Jee Main 2025 Brahmanda Practice Material-2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

Sri Chaitanya IIT Academy.,India.


 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sr.Elite,Target & Star
PHYSICS
RPTM-01
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Which of the following represents smallest and largest rise in temperature?
1) 1 0 F ,10 C 2) 1 0 R,10 C 3) 1 K ,10 R 4) 1 0 F ,10 R
Key: 4
Sol: No. of divisions in Fahrenheit scale = 180
No. of divisions in Reaumur scale = 80
(Between LFP and UFP)
2. S-I : When a bimetallic strip made of iron and brass is heated, then it bends in form of
concave towards brass.
S-II : The coefficient of linear expansion of iron is less than brass
1) Statement I is true, Statement II is true 2) Statement I is true, Statement II is false
3) Statement I is false, Statement II is true 4) Statement I is false, Statement II is false
Key: 3
Sol: As brass expands more than iron on heating,  Brass   Iron  , bimetallic strip bends with
brass on convex side
3. Identify the correct statements from following:
a) Apparent expansion of liquid depends on the expansion of material of container
b) Real expansion of liquids depends on the density of liquid
c) Expansion of liquid with respect to the container is called apparent expansion.
1) Only a and b are true 2) a, b and c are true
3) Only b and c are true 4) Only a and c are true
Key: 2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Sol: Conceptual
4. Heat is supplied to 2 kg of solid (initially at 200 C ) at the constant rate of 5 kJ/min.
Temperature is plotted as a function of time as shown in the figure. Latent heat of fusion
for solid is

1) 10 kJ/kg 2) 2.5 kJ/kg 3) 5 kJ/kg 4) 7.5 kJ/kg


Key: 3
Sol: Q  mL
Q  Heat supplied = 5 KJ/ min
During phase change,

Heat absorbed by solid = Q   4  2  min  5  2  10 KJ

10 KJ
L  5 KJ / Kg
2 Kg
5. Assertion(A) : The total translational KE of all the molecules of a given mass of ideal gas
is 1.5 times the product of its pressure and volume
Reason(R) : Molecules of gas collide with each other and the velocities of molecules
change due to the collision
1) Both A & R are correct and R is the correct explanation of A
2) Both A & R are correct but R is not the correct explanation of A
3) A is correct but R is not correct 4) A is not correct but R is correct
Key: 2
3 3
Sol: Total translational KE = nRT  PV  1.5 PV
2 2
(NUMERICAL VALUE TYPE)

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. A water heater of power 2000 W is used to heat water. The specific heat capacity of
water is 4200 J kg 1 K 1 . The efficiency of heater is 70%. Time required to heat 2 kg of
water from 100 C to 600 C is _______s. (Assume that the specific heat capacity of water
remains constant over the temperature range of the water).
Key: 300
Sol: Heat provided to water will be responsible for increase in temperature. Therefore,
We can write   P  t  M  s  T
70
Now,    0.7 and energy = power x time.
100

Therefore, t 

2  4200  600  100  s  300 s
0.7  2000
7. Two identical calorimeter A and B contain equal quantity of water at 200 C . A 5 gm piece
of metal X of specific heat 0.2 cal g 1  0 C  is dropped into A and a 5 gm piece of metal Y
1

into B. The equilibrium temperature in A is 220 C and in B 230 C . The initial temperature
of both the metals is 400 C . If specific heat of metal Y in cal / gm / 0 C is X . Find X+Y.
Y
[Here, X and Y have no common factor]
Key: 112
Sol: Quantity of water : (m=mass of water)
In calorimeter A,
Heat lost by metal X = Heat gained by water

 5  0.2   40  22   m  1   22  20   m  9 gms
In calorimeter B, Heat lost by metal Y = Heat gained by water

 5  S y   40  23   9  1   23  20   S y  9  3  27  x  y  27  85  112
5  17 85
8. A steam engine intakes 50 g of steam at 1000 C per minute and cools it down to 200 C . If
latest heat of vaporization of steam is 540 cal g 1 , then the heat rejected by the steam
engine per minute is ____ 103 cal.
Key: 31

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Sol: Heat rejected = mL f  mS T =  50  540   50 1100  20  = 31000 Cal = 31  103 Cal

9. A non-isotropic solid metal cube has coefficients of linear expansion as : 5  105 / 0 C along
the x-axis and 5  106 / 0 C along the y and the z-axis. If the coefficient of volume
expansion of the solid is C  106 / 0 C then the value of C is __________
Key: 60
Sol: The coefficient of volume expansion

   x   y   z  5  105  5  106  5  106   50  5  5   106

  60  106 ; C  60 ;

10. The total internal energy of two mole monoatomic ideal gas at temperature T  300 K will
be ______ J. (Given R  8.31 J / mol.K )
Key: 7479
3
Sol: U  nCV T  2  R  300  900 R  900  831  7479 J
2

11. The water equivalent of a calorimeter is 10 g and it contains 50 g of water at 150 C . Some
amount of ice initially at 100 C is dropped in it and half of ice melts till equilibrium is
reached; The initial amount of ice that was dropped is ________ (gms)
( sice  0.5 cal gm 1 0C 1; swater 1 cal gm 1 0C 1 ; Lice  80 cal gm 1 )

Key: 20
Sol: Heat lost = Heat gained by caloriemeter system by ice
m
 m  0.5  10    80   50  10   1  15  m  20 gms
2

12. If the coefficient of real expansion  r is 1% more than coefficient of apparent expansion,
r
then the linear expansion of the material is . The value of N is _________
N

Key: 303
Sol:  R   A  3  R  1.01 A

 R 100  R    A 1  R  R
A    R   
1.01 101 3 3  101  303

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-02
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. In a cyclic process shown in the figure an ideal gas is adiabatically taken from B to A, the
work done on the gas
During the process B  A is 30 J, when the gas is taken from A  B the heat absorbed by
the gas is 20J. The change in internal energy of the gas in the process A  B is

1) -30 J 2) 30 J 3) -60 J 4) -60 J


Key: 1
Sol: WBA =-30J, QBA =0; ΔU BA =-WBA =-30J
Now, ΔU AB =-ΔU BA =-30J
2. P – V diagram of a diatomic gas is a straight line passing through origin. The molar heat
capacity of the gas in the process is (Nearly)
R
1) 2) 2R 3) 4 R 4) 3R
2
Key: 4
Sol: P-V diagram of the gas is a straight line passing through origin. Hence,
P  V or PV -1 =constant  x=-1
R R
Molar heat capacity in the process C= +
γ-1 1-x
Hence, γ=1.4 (for diatomic gas)
R R
 C=  or C  3R
1.4  1 1  1
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
3. Two bodies A and B have thermal emissivity’s of 0.01 and 0.81 respectively. Their
surface areas are equal and radiant powers are equal. If the temp of A is 5820K, then
temp of B is _____ K.
Key: 1940
Sol: Conceptual
4. If a black body is radiating at T = 1650 K, the wavelength at the maximum intensity is
(in μm ) ( Wein’s Constant b= 0.298 cm-K)
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Key: 2
Sol: According to Wien’s law,
mT  2.9  10 3 mK
2.9 103
max  1.8 m
1650
5. A diatomic gas  γ=1.4  does 300 J of work when it is expanded isobarically. The heat
given to the gas in the process is ____________ J.
Key: 1050
Sol: Work done = PΔV  300=PV  300  nR T   P V  nRT at constant pressure 
Rγ γ 1.4
Now, Q=nC P ΔT =n ΔT=300× =300× =1050 J
γ-1 γ-1 0.4
6. A cylinder with fixed capacity of 67.2  contains helium gas at STP. The amount of heat
needed to raise the temperature of the gas by 100C is: [Given that R = 8.31Jmol-1K -1 ] (in J)
(nearest integer)
Key: 374
67.2 3R
Sol: As the process is isochoric so, Q=ncv T   10  45 R  45  8.31  374 J
22.4 2
7. A heat engine operates with the cold reservoir at temperature 324 K. The minimum
temperature of the hot reservoir, if the heat engine takes 300 J heat from the hot reservoir
and delivers 180 J heat to the cold reservoir per cycle, is _______________ K.
Key: 540
QL T Q T Q 300
Sol: Efficiency   1   1  L  L  L  TH  TL  H  324 
QH TH QH TH QL 180  540 K
8. A wall has two layers A and B, each made of different material. Both the layers have the
same thickness. The thermal conductivity of the material of A is twice that of B. Under
thermal equilibrium, the temperature difference across the wall is 360C . The temperature
difference across the layer A is in C0 .
Key: 12
Sol: Under thermal equilibrium, θ A -θ B =360 C (Given)
KA K
 A  B B 2 A   B 2 A   A  36 3  A  12 
K A =2K B (Given) C    C   
K A KB 3 3 3

 
 A   C  120 C Hence, the temperature difference across the layer A=120C
Dia 318
9. A body cools in 7 minutes from 60 C to 40 C . The temperature of the surrounding is 100C .
0 0

The temperature of the body after the next 7 minutes will be


Key: 28
Sol: From the Newton’s law of cooling
T1 -T2  T +T  60  40  60  40  20 1
=K  1 2 -Ts   K  10    40 K  K 
t  2  7  2  7 14
40  T 1  40  T 
&    10   T  280 C
7 14  2 
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-03
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Figure shows an arrangement of an equiconvex lens  f  20 cm in air  and a concave
mirror  R  80 cm  . A point object ‘O’ is placed on the principal axis at a distance 40 cm
from the lens such that the image is also formed at the position of object. Find d

1) 20 cm 2) 30 cm 3) 40 cm 4) 50 cm
Key: 2
R1
Sol: For the lens in air, f 0 
2 2  1
R1
20   R1  20cm
2 1.5  1
R1  R2  R1
3 1 2  1 2  3
  
v u R1 R2
here 3  2, 1  1.2, 2  1.5
Lens forms a virtual image I1 at a distance of 50cm from it. This act as real object to the
concave mirror.
If PL1  R  80cm, the rays after reflection from mirror retrace, their path and the final
image is formed at ‘O’ itself. Hence d  Pl1  50  80  50  30cm
2. A converging lens of refractive index 1.5 has a power of 25D. When it is completely
immersed in a liquid, it behaves as diverging lens of focal length 40 cm. Find the
refractive index of the liquid.
1) 1.58 2) 1.34 3) 1.43 4) 1.88
Key: 1
1 1
Sol: fa   m  4cm
p 25
1  1 1 
  a  g  1   
fa  R1 R2 
1  1 1 
 1.5  1   
4  R1 R2 
1 1 1
 
R1 R2 2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
1  g  1
a
1 
When the lens is immersed in water   a  1   
f L  l   R1 R2 
Given f L  40cm
a
l  1.58
3. A bird B in air is diving vertically downwards over a water tank with speed 5 cm/s. Base
of the tank is silvered. A fish ‘F’ in the tank is rising vertically upwards along the same
line with speed 2 cm/s. Water level is lowered at the rate of 2 cm/s. Tank  water  4 / 3
Column-I Column-II
A Speed of image of fish as seen by the bird directly in cm/s P 4
B Speed of image of fish formed after reflection in the mirror as seen Q 8
by the bird in cm/s
C Speed of image of bird as seen by the fish looking upwards in cm/s R 3
D Speed of image of bird as seen by the fish looking downwards in S 6
cm/s

1) A  S , B  R, C  Q, D  P 2) A  S , B  R, C  Q, D  Q
3) A  S , B  R, C  P, D  P 4) A  P, B  R, C  Q, D  S
Key: 1
Sol: Conceptual
 4
4. A container is filled with water  n   up to height of 40cm. A concave mirror is placed
 3
20cm above water level and the image of an object placed at the bottom is formed 25 cm
below the water. The focal length of mirror (in cm) approximately equal to
1) 29 2) 22 3) 30 4) 35
Key: 2
40  3
Realdepth
Sol: Apparent depth    30cm
 4
25
Distance of image from mirror  20   38.79cm
4
3
40  3
Distance of object from mirror  20   50cm
4

For concave mirror f 


uv

 50 38.79 
uv 50  38.79
f  21.8cm
5. Given below are two statements: one is labeled as Assertion A and the other is labeled as
Reason R.
Assertion A: For a simple microscope, the angular size of the object equals the angular
size of the image.

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Reason R: Magnification is achieved as the small object can be kept much closer the eye
than 25cm and hence it subtends at a larger angle.
In light of the above statements, choose the most appropriate answer from the options
given below:
1) Both A and R are true but R is NOT the correct explanation A
2) Both A and R are true and R is the correct explanation A
3) A is true but R is false
4) A is false but R is true
Key: Conceptual
Sol: 2

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. A triangular prism of glass is shown in the figure. A ray incident normally to one face is
totally reflected. If   450 , then minimum integral value of refractive index of glass is

Key: 2
1
Sol: For total internal reflection   
sin 
  1.41
7. A compound microscope consists of an objects lens of focal length 1 cm and an eye piece
of focal length 5cm with a separation of 10 cm. The distance between an object and the
n
objective lens, at which the strain on the eye is minimum is cm . Then value of n is ?
40
Key: 50
Sol: Length of compound microscope, L  10cm
f 0  1cm; f e  5cm
0  f c  5cm
Final image formed at 
ve  
V0  10  5  5
Using lens formula
1 1 1 1 1 1
    
V u f V0 u0 f 0
1 1 1 5
   u0 
5 u0 1 4

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
5 n

4 40
n  50
8. A bi-Convex lens is formed with two plano convex lenses as shown in figure. Refractive
index of the first lens is 1.5 and of the second lens is 1.2. Both the curved surfaces are of
the same radius of curvature R=14cm. For this biconvex lens, for an object distance of
40cm, the image distance (in cm) will be__

n  1.5 n  1.2

R  14cm
Key: 40
1  1 1  0.5
Sol: or the first lens  1.5  1    
f1  14   14
1 1 1  0.2
For the second lens  1.2  1   
f2   14  14
0.5 0.2 1
Focal lens of biconvex lens   
14 14 20
1 1 1
Acc to thin lens formula  
 40 20
v  40cm
9. A lens is placed between a candle and on fixed screen forms a real triply magnified image
of the candle on the screen. When lens is moved away from the candle by 0.8m without
changing the position of the candle, a real image one third the size of the candle is formed
x
on the screen. The focal length of the lens (in m ) is . The value of x is
10
Key: 3
Sol: As the object and image position are interchangeable when the lens is moved by 0.8 the
image distance becomes x

I
O

x 0.8m x

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
v 0.8  x
m   3
u x
x  0.4
1 1 1 1 1
   
f v u 1.2 0.4
f  0.3m
10. An astronomical telescope has angular magnification of 5 for distant objects. When image
is formed at infinity, the length of the telescope is 36 cm. The focal length of the eye-piece
(in cm) is :
Key: 6
Sol:
fo
m  5  fo  5 fe
fe
Also, f o  f e  L
5 f e  f e  36
f e  6 cm
11. As show in the figure, a plane mirror is fixed at a height of 50cm from the bottom of tank
containing water     . The height of water in the tank is 8cm. A small ball is placed at
4
 3
the bottom of the water tank. The distance of image of the bulb formed by mirror from
the bottom of the tank is …..cm.

50cm
8cm

Key: 98
 1
Sol: x   1   d
 
 1
Image distance formed in plane mirror  h  x  n   1   d  48
  
From the bottom the distance is = 48+50= 98cm
12. A plano convex lens of refractive index 1.5 and radius of curvature 30 cm is silvered at the
curved surface. Now this lens has been used to form the image of an object. At what
distance from this lens an object needs to be placed in order to have a real image of the
same size as that of the object.
Key: 20
Sol: As the curved surface of a plano convex lens is silvered, the focal length of the lens is given
1 2
by 
F R

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
R 30
F   10.cm
2  2  1.5
The real image will be the size of the object if the object is placed at u  2 F  20cm
13. A point object lies inside a transparent solid spheres of radius 20cm and of R.I.=2. When
the object is viewed from air through the nearest surface it is seen at a distance 5cm from
the surface. The apparent distance of object (in cm) when it is seen through the farthest
curved surface is ____
Key: 80
Sol: When seen from air through nearest surface

1 2 1 2
 
5 u 20
u  8cm
For second case u    40  8  32cm
1 2 1 2
  v  80cm
v 32 20
14. A fish looking up through the water sees outside world, contained in circular horizon. If
the R.I of water is 4/3 and the fish is 10cm below the water the radius of the circle is
30
cm x is
x
Key: 7
h 10 30
Sol: R  
 1
43 7
2 2
1
The real image will be the size of the object if the object distance u  2 F  20cm

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-04
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A progressive wave travels in a medium M1 and enters into another medium M 2 in which
its speed decreases to 75% . Ratio of amplitude and intensity of transmitted and incident
waves.
6 36 7 36 1 1 7 21
1) , 2) , 3) , 4) ,
7 49 6 49 7 49 3 9
Key: 1

At 2V2 3
Sol:  V2  V1
Ai V2  V1 4
I  A2
2. Which one of the following does not represent a travelling wave?
1) y  sin  x  vt  2) y  ym sin k  x  vt 

3) y  ym log  x  vt  
4) y  f x 2  vt 2 
Key: 4

Sol: Conceptual
3. A pressure of 100 kPa causes a decrease in volume of water by 5  103% . The speed of
sound in water is
1) 712 m / s 2) 340 m / s 3) 1414 m / s 4) 1000 m / s
Key: 3

P 
Sol: B V    1000 kg / m3
V 
V
4 The maximum number of possible interference maxima for slit separation equal to twice
the wavelength in young’s double slit experiment is
1) 3 2) 5 3) infinite 4) zero
Key: 2

Sol: d sin   n
Given d  2
2 sin   n
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
n
sin  
2
n  0,1,1,2, 2
5. Statement-1: Pitch of sound depends on intensity of wave
Statement-2: loudness of sound depends on frequency of wave
1) Both statement 1 and 2 are true 2) Statement-1 is true statement-2 is false
3) Statement-1 is false statement-2 is true 4) Both statements are false
Key: 4

Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. A tuning fork is vibrating at 250 Hz. The length of the shortest closed organ pipe that will
resonate with a tuning fork will be _____cm. (Speed of sound = 340 ms 1 )
Key: 34

V
Sol: 250  L  0.34 m
4L
L  34 cm
7. If the length of stretched string is shortened by 40% and tension is increased by 44%,
then the ratio of final and initial fundamental frequencies is x:1, where x =_____
Key: 2

T
Sol: n

n1 T  100 60 1
 1 2  
n2 T2 1 144 100 2
8. The ratio of speed of sound in nitrogen gas to that in helium gas at 300K. (both are
assumed to be ideal gases) is x : 5 , where x 
Key: 3


Sol: V 
M
9. A string of length  hangs freely from a rigid support. The time required by a transverse
x
pulse to travel from bottom to half-length of string is where x 
g

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Key: 2

Sol: Conceptual
10. A sonometer is set on the floor of a lift. When the lift is at rest, the sonometer wire
9g
vibrates with frequency 256 Hz. When the lift goes up with acceleration a  , the
16
frequency of vibration of same wire in Hz changes to _____
Key: 320

Sol: n g
n' ga

n g
11. A light ray incident on a transparent medium of   1.732 at the polarizing angle. The
angle of refraction is ____degrees.
Key: 30
Sol:

12. When temperature rises by 10 C then velocity of sound in air increases by ____cm/s.
[given: initial temperature is 0ºC)
Key: 61

Sol: Conceptual
13. Two sound waves of frequency 210 Hz and 225 Hz travel in the same direction and
superimpose on each other, the number of beats heard by a person are _____
Key: 0
Sol: Conceptual

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-05
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A particle having SHM is located at different positions as shown below. The phase
difference between the position marked by A and
y0
A

B
C
D
E


1) B is radian 2) C is  radian 3) D is > 2  radian 4) E is 2  radian
2
KEY: 1

SOL: In diagram, B particle is at extreme position, so phase difference is , In ‘C’ phase
2
difference is <  .

2. Statement (I): The force of attraction due to a hollow spherical shell of uniform density
on a point mass situated inside it is always positive.

Statement (II): The force of attraction between a hollow spherical shell of uniform
density and a point mass situated outside is same just as if the entire mass of the shell is
at the centre of the shell.

Which of the following is correct?

1) Both statements I and II are true 2) Statement I is true, but statement II is false
3) Statement II is true, but statement I is false 4) Both statements I and II are false
KEY: 3

SOL: Inside the shell, E  0

So no net force will act on the point mass so (I) is false.

Also hollow spherical shell behaves like point mass placed at center of shell for point
outside the shell so (II) is correct

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
3. Potential energy of a body of mass 1 kg free to move along X-axis is given by
 x2 
U ( x )    x  J .If the total mechanical energy of the body is 2J, then the maximum
 2 
speed of the body is (Assume only conservative force acts on the body)
1) 5 ms 1 2) 5 ms 1 3) 3.5 ms 1 4) 8 ms 1
KEY: 1
SOL: Conceptual

4. 9 kg solution is poured into a glass U-tube as shown in the figure below. The tube's inner

diameter is 2 and the solution oscillates freely up and down about its position of
5
equilibrium (x = 0). The period of oscillation in seconds is (1 m³ of solution has a mass

μ = 900 kg, g = 10 m/s², ignore frictional and surface tension effects)

1) 0.1 2) 10 3)  4) 1

KEY: 1

SOL: Diameter of tube, D  2 m
5


Radius of tube (r )  m
5

Mass of solution m = 9 kg
We know that, Mass  (m)   v
2
   2 5
 m   L  9  900    
2
 L  9  900  L ...(i )
 5  5 100 2

L
Time period of oscillation of solution T  2
2g

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
5 1 2
Substituting the respective value, we get T  2  T  2   T  0.1 s
200 10
2
400 20

5. Two particles execute S.H.M of the same amplitude and frequency along the same
straight line. They pass one another when going in opposite directions each time their
displacement is half their amplitude. The phase difference between them is
1)  / 3 2)  / 4 3) 2 / 3 4) 3 / 4
KEY: 3
SOL: S.H.M equation y  A sin t   

A
Since  A sin(t   )   t    300 or 1500
2

Since the two particle are going in opposite direction the phase of one is 300 and other is
150 0 hence phase difference = 120 0 .

6. A body is on a rough horizontal surface which is moving horizontally in S.H.M of


frequency 2 Hz. The coefficient of static friction between the body and the surface is 0.5.
The maximum value of the amplitude for which the body will not slip along the surface is
approximately

1) 9 cm 2) 6 cm 3) 4.5 cm 4) 3 cm

KEY: 4
SOL: Angular frequency   2 f  4 rad / s

Magnitude of maximum acceleration  amax   2 A

Where A is amplitude

2 A  g

 g 0.5  10
A   3cm
2 16 2
7. What is the period of the small oscillation of the block of mass m if the springs ideal and
pull is massless?

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
 m  m  2m m
1) 2) 3) 4) 
2 k 2 2k 2 k 2k

KEY: 1
m
SOL: T  2
keq

Fnet  (4k )(4 x)  16kx  keq  16k

8. Two identical balls A and B each of mass 0.1 kg are attached to two identical massless
springs. The spring mass system is constrained to move inside a rigid smooth pipe bent in
the form of a circle as shown in the figure. The pipe is fixed in a horizontal plane. The
centres of the balls can move in a circle of radius 0.06 m. Each spring has a natural length
of 0.06 m and force constant 0.1N/m. Initially both the balls are displaced by an angle  =
π/6 radian with respect to the diameter PQ of the circle and released from rest. The
frequency of oscillation of the ball B is

1 1
1)  Hz 2) Hz 3) 2 Hz 4) Hz
 2

KEY: 2
SOL: As here two masses are connected by two springs this problem is equivalent to the
oscillation of a reduce mass mr of a spring of effective spring constant.

mr
T  2
keff

m1m2 m
here mr   ;  K eff .  K1  K 2  2 K
m1  m2 2

1 K eff 1 2K 1 K 1 0.1 1
n   2    Hz
2 mr 2 m  m  0.1 

(NUMERICAL VALUE TYPE)


JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 20
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

M
9. The time period of simple harmonic motion of mass M in the given figure is  ,
5k
where the value of  is

KEY: 12
2k  k 5k
SOL: keq  k 
3k 3

keq
Angular frequency of oscillation ( ) 
M

5k
( ) 
3M

2 3M 12m
Period of oscillation ( )   2 
 5k 5k

10. In the given spring block system if k  25 2 Nm 1 , then find time period of oscillation.

KEY: 1
m1m2 m
SOL:     2.5kg
m1  m2 2

k
2k 
2  2k  2  25  10 2
2
Keq 
k 5 5
2k 
2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
 2.5 2 2.5 2
T  2  2    1sec
k 10 2
 10   2

11. A binary star consists of two stars A (mass 2.2M s ) and B (mass 11M s ), where M s , is the
mass of the sun. They are separated by distance d and are rotating about their centre of
mass, which is stationary. The ratio of the total angular momentum of the binary star to
the angular momentum of star B about the centre of mass is :-
KEY: 6
SOL: Conceptual
12. A satellite is seen after each 8 hours over the equator at a place on the earth when its
sense of rotation is opposite to the earth. The time interval after which it can be seen at
the same place when the sense of rotation of earth & satellite is same will be:

KEY: 24
SOL: Let angular velocity of earth is 1

Let angular velocity of satellite is 2 then relative angular velocity when both are rotating
in opposite direction = 1  2

2
T
1  2

2
8
2 2

T1 T2

24T2
8 (T1  24 Hr for earth)
24  T2

T2  12 Hr

Now, when both are rotating in same directions

relative  2  1

2
T
2  1

T  24 Hr

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
13. At certain height h from surface of earth, the value of g becomes 6.25% of its value of
h
surface of earth. The ratio of is (R is radius of earth).
R
KEY: 3
SOL: Let height be h
GM e
So g 1 
( Re  h) 2

GM e
g
( Re ) 2

2
g 1  Re  6.25
  
g  Re  h  100

h  3Re

14. In the reported figure of earth, the value of acceleration due to gravity is same at point A
and C but it is smaller than that of its value at point B (surface of the earth). The value of
OA: AB will be x:5. The value of x is..........

KEY: 4
SOL:
15. If one wants to remove all the mass of the earth to infinity in order to break it up
x GM 2
completely. The amount of energy that needs to be supplied will be where x is
5 R
(Round off to the Nearest Integer) (M is the mass of earth, R is the radius of earth, G is
the gravitational constant)
KEY: 3

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
GM (r )
SOL: g A 
R3

GM
gC  2
 R
R 
 2

g A  gC

r 1 4r
 r
R 3
9 2 9
R
4

OA : AB  4 : 5

16. A block of mass 5kg moves along the x-direction subject to the force F  (20 x  10) N,
with the value of x in meter. At time t = 0 s, it is at rest at position x = 1 m. The

magnitude of momentum of the block at t  s is
4
KEY: 5
SOL: Given F   20 x  10  N

1
F  20( x  )
2

F   Kx1

so K  20

K 20
  2
m 5

2
T 


so t  particle is at mean position
4

Now P  m( A)

P  5kg m / s .

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-06
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. (A): A electric field in front of infinite charged sheet is independent of distance of
point from sheet
(B): Electric field in front of finite charged sheet is dependent on distance of point
from sheet
1) A & B are false 2) A true, B false 3) A & B are true 4) A false, B true
Key: 3

Sol: E 
0
2. Assertion: Gauss theorem can be applied only for a closed surface.
Reason: Electric flux can be obtained passing from a closed surface only.
1) Both assertion and reason are correct and R is the correct explanation of Assertion.
2) Both assertion and reason are correct and R is not the correct explanation of
Assertion.
3) Assertion is true, Reason is false.
4) Assertion is false, Reason is true.
Key: 3
Sol: Gauss theorem applied only for closed surface but electric flux can be obtained passing
from an open surface also.

