignocellulosic biomass in fluidized beds for renewable energy development: A review, Renewable and Sustainable Energy Reviews 14, 2010, pp 2852-2862. [7] R. Warnecke, Gasification of biomass: comparison of fixed bed and fluidized bed gasifier, Biomass and bioenergy 18, 2000, pp. 489-497. [8] J. Zhou, Q. Chen, H. Zhao, X. Cao, Q. Mei, Z. Luo, K. Cen, Biomass-oxygen gasification in a high-temperature entrained-flow gasifier, Biotechnology advances 27, 2009, pp. 606611. [9] R. Moghadam, A. Alias, Air Gasification of Agricultural Waste in a Fluidized Bed Gasifier: Hydrogen Production Performance, Energies 2, 2009, pp. 258-268. [10] K. Mansaray, A. Ghaly, A. Al-Taweel, F. Hamdullahpur,V. Ugursal, Air gasification of rice husk in a dual distributor type fluidized bed gasifier, Biomass and bioenergy 17, 1999, pp. 315-332. [11] F. Pinto, C. Franco, R. Andre, C. Tavares, M. Dias, I. Gulyurtlu, I. Cabrita, Effect of experimental conditions on c o-gasification of coal, biomass and plastics wastes with air/steam mixtures in a fluidized bed system, Fuel 82, 2003, pp. 1967-1976. [12] P. Lv, Z. Xiong, J. Chang, C. Wu, Y. Chen, J. Zhu, An experimental study on biomass air-steam gasification in a fluidized bed, Bioresource Technology 95, 2004, pp. 95-101.

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[13] G. Xu, T. Murakami, T. Suda, Y. Matsuzaw, H. Tani, Two-stage dual fluidized bed gasification: Its conception and application to biomass, Fuel Processing Technology 90, 2009, pp. 137-144. [14] M. Campoy, A. Gmez-Barea, F. Vidal, P. Ollero, Air-steam gasification of biomass in a fluidised bed: Process optimisation by enriched air, Fuel Processing Technology 90, 2009, pp. 677-685. [15] G. Schuster, G. Lffler, K. Weigl, H. Hofbauer, Biomass steam gasification-an extensive parametric modeling study, Bioresource Technology 77, 2001, pp. 71-79. [16] P. Lahijani, Z.A. Zainal, Gasification of Palm Empty Fruit Bunch in a Bubbling Fluidized Bed: A Performance and Agglomeration Study, Bioresource Technology 102, 2011, pp. 2067-2076.

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