3. A point charge Q is located on the axis of a disc of radius R at a distance “a” from
the plane of the disc. If the flux from the charge that passes through the disc is
2 3
  times the total flux, then the relation between a and R is.
 4 

1) a  R 3 2) a  R 2 3) a  R 5 4) a  2R
Key: 1
Sol:

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

R

a q

Solid angle()  2 (1  cos )

 a 
  2  1  
 
 a2  R2 

 q
Flux through disc 
4 0

But given that

 q 2 3 q
 
4 0  4  0

2  a  1 3
1   
4   2 4
 a2  R2 

1 a 1 3
  
2 2 a2  R2 2 4

a 3

2 a2  R2 4

Squaring on both sides

a 3

4 a2  R2 16

4a 2  3R 2  3a 2

a 2  3R 2

a  3R

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
4. A point charge q1  4q0 is placed at origin. Another point charge q 2  q0 is placed at
x=15 cm. Charge of proton is 2q0 . The proton is placed on x- axis so that the
electrostatic force on proton is Zero, then the position of the proton from the
origin__________________ cm.
Key: 30
q0 2q0
4q0
15

Sol:
x
F1  F2  0

k 4q 0  2q 0  k  q 0  2q 0 
 0
x2  x  15  2

4 1
 0
2
x  x  15 2
4 1

x2  x  15 2
2 1

x x  15

2x  30  x

x  30 cm

5. The volume charge density of a sphere of radius 6m is 8.89 C cm3 . The number of
lines of force per unit surface area coming out from the surface of sphere is
_____________ 1010 NC 1 .   8.89  10 12 C 2 / N  m 2 
  
Key: 200

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
r 8.89  10 6  10 6  6
Sol: E 
3t 0 3  8.89  10 12

2  1012

200  1010 N /C
6. An electric dipole of dipole moment is 6  109 cm placed in a uniform electric field of

2.5  106 N /C; in such a way that dipole is along the electric field. The work done in
rotating dipole by 180 0 in this field will be________________ milli Jouls.
Key: 30
Sol: w  PE  cos 1  cos 2  1  0

2PE 2  180

 2  6  10 9  2.5  106

30  10 3

30 mJ

7. An electric charge 10 3 C is placed at the origin (0,0) of x-y co-ordinate system. Two

points A and B are situated at  


5 ,2 5 and (5,0) respectively. The potential difference

between the points A and B will be.


A 5,2 5 

B
103c (5,0)
Key: 0
Sol: . For A

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

A  5,2 5 

B
(5,0)

   2 
2 2
OA  5 0 5 0

a 5  20  5

VA 
kq


k 10 3 
a2 25

For B

OB  5  b

VB 
kq


k 10 3 
b2 25

VA  VB  0

8. On moving 20 mc charge by 2 cm, 4 J of work is done then the potential difference


between the points in volts is__________
Key: 200
w 4 400
Sol: w   dv  q ,  dv      200 V
q 20  10  3 2

9. If the electric potential of the inner shell is 15V and that of the outer shell is 4V,
then the potential at the center will be

Key: 15

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Sol: As the potential of inner metal sphere is 15V, the potential at the centre will be 15V.

10. An electric charge 4  10 8 C is placed at point (2, 3, 4) m. The electric potential At


(5,3,0) m is
Key: 72
Sol: . d  5  2 2   3  3 2   0  4 2  9  0  16  5

1 q 9  109  4  10 8 360
v    72
4 t0 d 5 5
11. Two small dipoles of moment “P” are placed as shown in the figure. The force between
nkp2 1
the two dipoles is Find “n” [where k  ]
x4 4  0

P P

x
Key: 3
1 3P1P2
Sol: F
4 0 d 4
12. Find the magnitude of potential difference between point A and B in an electric field
  
E  2i  3j  4k NC 1 where rA  i  2j  k m and r B  2i  j  2k m .   
Key: 1
Sol: We know that dV   E.d r
(1, 2,1)

 2i  3 j  4k . dxi  dy j  dzk 


B
VAB  VA  VB    E.d r   
A  2,1, 2

(1, 2,1)
(1, 2,1)
 
(2,1, 2)
(2dx  3dy  4 dz )  (2 x  3 y  4 z )
(2,1, 2)
 1 volt

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-07
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A capacitor of capacitance 10 µ F is charged to a potential 50 V with a battery. The
battery is now disconnected and an additional charge 200 µ C is given to the positive
plate of the capacitor. The potential difference across the capacitor will be
1)50V 2)80V 3)70V 4)60V
Key: 4

Sol:
2. In the adjoining figure the potential difference between the points D and B will be

5 4 8 10
1) V 2) V 3) V 4) V
3 3 9 3
Key: 1

Sol:

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
3. Three conducting spheres A, B and C of radii a, b and c respectively are shown in figure.
The capacitance of the system, when A and B are connected by conducting wire is

1) 4 0     2) 4 0    
1 1 1 abc bc
 3) 4 0  a  b  c  4) 4 0  
 a b c  ab  bc  ca
   cb 
Key: 4

Sol:

4. Match Column - I with Column – II


Column – I Column-II
A) Electrical conductivity of a conductor p) dimensions (length and area of
depends on cross- section)
B) Conductance of a conductor depends q) temperature
on
C) For a given conductor and at a given r) nature of conductor
temperature, current density depends
on
D) For a given potential differences s) electric field strength
applied across a conductor, current in it
will depend on

1) A-qr; B-pqr; C-s; D-pqr 2) A-pqr; B-qr; C-s; D-pqr


3) A-pqr; B-qr; C-s; D-qr 4) A-pqr; B-qr; C-qs; D-pqr
Key: 1
Sol: Conceptual

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
5. Two identical capacitors each of capacitance ‘C’ are connected as shown. The plates 2
and 3 are connected by a light rigid conducting rod. The gap between the plates 1 and 2 is
‘d’ and is also same between the plates 3 and 4. Now the rod between 2 and 3 is shifted
towards right by a distance d/2 so that both the plates 2 and 3 are shifted by same. The
heat developed in doing so is

CV 2 CV 2 CV 2
1) Zero 2) 3) 4)
20 4 5
Key: 1
Sol: Effective capacitance remains uncharged.

6. Initially the system is as shown in figure and s1, s2 , s3 are open. Now s1, s2 , s3 are closed.
As a result, the charges on 6µF and 3µF respectively

1) 900  c,150  c 2) 600  c,150  c 3) 500  c, 250  c 4) 400  c, 450  c


Key: 1
Sol: Conceptual
7. Two identical capacitor having plate separation d0 are connected parallel to each other
across points ‘A’ and ‘B’ as shown in the figure. A charge ‘Q’ is imparted to the system
by connecting a battery across A and B, and battery is removed. Now, first plate of first
capacitor starts moving with constant velocity u0 towards left and second plate of the
second capacitor moves to left with constant velocity u0. The magnitude of current
flowing in the loop during this process is

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

Qu0 Qu0 2Qu0 2 Qu0


1) 2) 3) 4)
d0 2d 0 d0 3 d0

Key: 2
Sol: Let each plate moves a distance ‘x’ from initial position. Let q be the charge flows in the
loop

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
8. Two cells are connected in opposition as shown cell E1 is of 8 V emf and 2  internal
resistance, the cell E2 is of 2 V emf and 4  internal resistance. The terminal potential
difference of cell E2 is _______V.

Key: 6
Sol: Effective potential difference across the circuit is veff  8V  2V  6V

Effective internal resistance is, Reff  2  4  6


JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 34
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
veff 6V
 Current in the circuit =   1A
Reff 6

Consider the following figure

Applying Kirchhoff’s voltage law across point B and C.

VB  Vc   2  4 V  0

 Terminal potential difference of E2 is 6 V.

9. In an electric circuit, a cell of certain emf provides a potential difference of 1.25 V across
a load resistance of 5  . However, it provides a potential difference of1 V across a load
x
resistance of 2  . The emf of the cell is given by v. Then the value of x is_____
10
Key: 15
Sol: Let the emf be E and let the internal resistance is r.
V 1.25
Case I: current, I  
r 5

As,   Ir  V
1.25
 r  1.25
5

V 1
Case II: current, I  
r 2

1
Also, e  Ir  V or   r  1
2

By solving eqnd. I and II we get   1.5V , r  1

x
On comparing the given value with V , we get x  15
10

10. In a meter-bride when a resistance in the left gap is 2  and unknown resistance in the
right gap, the balance length is obtained at 40 cm from left end. On shunting the unknown
resistance with 2  , the balance length changes by x cm then the value of 2x is ____
Key: 45
Sol: Conceptual
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 35
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
11. Wheatstone bridge principle is used to measure the specific resistance  S1  of given wire
having length L and radius r. If X is the resistance of wire ,then specific resistance is;
  r2 
S1  X   . If the length of the wire gets doubles the value of specific resistance is x S1
 L 

then x is ____
Key: 1
Sol: Specific resistance   S1 length =L, radius =r

  r2 
S1  X   where X is the resistance
 L 

Now, L’ =2L, as specific resistance does not depend on the geometry of wire

So, specific resistance remains same. Thus, S1 '  S1 value is 1

12. For the given circuit,

If heat produced in 5Ω resistor is 10 J/s, then heat produced in 4Ω resistor is ______J/sec


Key: 2
i1 10
Sol: Ratio of current   2
i2 5

13. Find out the value of current in ampere through 2Ω resistance for the given circuit is

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

Key: 0
Sol: Current in the respective loop will remain confined in the loop itself. Therefore, current
through 2Ω resistance is zero

14. Water boils in an electric kettle for 15 min. If length of heating wire is decreased to 2/3 of
its initial value (keeping cross-section area constant), then same amount of water will boil
with same supply voltage in____min
Key: 10
Sol: Let water requires H joule of heat to boil Then,

15. Twelve identical cells connected in series are kept in a closed box. Some of the cells are
wrongly connected. This battery is further connected in series with two more cells
identical with others. The current in the circuit is 3A when cells and battery aid each
other and 1A when cells and battery oppose each other. The number of cells in the battery
that are wrongly connected is
Key: 4
Sol: Let ‘m’ wrongly connected

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

16. Six plates of equal area A and separation as shown in figure are arranged. The equivalent
xA 0
capacitance between A and B is Then x is _____
d

Key: 1

Sol: then x=1

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 38


SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-08
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
-2 ˆ 2
1. A magnet of total magnetic moment 10 i A - m is placed in a time-varying magnetic
^
field, B (cos t ) i where B = 1 Tesla and  = 0.125 rad/s. The work done for reversing the
direction of the magnetic moment at t = 1 second, is:
1) 0.01 J 2) 0.007 J 3) 0.028 J 4) 0.014 J
Key: 4

Sol: Work done,   2m.B  2 102 1 cos(0.125)  0.014 J

2. A magnetic substance of volume 30 cm3 is placed in a magnetising field of 5 oersted. It


produces a magnetic moment of 6 A/m2. The value of magnetic induction will be:
1) 0.257 T 2) 0.025 T 3) 0.0025 T 4) 25 T
Key: 1
Sol: 0

3. Statement I: If the number of turns in the coil of a moving coil galvanometer is doubled
then the current sensitivity becomes double.
Statement II: Increasing current sensitivity of a moving coil galvanometer by only
increasing the number of turns in the coil will also increase its voltage sensitivity in the
same ratio.
In the light of the above statement, choose the correct answer from the options given
below
1) Statement I is false but Statement II is true
2) Both Statement I and Statement II are true
3) Both Statement I and Statement II are false
4) Statement I is true but Statement II is false
Key: 4
I  BNA
Sol: current sensitivity  
  k

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
 V  BNA
So, if N is doubled the circuit sensitivity is doubled, voltage sensitivity   =
  k

As N is doubled R is also doubled. So, no change in voltage sensitivity

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
4. A magnet makes 30 oscillations/min in the earths magnetic field. If the magnetic field is
doubled, the period of oscillation of magnet x sec, then x is _____

Key: 2
60 1
Sol: T1   2(sec); T1
30 B

T2 B1 B 1
  
T1 B2 2B 2

T1 2
T2    2(sec)
2 2

5. If a magnet is suspended at angle 300 to the magnetic meridian, the dip needle makes at

1
 3
450 with horizontal. The real dip is tan   , Then x is
 x 
Key: 2
BV
tan   
BH cos 30
   45
BV
tan 45  1 or  cos 30  3
Sol: BH
BV 3
tan   
BH 2
 3
  tan 1  
 2 

6. What is the radius of then path of the electron ( 9 1031 kg & ch arg e1.6 1019 C ) moving at a
speed of 3  107 m / s in a magnetic field of 6 104 T perpendicular to it? Find the answer in
cm.
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 40
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Key: 28
mv 9  1031  3  107
Sol: r  19 4
 28  102 m  28cm
qB 1.6  10  6  10
7. An element l  xiˆ is placed at the origin carries a large current I = 10A shown in fig.
The magnetic field on the y- axis at a distance of 0.5 m. [Take x  1cm ] is ___________
 10 8 T
Y

y  0.5m

X
x  1 cm

Key: 4
0 idl sin  107 (10)102 Sin 900
Sol: dB  =  4T
4 r2 (0.5)2

  900 ,sin   1
l  x  102 m
 10 A, r
r  0.5m  4
8. A straight wire of mass 200 g and length 1.5 m carries a current of 2 A. It is suspended in
mid-air by a uniform horizontal magnetic field B. The magnitude of the magnetic field is
_______ 10 2 T [Take g= 9.8]

Key: 65
Sol: We find that there is an upward force F of magnitude Bil. For mid-air suspension this
must be balanced by the force due to gravity
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 41
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
mg  Bil

mg 0.2  9.8
B   0.65T  65  102
il 2  1.5

9. A charged particle of charge 4 mc enters a uniform magnetic field of induction


B  4iˆ  yjˆ  zkˆ tesla with a velocity V  2iˆ  3 ˆj  6 kˆ .If the particle continues to move undeviated

then the strength of the magnetic field Induction B is ____tesla

Key: 14
Sol: Here v parallel to B

4 y z
 
2 3 6
 y  6 & z   12
B  16  36  144  196  14 T

10. The force exerted by the conductor AB on the loop CDFG shown in figure is  n 104 N 

attraction. The value of n is

Key: 7
i1i2
Sol: F1  2  107
1  102

i1i2
F2  2  107
10  102

FN  F1  F2  7.2  104 N ATTRACTIVE

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-09
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. Assertion (A) : Step-down transformer decreases the current
Reason (R) : Transformer obeys the law of conservation of energy
1) Both (A) and (R) are true and (R) is correct explanation of (A)
2) Both (A) and (R) are true but (R) is not correct explanation of (A)
3) (A) is true and (R) is false
4) (A) is false and (R) is true
Key: 4
1. Sol: Step-down transformer increases the current transformer obeys the law of
conservation of energy
02. A thin non conducting ring of mass `m`, radius ‘R’ carrying a charge `q` can rotate freely
about its own axis. At the initial moment, the ring was at rest and no magnetic field was
present. Then a uniform magnetic field was switched on, which was perpendicular to the
dB
plane of the ring and increased with time according to a certain law  k . Find the
dt
angular velocity of the ring as function of k
Kq m Kq Kt
1)   t 2)   t 3)   t 4)
m kq 2m 2mq
Key: 3
R dB
2. Sol: E
2 dt
dF  Edq
1  dB 
dF  R q
2  dt 
d  RdF
1 2  dB 
d  R  q
2  dt 
1
  R 2 Kq
2
1 2
I  R Kq
2
1
mR 2  R 2 kq
2
KL  kq
 , 
2m t 2m
kq
 t
2m

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
03. A coil of 100 turns and area 0.1 m2 is rotated at half a revolution per second and is placed
in uniform magnetic field of 0.04 T perpendicular to axis of rotation of the coil . The
2
maximum voltage generated in the coil is volt. The value of B is _______
B
Key: 5
2
Sol: Emax  NAB  100  0.1 0.04    4  0.1  0.4  
5
04. A square loop of area 2.5  103 m 2 and having 100 turns with a total resistance of 100 
is moved out of a uniform magnetic field of 0.40T in 1 s with a constant speed. Then the
work done in pulling the loop is x  104 J then the value of ‘x’ is

Key: 1
3. Sol: W  Fl  NIBl  l

 BVNl 
W  NBl 2  
 R 

N 2 B 2l 4
W
RT
104 16 10 2  625 10 8
W
100
4
W  1 10 J
05. A solenoid is of length 50 cm and has a radius of 2 cm it has 500 turns. Around its central
section of a coil of 50 turns is wound. The mutual inductance of the system is
788.76  10 x H . Then the value of ‘x’ is
Key: 7
0 N p N s A
4. Sol: M
l

4 10 7  500  50    0.02 


2

M  788.76  107 H
0.5
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
06. For a given series LCR circuit it its found that maximum current drawn when value of
variable capacitance is 25 nF. If the resistance 100  and 400 mH in inductor is being
10 x
used in a given circuit. The frequency of source is HZ then the value of ‘x’ is______
2
Key: 4
1
5. Sol: f 
2 Lc
1
f 
2 400  103  25  10 9

1
f 
2 104  1012
1 1
f  
2 108 2  10
4

104
f  x4
2
07. A uniform magnetic field B exists in a cylindrical region of radius 10 cm as shown in
figure. A uniform wire of length 80 cm and resistance 4.0  is bent into a square frame
and is placed with one side along a diameter of the cylindrical region. If the magnetic
field increases at a constant rate of 0.01 T/s The induced current in frame is x  106 A
Then the value of ‘x’ is

Key: 39
d dB
6. Sol: e A
dt dt
e  1.57  104 v
e 1.57  104
i 
R 4
i  3.9 10  39  106
5

08. A transmitter transmits at a wave length of 600 m a condenser of capacitance 2 F is


being used . The value of the inductance for the resonant circuit is x 108 H then the
value of x is ____(  2  10 )
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 45
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Key: 5
3 108 1
7. Sol:   600m, C  3  10 , f  c /  
8
 106
6 10 2
2
1
f  1
2 LC L 
1
1 4  10  1012  2  106
f 
2
, 4
4 2 LC 7
10
1 L  5  108
L 2
4 2 f 2C

09. A series LCR circuit is connected to AC source of 220 V, 50 HZ the circuit contains a
resistance R  60 , an inductor of inductive reactance xL  40 and a capacitor of
x
capacitive reactance xC  120 The power factor of circuit is The value of ‘x’ is
10
Key: 6
R 60
8. Sol: cos   , cos  
R  ( xL  xC )  60   120  40
2 2 2 2

60 60 60 6
cos   , cos   , cos   
36  10  64  10
2 2
100 10 2 100 10

10. In an LC oscillator, if values of inductance and capacitance become four and nine times,
1
respectively, then the resonant frequency of oscillator becomes times its initial
x
resonant frequency 0 . The value of x is:
Key: 6
1
9. Sol: f
LC

f1 L2 C2
 
f2 L1 C1

0 4 L 9c
 
f2 l c
0
 36
f2
0
f2 
6

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-10
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. The de Broglie wavelength of an electron moving with a velocity 1.5  108 ms 1 is equal
to that a photon. The ratio of the kinetic energy of the electron to that of the photon is
1 1
1) 2 2) 4 3) 4)
2 4
Key: 4

Sol: 1. The speed of photo  c  3  108 ms 1. Wavelength of photon is, say,  .

h
Wavelength of electron =  .
m

1
K.E of electron 2 m  2
1 m 2
  
K.E of photon h 2 hc

v 1 c
  v  
2c 2  2

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2. In a nuclear fission process, a high mass nuclide  A  236  with binding energy

7.6 MeV/nucleon dissociated into middle mass nuclide  A  118  , having binding energy
of 8.6 MeV/Nucleon. The energy released in the process would be …….. MeV

Key: 236

Sol: Energy released in fission reaction

Q  BE product  BE reaction  2 118  8.6   236  7.6   236  236 MeV

3. A nucleus with mass number 242 and binding energy per nucleon as 7.6 MeV breaks into
two fragment each with mass number 121. If each fragment nucleus has bind energy per
nucleon as 8.1 MeV, the total gain in binding energy is ……. MeV

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Key: 121
Sol: Initial binding energy = 242  7.6 MeV

Final binding energy = 2  121  8.1 MeV  242  8.1MeV

Total gain in binding energy = Final binding energy -initial bind energy
 242  8.1 7.6   121 MeV

4. The wavelength of the radiation emitted is 0 when an electron jumps from the second
excited state to the first excited state of the hydrogen atom. If the electron jumps from the
third excited state to the second orbit of the hydrogen atom, the wavelength of the
20
radiation emitted will be 0 . The value of ‘x’ is ……
x
Key: 27
Sol: Second excited state  first excited state
n  3 n  2
hc  1 1
 13.6  2  2  ........ i 
0 2 3 
Third excited state  second order
n 4n 2
hc  1 1   200 
 13.6  2  2    '  
' 2 4   x 

hc  1 1
 13.6  2  2  ......... ii 
 200 / x  2 4 

1 1 1 1 4 1 3
 
x 2 4 2 2
Divide equation (ii) by (i)   4 16  16  16  x  27
20 1 1 1 1 94 5
2
 2 
2 3 4 9 36 36
5. An atom absorbs a photon of wavelength 500 nm and emits another photon of
wavelength 600 nm. The net energy absorbed by the atom in this process is n  104 eV .
The value of ‘n’ is …. [Assume the atom to be stationary during the absorption and
emission process] (Take h  6.6  1034 Js and c  3  108 m / s )

Key: 4125
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Sol: Net energy absorbed

hc hc 1 1 
E  E1  E 2    hc   
1 2  1 2 
 1 1 
 6.6  1034  3  108  9
 9 
 6.6  1020 J
 500  10 600  10 
6.6  1020
 19
eV  4.125  101 eV
1.6  10

6. An X-ray tube operates at 20 kV. A particular electron loses 5% of its kinetic energy to
emit an X-ray photon at the first collision. The wavelength corresponding to this photon
is____× 102 nm.

Key: 124
hc
K  20  103 eV E  0.05  20 103 eV  103 eV  103 eV ;

Sol: 
hc

 4.14 1015 eV  S   3 108 m / s
103 eV 103 eV
  12.42 1010 m  1.24nm

7. The ionization energy of hydrogen atom is 13.6 eV. Hydrogen atoms in the ground state
are excited by electromagnetic radiation of energy 12.1 eV. How many spectral lines will
be emitted by the hydrogen atom?
Key: 3
Sol: When an electron in the ground state receives 12.1 eV of energy, it jumps to a level where
its energy = 13.6 – 12.1 = 1.5 eV. This corresponds to the third excited state corresponding
to n = 3. It can have three transitions, namely from n = 3 to n = 2, from
n = 2 to n = 1 and from n = 3 to n = 1. Hence three spectral lines will be emitted.
8. A uranium nucleus (atomic number 92, mass number 238) emits an alpha particle and the
resultant nucleus emits a  particle. The atomic number of new nucleus is
Key: 91
Sol: The emission of an  -particle decreases the mass number by 4 and atomic number by 2.
The emission of a  -particle increases the atomic number by 1. Hence the final nucleus
has a mass number = 238 – 4 = 234 and atomic number = 92 – 1 + 1 = 91.

9. The charge of   particle is ……… 1020 coloumb

Key: 32
Sol: Q  ne

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RPTM-11
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Given below are two statement:
Statement I: Area under velocity-time graph gives the distance travelled by the body in a
given time.
Statement II: Area under acceleration-time graph is equal to the change in velocity in
the given time. In the light of given statement choose the correct answer from the options
given below.
1) Statement I is correct but statement II is false.
2) Both statement I and statement II are true.
3) Both statement I and statement II are false.
4) Statement I is incorrect but statement II is true.
Key: 4
Sol: Conceptual
2. The velocity-displacement graph describing the motion of a bicycle is shown in the
figure. The acceleration-displacement graph of the bicycle’s motion is best described by.

1) 2)

3) 4)
Key: 4

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Sol: Given velocity – displacement graph

(50  10) x
Equation of line AB v   ( x  0)  10(0  x  200)  v   10
(200  0) 5

dv 1
Differentiate equation (i) w.r.t.x, we get 
dx 5
dv dv dx dv
Acceleration, a    
dt dx dt dx

x  1
a    10  
5  5

(using (i) and (ii)) a    2  m s 2 , Atx  0, a  2 m s 2


x
 25 

3. A ball is projected from a point A with some velocity at an angle 30 o with the horizontal
as shown in the figure. Consider a target at point B. The ball will hit the target if it is
thrown with a velocity v0 equal to

1) 5ms 1 2) 6 ms 1 3) 7 ms 1 4) None of these


Key: 4
 3
g 
3 0  2 
Sol: Applying the trajectory equation we get 0.5  tan 30  2 2 0 v0  
2 2v0 cos 30

4. The velocity time graph of a body is shown in fig. The ratio during the intervals OA and
AB of:

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1
1) Average velocities is 1:1 2) Displacement is
4
1
3) Average acceleration is same as distances covered 4) Distances covered is
2
Key: 1
u v 0v v
Sol: During interval OA acceleration is same. vavg   
2 2 2
u v 0v v
During interval AB acceleration is same. vavg   
2 2 2
Ratio of average velocity is 1 : 1
During interval OA, a = tan600 = 3
1 2 1
S at  3t 2
2 2
1
During interval AB, a = tan300 =
3
1 2 1 1 2
S at   t
2 2 3
S1 1
Ratio of displacements 
S2 3

1 2
3t1  t
a1t1  a2t2 3  3t1  t2
aavg  
t1  t2 t1  t2 3(t1  t 2 )

1 1 2 1 (3  1)
S  S1  S2  3t 2  t  (t1  t2 ) 2
2 2 3 2 3

4 MLg
5. In the determination of Young's modulus (Y  length L = 2m and diameter d =
 ld 2
0.5mm is used. For load M = 2.5kg an extension l  0.25mm in the length of the wire is
observed. Quantities d and l are measured using a screw gauge and a micrometer.
Respectively. They have the same pitch of 0.5 mm. The number of divisions on their
circular scale is 100 the contributions to the maximum probable error in the measurement
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of Y is
1) Same due to the errors in the measurements of d and l
2) Due to the error in the measurement of d is twice that due to the error in the
measurement of l
3) Due to the error in the measurement of l is twice that due to the error in the
measurement of d
4) Due to the error in the measurement of d is four time that due to the error in the
measurement of l
Key: 1
MLg  Y   l   d 
Sol: Y 
2      2 
 ld  Y  max  l   d 

 l 
   0.02
 l 

 d 
   0.01
 d 

 l   d 
   2 
 l   d 

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

6. A fighter jet is flying horizontally at a certain altitude with a speed of 200 m s 1 .When it
passes directly overhead an anti-aircraft gun, a bullet is fired from the gun, at an angle 
with the horizontal, to hit the jet. If the bullet speed is 400 m/s, the value of  will
be____________( in degrees).
Key: 60
jet u  200 m / s
Sol:
So, 400 cos  t  200t
1
cos      600
2
7. The acceleration due to gravity is found upto an accuracy of 4% on a planet. The energy
supplied to a simple pendulum of known mass m to undertake oscillations of time period
T is being estimated. If time period is measured to an accuracy of 3%, the accuracy to
which E is known as___________ %.
Key: 14

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2
1 T g
Sol: T  2 l  2
g 4

2 T 2 2
The energy is given by E  mgl  mg 2 (From (i))
2 8 2

dE  dg dT 
Differentiate above eqn, we get,   2    2(4  3)  14%
E  g T 

8. In a particular system of units, a physical quantity can be expressed in terms of the


electric charge e , electron mass me Planck's constant h , and Coulomb's constant
1
k where  0 is the permittivity of vacuum. In terms of these physical constants,
4 0

the dimension of the magnetic field is  B    e  me   h  k  . The value of
       is ____________
Key: 4
Sol: Conceptual
9. To find the distance d over which a signal can be seen clearly in foggy conditions, a
railways engineer uses dimensional analysis and assumes that the distance depends on the
mass density  of the fog, intensity (power/area) S of the light from the signal and its
frequency f. The engineer finds that d is proportional to S1/n. The value of n is______.
Key: 3
Sol: Let d   x S y f z or d  k  x S y f z
x y z
Writing dimensions on both sides, we get  M 0 LT 0    ML3T 0   ML0T 3   M 0 L0T 1 

 M 0 LT 0    M x 1L3 xT 3 y  z 
   
x  y  0 ...(i )

3 x  1 ...(ii )

3 y  z  0 ...(iii )

Solving eqns. (i), (ii) and (iii) we get


1 1
x   , y  , z  1
3 3

As d  S1/3 n  3

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10. The displacement and the increase in the velocity of a moving particle in the time interval
of t to (t + 1) s are 125 m and 50 m/s, respectively. The distance travelled by the particle
in
(t + 2)th s is __________ m.
Key: 175
Sol: Change in velocity, V  50m / s  a (t  1  t )

 a  50m / s 2
a
Distance travelled in (t+1)th second is St 1  u   2(t  1)  1  u  25(2t  1)
2
 125m  u  50t  25  u  125  (50t  25)

a
Distance travelled in (t+2)th second is St  2  u   2(t  2)  1  u  25(2t  3)
2
 125  50t  25  50t  75  St  2  175 m

11. Airplanes A and B are flying with constant velocity in the same vertical plane at
angles 300 and 600 with respect to the horizontal respectively as shown in the figure. The
speed of A is 100 3 m/s. At time t = 0s, an observer in A finds B at a distance of 500m.
The observer sees B moving with a constant velocity perpendicular to the line of motion
of A. If at t=t0, A just escapes being hit by B, t0 in seconds is .

Key: 5
Sol: Conceptual

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RPTM-12
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. In the figure shown, match the following two columns  g  10ms 2 

Column-I Column-II
(a) normal reaction (p) 5 N
(b) Force of friction when F  15 N (q) 10 N
(c) Minimum value of F for stopping the block moving down (r) 15 N
(d) Minimum value of F for stopping the block moving up (s) None of the above
1) a  P; b  P; c  s; d  r 2) a  s; b  p; c  s; d  s
3) a  s; b  p; c  r ; d  r 4) a  s; b  p; c  s; d  r
Key: 2

Sol:
a) N  10  ma
 N  10  2  5  N  20 N

2. A varying horizontal force F  at acts on a block of mass m kept on a smooth horizontal


surface. An identical block is kept on the first block. The coefficient of friction between
the blocks is  . The time after which the relative sliding between the blocks prevails is

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2mg 2 mg  mg
1) 2) 3) 4) 2 mga
a a a
Key: 2
f max   N   mg
Sol:
f max
Upper block moves only due to fraction amax   g
m

Relative motion will starts when common acceleration become  g


Net force
g 
Total mass

at 2  mg
g  :t 
2m a

3. A small particle of mass 0.36 g rests on a horizontal turntable at a distance 25 cm from


1
the axis of spindle. The turntable is accelerated at a rate of   rad s 2 . The frictional
3
force that the table exerts on the particle 2 s after the startup is

1) 40 N 2) 30  N 3) 50  N 4) 60 N
Key: 3
f  ma  m at2  ar 2
Sol:

  Rw2 
2
 Rd 
2
m

m  Rd 
2

 R  t  
2 2

2
1  1  
2 2
3 
 0.36 10  0.25     0.25    2  
 3  3  
 50 N

4. In the arrangement shown, m1  1kg , m2  2kg , the pulleys and strings are ideal and all
surfaces in contact are frictionless. The value of M for which the mass m1 moves with
constant velocity is

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1) 6 kg 2) 4 kg 3) 8kg 4) 10kg
Key: 3
Sol: Since mass m1 moves with const velocity
so, T  10 N

2T 20
Acceleration of ' M ' is a  
M M
From pulley 2 frame of reference
20
20  10  2   2a
M

40 20
10   2
M M
80
10 
M
 M  8kg

5. Blocks A and C start from rest and move to the right with acceleration a A  12t ms 2 and
aC  3 ms 2 Here t is in second. The time when block B again comes to rest is

3 1
1) 2 s 2) 1s 3) s 4) s
2 2
Key: 4
Sol: Apply constrain relations

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aC  a A 3  12t
aB   aB   1.5  6t
2 2
dvB
aB 
dt
dvB
 1.5  6t
dt
vB
t
 dV   1.5  6t  dt
o
B 0

 VB  1.5t  3t 2
1
VB  0 at t  s
2

6. A ball of mass 1 kg is released from position A inside a wedge which has a hemispherical
cut of radius 0.5 m as shown. Assuming all surfaces to be smooth, the force exerted by
the vertical wall OM on wedge, when the ball is in position B is  g  10ms 2 

15 3
1) 5 3 N 2) 10 N 3) N 4) 15 N
2
Key: 3
1 2
mv  mgh
Sol: 2

v  2 gh

1
h  R cos 60  0.5   0.25m  V 2  5m 2 s 2
2

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mv 2
N  mg cos 60 
R
mv 2
N  mg cos 60o
R
 N  15N
Force excreted by vertical wall on edge is F  N sin 60
3
F  15 N
2

7. Statement-I: A cloth covers a table. Some dishes are kept on it. The cloth can be pulled
out without dislodging the dishes from the table.
Statement-II: For every action there an equal reaction and opposite reaction.
1) Both statement I & II are correct and statement II is correct explanation of statement-I
2) Both statement I & II are correct and statement II is not correct explanation of
statement I.
3) Both statements I & II are false
4) Statement I is correct & statement II false
Key: 2
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
8. A body of mass ‘m’ is launched up on a rough inclined plane making an angle of  with
3
the horizontal. The coefficient of friction between the body and plane is if the time of
5
ascent is half of the time of descent. The value of  is___degree.
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Key: 45
a A    g sin    g cos  
Sol:

1
s  ut  at 2
2
2s
t
a
1
ta  t2
2
2s 1 2s

aa 2 ad
aa  4ad

 g sin   g  cos   4  g sin    g cos  


sin    cos   4sin   4  cos 
5 cos   3sin 
3
5  cos   3sin
 
5
 tan   1    45o

9. A block of mass 40 kg just don’t slide over a surface, when a mass of 4 kg is suspended
through an inextensible massless string passing over frictionless pulley as shown below.
If a mass of 8 kg is hanging in place of 4 kg mass, then the acceleration of block is

 Given g  10 ms 2  gx . The value of x is

Key: 12
Sol: By adding 8 kg in place of 4 kg additional force F  4mg Net mas  40  8  48kg
This additional force creates motion 4 g  48a

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4g g
a 
48 12

10. A bag is gently dropped on a conveyor belt moving at a speed 2 m / s. The coefficient of
friction between the conveyor belt and bag is 0.4. Initially, the bag slips on the belt before
it stops due to friction. The time in which the slipping between the bag and the belt stops
is
( x +0.5) second. The value of x is Take g  10 ms 2 

Key: 0
Sol: f  N

ma    N
 N
a
m
 a   g

v  u  at
0  2   gt
2 2 2
t    0.5 s
 g 0.4  10 4

11. A block of mass 10 kg lying on a horizontal surface is pulled by force F acting at an


angle 60o , with horizontal. For s  0.25 the block will just start to move for the value of

F is nearly:  Given g  10 ms 2 

Key: 35
Sol: N  mg  F sin 

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
f s  F cos 
f  N
F cos 60  0.25 10  10  F sin 60 
4 F cos 60  100  F sin 60
4 F cos 60  F sin 60  100
100
F
1 3
4 
2 2
200
  34.89  35 N
4 3

12. In the arrangement shown in figure, mA  1kg and mB  2 kg , while all the pulleys and
strings are massless and frictionless. At t  0, a force F  10 t starts acting over central
pulley in vertically upward direction. If the velocity of A is x  10 m / s when B loses
contact with floor, find x .

Key: 1
Sol: F  2T

10t  2T  T  5t
' A ' looses contact
1g  5t
10  5t
t  2s
' B ' looses contact
2 g  5t
20
t
5
 t  4s

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
T  mA g  ma
5t  10  a
dv
a
dt
v 4

 dv    5t  10  dt
0 2
4
 5t 2 
v  10t 
 2 2
5
 v  16  4   10  4  2 
2
5
  12  10  2
2
 30  20  10m / s

13. A piece of wire is bent in the shape of a parabola y  kx 2  y  axis vertical  with a bead
of mass ‘m’ on it. The bead can slide on the wire without friction. The wire is now
accelerated parallel to the x-axis with an acceleration ‘a’. the distance of the new
a
equilibrium position of the bead is where the bead can stay at rest with respect to the
xgk
wire from y-axis. The value of ‘x’ is
Key: 2
Sol: N cos   mg

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
N sin   ma
a
tan  
g
dy a

dx g
a
k 2x 
g
a
x
2 gk

14. A long block B rests on a smooth horizontal plane. A small block A of mass half that of
B is placed at one end of B and given a horizontal velocity u. if  is the co-efficient of
friction between the blocks, then the time elapsed before the two blocks attain a common
2u
velocity is where n is
n g

Key: 3
Pi  Pf
Sol:
mu  M  o    m  M  V
mu
v
m  M 
Maximum value of friction between A & B is  mg
a  g
v  u  at
mu
 u   gt
mM
 m 
 gt  u 1  
 M m
u M m  m
 
t 
 g  M  m 
Mu
t 
 g  M  m
Mu 2u
t  
 M 3 g
Mo  M  
 2 

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
15 In a circular motion of a particle the tangential acceleration of the particle is given by
at  2tm / s 2 . The radius of the circle describes is 4 m. The particle is initially at rest.

Time after which total acceleration of the particle makes 45o with radial acceleration is
____sec.
Key: 2

Sol: at  2t m / s 2

r  4m
uo
at
tan 45o 
ac
 at  ac
dv
 2t
dt
t

 dv   2t dt
0

t
2t 2
v
2 0

vt 2

ac  at
v2
2t 
r
t4
2t 
r
2r  t 3
1
t   2  4 3

t  2s

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RPTM-13
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. Two particles A and B of masses 1kg and 2kg respectively are projected in the directions
shown in figure with speeds u A  200 m / s and u B  50 m / s . Initially they were 90m
apart. They collide in mid air and stick with each other. Find the maximum height
attained by the centre of mass of the particles from the ground (assume acceleration due
to gravity to be constant).  g  10 m / s 2 

1) 115.55m 2) 157 m 3) 151.5m 4) 145m

Key: 1
Sol: Using m ArA  mB rB

 rA    2  rB  --------- (i) and rA  rB  90 m ------------- (ii)

Solving these two equation, we get rA  60m and rB  30m

i.e. COM is at height 60m from the ground at time t=0

mA a A  mB aB
Further, aCOM 
mA  mB

g  10m / s 2

As aA  ag  g

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
mAu A  mBu B 1 200    2  50  100
uCOM    m/s
mA  mB 1 2 3

Let h be the height attained by COM beyond 60m. using,

2
vCOM  uCOM
2
 2aCOM h

2
 100 
0    2 10  h
 3 

100 
2

h  55.55m
180

Therefore, maximum height attained by the centre of mass is

H  60  55.55  115.55m

02. A pump is required to lift 1000kg of water per minute from a well 20m deep and eject it
at a rate of 20ms 1 . What HP (horse power) engine is required for the purpose of lifting
water?

1) 88.5 2) 8.85 3) 885 4) 885.5

Key: 2
Sol: Work done in lifting water = gain in PE (potential energy)

1 1
Work done (per minute) in giving it K.E.  mv 2  1000  20   2  105 J min 1
2

2 2

1
Power of the engine = work done per second = 1.96  2  105 J  6.6  103 w
60
Since 1 HP = 746w, HP required = 8.85

03. The linear mass density of a rod of length 5m varies with distance from its end fixed at
the origin as represented in the graph shown below:

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

Then find the position of centre of mass of the rod w.r.t origin.

25 5 25 5
1) m 2) m 3) m 4) m
16 9 9 16
Key: 3
Sol:    5  x  kg / m

X CM 
 xdm  dm   5  x  dx
 dm
5

X CM 
 x  5  x  dx  25
0
5
  5  x  dx 9
0

04. A system of two identical particles loses 25% of its energy during collision where one
particle was initially at rest. The coefficient of restitution will be

1
1) 0.25 2) 2 3) 4) 0.5
2

Key: 3
m1m2vr2 KE m2 1
Sol: KE 
2  m1  m2 
1  e2  
KE m1  m2
1  e 2  where KE  m1v 2 ,
2

25 1 1
m1  m2  m    1  e2   KE of 25% of KE of m1 
100 4 2

1
e
2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
05. A small block starts slipping down from a point B on an inclined plane AB, which is
making an angle  with the horizontal section. BC is smooth and the remaining section
CA is rough with a coefficient of friction  . It is found that the block comes to rest as it
reaches the bottom (point A) of the inclined plane. If BC=2AC, the coefficient of friction
k
is given by   tan  . The value of k is ______
3

Key: 9
Sol: If AC  l then according to question, BC  2l and AB  3l

Here, work done by all the forces is zero W friction  Wmg  0

mg  3l  sin    mg cos  l   0   mg cos l  3mgl sin     3tan   k tan 

06. A car of mass m is accelerating on a level smooth road under the action of a single force
F. The power delivered to the car is constant and equal to P. If the velocity of the car at

xmv3
an instant is v, then after travelling a distance , it becomes double. Then x is _____
3P

Key: 7
2
 d  2 P s  3  Ps 7m 3
Sol: Power, P  F .  m  .  .   .d  . ds
2
 3   m or s  3P
 ds   m 0  
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RPTM-14
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. Velocity of the centre of smaller cylinder is v. There is no slipping anywhere. The
velocity of the centre of larger cylinder is:

3v
1) 2v 2) v 3) 4) none
2
Key: 2
Sol:  B  2  C

0  C  
2


02. A yo-yo arranged as shown, rests on a frictionless surface. When a force F is applied to
the string as shown, the yo-yo:


F
1) Moves to the left and rotates counterclockwise
2) Moves to the right and rotates counterclockwise
3) Moves to the left and rotates clockwise
4) Moves to the right and rotates clockwise
Key: 2
Sol: Conceptual

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a
r  F>f
F
f

03. A spherical ball of mass m and radius r is released from top of a fixed rough circular
track of radius R so that it always rolls purely. Its velocity at the bottom does not depend
on:

1) r 2) R 3) m 4) acceleration due to gravity


Key: 3
7
Sol: mg ( R  r )  m 2  0
10

10
  g (R  r)
7
04. Two particles A, B are moving on two concentric circles of radii R 1 and R2 with equal
angular speed ω. At t=0, their positions and direction of motion are shown in the figure

(R2= 2R1). The relative angular velocity of B with respect to A at t  is given by
2

1)  iˆ 2)  iˆ 3)  k̂ 4)  k̂
Key: 4
V  V A  R2   R1
Sol:  BA  B     Anti  clockwise 
R2  R1 R2  R1
05. Statement – 1: When a sphere is rolling without sliding it is possible that no point on it is
at rest.
Statement – 2: For rolling without sliding vCM   R (  and R have usual meaning and
vCM is w.r.t. ground)
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
1) Statement-1 is true, Statement-2 is true and statement-2 is correct explanation for
statement-1.
2) Statement-1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement -1.
3) State-1 is true, statement-2 is False.
4) Statement -1 is false, statement-2 is true.
Key: 3
Sol: Think what if the surface on which rolling takes place is moving with respect to ground.
06. A thin-walled hollow sphere shell of mass m and radius r starts from rest and moves
along a track as shown in figure. Assume that the shell successfully negotiates the loop.

Statement-1: Normal reaction at A is greater when friction is absent on the track as


compared to the case when sphere executes pure rolling.
Statement-2: Due to frictional torque, the shell have larger translational velocity at A in
case of pure rolling.
1) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for
statement-1.
2) Statement-1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement-1.
3) Statement-1 is true, statement-2 is false.
4) Statement-1 is false, statement-2 is true
Key: 3
Sol: Conceptual
07. A disc of radius R rolls and slips on a horizontal surface with linear velocity  i and
angular velocity  (k ) such that v  R. There is a particle P on the circumference of
the disc which has velocity in vertical direction. The height of that particle from the
ground will be:
Y

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
v v R R
1) R  2) R  3) R  4) R 
  2 2
Key: 2
Sol:   R cos 

R
V
 


cos  
R
h  R  R cos 
08. A rod OB of length l , hinged about its end O is rotating with an angular velocity  . The
rod breaks at its midpoint A and as a result the part OA starts rotating with angular
velocity 2. Then the angular velocity of AB about its centre of mass is:

O A B
1)  2) 3 3) 4 4) None
Key: 2
Sol: For OA :

 m  l 
  
 l   2  2 
J  (2   )
2 3
ml
J .......(i )
12
For AB : About its C.M.
2 2
l 1 m  l 
J      (1  2 ) .....(ii)
4 12  2   2 
From (i) and (ii)
 1  3

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
09. An equilateral triangular wire frame is made from 3 rods of equal mass and length l
each. The frame is rotated about an axis perpendicular to the plane of the frame and
passing through its vertex. What is the radius of gyration of the frame?
1 l l
1) 2) l 3) 4)
2 2 2 3
Key: 3
Sol: Conceptual
10. The following figure shows two situations in which a uniform round rigid body is
released from rest from the positions shown, such that it is just able to loop the loop
without leaving contact with the track. Assuming that radius of the track is large in
comparison to the radius of round body, the ratio h1 / h2 :

1) Must be greater than 1


2) Must be less than 1
3) Must be equal to 1
4) Can be greater than or less than 1, depending on the moment of inertia of the round
body
Key: 2
Sol:

1 2
Case1: mgh1   K .E   K  mv
2
Whole gravitational potential energy is converted into translation K.E only

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
1 2
Case 2: mgh2  K trans  K rot  mv  1cm  2
2
Some part of gravitational potential energy will be converted into rotational K.E also
Hence in second case, greater height is required.

SECTION-II (NUMERICAL VALUE TYPE)


This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
11. A uniform rod AB of mass 2kg and length 30 cm is at rest on a smooth horizontal
surface. An impulse of force 0.2 Ns is applied to end B. The time taken by the rod to

turn through at right angles will be s, where x = ________
x
Key: 4
Sol: Impulse is given by   Fdt  0.2 N  s

FL FL L L
Angular impulse is Q    dt  
2
dt  
2
dt   Fdt   J
2 2
0.3
  0.2  0.03
2
A

J
B MOI of rod

ML3 2   0.3
2
0.09
I cm     0.015
12 12 6
Q  I cm 2  1 

0.03  0.0152  2  rad / s


   
Also    t  t    s  s  given   x  4
 2 2 4 x
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RPTM-15
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. 6 litres of helium enclosed in a cylinder at a pressure ‘3 atm’ then its adiabatic bulk
modulus is (Take 1 atm = 105 Pa )
1) 3105 Pa 2) 4105 Pa 3) 5105 Pa 4) 6105 Pa
Key: 3
Sol: P=3atm= 3105 Pa  1atm  105 Pa 

5
K   P   3105  5 105 Pa  'He'is a mono-atomicgas
3

02. Two rods of different metals but of equal cross-section and length 1 m each are joined to
make a rod of length 2m. The metal of one rod has a coefficient of linear thermal
expansion 105 / C and young’s modulus 31010 N / m2 . The other metal has the values
2105 / C and 1010 N / m2 respectively. How much pressure must be applied to the ends
of the composite rod to prevent its expansion when the temperature is raised by 100C
1) 2.75107 N / m2 2) 2.25107 N / m2 3) 2107 N / m2 4) 3107 N / m2
Key: 2
Fl Pl  F 
Sol: e   where =pressure
AY Y  A 

Ye YY l  l 
P HereY  1 2 1 2 , l  l1  l2
l Y1l2  Y2l1

e  1t  2t

G.T l1  l2  1m, 1  105 / C , 2  2 105 / C , Y1  31010 N / m 2 , Y2  1010 N / m 2

 P  2.25107 N / m 2

03. Read the two statements carefully to mark the correct option out of the options given
below

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Statement -1: A hollow shaft is found to be stronger than a solid shaft made of same
amount of material
Statement -2: The torque required to produce a given twist in hollow shaft is greater than
that required to twist a solid shaft made of the same amount of material
1) Both the statements are true and the statement -2 is the correct explanation of
statement-1
2) Both the statements are true and the statement -2 is not the correct explanation of
statement-1
3) The statement-1 true but statement -2 is false
4) The statement-1 false but statement -2 is true
Key: 1
r 4
Sol:       r 4
2l

Size of hollow shaft will be greater than solid shaft made of same amount of material.

i.e,  hollow   solid

04. Two equal and opposite forces F & -F on a rod of uniform cross-sectional area ‘A’, as
shown in figure then sum of maximum longitudinal stress and maximum shearing stress
will be
A

F
 F

F 2F 3F F
1) 2) 3) 4)
A 3A 2A 2A
Key: 3
F
Sol: Longitudinal stress  cos 2 
A
F
If   0 then L.S is maximum  L.S max 
A
F
Tangential (or) shearing stress = sin 2 
2A

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If   45 then S.S is maximum

F
 S .S max 
2A
3F
Now  L.S max   S .S max 
2A
05. Assertion (A): Rain drops falling from a large height, accelerate initially and then fall
with constant velocity
Reason (R): For a spherical body falling with constant velocity then Buoyancy force is
equal and opposite to the weight of the drop
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not correct explanation of (A)
3) (A) is true and (R) is false
4) Both (A) and (R) are false
Key: 3
Sol: Initially W  FB  FV then ball accelerates after falling through certain distance

W  FB  FV and Fnet  0, a  0 & V  constant

Fv

FB

m
a
W  mg
 W  FB

06. Assertion (A): The impurities always decrease the surface tension of liquid
Reason (R): The change in surface tension of the liquid depends on the degree of
contamination of the impurity
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not correct explanation of (A)
3) (A) is true and (R) is false
4) (A) is False and (R) is True

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Key: 4
Sol: Surface tension depends on impurities, partially soluable impurities decreases the surface
tension and completely soluable impurities increases the surface tension.

07. Statement -1: A piece of ice floats in water then level of water remains unchanged when
ice melts completely
Statement -2: According to Archemedis principle, the loss of weight of the body in the
liquid is equal to Buoyancy force acts on a immersed part of the body
1) If both the statements are true and the statement -2 is the correct explanation of
statement-1
2) If both the statements are true and the statement -2 is not the correct explanation of
statement-1
3) If both the statement-1 true but statement -2 is false
4) Both the statement-1 and statement -2 are true
Key: 1
Sol: According to Archemedis principle and laws of floation.

08. A wind with speed 40 m/s blows parallel to the roof of a house. The area of the roof is
250m2 , Assuming that the pressure inside the house is atmospheric pressure, the force
exerted by the wind on the roof and the direction of the force will be air  1.2 kg / m3 

1) 4.8105 N , upwards 2) 4.8105 N , downwards


3) 2.4105 N , downwards 4) 2.4105 N , upwards
Key: 4
1
Sol: F  P A  V 2 A,V  40m / s,   1.2kg / m3 , A  250m 2
2

F  2.4105 N , upwards (  ' F ' is a force of dynamic lift)

09. In a cylindrical water tank, there are two small holes A and B on the wall at a depth of h1 ,
from the surface of water and at a height of h2 from the bottom of water tank. Surface of
water is at height H from the bottom of water tank. Water coming out from both holes
strikes the ground at the same point S. Find the ratio of h1 and h2
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h1
A
H

h2 B

S
1) Depends on H 2) 1:1 3) 2:2 4) 1:2
Key: 2

Sol: From hole ‘A’ range R1  4h1  H  h1 

From hole ‘B’ range R2  4 H  h2  H   H  h2   4h2  H  h2 

G.T R1  R2 , after solving H  h1  h2 this relation is not satisfied for given figure.
h
Because holes are at different heights, Hence h1  h2  1  1:1
h2

10. Two capillary tubes of equal length and inner radii 2r and 4r respectively are added in
series and a liquid flows through it. If the pressure difference between the ends of the
whole system is 8.5 cm of mercury, find the pressure difference between the two ends of
the first capillary tube.
1) 8.0 cm of Hg 2) 9.0 cm of Hg 3) 10.0 cm of Hg 4) 11.0 cm of Hg
Key: 1
 Pr 4 P P
Sol: According to poiseulli’s equation volume rate of flow V    
8l 8l R
r 4

8l
Where R  = resistance of fluid. In series combination of pipes
r 4
V  constant  P  R

P1 R1  r2   
4
1
     R  4 ,l ,   constants
P2 R2  r1   r 
r1  2r , r2  4r

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P1  4r 
4

    16, but whole pressure difference


P2  2r 

P1
 16, P  P1  P2  8.5cm of Hg
8  P1

P2  P  P1  8.5  P1

P1  16  8.5  16P1

17P1  16  8.5

16 8.5
P1   8 cmof Hg
17
11. Let T1 be surface tension between solid and air, T2 be the surface tension between solid
and liquid and T be the surface tension between liquid and air. Then in equilibrium, for a
drop of liquid on a clean glass plate, the relation is (  is angle of contact)

T T T  T2 T  T2
1) cos   2) cos   3) cos   1 4) cos   1
T1  T2 T1  T2 T T
Key: 4
Sol: T1  T cos   T2


T1 T cos  T2

T cos   T1  T2

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T1  T2
cos  
T
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
12. A steel wire of length ‘2L’ area of cross section ‘A’ and young’s modulus ‘Y’ is clamped
firmly at two points P & Q in the same plane. A body is hung from middle point of the
wire such that the middle point sags by a distance ‘x’ lower from original position. If
YAx P
tension in the string is then p  q 
2 Lq
Key: 4
Sol: From figure 2T sin   Mg

2T sin 

L L
P Q
 
T
x T
L1 L 1
 
T cos  T cos 
M

Mg

x
If '  ' is small then sin   tan  
L

YAL 
T =tension in string
2L
L  total elongation

 2 L1  2 L  2  
L2  x 2  2 L

 x 2   2
1/2

 2 L 1  2   2 L  2 L 1 
2 1 x   2L
 L  
 2 L 2

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 1 x  2
1 x 2
 2 L 1   2L  2L  2L  2  2L
 2 L 
2
2 L

x2
L 
L

x2
YA
YAL L YAx 2 YAx 2 YAx p
Now T     
2L 2L 2 L2 2 L2 2 Lq
p  2, q  2

pq4

13. Consider a water tank as shown in the figure. It’s cross-sectional area is 0.4m2 . The tank
has an opening B near the bottom whose cross-section area is 1cm2 . A load of 24kg is
applied on the water at the top when the height of the water level is 40 cm above the
bottom, the velocity of water coming out the opening B is v ms1 . The value of v, to the

nearest integer, is ______[Take g = 10ms2 ]

Key: 3
Sol: According to Bernoulli’s theorem,

T .E A  T .E B

mg 1 2 1
P0    A  hA g  P0  hB  g   B2
A 2 2
  A  0,  B   , hB  0, hA  h

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mg 1
 h g   2
A 2

m  24kg , g  10m / s 2 , A  0.4m 2 ,   103 kg / m3

 2  9.2    9.2  3m / s

14. Two soap bubbles ‘A’ and ‘B’ are kept in a closed chamber where the air is maintained at
pressure 8N / m2 . The radii of bubbles ‘A’ and ‘B’ are 2 cm and 4 cm respectively.
Surface tension of soap water used to make bubbles is 0.04 N / m . Then the ratio of
number of moles of air in soap bubble ‘B’ and ‘A’ is.
Key: 6
Sol: PV  nRT

PV  n

Pv n
1 1
 1
P2v2 n2

n2 P2v2

n1 Pv
1 1

 
 P  4T  4 r 3
n2  0 r2  3 2

n1  4T  4 3
 P0   r2
 r1  3

G.T P0  8 N / m 2

r1  2cm, r2  4cm

T  0.04 N / m
  4
8  4  0.04    4 
3

n2  4 10  3
 2

n1  4  0.04  4
8  4 102  3  2
3

n2 12 64
  6
n1 16 8
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RPTM-16
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. The potential barrier 'V0 ' volts exist across a p-n junction. An electron with velocity v
approaches P-N junction from N side. The velocity of electron across the junction is
2V e 2V e 2ve
1) v 2  0 2) v 2  0 3) v 4)
m m m
Key: 2
1 2 1 2 2eV0 2eV0
Sol: mv2  mv1  eV0  V22  V12   V12  V22 
2 2 m m
2eV0
V1  V22 
m
02. The V-I characteristics of diode is shown in figure. The ratio of forward to reverse bias
resistance is ____
I  mA

20

15

10

-10
7 8
1 v  volt 

I   A

5 3
1) 10 2) 10 3) 10 2 4) 10 7
Key: 1
87 1 10  0 7 RFB 100
Sol: RFB   3
 100 RRB  6
 10  7  105
20  10 10  10 1  10 RRB 10
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
03. In the semiconductor, the number density of intrinsic charge carries at 27 0 C is
1.5  1016 / m 3 . If the semiconductor doped with impurity atoms, the hole density increased
to 4.5  10 22 / m 3 . The electron density in the doped semiconductor is P  109 m 3 then P is
__
Key: 5
2.25  1032
Sol: ni  ne nL  1.5  10   ne  4.5  10   ne 
2 16 2 22
 0.5  1010  5  109
4.5  122

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CHEMISTRY
RPTM-01
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. In  321 the sum of angular momentum, spherical nodes and angular nodes is ________
6h 8h  6 6h  4 8h  4 
1) 3 2) 3) 4)
2 2 2 2
Key: 3
h h 6h
Sol: Angular momentum = l  l  1  2  2  1 
2 2 2
No. of spherical nodes = n  l  1  3  2  1  0
No. of angular nodes = l =2

6h 6h  4
Sum of the above = 2 
2 2
2. The minimum energy needed for excitation of an electron present in the ground state of
H-atom is _____
1) + 13.6 eV 2) + 3.4 eV 3) + 12.09 eV 4) + 10.2 eV
Key: 4
Sol: Minimum energy needed is excitation of electron from ground state to 2 nd orbit
-3.4
-13.6

n =1

n =2

 E  E2  E1  3.4   13.6   3.4  13.6  10.2 eV


3. Statement-I: In H-atom 4p and 4d orbitals are degenerate orbitals
Statement-II: In multi electron atom, all the orbitals in a given shell are degenerate
orbitals
1) Statement I is true, Statement II is true 2) Statement I is true, Statement II is false
3) Statement I is false, Statement II is true 4) Statement I is false, Statement II is false
Key: 2
Sol: In H-atom, energy depends only on principal quantum number n-only

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In multi electron atom, energy depends on both PQN &AQN  , n and l -values

4. Given below are two statements one is labelled as Assertion(A) and the other is labelled
as Reason(R).
Assertion(A): In the photo electric effect electrons are ejected from the metal surface as
soon as the bulb of light of frequency is greater than the threshold frequency strikes the
surface.
Reason(R): When the photon of any energy strikes an electron in the atom, transfer of
energy from photon to the electron takes place.
In the light of the above statements, choose the appropriate answer from the options
given below.
1) Both A & R are correct, and R is the correct explanation of A
2) Both A & R are correct, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is correct
Key: 3
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
th
5. In H-atom an electron jumps from 5 orbit to first orbit. The number of visible lines
emitted are _________
Key: 3
Sol: Visible lines means Balmer series.

5
4 Brackett=1
3 Pascher=2

2 Balmer = 3

1
Lyman=4

Total no. of spectral lines emitted =


 n2  n1  n2  n1  1
2

 5  1 5  1  1 45
=   10 lines
2 2
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In which Balmer = 3

6. In an atom an electron is moving with a speed of 600 m/sec with an accuracy of 0.005%
3
certainty with which the position of electron can be located as x  10 m . Then x is
______) (Nearest integer)
Key: 2
Sol:  V  600 m / s

0.005
Accuracy = 0.005% of 600 = 600   0.03
100
h 6.625  10 34
x    1.9  2
4   mV 22
4   9.11  10 31  0.03
7
7. Maximum number of electrons that can be accommodated in a P-orbital is ________
Key: 2
Sol: Any orbital can accommodate a maximum of two-electrons only. With opp. spin.
0
8. The shortest wavelength in Lyman series is 912 A . The longest wavelength in Balmer

series is ____ 10 A (nearest integer)


3 0

Key: 7
Sol: Lyman: n1  1, n2  
1 1 1
 Z 2R  2  2 
  n1 n2 
1 1 1 
 z2 R  2  2 
912 1   …..(1)
Balmer: n1  2, n2  3
  1 1  5
 z2 R  2  2   Z 2
R 
 2 3  36 ……..(2)
(1) by (2)

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1
912  Z R  1    36    6566 A0  6.566  103 A0  7  103 A0
2

1 5 912 5
Z 2R 
 36
9. C5H10 O is a carbonyl compound, the number of structural isomers possible for this
molecular formula are
Key: 7
CH 3  CH 2  CH  CHO

CH 3
Sol: (1) CH 3  CH 2  CH 2  CH 2  CHO (2)

CH 3
CH 3  CH  CH 2  CHO
CH 3  C  CHO

CH 3 CH 3
(3) (4)

(5) CH 3  CH 2 COCH 2 CH 3 (6) CH 3COCH 2CH 2  CH 3

CH 3CO  CH  CH 3

CH 3
(7)

10.
H 2 / Ni Cl2 / hv
M
 Alkyne 

N
(No. of mono-chloro
structural products)

M – possible alkynes, Write the sum of value of M + N.


Key: 9
b d
a f
e
Sol: M - c c
(6) Monochloro structural products
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(3+6) =9
11. Find the sum of the locants of substituent’s as per IUPAC naming for the given
compound.
OH

CN
Br
Key: 7
Sol: Principal functional group is CN, OH, Br are substituents
OH
5
4
3
2 1 CN
Br 257
12. In Duma’s method for estimation of nitrogen, 0.29 g of an organic compound gave 50 ml
of Nitrogen collected at 300 K temperature and 715 mm pressure. Calculate the
percentage composition of nitrogen in the compound. (Aqueous tension at 300 K = 15
mm)
Key: 18
Sol: Volume of Nitrogen collected at 300 K and 715 mm pressure is 50 ml.

Actual pressure = 715 – 15 = 700 mm


273  700  50
Volume of nitrogen at STP =  41.9 ml
300  760
22,400 ml of N 2 at STP weighs = 28 g
28  41.9
41.9 ml of nitrogen weighs = g
22400
28  41.9  100
Percentage of Nitrogen =  18.06%
22400  0.29

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RPTM-02
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Atomic radii of fluorine atom and neon atom in angstrom units are respectively given by
1) 0.762, 1.60 2) 1.60, 1.60 3) 0.72, 0.72 4) 1.60, 0.762
Key: 1
Sol: rF  rNe
4 3
2. Hydrogen peroxide oxidises  Fe  CN 6  to  Fe  CN 6  in acidic medium but reduces
3 4
 Fe  CN 6  to  Fe  CN 6  in alkaline medium. The other products formed are,
respectively
1)  H 2O  O2  and  H 2O  OH   2) H 2O and  H 2O  O2 
3) H 2O and  H 2O  OH   4)  H 2O  O2  and H 2O
Key: 2
Sol: Chemical equations are given below:
4 3
2  Fe  CN 6    H 2O2  2 H   2  Fe  CN 6   2 H 2O

3 4
2  Fe  CN 6    H 2O2  2OH   2  Fe  CN 6   2 H 2O  O2

3. Considering the basic strength of amines in aqueous solution, which one has the smallest
pK b value?
1) C6 H 5 NH 2 2)  CH 3 2 NH 3) CH 3 NH 2 4)  CH 3 3 N
Key: 2
Sol:  CH 3 2 NH is a stronger base in aqueous medium than Me3 N . So its pKb value is smallest
4. Statement-1: The electron gain enthalpy of N is +ve while that of P is –ve.
Statement-2: This is due to the smaller atomic size of N in which there is a considerable
electron-electron repulsion and hence the additional electron is not accepted easily.
1) Statement-1 is True; Statement-2 is True; Statement-2 is correct explanation for
Statement-1.
2) Statement-1 is True; Statement-2 is True; Statement-2 is NOT a correct explanation
for Statement-1.
3) Statement-1 is True; Statement-2 is False.
4) Statement-1 is False; Statement-2 is True.
Key: 1
Sol: Statement-2 is the correct explanation for Statement-1.
5. Which of the following pairs is chemically similar?
1) Zr  Hf 2) Cu  Ag 3) Fe  Au 4) Hf  La
Key: 1

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Sol: Zr and Hf have almost equal ionic radi due to Lanthanide contraction. Thus their
chemical properties will almost similar
6. The bond dissociation energies of H–H, C–C and C–H bonds respectively are 104  2, 83 1
and 98  8 kcal mol 1 . The electro negativity of carbon is
1) 2.6 2) 2  51 3) 2  50 4) 2  52
Key: 1
Sol:   EC  H  EH  H  EC C

xC  xH  0  208 

xC  xH  0  208   0.208  5.75 


1/ 2
 0.498

xC  0.498  2.1  2.598  2.6

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
7. How many of the following are more acidic than benzoic acid?
COOH COOH COOH COOH

CHO NO2 Cl NH 2
Key: 3
Sol: – I effect increases the Acidity
8. The total number of   hydrogen’s contributing structures showing hyperconjugation
(involving C – H bonds) for the following carbocation is
H 3C CH 2CH 3

Key: 6
(a) (b)
H 3C CH 2CH 3
(c)

a3 Hyperconjugative H'S


b2 Hyperconjugative H'S

Sol: c 1 Hyperconjugative H'S

9. How many –I groups are present in the following?

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COO , O ,  NO2 , COOH , CH 3 ,  F , CH 2 R
Key: 3
Sol: Conceptual
10. How many of the following are stronger acids than phenol?

Key: 3
Sol: - I effect
11. How many pairs in their first species have lower ionization energy than second species?
a) N and O b) Li and Li  c) O and S d) Sr and Ba.
Key: 1
Sol: Conceptual
12. I.E. and E.A. of an element are 13 eV and 3.8 eV respectively. The electronegativity of
the element on Pauling’s scale is.
Key: 3
13  3.8 16.8
Sol: On Mulliken Scale E.N .    8.4 eV
2 2

E.N . Mulliken 8.4


On Pauling’s Scale E.N .    3 eV
2.8 2.8
13. The molarity of 33.6V of H 2O2 of solution is____
Key: 3
1
Sol: H 2O2  aq   H 2O1  O2 g 
2

1M  0.5 mol of O2  11.2 L (STP)

33.6
Hence, molarity   3M
11.2
14. Find the total number of species having magnetic moment value of 5.9 B.M. from
following species. Fe 2 , Cr , Cr 3 , Fe3 , Ti 2 , Mn 2 ,V 3
Key: 2
Sol: Fe3 , Mn2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-03
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Assuming 2 S  2 P mixing is not operative. The paramagnetic species among the following
1) Be2 2) B2 3) C 2 4) N 2
Key: 3
Sol: C2 is paramagnetic

2. Given below are two statements: One is labeled as Assertion (A) and the other is labeled
as Reason (R)
Assertion (A) Treatment of bromine water with propene yields 1-bromopropan-2-ol.
Reason (R) Attack of water on bromonium ion follows Anti Markovnikov rule and
results in the formation of 1-bromopropan-2-ol.
In the light of the above statements, choose the most appropriate answer from the options
given below.
1) Both Assertion and reason are true, but reason is not the correct explanation of
assertion.
2) Assertion is false, but reason is true.
3) Both assertion and reason are true, and reason is the correct explanation of assertion.
4) Assertion is true, but reason is false
Key: 4
Sol: Both Assertion and Reason are true and Reason is correct explanation of Assertion.

Br
CH 3CH  CH 2 
Br2
 CH 3  CH  CH 2 
H O
 CH 3  CH  OH   CH 2 Br
2

Markownikoff product
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
3. Total number of covalent bonds between carbon and carbon atoms in C3O2 molecule is
____
Key: 4
Sol: O  C  C  C  O
4. The number of species given below that have two lone pairs of electrons on their central
atom is
SF4 , BF4 , ClF3 , AsF3 , PCl5 , BrF5 , XeF4 , SF6
Key: 2
Sol: SF4  1 L. P

BF4  O L. P

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ClF3  2 L. P

XeF4  2 L. P

5. Maximum number of planar atoms in SF6 molecule is___


Key: 5
Sol: SF6 Central atoms sulphur and four F atoms in same plane

*
6. Total number of e Present in ^ (pi*) molecular orbital of O2 , O2 , O2
Key: 6
O2  O2 
O2 
2 Pn1 2 p 1e 3e
Sol:
7. Number of molecules from the following which can exhibit hydrogen bonding is --------
(nearest integer)
NO2
CH 3OH ; H 2O; C2 H 6 ; C6 H 6 ; HF , NH 3

OH
Key: 5
NO2

CH 3OH ; CH 2O; ; 1F ; NH 3

Sol: OH
8. The number of different chain isomers possible for C6 H14
Key: 5
Sol: Total six different chain isomers for C6 H14 is possible. These are as follows.

Cl2  excess  / hv
 
9.
How many dichloro products are formed in the above reaction (including stereoisomers)?
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Key: 7
Cl
Cl Cl Cl

* Cl
Cl2  excess 
  * 
 3stereoisomers 
Cl
Sol:   3stereoisomers

10. 3-methylpent 2-ene on reaction with HBr in presence of peroxide forms an addition
product (A). The number of possible stereoisomers for ‘A’ is……..
Key: 4
Sol: The complete reaction is as follow
HBr * *
CH 3  CH  C  CH 2  CH 3 CH 3  CH  CH  CH 2  CH 3
Peroxide
CH 3
3  methylpent  2  ene Br CH 3
 A

Number of stereocenter  n   2

Number of possible stereoisomers  2 n  2 2  4


11. How many isomers with molecular formula C6 H12 gives Acetaldehyde in reductive
ozonolysis as one of product
Key: 6
Sol: C  C  C  C  C  C cis & trns
C

C  C  C  C  C cis & trns

C  C  C  C  C cis & trans

Total six isomers give acetaldehyde on reductive ozonolysis.


12. How many alkenes on catalytic hydrogenation given isopentane as a product?
Key: 3

H 2 Pt

H 2 Pt

H 2 Pt
Sol:
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 97
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-04
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Statement–I: Sulphate of element ‘A’ has the formula A SO4
Statement –II: Nitride of same element has the formula A3 N 2
1) Statement – I is true, statement – II is true; Statement – II is correct is a correct
explanation for statement – I.
2) Statement – I is true, statement – II is true; statement – II is not correct explanation for
statement – I
3) Statement – I is true; statement – II is false
4) Statement – I is false; statement – II is true
Key: 1
Sol: The valency of ‘A’ Is +2 and Nitride is -3.
2. If 1.15% by mass of sodium is present in 500g of solution of NaOH in water. The
molality of the solution is
1) 0.15 2) 0.75 3) 0.25 4) 0.5
Key: 4
wt of solute 1000
Sol: m 
molecular weight of solute Weight of solvent
3. ' P ' gm of sodium hydrogen carbonate on strong heating gives ' Q ' gm of solid residue and
0.112 L of CO2 at S.T.P. The normality of solution obtained by dissolving solid residue
in
500ml water is
1) 0.5 2) 0.3 3) 0.1 4) 0.02
Key: 4

Sol: 2NaHCO3  Na2CO3  H 2O  CO2


weight 1000
Normality 
equivalent weight vol in ml
4. Choose the correct statement (s) regarding alkynes.
Statement-I: All alkynes are gases at room temperature
Statement-II: Except ethyne, alkynes are odorless
1) Statement-I and II are true 2) Statement-I is true II is false
3) Statement-I is false II is true 4) Statement-I and II are false
Key: 3
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C2  C4 gases  C13 Solids
C5  C12 Liquids
Sol:
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
5. The mole fraction of sucrose  C12 H 22O11  in an aqueous binary solution is 0.2. the mass
percentage of sucrose in the solution is, _____ (nearest integer)
Key: 83

number of moles of sucrose


Sol: mole fraction of sucrose=
total number of moles
weight of sucrose
mass percent of sucrose=  100
total weight of solution
6. The degree of unsaturation for Naphthalene is ____
Key: 7

Sol: Degree of unsaturation = No of bond + number of rings

527

7. 0.6g of an organic compound (A) with 40% carbon will produce _______ 103 liter of
CO2 at STP on complete combustion (Molar volume  22.4 )
Key: 448

0.6 g  100% 0.6  40 12 g  22.4


Sol: ;  0.24;
?  40% 100 0.24  ?
8. How many different isomeric alkynes on catalytic hydrogenation can give 2,3,4, -
trimethyl heptane
Key: 8

6 *
5 * 2 2 H 2 / pt
4 * *
7 3 1
Sol:
4,5,6-trimethyl -1-hept ne

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* 2 2 H 2 / pt
* 1
7 6 5 4
3

4,5,6- Trimethyl hept – 2-yne


9. The density of 1.4M solution of sulphuric acid is 1.372 g/ml. the percentage by mass of
solution will be ____
Key: 10
% w / w  density  10
Sol: M 
mol.wt of solute
10. How many of the following are Meta directing groups in electrophilic substitution in
benzene nucleus is/are
O O O
O  C  CH 3 ,  C  O  CH 3 ,  NH  C  CH 3 ,  NH 2
Key: 1

O
C  O  CH3
Sol: is a meta directing group
11. One litre of an alkene with the formula C x H y [mol. wt- 56 ] reacts with ‘X’ litres of
oxygen for its complete combustion at STP. The value of ‘X’ is
Key: 6
Sol: C4 H 8  6O2  4CO2  4 H 2O
12. The number of atoms present in 32g of oxygen gas is [At wt of ' O '  16 ] A 1023
 N  6  1023  the value of ‘A’ is
 A 
Key: 12
Sol: moles  N A  2
cold dil alk KMnO4
1  Butyne A  CO2
13. The total number of SP 2 hybrid orbitals
present in
product A.
Key: 3

cold .dil.alk
CH 3  CH 2  C  C  H CH 3  CH 2  COOH  CO2
KMnO4
Sol:
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RPTM-05
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The decreasing order of reactivity of the following compounds towards nucleophilic
substitution reaction is

1) (II>(III)>((I)>(IV) 2) (II)>(III)>(IV)>(I)
3) (III)>(II)>(IV)>(I) 4) (IV>(II)>(III)>(I)
KEY: 2
SOL: Conceptual

2. An 'Assertion' and 'Reason' are given below. Choose the correct answer from the
following options.

Assertion (A): Vinyl halides and Aryl halides do not undergo nucleophilic substitution
easily.
Reason (R): Even though the intermediate carbocation is stabilized by loosely held π-
electrons, the cleavage is difficult because of strong bonding.
1) Both (A) and (R) are wrong statements
2) Both (A) and (R) are correct statements and (R) is the Correct explanation of (A)
3) Both (A) and (R) are correct statements but (R) is not the correct explanation of (A)
4) (A) is a correct statement but (R) is a wrong statement.
KEY: 4
SOL: Conceptual
3.

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Cl
Br


Aqueous . KOH
 Product

NO2

The product mixer obtained is treated with AgNO3 solution correct statement is

1) A pale-yellow precipitate of AgBr is formed 2) A white precipitate of AgCl is formed


3) No precipitate is formed 4) It is a nucleophilic addition substitution reaction
KEY: 2
SOL: Conceptual
4. Ratio of mole of FeSO4 oxidized by equal volume of equimolar K 2Cr2O7 and KMnO4
solution in acidic medium is

1) 6: 5 2) 5 : 6 3) 5 : 3 4) 3 : 5

KEY: 1
SOL: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
5. The total number of monohalogenated organic products in the following (including
stereoisomers) reaction is ….
( i ) H 2 / Ni / 
A ( ii ) X 2 / 

( simplet optically
active hydrocarbon alkene )

KEY: 8
SOL: Conceptual

6. Identify number of substrates those can give S N 1 and S N 2 reactions both:

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CH 3

H 3C Cl Br

CH 2 Br O Cl
CH 3 Br , Ph H 3C
, , ,
OTf
Br Cl

Cl
O CH 3 CH 2 Cl
, , , ,
Br

KEY: 6
SOL: Conceptual

7. CHCl3 Ag
powder
 ‘A’ 
5000 C
 ’B’ 
Cu red hot
CH 3COCl
AlCl3
 ‘C’ 
PCl5
 ‘D’ 
3 NaNH
 ‘E’ 2

 ‘F’   ‘G’ The number of oxygen atoms in ‘G’ are``


HgSO4 / H 2 SO4

CH 3 I

KEY: 1
SOL: Conceptual

8. Total number of species from the following which can undergo disproportionation
reaction is ……. H 2O2 , ClO3 , P4 , Cl2 , Ag , Cu 1 , F2 , NO2 , K 

KEY: 6
7 3 4
SOL: K MnO4  H 2 C2 O4  Mn 2  C O2 (Unbalanced) (n factor =5) (n factor = 1 2  2 n factor of
KMnO4

nKMnO4  Change in O.N. of Mn × no. of atoms in 1 molecule of KMnO 4=5×1=5

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N factor of H 2C2O4
n
H 2C2O4  changeinO.N .of C ×no. of atoms in 1 molecule of H 2C2O2 = 1  2  2

By law of equivalence:

Equivalents of KMnO4  Equivalents of H 2C2O4

N factor of KMnO4  moles of KMnO4 =n factor of H 2C2O4 = n factor H 2C2O4  moles of


H 2C2O4

5 milli moles of KMnO4 =2× mill moles of H 2C2O4

5× M KMnO 4  VKMnO4  (in mL )  2  M H 2C2O4  VH 2C2O4 (in mL )

5  M KMnO4  2mL  2  2 M  2mL

M KMnO4  8M

9. When 10 ml of an aqueous solution of KMnO4 was titrated in acidic medium, equal


volume of 0.1 M of an aqueous solution of ferrous sulphate was required for complete
discharge of colour. The strength of KMnO4 in grams per litre is …. 10 2 .

[Atomic mass of K = 39, Mn = 55, O = 16]


KEY: 316
SOL: In acidic medium MnO  of KMnO4 changes to Mn 2

MnO4  5e  Mn2 .....(i)

Fe2  Fe3  e ..........(ii)

eqn.(1)  1  eqn(2)  5

MnO4  5Fe2  pdt

M 1V1 M 2V2

1 5

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M 1 10 0.110

1 5

1 1
M1   KMnO4 is mol per litre
50 50

1
Thus KMnO4 is  158g per litre
50

Thus strength = 3.16 g/L

3.16 g/L

316×10-2 g/L


10. 2MnO  4  bI   x I 2  yMnO2  z O H . If the above equation is balanced with integer

coefficients the value of z is


KEY: 8
SOL: In a disproportionation reaction an element in one oxidation state is simultaneously
oxidized and reduced. (a) and (b) are disproportionation redox reactions.

11. One gram of metallic chloride was found to contain 0.835 g of chlorine. Its vapour
density is 85.5. If its molecular formula is M x Cl y , then what is value of ( x  y ) ?
KEY: 5
SOL: Molar mass of M 2 Cl y =85.5×2= 171 g/mol

(M)(x)+(35.5) (y) =171


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mass of chlorine 0.835 35.5 y
 
mass of metallic chloride 1 M ( x)  (35.5)( y )

On solving y = 4 and x = 1

X+y=5

12. When BrO3 ion reacts with Br  ion in acidic medium, Br2 is liberated. Calculate the ratio
of molecular mass and equivalent mass of KBrO3
KEY: 5
5 1 0
SOL: BrO  Br   H   Br2 (l )

3

n-factor =5

M KBrO3
EKBrO3 
5

13. A sample of 28 ml of H2O2 (aq) solution required 10mL of 0.1 M KMnO4 (aq) solution for
complete reaction in acidic medium. What is the volume strength of H2O2 ?
KEY: 1
SOL: eq. of H 2O2  Eq of KMnO4

(25×M×2)=(10×0.1×5)

M=0.089

Volume strength =M×11.2=1

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-06
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Consider the following table.
Gas a / k Pa ( dm6mol 2 ) 
b / d dm3mol 1 
A 642.32 0.05196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a and b are van der Waals’ constants. The correct statement about the gases is:
1) Gas C will occupy lesser volume than gas A; gas B will be lesser compressible than gas D.
2) Gas C will occupy more volume than gas A; gas B will be more compressible than gas
D.
3) Gas C will occupy more volume than gas A; gas B will be lesser compressible than
gas D
4) Gas C will occupy more volume than gas A; gas B will be lesser than gas D.
Key: 2
 a 
Sol: . For 1 mole of real gas, the van der Waals’ equation is  p   (V  b )  RT
 V2 

The constant ‘a’ measures the intermolecular force of attraction of gas molecules and the

constant ‘b’ measures the volume correction by gas molecules after a perfectly inelastic
binary collision of gas molecules.

For gas A and gas C given value of ‘b’ is 0.05196 dm3 mol 1 .Here, a  intermolecular
force of attraction  compressibility  real nature  1/volume occupied value of
a / (kPa dm6 mol 1) for glass A (642.32)>gas C (431.91) So, gas C will occupy more
volume than gas A. Similarly, for a given value of a say 155.21kPa dm3 mol 1 for gas B
and gas D 1/b  intermolecular force of attraction  compressibility  real nature  1/
volume occupied

b/( dm3 mol 1 ) for gas B(0.04136)< gas D (0.4382)


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So, the gas B will be more compressible than gas D.

2. Two flasks I and II shown below are connected by a value of negligible volume.

When the value is opened, the final pressure of the system in bar is x  102 . The value of
x is ………… (integer answer) [Assume, Ideal gas, 1 bar = 105 pa, molar mass of
N 2  28.0 g mol 1; R  8.31 J mol 1k 1 ]
1) 34 2) 59 3)84 4) 14
Key: 3

Sol: .

On mixing the temperature of gas become T. Internal energy lost by has A is the internal
energy gained by gas B.

U A  U B

f f
n A RTA  nB RTB (As both gases are diatomic, f is same on both sides)
2 2

n ATA  nB TB

2.8 0.2
 T1  T   T  T2 
28 28

1 1
 300  T   T  60 
10 140

T  248K

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
On mixing temperature becomes 284 K and volume becomes 3L and total number of
moles becomes  n A  nB   0.10 moles.

0.10  8.3  284


According to gas equation, pV   n A  nB  RT   84.13atm or 84.18 bar
3

This is final pressure of gas.

3. Which is valid at absolute zero?


1) KE of the gas becomes zero, but molecular motion does not become zero.
2) KE of the molecules becomes zero and the molecular motion also becomes zero.
3) KE of the gas decreases but does not become zero.
4) KE of the gas decreases but molecular motion increases.
Key: 2
Sol: A fact at zero Kelvin.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

4. An open steel vessel has an ideal gas at 270 C . The fraction of the gas escaped if the
vessel and its contents are heated to 1270 C is x  102 . (Neglect the expansion of the
steel). x value is ___
Key: 25
Sol: n1T1  n2T2

300
n2 
400

The fraction of gas escaped from vessel upon heating 1-3/4=1/4

5. A balloon has a maximum capacity of 20L. At one atmosphere pressure less than 10L of
air is filled in the balloon. It will burst when pressure is x  101 atm. (assuming
isothermal condition). x value is ___
Key: 5
Sol: The balloon would burst when V> 20 L

1 1  P2V2
PV

110  P2  20

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P2  0.5 atm (no bursting)

Thus, a pressure below 0.5 atm, it would burst.

6. Calculate the kinetic energy of 1 mole of oxygen molecules in cal mol 1 at 270 C is--------
---
Key: 900
3 3
Sol: KE  nRT   1  2  300 = 900
2 2
7. Two grams of hydrogen diffuse from a container in 10 minutes. How many grams of
oxygen would diffuse through the same container at the same time under similar
conditions?
Key: 8
nH 2 MO2
Sol: 
nO2 M H2

2
2
2  3  16  4
wO2 2
32

32
wO2   8 gm
4

8. How many structural cyclic ethers are possible for C 4H8O _________
Key: 6
Sol:

9. How many monohydric phenols are possible for the molecular formula C7 H8O _______
Key: 3
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OH OH OH

CH 3

CH 3

CH 3
Sol:
10. How many structural primary alcohols are possible for C5H12O ________
Key: 4
C

C  C  C  C  C  OH C  C  C  C  OH
Sol:

C C
CCCOH CCCOH
C C
11. How many given compounds can react with NaOH _______

C2H5OH,CH3COOH,C6H5OH,Picric acid
Key: 3
Sol: CH3COOH , C6 H5OH , Picric acid.

Because they are more acidic than water.

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RPTM-07
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Which of the following statements is incorrect?
1) In equilibrium mixture of ice and water kept in perfectly insulated flask mass of ice
and water does not change with time.
2) The intensity of red colour increases when oxalic acid is added to a solution
containingiron (III) nitrate and potassium thiocyanate.
3) On addition of catalyst the equilibrium constant value is not affected
4) Equilibrium constant for a reaction with negative H value decrease as the temperature
increase
Key: 2
Sol: The red color intensity remains constant

2. Assertion (A): In the dissociation of PCl5 at constant pressure and temperature addition of
helium at equilibrium increases the dissociation of PCl5
Reason (R): Helium removes Cl2 from the equilibrium mixture.
1) Both A and R are true, and R is correct explanation of A
2) Both A and R are true, but R is not correct explanation of A
3) A is true but R is false.
4) Both A and R are false.
Key: 3
Sol: Conceptual
3. The major product of the following reaction is:
1)DIBAL  H
2)H 3O 

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OH

CHO

1) CH2-CHO 2) CH2OH

OH

3) CH2-CHO 4)
Key: 3
DIBAL  II
Sol: a ) R  CN   R  CHO
DIBAL  II
b) RCOOR '   R  CHO  R ' OH
1) AlH  i  Bu  2 ?
R C  N
2)H 3O 
4.
Consider the above reaction, when in reagent hydrogen atom is replaced by deuterium.
The product formed is
1) R  CHO 2) R  CONH 2 3) R  COND2 4) R  CDO

Key: 4
N-Al (i-Bu2)

D
Sol: DIBAL  D
R  C  N   R

5. Statement-(I): A buffer solution is the mixture of a salt and an acid or a base mixed in any
particular quantities.
Statement-(II) Blood is naturally occurring buffer solution whose pH is maintained by
H 2CO3 / HCO 3 concentrations
Choose the most appropriate answer from the options given below.
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1) Statement I is incorrect, but statement II is correct
2) Both statement I and statement II are incorrect
3) Statement-I is correct but Statement II is incorrect
4) Both statement -I and statement II are correct
Key: 1
Sol: Acidic buffer: solution of weak acid and its salt with strong base.

Basic buffer: solution of weak base and its salt with strong acid

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. How many different aldehyde isomers (including stereo isomers) exist for C5 H10O
Key: 5

CHO
CHO CHO
* 3) 4)
1) CHO 2)
Sol:

3CH  CH 
Fe
 A 
CH 3Cl
B
1 2Cl2 / h X
7.  AlCl3
 2  H 2O / 
How many C-atoms are present in x
Key: 7
A  C6 H 6
Sol: B  C6 H 5CH 3
C  C6 H 5CHO

8. A buffer solution contains 0.2 mole of NH 4OH and 0.2 mole of NH 4Cl per liter. The P of kb

NH 4OH is 4.75 calculation the P H of the buffer (Round off to nearest integer)

Key: 9
salt 0.2
Sol: P kb  log  4.75  log
base 0.2

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 P  14  P
H OH
 14  4.75 =9.25
10. What is the sum of basicity of H3 PO4 , H3 PO2 , H 3 BO3 ,

 COOH 2 , H 2 S2O8 , H 2 SO3 , H 2CO3 , H 2 S , H 4 P2O5 , H 2 SO4


Key: 21
Sol: H 3 PO4  3, H 3 PO3  2, H 3 PO2,  1, H 3 BO3  1,  COOH 2  2

H 2 S2O8  2 H 2 SO4  2, H 2 SO3  2, H 2CO3  2, H 2 S  2, H 4 P2O7  4

11. If Ksp of Ag2CO3 is 8 1012 , the molar solubilities of Ag2CO3 in 0.1 M AgNO3 is___ 1010
Key: 8
2
Sol: K SP   Ag   CO32 

8  1012  0.1 CO32 


2

CO3 2   8  1010

OH

Pcc  excess 
OH  A

12.
Number of oxygen atoms in product ‘A’ is
Key: 2
O
OH
CHO

OH
PCC

Sol:
13. Vanillin compound obtained from vanilla beans. The ratio of number of SP 2 hybridised
carbon atoms and the number of pi bonds present in vanillin is “X”. Find the value of
4X?
Key: 7
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Sol:
14. Calculate the approximate PH of a 0.1M H 2 S  aq  solution. The first and second
dissociation constant of H 2 S are 1 10 7 and 1.3  1014 respectively
Key: 4
Sol:  H 2S   0.1  x  0.1
 H  HS   x Ka  Ka
  2
1 2

1 107  x 2 / 0.1 , x  1 104   H  

 P H  4.
 NH 3  H 2 S is Kp  12
NH 4 HS 
15. If 250 C , the equilibrium constant for the reaction
s g g
A 10.0 liter flask is discharged with 1 atm of pure NH 3  g  at 250 c what is the minimum

mass in grams of NH4 HS , that must be added to the flask in order to achieve equilibrium?
(round off the nearest integer)
Key: 63
NH 4 HS  NH 3  H 2 S KP  PNH 3 .PH 2S
Sol: S  g g 12   p  1 p
p 1 p p  3 atm

Applying ideal gas equation for H 2 S

PV  nRP
3  10  n  0.0821 298, n  1.2262
 moles of NH 4 HS is =1.2262

Wt. of NH 4 HS  1.2262  51  62.54 g  63 g

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-08
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Identify the reagents used for the following conversion

1) A  LiAlH 4 , B  NaOH  aq , C  NH 2  NH 2 / KOH , Ethylene glycol

2) A  DIBAL  H , B  NaOH  aq  , C  NH 2  NH 2 / KOH , Ethylene glycol

3) A  DIBAL  H , B  NaOH  aq , C  Zn / HCl ,

4) A  LiAlH 4 , B  NaOH  aq , C  Zn / HCl ,

Key: 2
OCH3
DIBAL-H CHO
O NAOH(aq)
OH CHO aldol
CHO OH
Sol: .

CHO

NH2NH2/KOH
ethylene glycol

OH
2. In the given reaction the main product will be

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1) 2)

3) 4)
Key: 1

CH MgBr

3

O O OMgBr



H

O O
Sol: Me
3. Reagent that can be differentiate 2-propanol from acetone is
3) Ce  NO3 4
 2
1) NaOH / I 2 2)  Ag  NH 3 2  4) Cu  NH 3 4 

Key: 3
Sol: Ce  NO3 4 is used to differentiate

4. Me3B, BH3 and BF3 are three Lewis acids, which one of the following is the correct
sequence of acid strength?
1) Me3 B  BH 3  BF3 2) Me3 B  BF3  BH3
3) BF3  BH3  Me3 B 4) BF3  Me3 B  BH3
Key: 4
Sol: Lewis acids are electron deficient species, A species with more deficient central atoms
will be a strong Lewis acid. F being an electron with drawing group, makes B more
deficient but on the other hand, it decreases the deficiency by back bonding. H is unable

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to do such a back bonding due to the absence of lone pair. Me is an electron releasing
group. Thus, makes the boron least electron deficient.
5. Assertion (A): The stability of superoxide’s of alkali metals follows the order
CsO2  RbO2  KO2

Reason (R): As the size of alkali metal ion increases the lattice energy increases and
hence the stability of super oxides increases
1) Both (A) and (R) are true and (R) is correct explanation of (A)
2) Both (A) and (R) are true but (R) is not correct explanation of (A)
3) (A) is true but (R) is not true
4) (A) is not true (R) is true
Key: 1
Sol: Both (A) and (R) are true and (R) is the correct explanation of (A)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. How many of the following can be used to distinguish acetaldehyde and benzaldehyde
(i) Tollen’s (ii) Fehling’s (iii) Benedict’s (iv) NaHSO3 (V) NaOI
(vi) 2,4-DNP (vii) CAN (viii) NaHCO3 (ix)NaOH/I2 (X) Lucas
reagent (xi) Neutral FeCl3
Key: 4
Sol: ii, iii, v, ix,  +ve test with Acetaldehyde
I, iv,vi,  +ve test with both Acetaldehyde and Benzaldehyde
Vii,viii, x, xi  -ve test with both

7.
Number of halogens, hydrogen and carbon atoms in the molecular formulae of compound
‘A’ are x, y, z respectively. Find x+ y- z value.
Key: 3
Sol: A is CHCl3
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X =3 , Y = 1 , Z = 1
X +Y –Z = 3 +1 – 1= 3

8.
Find the value of 2 x  3 y  ________
Key: 17
Sol: Butanone +4 KOH +3 I 2  CH I 3 

X=4,y =3
2x + 3y = 2 (4)+3(3) = 8 + 9 = 17
Cl

NBS Aq.KOH CrO3/py/HCl


C D
A B
NaNH2
(excess)

Cl Cl

CH3
9.
Calculate the number of SP 2 hybrid orbitals of carbon atoms in the structure of ‘D’
Key: 21
Cl

CrO3 / Pg / HCl
3NaNH2 NBS
Cl
Cl
CH3
CH2Br CH2OH O=C-H
CH3 (B) (C) (D)
Sol: (A)

Total no. of Sp 2 carbons in ' D '  7

1S  2 P  3SP 2

7  3  21

10. How many of the following undergo disproportionation on reaction with NaOH

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i) Cl2 ii) S iii) P( white) iv) B v) Si vi) Al vii) Hg
Key: 3
Sol: P4  s   3OH   aq   3H 2O(l )  PH 3  g   3H 2 PO2  aq 

S8  s   12OH   aq   4S 2  aq   2S 2 O32  aq   6 H 2O(l )

Cl2 ( g )  2OH   ClO   aq   Cl   aq   H 2O  l 

11. How many water molecules are associated with “EPSOM Salt”?
Key: 7
Sol:
12. How many of the following pairs show similarity in their radii?
Li  ; Mg 2 ; Na , Ca 2 ; K  , Sr 2 ; Be2 , Al 3 ; B , Si; N , S ; F , Ar ; Mg 2 , Al 3

Key: 2
Sol: MgSO4 7 H 2O

13. How many of the following salts gives Borax bead test.
1) Copper salts 2) Cobalt salts 3) Nickel salts 4) Aluminium salts
Key: 3
Sol: ‘3’ [Copper salt, cobalt salts, Nickel salts]
14. How many compounds given below are correctly matched with their uses?
1) Borax solution : Buffer
2) AlCl3 : Friedel-crafts reaction
3) Ca  OH 2 : Bleaching powder

4) CaCO3 : mild abrasive in tooth paste


5) B(OH )3 : Manufacture of heat resistant glasses
6) NaBH4 : Reducing Agent
Key: 6
Sol: All are correct

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RPTM-09
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The correct statement among the following is.
1) ( SiH 3 )3 N is planar and more basic than  CH3 3 N

2) ( SiH 3 )3 N is pyramidal and more basic than  CH3 3 N

3) ( SiH 3 )3 N is planar and less basic than  CH3 3 N

4) ( SiH 3 )3 N is pyramidal and less basic than  CH3 3 N


Key: 3
Sol: In  SiH 3 3 N , “Si” has vacant d- orbital it’s overlap with lone- pair electron from
nitrogen, due to overlapping it is in planar

2. The increasing order of the acidity of the following carboxylic acids is?

1) III  IV  I  II 2) IV  III  I  II 3) II  I  IV  III 4) I  II  III  IV


Key: 1
Sol: Acidic strength of benzoic acid depends on nature of the substituent on benzene ring

Note: Ortho substituted benzoic acid is stronger acid (due to ortho effect)

3.
The major product is.
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1) 2)

3) 4)
Key: 2
Sol:

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
4. The number of ions from the following that are expected to behave as oxidizing agent is
___
Sn 4 , Sn 2 , Pb 2 , Ti 3 , Pb 4 , Tl 
Key: 2

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2 3
Sol: Pb , Tl act asa a oxidizing agents (due to inert pair effect)

5. Total number of pi (  ) bonds in CO2 , C3O2 molecules _____________


Key: 6
Sol: CO2 O  C  O 2 Pi ( )  bonds

C3O2 O  C  C  C  O 4 Pi( )  bonds

SIX Pi ( )  bonds

6. ‘CO’ forms carboxy hemoglobin on combining with hemoglobin. It is


X
‘X’ times stronger than oxy- Hemoglobin complex, then is _____________
2
Key: 150
Sol: Carboxy- Haemoglobin 300 times stable than oxy-Haemoglobin

7. How many moles of CO2 will released when following compound on heating?

Key: 4
Sol:  - Keto carboxylic acids undergo decarboxylation

8. Sodium benzoate
NaOH  CaO Conc  H 2 SO4

X 
Cl2 , FeCl3
310 320 K
 Y  
 Z ( Major product )
Gram molecular weight of the major product (in grams) is __________ (Nearest Integer)
Key: 193
Sol: Molecular weight = 192.5

9. How many bromine atoms are there in the final product in the reaction? __________
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Key: 3

Sol:
10. How many of the following reagents can be used to convert carboxylic acid to the
corresponding acid chloride?
i) NaCl ii) Cl2 iii) PCl3 iv) PCl5 v) SOCl2
Key: 3
Sol: PCl3, PCl5, and SOCl2 can be used for this conversion.

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RPTM-10
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. SbF5 reacts with XeF4 to form an adduct. the shape of cation and anion in the adduct are
respectively
1) Square planar, trigonal bi pyramidal 2) T-shaped, Octahedral
3) Square pyramidal, octahedral 4) Square planar, octahedral

Key: 2

Sol: XeF4  SbF5   XeF3  SbF6 


 

  XeF3   SbF6 
 

sp3d sp3d 2

T-shaped octahedral

2. The correct order of Cl–O bond length in ClO  , ClO2 , ClO3 , ClO4

1) ClO  ClO2  ClO3  ClO4


   
2) ClO4  ClO3  ClO2  ClO 

3) ClO3  ClO4  ClO2  ClO


   
4) ClO4  ClO3  ClO2  ClO 
Key: 2

Sol: Bond length is inversely proportional to bond order. Greater than delocalization of  e  (-
ve charge) shorter the bond length.

3. The major product (70% to 80%) of the reaction between m-dinitrobenzene with NH 4 HS
is

1) 2) 3) 4)

Key: 3

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Sol: With NH4HS, m-dinitrobenzene undergoes selective reduction to afford m-nitroaniline.
4. Which of the following gives positive Libermann–nitroso test?
1) 2–butanamine 2) N–ethyl–2–pentanamine
3) N–methylpiperidine 4) N, N–dimethylcyclohexylamine
Key: 2

Sol: 20 amine will give positive nitrosamine test.

CH3
|
CH3  CH 2  CH 2  C H  NH  Et
N-ethyl-2-pentamine)
2 0
a min e 

5. The product of a reaction between methyl isocyanate (MIC) and ethanol is urethane with
formula
1) CH 3  NHCOOC2 H 5 2) C 2 H 5  NHCOOCH 3

3) CH3  NHCOOCH3 4) C2H5  NH  COOC2H5

Key: 1
    CH3  N  C  OH 
Sol: CH3  N  C  O CH3 CH2 O H   |
 
Tautomerises

 OCH CH3
Methyl isocyanate 2

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. 9.3 g of pure aniline upon diazotization followed by coupling with phenol gives an
orange dye. The mass of orange dye produced (assume 100% yield/conversion) is …….
g. (nearest integer)
Key: 20
Sol:

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1 mole of aniline give 1 mole of orange dye,


so  mol aniline   mol orange dye

9.3g mass of orange dye


1

93g mol 199g mol1

Mass of orange dye = 19.9 g = 20 g.

7. A compound (x) with molar mass 108 g mol1 undergoes acetylation to give product with
molar mass 192 g mol1 . The number of amino groups in the compound (x) is ….

Key: 2
O O
|| ||
Sol: R  NH 2  CH 3  C  Cl  R  NH  C  CH 3

Gain in molecular weight after acetylation with one  NH 2 Group is 42.

Total increase in molecular weight = 192 – 108 = 84


84
 number of amino groups  2
42
8. How many isomeric amines with the formula C7 H 9 N contain a benzene ring

Key: 5

Sol:
9. The number of moles of electrons involved in the reduction of one mole of nitrobenzene
by H 2 gas with Ni-catalyst is:

Key: 6
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Ni  catalyst
Sol: CH 3  NO2  6  H   CH 3  NH 2  2H 2O

10. Reaction of benzamide with Br2 in aqueous NaOH gives aniline, sodium carbonate and
sodium bromide. The stoichiometric coefficient of NaOH in the reaction is :
Key: 4
O
||
Sol: C6 H 5  C  NH 2  Br2  4NaOH  C6 H 5  NH 2  2NaBr  Na 2CO3  2H 2O

11. Cyclic trimer structure of SO 3 contains …… number of ‘S = O’ bonds.


Key: 6

Sol:
12. The sum of bond order in O 2 and O3 molecules is ……. (nearest integer)
Key: 4
Sol:

O=O
Bond order O 2 = 2, Bond order O3 = 1.5
13. The sum of lone pairs present in interhalogen BrF5 and IF7 is …….
Key: 37

Sol: BrF5 has 1 lone pair and IF7 has zero lone pair on central atom
F has 3 lone pairs
Total no. of lone pairs = [1 + 3(5)] + [0 + 7(3)] = 37
14. The ratio of number of p  p bonds to p  d bonds in XeO 3 is
Key: 0
Sol: p  p  0, p  d  3
15. What is covalency of chlorine atom in second excited state?
Key: 5
Sol: Conceptual

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RPTM-11
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Ebonite is
1) Natural rubber 2) synthetic rubber
3) highly vulcanized rubber 4) poly propene
Key: 3
Sol: Huge cross linking substance

2. Statement 1: Glyptal is obtained by the condensation polymerization of ethylene glycol


and phthalic acid.
Statement 2: Glyptal is used in the manufacture of paints and lacquers.
1) Statement 1 is false, statement 2 is true
2)Statement 1 is true, statement 2 is true; statement 2 is not a correct explanation of
statement 1
3) Statement 1 is true, statement 2 is true; statement 2 is a correct explanation of
statement 1
4) Statement 1 is true, statement 2 is false
Key: 2
Sol: Due to cross links by Sulphur

3. Number of peptide linkages in the artificial sweetener “aspartame” is


1) 2 2) 21 3) 1 4) 11
Key: 1
Sol: Conceptual
4. How many base pairs are present in each full turn of the DNA double helix?
1) 4 2) 6 3) 8 4) 10
Key: 4
Sol: Conceptual
5. Isoelectric point is
1) the pH at which all molecular species are ionised and that carry the same charge
2) the pH at which all molecular species are neutral and uncharged
3) the pH at which half the molecular species are ionised (charged) and other half
unionized
4) the pH at which negatively and positively charged molecular species are present in
equal concentration
Key: 2
Sol: Conceptual
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6. (A): Lactose on hydrolysis gives glucose and galactose.
(R): Lactose is an example of disaccharide.
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct and R is correct
Key: 2
Sol: Conceptual
7. A. Ammonium salts produce haze in atmosphere.
B. Ozone gets produced when atmospheric oxygen reacts with chlorine radicals.
C. Polychlorinated biphenyls act as cleansing solvents.
D. 'Blue baby' syndrome occurs due to the presence of excess of sulphate ions in water.
Choose the correct answer from the options given below:-
1) A, B and C only 2) B and C only 3) A and D only 4) A and C only
Key: 4
 
Sol: B) C l  O3  O2  Cl O
(D) ‘Blue baby’ syndrome occurs due to the presence of excess of NO3 ions in water

8. (A): Polluted water may have a value of BOD of the order of 17 ppm.
(R): BOD is a measure of oxygen required to oxidize both the biodegradable and non-
biodegradable organic material in water.
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct and R is correct
Key: 3
Sol: A: Clean water should have B.O.D < 5ppm. While highly polluted water have

B.O.D > 17ppm.


R: Only Bio-degradable organic matter

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
9. Sum of nitrogen atoms in the monomers of nylon-6 and nylon-6,6 is x and sum of carbon
y
atoms in them is y. Then is ___________
x
Key: 6
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Sol: C-atoms = 6 + 6 + 6 = 18 = y. (nylon – 6, Nylon – 6, 6)
N-atoms = 2 + 1 =3 = x
y/x = 18/3 = 6

10. In a polymer sample, 25% molecules have a molecular mass of 14,000, 50% have
molecular mass of 40,000 and rest have 50,000. Calculate the sum of mass average and
K
number average molecular masses = K then,  _____________(Nearest integer)
100
Key: 769
Sol: K = 76944
K/100 = 769.4

11. The total number of lone pairs of electrons in melamine is __________


Key: 6
Sol: Conceptual
12. How many compounds which is given below is isomer of D-Glucose?
a. D-Mannose, b. D-Fructose, c. D-Glucose, d. D-Idose, e. D-Galactose, f. D-Arabinose,
g. D-Ribose. ___________
Key: 5
Sol: a, b, c, d, e

13.
CH2OH
C=O

H OH

(i) NaBH4
HO H (P)
(ii) H+, H2O
H OH

CH2OH
D-sorbose
Numbers of stereoisomer of product (p) is: ____________
Key: 10
Sol: 241  2(4/2)1  10

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14. An atomic substance A of molar mass 12 g mol 1 has a cubic crystal structure with edge
length of 300 pm. The no, of atoms present in one unit cell of A is __________. (Nearest
integer). Given the density of A is 3.0 g mL1 and N A  6.02  1023 mol 1
Key: 4
d  N A  a3
Sol: Z
M
15. Atoms of an element B form hcp lattice and those of the element A occupy 2/3 rd of
tetrahedral voids. How many number of atoms of A and B (in total) are present in the
help lattice?
Key: 7
Sol: The ratio of A : B = 4 : 3
A4B3 A + B = 4 + 3 = 7

16. In CsCl with cubic structure, Cl- ions are located at each corner and Cs+ ions at the centre
 
of the unit cell. If rCs  and rCl  are 1.69 A and 1.81 A respectively. Find the value of edge
length of cube.
Key: 4
Sol: Body diagonal 3a  AB
2(rCs   rCl  )  3a

22(1.81  1.69)  3a
a  4.04 A

17. An element crystallizes into a structure which may be described by a cubic of unit cell
having one atom on each corner of the cube and two atoms on one of its diagonals.
Volume of the unit cell is 2.4 x 10-23 cm3 and density is 13.82 g cm-3. Number of atoms
present in 200 g of the element is y x 1023. What is the value of y?
Key: 18
ZM
Sol: d 3 30
g / cm3
N A  a  10
18. Calcium crystallizes in fcc unit cell with 0.556nm. Calculate the density in (g/cm3). It
contains 0.2% Frenkel defects and 0.1% Schottky defects. (Round off Nearest Integer)
Key: 2
Z eff  Aw
Sol: d
N A  a3

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RPTM-12
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Henry’s law is valid for
A) Ammonia gas dissolution in water B) O2 gas dissolution in unsaturated blood
C) O2 dissolution in water D) Argon dissolution in water
1) A and B 2) B and C 3) C and D 4) B and D
Key: 3
Sol: For a gas is abey henry’s daw , it should not react with the liquid , Henry’s law is valid
for O2 and CO2 dissolution in water
2. What mass of non – volatile solute of urea to be dissolved in 100 g of water in order to
decrease it’s vapour pressure by 30% (consider solution is dilute)
1) 132.3 g 2) 100 g 3) 153.3g 4) 163.3 g
Key: 2
P 0  100 mm
P O  Ps  30 PO  P S
m1 W2
Sol:  X
100  Ps  30 PO m2 W1
p s  70
100  70 w2 x18

100 100 x60
w2 x18
0.3 
100 x 60

w2  100 g
3. The strength as oxidizing agent of following species in acidic medium decreases in the
order
2
2 2 
1) S 2O8  Cr2O7  MnO4 2) C r2 O 2
7  S 2 O 8  M nO 4
 2 2
3) MnO4  Cr2O7  S2O8 4) S 2O8 2  MnO4  Cr2O72
Key: 4
Sol: S 2O82  2e  2So42 E 0  2.01V

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   2
MnO 4  8H  5e  Mn  4 H 2O E  1.77V O

Cr2o72  14 H   6e  2cr 3  7 H 2O E O  1.33V

The highest Eo value of atom is best oxidizing agent


4. The sum of the first three ionization energy of the lanthanoids Ce, Eu, Gd , Yb , Lu is
1) Ce > Eu > Gd > Yb > Lu 2) Yb > Lu > Eu > Gd > Ce
3) Yb > Eu > Lu > Gd > Ce 4) Yb > Eu > Gd > Lu > Ce
Key: 3

Sol: In lanthanoides from left to right size  I P 

Yb  Eu  Lu  Gd  Ce
5. Assertion (A): Zn 2 is diamagnetic nature.
Reason (R): The electrons are lost form 4s orbital to from Zn 2
Choose the correct option from following for above.
1) Both A and R are true, and R is the correct explanation of ‘A’
2) Both A and R true and R is not the correct explanation of ‘A’
3) A is true and R is false
4) A is false and R is true
Key: 2
Sol: Zn   Ar  3d 10 4s 2

Zn 2   Ar  3d 10 4 s 0
Zn 2 ion is diamagnetic nature due unpaired electrons absent in d orbitals both (A) and (R)

true and R is not the correct explanation of ‘A’


(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. 0.004M K 2 SO4 solution is isotonic with 0.01 M glucose solution. Percentage dissociation
of
K 2 SO4 is ______________ (Nearest integer)
Key: 75
Sol: Isotonic solution

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 K so   Glu cos e
2 4

i X 0.004 X RT  0.01 X RT
0.01
i   i  2.5
0.004
i  1  (n  1) 
For K 2 So4 ( for dissociation )   i  1  2.5  1  0.75
n 1 3 1
Dissociation = 75
7. How many of the following show positive deviation.
CS 2  CH 3  CO  CH 3 ; CS 2  CH 3  CO  CH 3 ; C6 H 6  C6 H 5CH 3 ;
CH 3  CO  CH 3  CHCl3 ; C2 H 5OH  H 2O ; C2 H 5 Br  C2 H 5Cl ;
C6 H 5OH  C6 H 5 NH 2 ; C2 H 5OH  CH 3  CO  CH 3
Key: 3
Sol: Positive deviation of Negative deviation
Of ideal solution of ideal solution.
H2 0  CH3COOH
H 2O  CH 3OH O

H 2O  C2 H 5OH CHCl3  CH3  C CH3
CHCl3  CCl4
H2O  HNO3
+ CH3OH
O

8. If Hg 2Cl2 is 100% ionized, then its vant’s Hoff’s factor is ______.


Key: 3
100
 1
100
Hg2cl2  Hg 2  2cl
n 3
Sol: i 1
 
n 1
i 1
1
3 1
2  i 1
i  1 2  3
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9. The number of moles of KMnO4 required to oxidise 20 moles of ferrous oxalate in acidic
medium is ______
Key: 12
Sol: The balanced reaction
1 0 F e C 2 O 4  6 K M n o 4  2 4 .H 2 S o 4  3 K 2 S o 4  6 M n S o 4
5 Fe( so3 )3  24 H 2o  2OOCO2

10 Fe c2o4 6 KMno4
20 mole s  x
206
x  12 moles
10
10. The sum of the sigma   and pie (  ) bonds are present in dichromate ion?
Key: 12
2
Sol: Dichromate ion Cr2o 7
O O
O O O
Cr Cr

O O
11. Total number for ions from the following with noble gas configuration is ___________
Sr 2 ( z  38) Cs  ( z  55) , La 2 ( z  57)
pb2 ( z  82) : Yb 2 ( z  70) , Fe 2 ( z  26)
Key: 2
Sol: Sr 2 ( z  38)   Kr  4s 0 ( noble gas )
Cs  ( z  55)  Xe 6s 0 (noble gas ).
12. Number of colorless lanthanide ions among the following is _______________
E u 3 , L u 3 , N d 3 , L a 3
Key: 2
Lu 3   Xe  4 f 14  f 14  n  o colourless
Sol:
La 3   Xe  4 f o  f o  n  o colourless
13. When HCl is passed over one mole of K 2Cr2O7 , the no moles of Cl2 formed is _______
Key: 3
K 2Cr2O7  14 HCl  2 KCl  2CrCl3  7 H 2O  3Cl2
Sol:
One mole of K 2Cr2O7 reacts HCl produces 3 moles of Cl2

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RPTM-13
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. (A): The Daniel cell becomes dead after some time.
(R) : Oxidation potential of zinc anode increases and that of copper cathode decreases.
1) Both (1) and (R) are true and (R) is the correct explanation of (1)
2) Both (1) and (R) are true and (R) is not the correct explanation of (1)
3) (1) is true but (R) is false

4) (1) is false but (R) is true

Key: 1
0
Sol: Ecell becomes zero
2. Resistance of 0.2M solution of an electrolyte is 50 . The specific conductance of the
solution is 1.4 S m 1 . The resistance of 0.5M solution of the same electrolyte is 280 .

The molar conductivity of 0.5M solution of the electrolyte in S mol 1 is

1) 5  104 2) 5  103 3) 5  103 4) 5  102

Key: 1
1 1
Sol:   cm
k 1.4  102

l 1
 R   50  1.4  102 cm
a 

1
k  50  1.4  102  2.5  103 S cm1
280

k  1000 2.5  103  1000


^m  
M 0.5

5.5cm2mol 1  5  104 S m2mol 1

3. When aq. AgNO3 is subjected to electrolysis using inert electrodes, 10.8 grams of silver
is deptosited at cathode. Weight of oxygen liberated at anode will be

a) 1.6g 2) 3.2g 3) 0.8g 4) 0.4g


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Key: 3

WAg E Ag

WO2 E O2
10.8 108
Sol: 
WO2 8
WO2  0.8g
4. Statements are given below:
A) Leclanche cell -------- Reaction at anode Zn  Zn2  2e
B) Ni-Cd cell --------- Rechargeable
C) Fuel cell --------- Does not involve any ion in solution and is used in hearing
aids
D) Mercury cell --------- Converts energy of combustion into electrical energy
Choose the correct answer from the options given below:
1) A,B & C are correct 2) A and B are correct

3) A is correct 4) All are correct

Key: 2
Sol: A. Leclanche cell: It is commonly used dry cell in our clocks the cell consists of a zinc
container that also acts as anode and the cathode is a carbon (graphite) rod surrounded by
powdered managanese dioxide and carbon. The space between the electrodes is filled by
a moist paste of ammonium chloride and zinc chloride.

Anode reaction; Zn  s   Zn 2  2e 

Cathode reaction: MnO2  NH 4  e  MnO  OH   NH 3

B. Ni  Cd Cell: it is a rechargeable cell. It is more expensive to manufacture than lead


storage battery.

Cd  s   2 Ni  OH 3  s   CdO  s   2 Ni  OH 2  s   H 2O  l 

C. Fuel cell: these are galvanic cells that are designed to convert the energy of
combustion of fuels like hydrogen, methance methanol, etc. directly into electrical
energy.

D. Mercury cell:

Zn  Hg   HgO  s   ZnO  s   Hg  l 
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The cell potential is approximately 1.35 V and remains constant during its life as the
overall reaction does not involve any ion in solution whose concentration can change
during its life time.
5. Regarding the process involving discharge of lead storage battery, the correct statements
are
A) Lead sulphate is formed. B) Sulphuric acid is consumed.
C) Specific gravity of sulphuric acid decreases. D) Lead undergoes oxidation.
1) B and D only 2) A, B and D only
3) A, B, C and D 4) B and C only
Key: 3
Sol: During the discharge of lead storage battery,
0 4 2F 2
Pb  Pb O 2  2H 2 SO4  2 Pb SO4  2H 2O
6. The number of linkage isomers for the compound K 4  Fe Cl2  CN 2 C2O4  are
1) 4 2) 6 3) 3 4) 2
Key: 4
Sol: With respect to –CN two linkage isomers. (ambidentate)
SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
7. Molar conductivities at infinite dilution of KCl , HCl and CH 3COOK are 0.013, 0.038

and 0.009 Sm2mol 1 respectively at 291K. If conductivity of 0.001 M CH 3COOH is

2.72  103 Sm1 then find % degree of ionization of CH 3COOH .


Key: 8
 ^ 0M  ^ 0M  ^ 0M 
Sol: ^ 
0
M 
CH 3COOk HCl KCl 
  0.009  0.038  0.013 = 340S  cm2  mole1
^0M  K  103 / M  2.72 103 103 102 / 0.001  27.2S  cm2  mole1
   27.2 / 340   0.08  8%

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RPTM-14
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The reaction A  D goes in three steps:
Step-1: A  B Step-II B  C Step - III C  D
The energy profile diagram is shown below:

Choose the correct:


Number of Number of Rate determining
Intermediates Transition states Step
1) 3 2 II
2) 2 3 II
3) 2 3 I
4) 2 3 III
Key: 3
Sol: B and C are intermediates (2); number of peaks correspond to transition states (3);
step I  A  B  has highest activation energy, and is slowest step (rate determining
step).
2. In the back bonding in metal carbonyls, the orbitals involved are
1) Vacant metal d-orbital and  -orbital of CO having electron pair
2) Vacant metal d-orbital and  -orbital of CO having electron pair
*
3) Metal d-orbital having electron pair and vacant  orbital of CO
*
4) Metal d-orbital having electron pair and vacant  of CO
Key: 4
Sol: Back bonding or synergic bond in metal carbonyls involves metal d-orbital having
*
electron pair and vacant  of CO .
3. Mechanism of hypothetical reaction, X 2  Y2  2 XY , is given below:
(i) X 2  X + X (fast) (ii) X + Y  XY + Y (slow)2
(iii) X + Y  XY (fast)
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The overall order of the reaction will be
1) 2 2) 0 3) 1.5 4) 1
Key: 3
Sol: From the rate determining step (slow step, step-ii), rate  k ' X Y2 
2
From step-i, Kc 
 X
and  X    K c  X 2 
1/2
 X2 
 rate  k '  Kc  X 2 1/2 Y2  or rate  k  X 2 1/2 Y2  . Hence, order of reaction is
1.5
4. Low spin tetrahedral complexes are not formed because:
1) For tetrahedral complexes, the crystal field splitting energy is lower than pairing
energy
2) For tetrahedral complexes, the crystal field splitting energy is higher than pairing
energy
3) Electrons do not go to e-set in case of tetrahedral complexes
4) Tetrahedral complexes are formed by weak field ligands only
Key: 1
Sol: All tetrahedral complexes are weak-field complexes and t  P (pairing energy).
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases

5. If x is number of successive stability constants for  Ag  NH 3 2  , and y is number of
3
successive stability constants for Co  NH 3 6  , then x  y  ________
 
Key: 8

Sol: In  Ag  NH3   , number of successive stability constants is 2, and in
 2
3
Co  NH3   , number of successive stability constants is 6.
 6

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RPTM-15
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Simplified absorption spectra of three complexes i ,ii and iii  of M n ion are

provided below; their max values are marked as A, B and C respectively. The correct
match between the complexes and their max values is:


 6 n 
i)  M  NCS 6 
6n
ii)  MF6  iii)  M  NH 3 6 
n

1) A-(iii), B-(i), C-(ii) 2) A-(ii), B-(i), C-(iii)


3) A-(ii), B-(iii), C-(i) 4) A-(i), B-(ii), C-(iii)
Key: 1
Sol: Stronger the ligand, greater is splitting of d-orbitals and smaller will be wavelength of
light absorbed. According to spectro chemical series the splitting power of ligands is
NH 3  NCS   F  thus order of wavelength of light absorbed is NH 3  NCN   F 

2. Given below are two statements, one is labelled as


Assertion A and the other is labelled as Reason R.
Assertion A: The metal carbon bond in metal carbonyls possesses both  and 
character.
Reason R: The ligand to metal bond is a  bond and metal to ligand bond is a  bond.
In the above statements, choose the correct answer from the options given below:
1) A is false but R is true
2) A is true but R is false
3) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not correct explanation of (A)
Key: 2

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Sol: In metal carbonyls, L 
 M , M 
L 

3. A heat engine absorbs heat Q1 at temperature T1 and heat Q2 at temperature T2. Work
done by the engine is (Q1 + Q2). This data
1) Violates 1st law of thermodynamics
2) Violates 1st law of thermodynamics if Q1 is -ve
3) Violates 1st law of thermodynamics of Q2 is -ve
4) Does not violate 1st law of thermodynamics.
Key: 4
Sol: According to first law of thermodynamics, energy can neither be created nor be destroyed
although it can be converted from one form to another. Hence, the given data does not
violate 1st law of thermodynamics but it violates 2nd law of thermodynamics.

SECTION-II (NUMERICAL VALUE TYPE)


This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
4. 10 grams of argon gas is compressed isothermally and reversible at a temperature of 27oC
from 10 L to 5 L. Calculate the work done for this process in multiple of 102 calories
(R=2 cal. k-1 mol-1)
Key: 1
10
Sol: nAr   0.25
40
v 
W  2.303nRT log  2 
 v 
1

5
 2.303 0.25 2  300log  
10 

10 
 2.303 0.25  2  300log  
 5 

 104 cal  1.04 102 cal

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5. Complexes  ML5  of metals Ni and Fe have ideal square pyramidal and trigonal

bipyramidal geometries respectively, the sum of the 90,120 and 180 L - M - L angles
in the two complexes is _____
Key: 20
Sol: (Trigonal bipyramidal)

L
L
M L
L
L
120  3, 90  6, 180  1 Total  10

L
L L
M

L L
(square pyramidal)

90  8, 180  2 Total  10

 Sum of 90,180,120 angles in both complexes = 20

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RPTM-16
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. For freezing of water
LIST-I LIST-II
A) Water at 100 C I) G  O
B) Water at 0 0 C II) G  ve
C) Water at 100 C III) G  ve
1) A  II , B  I , C  III 2) A  III , B  I , C  II
3) A  I , B  II , C  III 4) A  III , B  II , C  I
Key: 2
Sol: For spontaneous process,
For non-spontaneous process
At equilibrium
2. Which of the following lines correctly show the temperature dependence of equilibrium
constant K, for an endothermic process?
A
B
lnK

(0, 0)
C
1/T

1) A and B 2) A and C 3) B and D 4) C and D


Key: 4
Sol: For endothermic process the slope of the line is negative

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3. The entropy change associated with the conversion of 1Kg ice at 273K to water vapour at
373K is (specific heat of water liquid is 4.2 kJ k 1kg 1 ; heat of fusion of ice and

 373 
vaporization of water are 334kJ kg 1 and 2491kJ kg 1 respectively;  ln  0.31
 273 
1) 9.19 kJ kg 1k 1 2) 9.26 kJ kg 1k 1 3) 7.9kJ kg 1k 1 4) 8.49 kJ kg 1k 1
Key: 1
Ice S water S water S watervapour
Sol: 273 K 
1
 273 K 
2
373 K 
3
373 K

334
S1   1.22
273
373
S 2  4.2ln  1.30
273
2491
S 3   6.67
373
4. Assertion: For every chemical reaction at equilibrium, standard Gibbs energy change of
reaction is zero.
Reason: At constant temperature and pressure, chemical reactions are spontaneous in the
direction of decreasing Gibbs energy.
1) Both Assertion and Reason are correct and Reason is a correct explanation of
Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation of
Assertion
3) Assertion is correct but Reason is incorrect
4) Assertion is incorrect but Reason is correct
Key: 4
Sol: At equilibrium G is zero but not G 0
5. Statement-1: Enthalpy and entropy of any elementary substance in the standard state are
taken as zero
Statement-2: The absolute value of enthalpy and entropy of chemical substance can be
determined by using 3rd law of thermodynamics.
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1) Both statement-1 and statement-2 are true
2) Statement-1 is true, statement-2 is false
3) Statement-1 is false, statement-2 is false
4) Both statement-1 and statement-2 is false
Key: 3 or 4
Sol: Enthalpy of elements in the standard state is taken as zero. The absolute value of entropy
can be determined by using 3 rd law of thermodynamics
6. K 2Cr2O7  X  conc H 2 SO4 
heat
 A 
NaOH
B.
In the above reaction, “A” is reddish brown gas soluble in NaOH forming yellow solution
of “B”. ‘X’ and ‘A’ are
1) NaCl , CrO2Cl2 2) CrO2Cl2 , Na2CrO4 3) SO2 , NO2 4) NaCl , Na2CrO4
Key: 1
Sol: It is chromyl chloride test
7. Statement-1: Addition of NH 4OH to an aqueous solution of BaCl2 in the presences of
NH 4Cl (excess) precipitate Ba  OH 2

Statement-2: Ba 2 belongs to group-III


1) Both Statement-1 and Statement-2 are true 2) Both Statement-1 and Statement-2 are
false
3) Statement-1 is true, Statement-2 is false 4) Statement-1 is false, Statement-2 is true
Key: 2
Sol: Ba 2 ion belongs to group-V
8. Statement-1: Sulphanilic acid gives esterification test for carboxyl group
Staement-2: Aniline gives carbylamine test
1) Both Statement-1 and Staement-2 are true 2) Both Statement-1 and Staement-2 are
false
3) Statement-1 is true, Statement-2 is false 4) Statement-1 is false, Statement-2 is true
Key: 4

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NH2

3 SO H
Sol: Sulphanilic acid is
9. Which of the following is a bactericidal antibiotic?
1) Ofloxacin 2) Tetracycline 3) Chloramphenicol 4) Erythromycin
Key: 1
Sol: Ofloxacin is a bactericidal antibiotic.
10. Which of the following is a cationic detergent?
1) Sodium Stearate 2) Sodium lauryl Sulphate
3) Cetyltrimethyl ammonium bromide 4) Glyceryl oleate
Key: 3
Sol: Cetyltrimethyl ammonium bromide is cationic detergent
11. Drugs used to bind to receptors, inhibiting its natural function and blocking a message are
called
1) Agonists 2) Antagonists 3) Anti histamines 4) Allosterists
Key: 2
Sol: Antagonist inhibits the natural function and blocks the message

SECTION-II (NUMERICAL VALUE TYPE)


This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
12. An organic compound C x H 6O2 was treated with I 2 / NaOH consumes 6 moles of I 2 to
produce Iodoform and a dibasic acid salt. Which when treated with acidified KMnO4 ,
pink colour of KMnO4 gets decolourised with no organic compound left. The minimum
value of ‘x’ is
Key: 4

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Sol: CH 3  C  C  CH 3  6 I 2  CI 3  C  C  CI 3
|| || || ||
O O O O

NaOH

COONa
2CHI 3  |
COONa
13. Number of following metal ions are precipitated on reaction with NH 4Cl  NH 4OH  H 2 S

Cu 2 , Cd 2 , Mn 2 , Zn2 , Ni 2 , Hg 2 , Ba 2 , Ca 2 , Mg 2
Key: 6
Sol: Cu 2 , Cd 2 , Mn 2 , Zn 2 , Ni 2 and Hg 2 are precipitated
14. The number of chlorine atoms in bithionol is ____

Key: 4

Cl OH OH Cl

Cl
Sol: Cl

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MATHEMATICS
RPTM-01
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

01.    
Let f  x    a   5 a   4 x3  6a  5a  1 x   tan x  sgn x , be an even function
2 2

for all x  R , then sum of all possible values of a is (where [.] and . denote the greatest
integer function and fractional part function respectively)
17 53 31 35
1) 2) 3) 4)
6 6 3 3
Key: 4

Sol: f  x   x 3  x   tan x  sgn x


f   x   f  x    x3  x  tan x sgn x
 x3  x   tan x   sgn x   2  x 2    x  0 x  R
   0 and   0   a   5  a   4  0
2

And 6 a  5 a  1  0  3a  1 2 a  1  0


2
  
  a   1, 4 anda  1 / 3,1 / 2
1 1 1 1
 a  1  ,1  , 4  , 4 
3 2 3 2
35
Sum of values of a 
3
02. Consider f : R   R such that f  3  1 for a  R  and
3  3
f  x  . f  y   f   f    2 f  xy   x, y R  , then f  97  can be
x  y
1) 1 2) -1 3) 2 4) 97
Key: 1
Sol: Put x  y  1

f 2 1  f 2  3  2 f 1   f 1  1  0  f 1  1


2

Now put y  1

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3 3
 f  x  f 1  f   f  3   2 f  x   f  x   f    x  0 ….(i)
x x

3 3
 f  x  f    f   f  x   2 f  3
x  x
3
f  x  f    1 …….(ii)
x
 From (i) and (ii)
f 2  x   1 x  0  f  x   1  x  0
03. If x  1  3 x  2  5 x  4   ,   R , then which of the following is not true?
1) for   9 equation has one solution 2) for   10 equation has no solution
3) for   0 equation has two solution 4) for   9 equation has only one solution
Key: 4

 1  x  6  3 x  20  5 x, x  1
 x  1  6  3 x  20  5 x,1  x  2

Sol: x  1  3 x  2  5 x  4  
 x  1  3 x  6  20  5 x,2  x  4
 x  1  3 x  6  20  5 x, x  4
 13  x, x  1
 15  3 x,1  x  2


27  9 x,2  x  4
 13  x, x  4
Graph of the function is as shown in the following figure.

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04. Consider a differentiable f : R  R for which f   0   log 2 and
f  x  y   2 x f  y   4 y f  x   x, y  R , then the minimum value of f  x  is
1 1 1
1) 1 2)  3)  4)
2 4 4
Key: 3
Sol: f  x   f 1  x   1

 m3 n3  m
   
3 3
  m, n  Z  then 
1 1
05. Range of sin x  cos x is  ,
 32 32  n
1 1
1) 7 2) 3) 28 4)
7 28
Key: 4

3 3    1 
     
3 3 2
1 1 1
Sol: sin x  cos x   sin x  sin x 
8 2  2 
3 3  1    3  3  3 3   1
2 2

   sin x        sin x  
8 2  4   32 8 2  4
 3 7  3 
Range =  , 
 32 8 
 1  sin x  1  sin x   
06. If y  x   cot 
1
 , x   ,   then y  x  
 1  sin x  1  sin x  2 
 
x  x x  x
1)  2)  3)  4) 
2 2 2 2 2 2
Key: 2

 x x x x
 cos  sin  sin  cos  x  
Sol: y  x   cot 
1 2 2 2 2
x x x x    , 
 cos  sin  sin  cos  2  4 2 
 2 2 2 2
 x
 sin
 cot 1  2   cot 1  Tan x   cot 1  cot    x  
x      
 cos   2   2 2 
 2
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 x
y  x  
2 2
 n
12 r 
If Sn   Tan  2 r 1
1
07. 2 r 1 
then Lt S n 
r 1 3 4  n

1 4 1 4  1
1) Cot 2) Tan 3) 4) Tan 4
3 3 2
Key: 1

   4r 
 r 2r   
n
1  12 / 3 1 n 1  3 r 1

Sol: Sn   Tan   Tan
r 1
 4
2 r 1
 r 1
  4 r 1  4 r 
 1    1     
 3
    3 3 
  4 r 1  4  r 
      n 1
n
3 3  4  1  4 
  Tan 1    r 1  r   Tan 1
   Tan  
r 1
 4 4  3 3
1     
 3 3 
n 1
4 4  4 4
 Sn  Lt Tan 1    Tan 1   Tan 1  Cot 1
n
3 3 2 3 3

 1  2   1 
1 4 2

  2Tan  2    2 2Tan  Tan 
1
08. 96 Tan  3 Cos    
  5    2  7 
1) 6 2) 8 3) 11 4) 7
Key: 4

 2   1 
Sol: Tan  3 Cos 1  2 Tan 1 2   Tan  3Tan 1  2Tan 1 2 
 5   2 
 1  1   1 1 4 2
 Tan  Tan 1  2  Tan 1  Tan 1 2    Tan    Tan 1   , Tan 
 2  2   2 2 7
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).

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Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

 x  3 1 
09. Let S   x   6,3  2,2 :
x 2

 0  and T  x   : x 2  7 x  9  0 
 
Then the number of elements in S  T :
Key: 3
Sol: S  T in only integers satisfies integers are 5, 4,3

 1 3n 
10. Let f  n      n , where [n] denotes the greatest integer less than or equal to
 3 100 
56
n. Then  f  n  is equal to :
n1
Key: 1399
Sol:
Let
 1 3n 
f n     n
 3 100 
 3n 
Where  n  is greatest integer function =  0.33  n
100   
For n  1,2,...22, we get f  n   0
And for n  23, 24....,55 we get f  n   1  n
For n  56, f  n   2  n
56
So,  f  n   1 23  1 24   ....  1 55  2  56 
n1

33 33
  23  24  .....  55   112   46  32  112   78   112  1399
2 2
11. If f  x  and g  x  are periodic functions with periods 7 and 11, respectively then the

x x
period of F  x   f  x  g    g  x f   is
5 3
Key: 1155
f  x  7
Sol: The period of .
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 x
So, the period f    21
3
The period of g  x   11

x
So, the period of g 
5   55
 
x
Hence T1  Period of f  x  . g    385
5
x
T2  Period of g  x  . f    231
3
 Period of F  x   LCM T1 , T2  =  LCM 385,231 = 1155
12. If f  x   ax 7  bx 3  cx  5 (a,b,c are real constants) and f  7   7 , then the
range of f  7   17 cos x is  m, 0  then m is
Key: 34
Sol: f  x   ax  bx  cx  5
7 3

f   x   ax 7  bx3  cx  5
f  x   f   x   10
x7
f  7   f  7   10
f  7   7  10
f  7   17
1  cos x  1
17  17 cos x  17
34  f  7   17 cos x  0
m  34  m  34
 2 2   1 2 
13. Let A    and B    Then the number of elements in the set
 1  1    1 2 
 n, m  : n, m  1, 2,....2024 and nAn  mB m  I  is
Key: 3
Sol: sin 1 x  0,1, 1
sin 1 x  0,1, 1

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14. Let f  x  and g  x  be two real polynomials of degree 2 and 1 respectively. If
f  g  x    8 x 2  2 x , g  f  x    4 x 2  6 x  1 , then the value of f 1  g 1 is
____
Key: 7
Sol:
Let
f  x   ax 2  bx  c, g  x   lx  m
f  g  x    8 x 2  2 x; g  f  x    4 x 2  6 x  1
 a  2, b  3, c  1, l  2, m  1
 f  x   2 x 2  3 x  1, g  x   2 x  1 Now f 1  g 1  7
15. Number of integers in domain of function f  x   log  x2   4  x   log 2
 
 x are (where
. is GIF and  .  is fractional part function of x)
Key: 2
Sol: f  x   log  x2   4  x   log2
 
 x
4  x  0  x  4  4  x  4 …….(i)
 x 2   0,  x 2   1 ……. (ii)
  x 2   2  2  x 2   or    x   2

 x  0, x  I  x  I 2 …..(iii)
 x  2,3
1  12 x  x 
3
1  x 
16. If Tan    aTan    a, b  0  then a  b  _____
 8  6 x 2
 b
Key: 5
 12 x3 
 x 
Sol: Tan  8
1 8   aTan 1  x 
 
 1  6 x2  b
 8 
 
 x  x 3 
3   
2 2  1  x  1  x 
Tan 1   aTan    3Tan    a  3, b  2
 x
2
 b
  2
 1  3.   
 2 
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1 x  2
1  2 x  2
17. Sum of all solutions of Tan 
1
  Cot  2 
  1  x  1, x  0  is
 2 x   1  x  3
n  n  2 3
 n  N  then n3 
3
Key: 3
 1  x2 
1 1  1  x 
2
2
Sol: If 0  x  1 then Tan    Tan   
 2x   2x  3
1  1  x   1  x2
2
 Tan     3  x 2 3
 2 x  3 2 x
1 1  x2  1  1  x 
2
2
If 1  x  0  Tan      Tan   
 2x   2x  3
1  1  x   1  1  x   1  x 2 1
2 2
 2 Tan    Tan    
 2 x  3  2 x  6 2 x 3
64 3 1
Sum of solutions = 2  3  
 n 6 n3 3
3 3
 x 2025  y 2025   x 2024  y 2024 
If cos x  cos y  cos z  3 then   2023
1 1 1
18. 2023   2022 
 x  y  x  y
2022

Key: 3
1 1 1
Sol: cos x  cos y  cos z  3  x  1  y  z
  12025   12025   12024   12024 
     1  3
  12023   12023   12022   12022 
  

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RPTM-02
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. Let f , g : R  R be two real valued functions defined as
 x  3 , x  0  x 2  k1 x, x  0
f  x   and g   
x  , where k1 and k2 are real constants. If
 e x
, x  0  4 x  k 2 , x  0
 gof  is differentiable at x  0 , then  gof  4    gof  4  is equal to
1) 4  e 4  1 2) 2  2e4  1 3) 4e 4 4) 2  2e4  1
Key: 4
Sol: g  f  x   is differentiable at x  0 .
 g  f  x   must be continuous at x  0 .
   
 g f  0   g f  0   g  f  0  
 g 1   g  3   g  f  0  
 4  k2  9  3k1  3k1  k2  5
For differentiability at x  0 ,
 
g  f  0  f   0   g  f  0  f   0     4 1   2  3  k1   1
 k1  2 and k2  1   gof  4    gof  4   g  f  4    g  f  4  
 g  1  g  e 4   4e 4  2  2  2e 4  1
1
02. If g is the inverse of a function f and f   x   , then g   x  is equal to
1  x5
1
4) 1   g  x 
5
1) 1  x 5 2) 5x 4 3)
1   g  x 
5

Key: 4
Sol: Since g is inverse of f , f  g  x    x
 f  g  f  g  x  1  g x   1   g  x
5

log10  x  2    x   2
03. lim (where . is G.I.F =
x   
1 
r

x    
 r 0  2  
1) 1 2) 0 3) 2 4) does not exist
Key: 1
log10  x  2 
log  x  2    x   2 log  x  2  x
Sol: lim 10 1  lim 10  1  1  lim  1 0  1
x   x  2 x   x  2 x   x  2
x x
sin 1   x  .cos 1   x 
1 1

04. Let f  x   , where {.} denotes the fractional part function.


2  x. 1   x 

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If R  lim f  x  , then the value of cos 100R  is:
x  0

1) –1 2) 0 3) 1/2 4) 1
Key: 4
sin 1 1   x  .cos 1 1   x 
Sol: We have f  x  
2  x 1   x 
sin 1 1  0  h  .cos 1 1  0  h sin 1 1  h  .cos 1 1  h 
(D) R  lim f  x  lim f  0  h   lim  lim
x  0 h 0 h0
2 0  h 1  0  h  h 0 2h 1  h 
sin 1 1  h  cos 1 1  h 
 lim lim
h0 1  h  h0 2h
sin 1 1  h 
in second limit put 1  h  cos   lim
h 0 1  h 
cos 1  cos   sin 1 1  h  
lim  lim lim  sin 1 1.1   / 2  100 R  50
 0
2 1  cos   h 0 1  h    0 2sin  / 2 

 cos 100 R   cos 50   1  1


50

The number of points in 1,3 , where f  x   a   , a  1 , is not differentiable where  x 


x2 
05.
denotes the integral part of x is
1) 0 2) 3 3) 5 4) 7
Key: 4
Sol: Here 1  x  3 and in this interval x 2 is an increasing function.
 1  x2  9  x 2   1,1  x  2  2, 2  x  3
 3, 3  x  2  4, 2  x  5
 5, 5  x  6  6, 6  x  7
 7, 7  x  8  8, 8  x  3
 x2 
Clearly  x 2  and also a   is discontinuous and not differentiable at only 7 points which
are x  2, 3, 4, 5, 6, 7, 8
  1x 1

x  e  e x
, x  0
  1
06. If f  x     x x  1 
then
 e e 
 0, x0
1) f  x  is discontinuous at x  0 2) f  x  is not differentiable at x  0
3) f  x  is differentiable at x  0 4) f   0   2
Key: 2
 h2 
f  0  h   f  0 e 1  0 1
Sol: We have f   0   lim
 
 lim 2
h0  
  1
h 0 h  e h 1  0 1
 

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f  0  h   f  0
Similarly f   0   lim 1
h 0 h
 f is not differentiable at x  0
07. It y  f  x  is a real valued twice differentiable function defined on R , then
3
d 2 y  dx  d 2 x
   
dx 2  dy  dy 2
dy dx d2y
1) 2) 3) 2 4) 0
dx dy dx
Key: 4
    d 2x d2x

d 2 y d  dy  d  1  d  1  dy dy 2 dy dy 2
Sol:           .  
dx 2 dx  dx  dx  dx  dy  dx  dx 2
 dx  dx  dx 
3

 dy   dy   dy   dy 
       
3
d 2 y  dx  d 2 x
 2 .   2  0
dx  dy  dy
d2y dy
08. If 2x  y1/5  y 1/5 and  x 2  1 2
x  Ky,  K  R  then K  ___
dx dx
1) –5 2) 5 3) 25 4) –25
Key: 3
 
5
Sol: y  x  x2  1
dy 5 y

dx x2 1
2 x  a  1 a  a 2  2 ax  1  0
2x  4x2  4
a
2
a  x  x2  1
y 5  x  x2  1
1

 
5
y  x  x2  1

 sin 1 x 2 cos  1  , x  0


09. Consider f  x    x

 0 , x0
Statement-1: f  x  is continuous everywhere in 1  x  1
Statement-2: f  x  is differentiable everywhere in 1  x  1
1) Both statements are true
2) Both statements are false
3) Statement 1 is true, statement 2 is false
4) Statement 1 is false, statement 2 is true
Key: 1

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Sol:
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
 P  x
, x2
10. Consider the function f  x    sin  x  2  , where P  x  is a polynomial such that
 7, x2

P  x  is always a constant and P  3  9 . If f  x  is continuous at x  2 , then P  4 is equal
to_______.
Key: 22
Sol: Therefore, P  x  is a polynomial of degree 2.
 f  2   f  2   f  2 
P  x
lim 7
x 2 sin  x  2 

lim
 x  2  ax  b   7  2a  b  7 ... 1
x2 sin  x  2 
P  x    x  2  ax  b  and P  3  9 (gives)
  3  2  3a  b   9  3a  b  9 ...  2 
Solving (1) and (2) we get, a  2, b  3
 P  4    4  2   2  4   3  2 11  22
 1
 , x 2
11. If the function f  x    x is differentiable on R , then 48  a  b  is equal
ax  2b , x  2
2

to____.
Key: 15
1  1
 , x2  2 , x  2
 x  x
Sol: f  x   ax  2b, 2  x  2 and f  x   2ax, 2  x  2
2

 1 1
 , x  2  2, x  2
 x  x
1 a
f  x  is continuous at x  2 and –2, if   2b
2 4

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1
f  x  is differentiable at x  2 and –2 if  4a
4
1 3
a and b 
16 8
12. Let a  Z and t  be the greatest integer  t . Then the number of points, where the
function f  x    a  13sin x  , x   0,   is not differentiable, is ______.
Key: 25
Sol: f  x    a  13sin x  , x   0,    a  13sin x 
So, the number of points of non-differentiablility is 2 13  1  25 .
1  x2 x2 x2 x 2  
13. If lim  8 
1  cos  cos  cos cos    2 , then the value of 2k is______.
k
x 0 x
  2 4 2 4  
Key: 16
 x2   x2  2 2
1  cos 1  cos 2 x 2 x
   2sin 2sin
2  4 
Sol: lim   lim 4 8  28  2 k  2k  16 .
x4 x4 2 2 2 2
x 0 x 0
x  x 
16   64  
 4  8 
ax 2 e x  b log e 1  x   cxe  x
14. If lim 2
 1 , then 16  a 2  b 2  c 2  is equal to_____.
x 0 x sin x
Key: 9
ax 2 e x  b log e 1  x   cxe x
Sol: lim 1
x 0 3 sin x
x
x
 x  x 2 x3   x x2 
ax 2 1    b  x     cx  1   
 1!   2 3  1! 2!   1
 lim 3
x 0 x
b b c
 c  b  0,  c  a  0 and a    1
2 3 2
3 3
Solving, we get a  , b  c   16  a 2  b 2  c 2   9
4 2
 m 1
 x sin , x  0, m  N
15. A function f  x  is defined as f  x    x
 0, if x  0
The least value of m for which f  x  is continuous at x  0 is_____
Key: 1
 m 1
 x sin   x0
Sol: The given function can be represented as f  x    2
 0 x0

The given function f  x  is continuous at x  0 , it lim f  x   lim x m sin  
1
x 0 x 0
x
The above limit will become zero for all values of m  0

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m N  m 1
16. Let f  x  be a continuous function defined for 1  x  3 . If f  x  takes rational values for
all x and f  2   10 , then f 1.5  _____.
Key: 10
Sol: As f  x  is continuous in 1,3 . f  x  Will attain all value between f 1 and f  3 .
Then f  x  will attain innumerable irrational values between f 1 and f  3 . But given
that f  x  attain rational values only, then we must have f 1  f  3
infact f  x  constant for x  1,3
Since f  2   10, f  x  2, x  1,3 ,
so f 1,5   10
x 2 sin   x 
17. Let  ,   R be such that lim  1 . Then 6     equals_____.
x 0  x  sin x

Key: 5
   x 
3

x  x 
2
 ....   3 x3 
x3    ....
 3!  3!
Sol: lim   1  lim   1
x 0  x 3
 x  0 x 3
x 5
 x   x   ....    1 x    ...
 3!  3! 5!
  3 x3 
x  
3
 ....
 3!   1   1 or   1
 lim
x 0 x3 x 5
  1    ...
3! 5!
3
 x 2 ...
3 1 1
 lim 2
  
x 0 1 x 3! 6
  ...
3! 5!
 1
 6      6  1    5
 6
18. If graph of y  f  x  is symmetric about the point  5, 0 and f   7   3 , then the value of
f   3  3 is______.
Key: 6
Sol: We have f  5  x    f  5  x 
or  f   5  x    f   5  x   f   5  2   f   5  2 
or f   3  f   7   3
f   3  3  6

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RPTM-03
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
 x if 0  x  2
01. If f  x    then at x  0 ' f ' has
1 if x0
1) local maximum 2) Local minimum 3) no extreme value 4) Not determined
Key: 1

2 2

Sol:
Clearly at x=0 f has local maximum
02. Which one of the following curves the parabola y 2  4ax at right angles
x

1) x 2  y 2  a 2 2) y  e 2 a 3) y  ax 4) x 2  4ay
Key: 4
Sol: Equation of Tangent is y  y1  m  x  x1 
2 
03. For the function f  x   sin x  3x  x 2
 x  where x  0, 
  2
Consider the following two statements

I: f is increasing in  0, 
2  

II: f 1 is decreasing in  0, 
2  
Among the above two statements
1) Neither I nor II is true 2) Both I and II are true 3) Only I is true 4) Only II is true
Key: 2
2 4x 2  
Sol: f 1  x   cos x  3   2 x  1  cos x    3 When x   0,  , f 1  x   0  f  x  is increasing
    2

Now f 1  x   0, when x   0,  , f 1  x  is decreasing
 2

04. A point ‘P’ moves with an angular velocity 2 radians / sec on the circumference of a
circle with center ‘O’ and radius 2cm. PM is perpendicular to the diameter of the circle
such that POM   . If the velocity of the Point M is zero, then values of '  ' are

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    3
1) , 2) 0,  3) , 4) ,
2 3 6 4 4
Key: 2
d
Sol: OM  cos  , OM   0
dt
3a  2b 3
05. If a,b,c are real numbers such that   0 then the equation ax 3  bx 2  cx  d  0
cd 2
has
1) At least one root in  2,0 2) At least one root in 0, 2
3) At least two roots in  2, 2 4) No root in  2, 2
Key: 2
Sol: Conceptual
06. The maximum height of an arc of the cycloid x  a   sin   , y  a 1  cos   is
1) a 2) a 3) 2a 4) 3a
Key: 3
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
07. A curve passes through Point  2,0 and the slope of the tangent at any point  x, y  is
x 2  2 x for all values of ' x ' then 3Y max is equal to
Key: 4
dy
Sol:  x2  2x
dx

x3 4
y   x 2  c passes through  2, 0  , C 
2 3

x3 4
y   x2 
3 3

4
 y max 
3

08. For a cubic function y  f  x  , f 11  x   4 x, at each point  x, y  on it and it crosses the


x  axis at  2,0  at an angle of 450 with positive direction of x-axis then the value of
f 1 is
Key: 2
Sol: f 11  x   4 x, f 1  x   2 x 2  c

f 1  2   1  C  7

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f 1
 x  2x 2
7

2 x3
f  x   7x  k
3

26
f  2   0  c 
3

2 3 26
 f  x  x  7x 
3 3

1
f  x 
3
 2 x 3  21x  26 

1
 f 1   2  21  26   15
3

09. A soft drink manufacturer wants to fabricate cylindrical cans for its products. The can is
to have a volume of 343.75cu.cm if r is the radius for can to require least amount of
material then 8 r 2 is equal to
Key: 1375
Sol: Let r be the radius and h be the height of the can,

Total surface area S  2 r 2  2 rh

343.75
We need to minimize ‘s’ so that V   r 2 h  343.5  h 
 r2

 343.75  687.5
 S  r   2 r 2  2 r    2 r 
2

 r  4
2

ds 687.5
 0  r2  8 r 2  1375 cm 2
dr 4

10. If P1 and P2 are the lengths of the perpendiculars from origin on the tangent and normal to
2 2
the curve x 3  y 2/3  6 3
then the value of 4P12  P22 is equal to
Key: 36

Sol: Any point on the curve x 3  y  6 be P  6cos3  ,6sin 3  


2 2 2
3 3

 dy 
    tan 
 dx  p

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 P  x 
11. Let P  x  be a polynomial of degree ‘4’ having extreme at x  1,2 and Lt 1  2   2 then
x 0
 x 

the value of P  2  is
Key: 0
 P  x  P  x
Sol: Let  1  2   2  Let 2  1
x 0
 x  x 0 x

Let P  x   a0 x 4  a1 x 3  a2 x 2  a3 x  a4 given limit is finite only if a3  a4  0 and is 1if a2  1

Thuse P  x   a0 x 4  a1 x 3  x 2 P  x  has extremum at x  1, 2

If P1 1  0, P1  2   0  4a0  2a1  2

32a0  12a1  4

1
Solivng a0  , a1  1
4

1 4
 P  x  x  x3  x 2  P  2  0
4

2
12. The number of critical points of the function f  x    x  2  3  2 x  1
Key: 2
Sol: f 1  x   0  x  1, 2

13. Let x, y ,  0 If x 3 y 2  215 then the least value of 3x  2 y is

Key: 40
Sol: x 3 y 2  215

 3x   2y 
3x  2 y  3    2  
 3   2 

A.M  G.M

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 3x   2y  1
3   2  
 3  3
 2    3x   2 y  
2 5

      3 x  2 y  410
5  3   2  

14. If the function f  x   2 x 3  9ax 2  12a 2 x  1 where a  0 attains its maximum and minimum at

p, q respectively such that p 2  q then ‘ a ’ is equal to

Key: 2
Sol: f 1  x   0  x  a , x  2a

f 11  a   0  f  x  will be maximum

at x  a pa

Again f 11  2a   0

 f  x  Will be maximum at x  2a

 q  2a

Given
p2  q a  2

15. If f  x  is continuous and differentiable over  2,5 and 4  f 1  x   3 for all x in  2,5 then

the greatest possible value of f  5  f  2  is


Key: 21
Sol: By L MVT on  2,5
f  b   f  a  f  5   f  2  f  5   f   2 
f 1  x   
ba 5   2  7

7 f 1  x   f  5  f  2  But 4  f 1  x   3

28  7 f 1  x   21  28  f  5  f  2   21

Maximum value  21

16. The value of k for which to length of the sub tangent to the curve xy k  c 2 is constant is
Key: 1
Sol: Conceptual
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-04
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

1 1  2 tan x
01. If  cos2 x 1  4tan 2 x dx  k log  c then 4k  ____ .
  1  2 tan x

Key: 1

Sol: Put tan x  t


2
02. If the graph of the anti derivative F  x  of f  x   log  log x    log x  passes through

 e,2014  e  , then the term independent of x in F  x  is ' k ' , then sum of digits of ' k ' is

___ .
Key: 7

2  1
Sol: F  x    log  log x    log x  dx  x log  log x   x  log x  c
 
Passes  e,2014  e 
c  2014
k  2  0 1 4  7
x2 x
03. If  dx  A log  x  1  x 2   B  C then A  B  _____ .

1 x 2 32
   1 x 2

Key: 2

 x2  1  1 dx  1 1
Sol:   dx   dx
1  x 
2 32 1 x 2
1  x 
2 32

x
put x  tan   sinh 1 x  c
2
1 x
A  1, B  1
A B  2
sin x  2 tan x  1 
04. If  sin3 x  cos3 x dx  log 1  tan x   log 1  tan x  tan
2
x   tan 1  c,
 3 
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where c is constant of integration, then the values of 18      2 is ______ .  


Key: 3

tan x sec2 x tan x sec 2 x


Sol: I  dx   dx
1  tan x 3
1  tan x  1  tan x  tan 2
x 
put tan x  t & use partial fractions
1 1 1  2tan x  1 
I   log 1  tan x  log tan 2 x  tan x  1  tan 1  c
3 6 3  3 
1 1 1
   ,   , 
3 6 3


18      2  3 
dx  2x  1   2x  1 
05. If   a tan 1    b   c , x  0 , where c is constant of
 
2  3  2
2
x  x 1  x  x 1

integration, then the value of 9  


3a  b is ____ .

Key: 15

dx
Sol: I 
2
 1
2
3
 x    
 2 4

1
Put x  t
2
dt
I 
2
 2 3
t  
 4
3
Put t  tan 
2
4 3  2x  1  1  2x  1 
I  tan 1    c
9  3  3  x2  x  1 
9  
3a  b  15
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1 1  x3  1
06. If  3
dx  a log
3
 b , then 3a  _____ .
x 1 x 1 x 1

Key: 1

1
Sol: I  dx
3
x 1 x
Put 1  x3  t 2
 3 x 2 dx  2t dt

2 1 1 t 1 1 1  x3  1
I   dt  log  c  log c
3 1 t2 3 t 1 3 3
1 x 1
1
a  3a  1
3
5 tan x
07. If  dx  x  b log  sin x  2cos x   k , then b  _____ .
tan x  2
Key: 2

5tan x 5sin x
Sol:  tan x  2  sin x  2cos x dx
dx 


 sin x  2cos x   2  cos x  2sin x  dx
 sin x  2cos x 
 1dx  2 
 cos x  2sin x  dx
 sin x  2cos x 
 x  2log sin x  2cos x  c
b2

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RPTM-05
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1
 n
 n
1 
01. The value of    ( x  r )    dx equals
0
xk 
 r 1   k 1 

1) n 2) n! 3) (n+1)! 4) n.n!

KEY: 4
n
SOL: The given integrand is a prefect differential coefficient of  (x  r)
r 1
1
 n

 I   ( x  r )   ( n  1)! n !  n  n !
 r 1 0
1 1
02. If A   x (2  x) dx, B   x50 (1  x)50 dx, which of the following is true?
50 50

0 0

1) A  250 B 2) A  250 B 3) A  2100 B 4) A  2100 B

KEY: 3
1 1
SOL: Given A   x50 (2  x)50 dx; B   x50 (1  x)50 dx
0 0

In A, put x  2t or dx  2dt (i)


1/ 2
 A  2  250 t 50 250 (1  t )50
0
1/ 2
Now B  2  x 50 (1  x )50 dx (ii)
0
2a
[Using 
0
f ( x ) dx  2  0a f ( x ) dx if (2a  x )  f ( x ) ]

From equation (i) and (ii) we get A  2100 B .

  /2
cos x sin 2 x
03. If A   dx then  dx is equal to
0
( x  2) 2 0
x 1

1 1 1 1 1 1
1)  A 2) A 3) 1  A 4) A  
2  2  2  2 2  2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
KEY: 1
 /2 sin 2 x
SOL: I  0 dx. put x  y / 2 then
x 1

sin y
   cos y   cos y
I  dy     dy (Integrating by parts)
0 y2
 y  2 0 0 ( y  2)
2

1 1
  A
 2 2

2
dx
04. The value of


 [ x]  [sin x ]  4
, where [t] denotes the greatest integer less than or equal to
2

t, is
1 1 3 3
1) (7  5) 2) (7  5) 3) (4  3) 4) (4  3)
2 12 20 10

KEY: 3
 /2
dx
SOL: I 


 /2
[ x ]  [sin x ]  4
1  /2
dx dx
0
dx
1
dx   1 1 1 

 / 2
 
 2  1  4 1  1  1  4 0 0  0  4
  1  0  4   1  2   2 (0  1)  4 (1  0)  5  2  1
1

3 9 3
  (4  3)
5 20 20
1a  2a  .......  n a 1
05. If lim a 1
 for some positive real number a, then a is
n  (n  1) [(na  1)  ( na  2)  ...  (na  n)] 60
equal to:
15 17
1) 7 2) 8 3) 4)
2 2

KEY: 1
SOL: Conceptual
2 n 4
 1   22   n2 
If U n  1  2   1  2  .... 1  2  , then lim(
2
06. U n ) n is equal to
 n  n   n  n 

16 4 4 e2
1) 2) 3) 4)
e2 e e2 16

KEY: 4

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r
n
 2

SOL: U n    1  r 2 
r 1  n 
2
L  lim(U n ) 4 / n
n 
r
4 n  r2  n
1 r  r2 
 log L  lim 2  log  1  2   log L   lim   log 1  2 
r 1 n n  n 
n  n
r 1  n  n 

1
 log L  4  x log(1  x 2 ) dx
0

put 1  x  t 2

 2xdx  dt
2
 log L  2  log(t )dt  2[t log t  t ]12  log L  2(2 log 2  1)
1

  4   4  2
2(2log 2 1)
2 log    log   e2
Le e   e 
e e

16
 /2
dx
07. The value of the integral


/2
(1  e )(sin 6 x  cos 6 x)
x


1) 2 2) 0 3)  4)
2

KEY: 3
 /2
dx
SOL: 2 I 


 /2
sin x  cos 6 x
6

 /2
dx
I 
0
sin x  cos 6 x
6

 /2  /2
dx (1  tan 2 x ) sec 2 x
 
0
(sin x  cos x )(sin x  sin 2 x cos 2 x  cos 4 x)
2 2 4
 
0
tan 4 x  tan 2 x  1)
dx


1 r 2

t
0
4
 t2 1
dt ( putting tan x  t )

1 1
 1  1
t2 t 2 dt
0 2 1
dt  0  1 2
t 1  2
t  t   1
 t

dy  1 
 1 y

2  putting t  
 t
y

  
 tan 1 y )       .
2  2

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 
sin x  sin x 3
08. If 
0
x
dx  Then
2 
0
x
dx

   
1) 2) 3) 4)
4 3 2 6

KEY: 1

1 3sin x  sin 3 x
SOL:  dx
40 x
 
3 sin x 1 sin 3 x

40 x
dx  
40 x
dy


3    1 sin t dt
4  2  4 0 t 3
  (3x  t )

3
3  1 
   
4 2  4 2 
1  
 (2) 
4 2 4
 /2  /4
09. If f : R  R be continuous function satisfying 
0
f (sin 2 x) sin xdx   
0
f (cos 2 x) cos xdx

then 

1) 3 2) 2 3)  3 4)  2
KEY: 2
 /2
SOL: I1  
0
f (sin 2 x ) sin xdx

 /2
2I   0
f (sin 2 x )(sin x  cos x ) dx

 /4
2I  2 
0
f (sin 2 x)(sin x  cos x) dx

 /4
 
I 2 
0
f (sin 2 x )(cos( x  ) ) dx
4
x
4
t

 /4
I 2 
0
f (cos 2 x) cos( x )dx

 /4 
10. Statement –I: 
0
log(1  tan  )d 
8
log 2.

 /2
Statement-II: 
0
log sin  d   log 2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
1) Both (I) and (II) are wrong statements
2) Both (I) and (II) are correct statements and (II) is the Correct explanation of (I)
3) Both (I) and (II) are correct statements but (II) is not the correct explanation of (I)
4) (I) is a correct statement but (II) is a wrong statement
KEY: 4
SOL: Conceptual
(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
x
 1 t 
11. Let f ( x)   g (t ) log e   dt where g is a continuous odd function. If
0  1 t 
 /2 2
 x 2 cos x   
 
 / 2 
f ( x )  x 
1 e 
dx      then  equal to _____ .
 

KEY: 2
SOL: clearly f ( x ) odd function
 /2
x 2 cos x
I  
 / 2
1  ex
 /2
2I  

 /2
x 2 cos xdx

 /2
2I  2 
0
x 2 cos xdx

2

By integration by parts I     2
2
1

 (1  x
7 k
) dx 10
1
12. Let rk  0
, k  N . Then the value of  7(r is equal to ….
k  1)
1

 (1  x
7 k 1 k 1
) dx
0

KEY: 65
SOL: I k   1.(1  x 7 )k dx
1 1
 1  x 7  x   7 k  (1  x 7 ) k 1 x 6 .xdx
k

 0 0
1
 7 k  (1  x 7 )k 1 ((1  x 7 )  1)dx
0

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 I k  7k ( I k )  7k ( I k 1 )
I k 1 7 k  1 I 7k  8
   rk  k 
Ik 7k I k 1 7 k  7
1
7(rk  1) 
k 1
10
10  11
  ( k  1)  10  65
k 1 2
5

13. The value of  ( x  1)( x  2)( x  3)( x  4)( x  5)dx is _____ .


1

KEY: 0
5
SOL: let I   ( x  1)( x  2)( x  3)( x  4)( x  5) dx
1
5
  (6  x  1)(6  x  2)(6  x  3)(6  x  4)(6  x  5)dx
1
5
  (5  x)(4  x )(3  x)(2  x)(1  x) dx
1
5
   ( x  1)( x  2)( x  3)( x  4)( x  5)dx
1

I  I
2I  0
I 0

 cos x  2023 sin x  2023 tan x dx


2023

14. The value of the integral 0


 /2
= _____ .

2023
sin x dx
0

KEY: 1
SOL: Conceptual


2
8  7 cos x a
15.  (7  8 cos x)
0
2
dx 
7
Then a = ____ .

KEY: 1
 /2  /2  /2
8  7 cos x  cos x(7  8cos x) 8sin 2 x   cos x 8sin 2 x 
SOL:  
0
(7  8cos x ) 2
dx  
0
 (7  8 cos x) 2


(7  cos x) 2 
dx  0  (7  8cos x) (7  cos x)2 dx

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2

By integration by parts of first integration   


1
sin x 
 7  8cos x 0
a 1

7 7
1
 (n  1)(n  2).....(3n)  n 
16. lt    2 Then  = ______ .
n 
 n2n  e

KEY: 27
SOL: Conceptual
p  a7
a 3
17.  x (ax  x ) 2 dx  then p  q = _____ .
3 2

0
2q

KEY: 20
 /2
SOL: x  a sin  , dx  2a sin  cos  d ,  2a sin10  cos 4 
2 7

Bye Walli’s reduction formula


9 a 7
, p  9 , q  11
211
18. Let the domain of the function f ( x)  log 4 (log 5 (log 3 (18 x  x 2  77))) be (a, b), then the value
b
sin 3 x
of the integral a sin3 x  sin 3 (a  b  x) dx is equal to
KEY: 1
SOL: f ( x ) is defined if
log 5 (log 3 (18 x  x 2  77)  0
 log 3 (18 x  x 2  77)  1  18 x  x 2  77  3  x 2  18 x  80  0  a  8 and b  10
b 3
sin x
Now I   dx.........(i)
a
sin x  sin 3 (a  b  x)
3

b
sin 3 (1  b  x )
I   dx............(ii)
a
sin 3 (a  b  x)  sin 3 x
Adding (1) and (ii) ,we get
b
2 I   1dx  b  a  2
a

I 1

120 x 2 sin x cos x
 3 0 sin 4 x  cos4 x
19. dx is equal to …

KEY: 15
SOL: Conceptual

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RPTM-06
MATHEMATICS
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
 x2 
01. Area bounded by the curves y    2  , y=x-1 and x=0 above the x-axis is _____
 64 

(where [.] denotes the greatest integer function),


1) 2 2) 3 3) 4 4) 2 3
Key: 3
Sol: .   
If -8<x<8, then y=2; If x  8 2 , 8  8,8 2 , then y=3, etc. 
 x2 
y=x-1 will not intersect y    2  at any other interval, except in the
 64 

interval , x   8,8  ,
y

3
Q
2R

x
R

O p 3 8

1
 2  3   2  2  4 sq.unit
The required area 2

02. The smaller area enclosed by y=f(x), when f(x) is a polynomial of least degree satisfying
1
 f ( x)  x 2 2
lim 1 
3   e and the circle x  y  2 above the x-axis is
x 0  x 
 3  3  3
1) 2) 3)  4) 
2 5 2 5 2 5
Key: 3

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1
 f(x)  x f(x)
Sol: . Since lim 1  3  exists, so lim 3  0
x 0  x  x 0 x

 f(x)  a 4 x 4  a5x 5  .........  a n x n ,a n  0, n  4

Since f(x) is of least degree  f(x)  a 4 x 4

A(1,1)

O B(1,0)

1
 f(x)  x
again lim 1   e
x 0  x3 

 a4  1  f(x)  x 4

The graph of y  x4 and x 2  y 2  2

1
 3
 The required area  2   2  x 2  x 4 dx  
  2 5
0

03. The area bounded by the curve f  x   x  sin x and its inverse function between the
ordinates x  0 to x  2 is
1) 4 Square units 2) 8 square units 3) 4 square units 4) 8 square units
Key: 4
 
Sol: Required area=4A, where A    x  sin x  dx   xdx
0 0

2 2
A  cos   cos0   2 squareunits.
2 2

04. If [x] is the greatest integer  x , then area bounded by min {x  [x], x  [ x]} in the
interval [-2, 2] with x-axis
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
1) 1 2) 2 3) 3/2 4) 0
Key: 1
Sol: The graph of f(x) = min{x  [x], x  [ x]}

2
1 1
 min{x  [x], x  [ x]}dx  Area of shaded region  4  2  1  2   1
2

2
1

2 1 0 2
1

05. A square ABCD is inscribed in a circle of radius 4. A point P moves inside the circle
such that d(P,AB)  min(d(P,BC),d(P,CD),d(P,DA)) where d(P,AB) is the distance
of a point P from line AB. The area of region covered by moving point P is
1) 4 2) 8 3) 8  16 4)16
Key: 1
r 2
Sol: Shaded area of the required region=  4
4

A B

C D

06. If the area of the region bounded by the curves y  x 2  1 , y=x and the pair of the Lines

x 2  y 2  2xy  5x  5y  4  0 is k units, then the area of the region bounded by the curve

y  x2  1, y  x  1 and the pair of lines  x  y  1 x  y  4   0 is

1) k2 2) 2k 3) k/2 4) k+2
Key:
Sol: y  x2  1 and y  x  1 are inverse of each other.

The shaded area is given as k units  Area of region bounded by


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y  x 2  1, y  x  1 and ( x  y  2)( x  y  3)  0 is 2k units

y  x2 1

yx

y  x 1

x  y 4 0

X
x  y 10

1
2
07. The area bounded by the curve f(x)  max.{4  x ,|x  2|,(x  2) 3 } for x  [ 1, 4] and x-
axis is
45 23 59 53
1) sq units 2) sq units 3) sq units 4) sq units
4 4 4 4
Key: 1
Sol: y  4  x 2 is the parabola

y |x  2|is the pair of straight lines,

1
y  (x  2) 3 is the curve

By drawing diagram required area=45/4 sq. units.

08. The area enclosed by the curve x  a cos 3 t, y  bsin 3 t is


ab 3ab ab 
1) 2) 3) 4 4) ab   4 
8 8 8 4 
Key: 2
Sol: Clearly as t varies from 0 to 2 the given equations describe a closed loop, we Have

Put x= b sin 3 t

y  a cos3 t

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2
3 ab
A  4  ydx = sq. units
8
0

09. If x-intercept of any tangent is 3 times x-coordinate of the point of tangency, then the
equation of the curve lying in the first quadrant, given that it passes through (1, 1) is
1 1 1
1) y  2) y  2 3) y  4) y  x
x x x
Key: 3
dy
Sol: Equation of the tangent is Y  y  ( X  x)
dx

dy y dy 1 dx
For Y  0, X  3x, We get  y  
dx 2x y 2 x

1 c
 ln | y |  ln | x |  ln c  y 
2 x

1
y (c=1, as the curve passes through(1,1))
x

xdy  y 
10. The solution of the   1 dx is
x 2  y 2  x 2  y 2 

1  y  y2
1) y  x cot( c  x ) 2) cos     x  c 3) y  x tan( c  x ) 4)  x tan(c  x)
x x2
Key: 3
xdy  y 
Sol:   1 dx
x 2  y 2  x 2  y 2 

xdy  ydx   y 
  dx   d  tan 1       dx
2 2  x 
x y 

 y y
 tan 1     x  c   tan(c  x )
x x

xdx  ydy a2  x2  y2
11. The solution of the  is
xdy  ydx x2  y 2
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  y   y 
1) x 2  y 2  a sin  tan 1  C   2) x 2  y 2  a cos  tan 1  C  
  x   x 
  y    y 
3) x 2  y 2  a  tan  sin 1  C   4) x 2  y 2  a cot  sin 1  C  
  x    x 
Key: 1
Sol: Taking x  r cos and y  r sin , so that

x 2  y 2  r 2 and y / x  tan  , we have

xdx  ydx  rdr and

xdy  ydx  x 2 sec 2  d  r 2d .

The given equation can be transformed into

rdr a2  r 2 dr
   a2  r 2
r 2d r2 d

 C  sin 1 r / a    tan 1 y / x

r
sin 1   c
a

r
 sin(  c)
a

y
r  a sin(tan 1  c)
x

y
x 2  y 2  a sin(tan 1  c)
x

 1 y2   x 2 1 
12. Solution of the differential equation    dx   
2 y
dy  0 is
 x ( x  y ) 2   ( x  y ) 

x xy xy xy xy
1) ln   c 2)  ce x / y 3) ln xy  c  4)  ce y / x
y x y x y x y x y
Key: 1
Sol: The given equation can be written as

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

 dx dy   x 2dy  y 2dx 
     0
2 
 x y   ( x  y ) 

 dy dx 
  
 dx dy   y 2 x 2 
or      0
 x y   1 1 2 
 
 y  x 
  

 dy dx 
  
 dx dy   y 2 x 2 
or      0
 x y   1 1 2 
 
 x  y 
  

x xy
Integrating we get or ln  c
y ( x  y)

x xy
or ln  c
y ( x  y)

Where ‘c’ is an arbitrary constant


(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
13. The area of the region enclosed by the curve y  x3 and its tangent at the point (-1,-1) is A
then 4A is__________.
Key: 27
Sol: Given, y  x 3

3
Equation of tangent to the curve y  x , at point (-1,-1) is

y  1  3( x  1)  y  3x  2

Point of intersection with curve is (2,8)

2  2 4 2
(3 x  2)  x3 dx  3  x x 27

So, area=   2
 2 x 
4 
 
4 sq. units
1  1

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14. The differential equation of the family of circles passing through the points (0,2) and (0,-
dy 2 2
2) is  xy dx  ( x  y   )  0 then    
Key: 6
Sol: Equation of circle passing through (0,-2) and (0, 2) is

( x  0)( x  0)  ( y  2)( y  2)   x  0

 x2  y 2  4   x  0 ....(i )

dy dy
2x  2 y    0    2 x  2 y
dx dx
Y

(0,2)

X' X
O

(0,2)

Y'

Putting the value of  in (i), we get

 dy  dy
x 2  y 2  4  x  2 x  2 y   0  2 xy  ( x 2  y 2  4)  0
 dx  dx

dy
15. If y(x) is the solution of the differential equation  2 x( y  1) with y(0) =1 then
dx
lim y( x) , equals to __________.
x
Key: 1
dy dy
Sol: .  2 x( y  1)   2 xy  2 x
dx dx

2
Integrating factor= e 
2xdx
 ex
2 2 2 2
 Solution of the d.e. is ye x   2 xe x dx  c  ye x  e x  c

2 2
Given y(0)=1  c  0. So ye x  e x

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 lim y ( x )  lim (1)  1
x 0 x 0

dy
16. Let the solution y=y(x) of the differential equation  y  1  4sin x satisfy y ( )  1 .
dx

Then y    10 is equal to ___________.
2  

Key: 7
Sol: Given, dy  y  1  4sin x, Which is a linear differential equation.
dx
 integrating factor

x x
Hence the solution is ye   (1  4sin x )e dx …..(i)

 e  x  2e  x (  sin x  cos x)  C

y( )  1 i.e., at x   , y  1

 from (i), we gets e   e  2e  C  C  0

Hence, y( x)   1  2(Sinx  cos x)

    
Now, y    10  1  2  sin  cos   10
2  2 2

 1  2(1)  10  7

17. If the solution y(x) of the given differential equation (e y  1)cos xdx  e y sin xdy  0 passes
 
y 

through the point  ,0  , then the value of e 6 is equal to_______________.
2 
Key: 3
Sol: Given,(e y  1) cos xdx  e y sin xdy  0

 d (e y sin x)  cos xdx  0  e y sin x  sin x  C

dy  
 y  1
The curve passes 4sin x, the
through  ,0 
dx 2 

 C  2  e y sin x  sin x  2

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 y     
y 
 
y 
  6  1 1 
 e    2  e  6  1  4  e  6   3
 2 2
 
2
18. The area enclosed by the curves x  4 y  4 and x-2y=2 is_________.
Key: 9
3/2
Sol: Eliminate y and use
6A2

dx 1  x  y 2
19. If  , x(1)  1, then 5 x(2) is equal to __________.
dy y
Key: 5
Sol: We have,

1
  dy
1
I .F .  e y
 e  log y 
Now, y

dx 1  x  y 2 dx x 1  y 2
   
dy y dy y y

So, solution is given by

x 1  y2 x 1
 dy  C    yC
y y2 y y

 x  1  y 2  Cy

 x(1)  1  1  1  1  C  C  3

 x  1  y 2  3 y

 5 x(2)  5(1  4  6)  5

20. Let y=y(x) be the solution of the different equation

( x 2  3 y 2 ) dx  3 xydy  0, y (1)  1 . Then 6 y 2 (e) is equal to ke 2 then k=________.


Key: 2
dy
Sol: . ( x 2  3 y 2 )dx  3xy dy  0  x 2 dx  3 y 2 dx  3 xydy  0  x 2  3 y 2  3 xy 0
dx

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2 dy
2 dt 3 x dt
Put y  t  2 y dt  dx  x  3t  2 dx  0
2 x 2t dt dt 2t 2 x
   0   ,
3 3 dx dx x 3 Which is linear D.E.

2 1
ln
  x dx x2 1
e  e 2ln| x|  e 
x2

1 1  2 x  y2 2
So., t. x 2   x 2  3  dx  x 2

3
ln | x | C

When,x  1, y  1

2 y 2 2
1 ln(1)  C  C  1   ln | x | 1
3 x2 3
y 2 (e) 2 2 e2
At x  e,   1  y ( e )   6 y 2 (e)  2e 2
2 3 3
e
21. If the solution of the curve y=y(x) of the differential equation

(1  y 2 )(1  loge x)dx  xdy  0, x  0 passes through the point and (1,1) and

3
  tan  
y ( e)    , then   2  is___________.
2
3
  tan  
2
Key: 3
Sol: . we have (1  y 2 )(1  log e x) dx  xdy  0

dy (1  log e x ) dx
  Integrating both sides, we get
1  y2 x

1  1  1
tan 1 y   (1  log e x) 2 C , At (1,1),  C C  
2 4 2 4 2

 3 3
tan  tan 1  tan
 1   3
 y  tan   1  (1  (log e x) 2    y (e)  tan     4 2  2
4 2  
 4 2  1  tan tan 3 3
1  tan
4 2 2

So,   1 and   1    2  3

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-07
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
x 1 y  2 z  3 x y 1 z 1
01. Consider the line L1 and L2 given by L1 :   , L2 :   . A line L
1 4 3 1 2 2

having dr’s 0,1,1 intersects. L1 and L2 at A and B respectively. Then the length of AB is

1) 5 2 2) 6 3 3) 2 2 4) 6 3
Key: 1
x y 1 z 1
Sol: L2 :   
1 2 2
x 1 y 1 z  3
L1 :   
1 4 3

B   , 2  1, 2  1 , A    1, 4  2,3  3

AB lies on L, So AB dr’s are equal to lines dr’s


   1 4   2  1 3  2  4
 
0 1 1
    1, 4   2  1  3  2  4
4   1  3  4;   3;   3  1  4

A  4,14,12  B  4,9,7  ;

AB  02  52  52  5 2
x 1 z  2 x  2 y  1 2z  3
02. If the two lines L1 :  , y  1 and L2 :   perpendicular, then an angle
2 1 1 2 
x 1  2 y z 1
between the lines L2 and L3 :   is
2 3 1
 2 
1) cos 1   2) sec1   3) cos 1  
29 29 2
4) cos 1  
 4   4   29   29 

Key: 4
x  2 y 1 z  2
Sol: L1   
1 0 1
3 1
z y
x  2 y 1 x
2 ,L :  2  z 1
L2 :  
1 2  3
2 3 1
2 2

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

2
2
L1  L2   0    4
2
5  4 5
4

Angle between L2 and L3

 3   4 
1 2   2       1
2  2 
cos  
9
5 5
4

3 2  2 
    cos 1  
29 29  29 
3
2
03. Statement-1: The point A(1,0,7) is the mirror image of the point B(1,6,3) in the line
x y 1 z  2
 
1 2 3
x y 1 z  2
Statement-2: The line:   bisects the line segments joining
1 2 3
A 1, 0, 7  and B 1,6,3
1) Statement-1 is true, Statement -2 is false
2) Statement-1 is false, Statement -2 is true
3) Statement-1 is true, statement-2 is true: statement -2 is a correct explanation for
statement-1
4) Statement-1 is true, statement-2 is true: statement -2 is not a correct explanation for
statement-1
Key: 4
Sol: Statement-I Any point on line P= (t,2t+ 1,3t+2)
D.r ' s of PB   t  1; 2t  5,3t  1

PB  to the line

1  t  1   2t  5   3  3t  1  0

P  1,3,5 

M .Pt of AB

 11 6  0 7  3 
 , , 
 2 2 2 

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1, 3,5 
11 6  0 7  3 
Statement-II: midpoint of AB   , ,   1,3,5 
 2 2 2 

04. If a,b,c be three distinct real numbers, non equal to one. If the vectors ai  j  k , i  b j  k
1 1 1
and i  j  ck are coplanar then    ____
1 a 1 b 1 c
1) 0 2) 2 3) 1 4) 3
Key: 3
Sol: Given that vectors are coplanar
a 1 1
  a b c   0  1 b 1  0
1 1 c

R1  R1  R2 and R2  R2  R2

a 1 1 b 0
0 b 1 1 c  0
1 1 c

On expanding determinate, we have


1 1 1
  1
1 a 1 b 1 c
2 2 2
05. If a, b, c are unit vectors, then a  b  b  c  c  a does not exceed
1) 4 2) 9 3) 8 4) 6
Key: 2
2 3 2
Sol: a  b  c  0  a.b  b.c  c.a    ab  bc  ca  9
2
  
06. Let a  i  4 j  2k , b  3i  2i  7k and c  2i  j  4k . If a vector d satisfies
       2
d  b  c  b and d .a  24, then d is equal to

1) 323 2) 423 3) 313 4) 413


Key: 4
           
Sol:     
d  b  c  b  d  c  b  0  d  c  b  0  d  c as c.a  b 
  
 
 d  c   b ; a.b.  24  given   9  18    9

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2
d  64  25  324  413

Option (d) is correct

07.

a. b  c   b. c  a   c. a  b  
 c  a  .b  a  b  .c  b  c  .a
1) 3 2)  a b c  3)   a b c  4) 0

Key: 1
Sol: Conceptual
     
08. Statement1: The vectors a, b and c lie in the same plane if and only if a.  b  c   0
    
Statement 2: The vectors u and v are perpendicular if and only if u.v  0 and u  v is
 
vector perpendicular to plane of u and v .
1) Statement 1 is true, statement 2 is false
2) Statement 1 is true, statement 2 is true, Statement 2 is correct explanation for statement
1
3) Statement 1 is false, statement 2 is false.
4) Statement 1 is true, statement 2 is true, Statement 2 is a not correct explanation for
statement 1
Key: 2
     
Sol: The vectors a , b and c lie in the same plane  a, b and c are coplanar
We know, the necessary and sufficient conditions for three vectors to be coplanar is that
  
 a, b, c   0 a.  b  c  i  0
 

Hence, statement-1 is true.


(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
09. If origin is the orthocenter of a triangle formed by the points
 cos  ,sin  ,0  ,  cos  ,sin  ,0  ,  cos  ,sin  ,0  then  cos  2       __

Key: 3
Sol: Conceptual

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10. Let Q be the foot of the perpendicular from the point  2, 2, 1 on the plane containing the
x 1 y  2 z  3 x 1 y  2 z  3
then 3  PQ  is _____ .
2
lines   and  
1 2 3 3 1 2
Key: 25
x 1 y  2 z  3 x 1 y  2 z 1
Sol:   ;  
1 2 3 3 1 2

x 1 y  2 z  3
1 2 3 0
3 1 2

 x  1 7    y  2  7    z  3 7   0
x 1 y  2  z  3  0  x  y  z  0

P  2121  1 

2  2  1 5
PQ  
111 3
25
3  PQ   3 
2
 25
3
x 1 y  6 z  5
11. Let P be a plane containing the line   and parallel to the line
3 4 2
x3 y 2 z 6
  If the point 1, 1,   lies on the plane P, then the value of | 5 | is equal
4 3 7
to __.
Key: 38
x 1 y  6 z  5
Sol: Equation of plane is 3 4 2 0
4 3 7

0 6  5
1, 1,    3 4 2 0
4 3 7

5  21  8     5  9  16   0

65  25  125  0  25  190


38
 | 5 | 38
5

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12. If the distance between the plane, 23 x  10 y  2 z  48  0 and the plane containing the lines
x 1 y  3 z 1 x  3 y  2 z 1 k
  and      R  is equal to , then k is equal to_____ .
2 4 3 2 6  633

Key: 3
Sol: Point of intersection
x 1 y  3 z 1
   t;
2 4 3
x  3 y  2 z 1
  s
2 6 
  2t  1, 4t  3,3t  1   2 s  3, 6s  2,  s  1

1 1
By solving, we get t  , s  ,   7
2 2

13. If the point whose position vectors are 3i  2 j  k , 2i  3 j  4k  i  j  2k and 4i  5 j   k lie on


17
a plane, then .  2  _____ .
146
Key: 1
Sol: Let OA  3i  2i  k , OB  2i  3 j  4k
OC  i  j  2k and OD  4i  5 j   k

Since, AB, AC and AD are coplanar


146
 AB, AC , AD   0   
17
       
14. If  a  3b  is perpendicular to  7a  5b  and  a  4b  is perpendicular to  7a  2b  , then angle
 
between a and b (in degrees) is _____ .
Key: 60
Sol:  a  3b  . 7a  5b   0 _____ 1
 7a  2b  . a  4b   0 _____  2 
solve 1& 2
2 2
b  2a.b, a  2a.b

1
a.b  a b cos   cos      60
2
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15. If  b  c    c  a   3c then b  c c  a a  b   _____ .

Key: 9
Sol: b c a  c  3c   a b c   3
   
2
then b  c c  a a  b    a b c   9

   2 2 2    2 2
16. Let a and b be two vectors such that , a  b  a  2b , a  b  3 and a  b  75. then a is

equal to _____ .
Key: 14
2 2 2
Sol: ab a 2 b

2 2 2 2 2
a  b  2a.b  a  2 b  b  6

 
2 2 2 2 2
a  b a b  a.b  a  14
    
17. Let a  2i  j  2k and b  i  j. If c is a vector such that a.c | c |,| c  a | 2 2 and the angle
     
between  a  b  and c is 300 , then  a  b  c  ____ .
Key: 3
i j k
Sol: a  b  2 1 2  i  0  2   j  0  2   k  2  1
1 1 0

 a  b   3, c  a  2 2, a  3

 
2 2
c  a 2 ca 8

2
c  9  2 c 8  0

 c  1
2
 0  c 1

 a  b, c   30 0

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-08
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
( n  2) ( n  2) ( n  2)
n
C( r 2) C( r 1) C( r )
  2  ,  n  2  is
r
01. The value of 3 1 1
r 2
2 1 0
1) 2n 1  (1)n 2) 2n 1  (1)n1 3) 2n  3  (1)n 4) 2n  2
Key: 1
Sol: Applying C1  C1  2C2  C3
n n2 n2
n r
Cr Cr 1 Cr
S    2  0 1 1  2n  1  (1) n
i2
0 1 0

02. Let S be the set of all integer solutions  x, y , z  of the system of equations
x  2 y  5 z  0, 2 x  4 y  z  0, 7 x  14 y  9 z  0 . Such that 15  x 2  y 2  z 2  150 .
Then the number of elements in the set S is equal to
1) 4 2) 6 3) 8 4) 2
Key: 3
Sol: Given system equations
x  2 y  5 z  0  (1)
2 x  4 y  z  0  (2)
7 x  14 y  9 z  0  (3)
solve (1), (2) z  0
Substitute z=0 in (1) we get x  2 y
15  x 2  y 2  z 2  150
15  4 y 2  y 2  150
3  y 2  30
 x  2 y, z  0
 y  2, 3, 4, 5
8 points
If AK  O for some value of K.  I  A   I  A  A2  ...  AK 1 , where A is nil potent
P
03.
with Index K. Then P 
1) - 1 2) - 2 3) - 3 4) 0
Key: 1
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Sol: Let Let B  I  A  A  ...  A 2 n 1

B( I  A)  (1  A  A2  .......  An 1 )  I  A   I  A  A  ....  A K 1  A K 1  A K  I  A K  I  A K  0 

B   I  A   I  A  A2  ....  A K 1
1

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
04. The Number of possible matrices of order 3  3 , whose entries are either 0 or 1 and the
sum of all the entries is a prime number is ________
Key: 282
 a11 a12 a13 
Sol: A   a21 a22 a23  , aij   0,1
 a31 a32 a33 
 aij  2,3,5, 7
Total matrices  9C2  9C3  9C5  9C7  282

1 0 0  1 0 0 
05. If the matrix A  0 2 0  satisfy the equation A20   A19   A  0 4 0  for some
   
3 0 1 0 0 1 
real number  ,  . Then    = _________
Key: 4
1 0 0  1 0 0 1 0 0
Sol: A2  0 4 0  A3  0 23 0  , A4  0 24 0 
0 0 1   3 0 1 0 0 1 

1 0 0 
A   A   A  0 4 0 
20 19

0 0 1 

1     0 0  1 0 0 
 0    2  2
20 19
0   0 4 0 
   
 3  3 0 1      0 0 1 

compare and solve we get   2,   2

   4

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 1 5  1
06. If A    , A   A   I and     2.Then 4 2   2   2  ________
 10 
Key: 14
Sol: A  XI  0

1 x 5
0
 10  x

 2  11x  10  5  0
A2  11A  10  5  I  0
(10  5 ) A1   A  111 ( A1   A   I )
1 11
Compare we get   ,
10  5 10  5
1 11
 , ,  3
5 5

1  1 2 3 
07. Let X  1 ; A   0 1 6  for k is even naturalnumber. If X 1 AK X  33 then K=
  
1  0 0 1

____
Key: 10
Sol: Conceptual
1 2 
08. Let A be matrix such that A.   is a scalar matrix and 3 A  108 then sum of
0 3
elements of principal diagonal of A2 is ____
Key: 40
1 2  k 0
Sol: A  scalar matrix 0 t 
0 3   
1 2 k 0
A 
0 3  0 k 
1
k 0  1 2
A
0 k   0 3 
 2   2 
1   k  k
k 0 3 3 
A    
0 k   1  0 k 
0  
 3   3 
3 A  10 8
3k 2k
 1 08
0 k
k  6

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 
 0 Tan 
2 and I  A I  A 1   a b 
09. If A     2  2    
. Then 13 a 2  b 2 
Tan  0  b a
 2 
=__________
Key: 13
   
 1 Tan   1 Tan 
Sol: 2 2
I2  A    I2  A   
Tan  1   Tan  1 
 2   2 

 
 1 Tan 2
1 2
 I 2  A
1
  

1  Tan 2 Tan  1 
2  2 

 cos   sin  
 I 2  A I 2  A
1
 
 sin  cos  

comparing a  cos  , b  sin 

 b c
a b 
10. If   a,   b,   C and a  c  0 Then    __________
 a  b  c
a b 
Key: 0
 b c
Sol: a  c 0
a b 

   a    b   b   a  c     a  b    c     0

Dividing by   a    b    c 

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1 3  
11. Let B   1 2 3  ,  2 be the adjoint of matrix A and A  2 Then
 
  4 

  
  2   B 2   K  then K  _________
  

Key: 16
B  A  4 ,   2 or 4 ,   4   2 
2
Sol: B  adj A ,

 2 1
12. Let A    if B  I  5C1 (adjA)  5C2 (adjA) ......  5C5 ( adjA) . Then the sum of all
2 5

0 2 
elements of the matrix B = k then k  _____________
Key: 7
 2 1 2 1
Sol: A  adj A   
0 2   0 2

B  I  5C1  adjA   5C2  adjA   ....  5C5  adjA


2 5

5
 1 1  1 5 
  I  adjA   
5
  
 0 1  0 1 
a b c 
13. A   b c a  where a, b, c are real positive number abc = 1 and AT A  I then the
 
 c a b 

value of a 3  b3  c3  ___
Key: 4
Sol: AT A  I

a 2  b 2  c 2  1, ab  bc  ca  0
a 3  b3  c 3   a  b  c  (a 2  b 2  c 2  ab  bc  ca)  3abc
a 3  b3  c 3   a  b  c   3

( a  b  c ) 2  1  2(0)  1
a b  c 1
 a 3  b3  c3  1  3  4

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RPTM-09
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

01. The straight lines represented by ( y  mx) 2  a 2 (1  m 2 ) and ( y  nx) 2  a 2 (1  n 2 ) form a


1) Rectangle 2) Rhombus 3) trapezium 4) scalar
Key: 2
Sol: ( y  mx) 2  a 2 (1  m 2 )

Pair of parallel lines y  mx   a(1  m 2 )

Distance between then is 2a 1  m2

 y  nx 
2
 a 2 (1  n2 )

Pair of parallel lines

Distance between then is 2a 1  n2

It form rhombus
4
02. If  x
i 1
2
i  yi2   2 x1 x3  2 x2 x4  2 y2 y3  2 y1 y4 the points

 x1 , y1  ,  x3 , y3  ,  x2 , y2  and  x4 , y4  are
1) Vertices of a rectangle 2) Collinear
3) Vertices of trapezium 4) Vertices of a parallelogram
Key: 1
4
Sol:  x
i 1
2
1  y12   2 x1 x3  2 x2 x4  2 y2 y3  2 y1 y4

  x1  x3    x2  x4    y2  y3    y1  y4   0
2 2 2 2

x1  x3 , x2  x4 , y2  y3 , y1  y6

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03. If p  0 , the straight lines ax  by  p  0 and x cos  y sin   p are inclined at an

angle and concurrent with the straight line x sin   y cos  0 then the value of
4
a 2  b 2 is
1) 0 2) 1 3) 2 4) 7
Key: 3
Sol: ax  by  p  0  (1)

x cos   y sin   p  (2)


is angle between (1) & (2)
4

 a cos   b sin 
cos 
4 a 2  b2 1

a b p
cos  sin  p 0
sin   cos  0

a ( p cos  )  b( p sin  )  p (1)  0

 a cos   b sin   1

1 1
from(3)   a2  b2  2
a2  b2 2

04. If the line y  3 x cuts the curve x 4  ax 2 y  bxy  cx  dy  6  0 at A, B, C and D then


the value of OA.OB.OC.OD (O is origin) is
1) a  b  c 2) 2C 2d 3) 96 4) 6
Key: 3
Sol: Given curve is x 2  ax 2 y  bxy  cx  dy  6  0  (1)

Parametric form of the line is (x,y) = ( x, y )   r cos 600 , r sin 600 

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 r 3r 
  intersect at A,B,C,D of (1)
 2 2 

r4 3 3 3 2 3 2 3 2
 a r b r c r d r 60
16 4 4 4 4

6
OA.OB.OC.OD  r1r2 r3r4   96
1 / 16

05. The reflection of the pair of straight lines x 2  y 2  2 x  1  0 in the point (1, -1) is

1) x 2  y 2  6 x  4 y  5  0 2) x 2  y 2  6 x  4 y  4  0

3) x 2  y 2  6 x  4 y  5  0 4) x 2  y 2  6 x  4 y  4  0
Key: 1
Sol: Given pair of straight lines x 2  y 2  2 x  1  0  (1)

The reflex ion of (1) in the point (1,-1) is (2  x) 2  (2  y ) 2  2(2  x)  1  0

x2  y2  6x  4 y  5  0

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
06. P(3,1), Q(6,5) and R(x, y) are three points such that angle PRQ is right angle and the
area of PRQ is 7 sq. units , then number of such points R is_____.
Key: 0
Sol:  given  7

1 1 25
 max  PQ.. CR   6.25
2 2 4
 given   max

No point satisfied

07. The number of integral values of a for which the point P  a 2 , a  lies in the region
corresponding to the acute angle between the lines 2 y  x and 4 y  x is_____ .
Key: 1
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Sol: a 2
 4a  a  2a   0
2

a 2 ( a  2)(a  4)  0

2a4

a3

08. If the pair of lines 6 x 2  axy  3 y 2  24 x  3 y    0 intersect on x- axis then the value
of  20    is _______ .
Key: 6
Sol: 6 x 2  2 xy  3 y 2  24 x  3 y    0

y0

6 x 2  24 x    0
0
2 y 2  4.6   0
  24

For point of intersection to partical lift


12 x   y  24  0

 x  6 y  3  0

Put y  0

3
  2, 
2
3
 20     20.  24  30  24  6
2

09. n1 is the number of points on the line 3x  4 y  5 which is at distance 1  sin 2  units
from (2,3) and n2 denotes the no of points on the line 3x  4 y  5 which is at distance of
sec2   2cosec 2 unit from the (1,3) then the sum of roots equation n2 x 2  6 x  n1  0 is
_.
Key: 3

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6  12  5 13
Sol: er distance from (2,3) to the line 3 x  4 y  5  0 is 
5 5

13
1  sin 2  
5

 x1  0

3  12  5
er distance from (1,3) to the line 3 x  4 y  5  0 is 2
5

sec 2   2cos ec 2  3  2  2

Number of points 2

 n2  2

nL n 2  6 x  n1  0

2n 2  6 x  0  0

x 2  3x  0
x  0,3

Sum of roots = 0+3 = 3

10. The base of an isosceles triangle is the intercept made by the line x  2 y  4 with the
coordinate axis. If the equations of the equal sides be x  4 and y  mx  c then the value
of 8m  c is _____ .
Key: 8
Sol:  CA  CB
 8m  6
8m  c  8

11. The slope of one of lines given by ax 2  2hxy  by 2  0 be square of the slope of the
other, if ab(a  b)   abh   h3  0 then    is equal to ______ .
Key: 2
Sol: ax 2  2hxy  by 2  0

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2h
m  m2 
b

a
m3 
b

8h3
m  m  3m (m  m )  3
3 6 3 2

a a 2 6ah 8h3
   3 0
b b2 b 2 b

ab 2  a 2b  6abh  8h3  0

ab(a  b)  6abh  8h3  0

  6,   8

  2

12. If A (1,1) B (2,3), C (-1,1) are three points. If P is a point such that the area of the
quadrilateral PABC is 3 sq. units and locus of P is y 2   y  0 then   ____.
Key: 6
Sol: p ( x, y ) A(1,1) B (2,3)C ( 1,1) are vertices

Area =3

1 x2 2
3
2 y 3 0
( y  3)  3
( y  3)2  9
y2  6 y  0  y2   y
 6

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RPTM-10
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. The area of equilateral triangle in which 3 circles of radius 1 are placed as shown in
figure is
A

B C

1) 2  2 3 2) 4  2 3 3) 4  4 3 4) 6  4 3

Key: 4

Sol: a  si de  2 3  2

3
 
2
area  2 32 64 3
4
02. Let ABCD be a quadrilateral with area 18, side AB parallel to the side CD & AB = 2CD.
Let AD be perpendicular to AB and CD. If a circle is drawn inside the quadrilateral
ABCD touching all the sides. Then its radius is

1) 3 2) 2 3) 3/2 4) 1

Key: 2

Sol: ABCD   a  2a  2r  18  ar  6

eq. of BC is 2rx  ay  4ar

2r 2  ar  4ar
r r2
4r  dt
2

03. The point ‘P’ on the parabola y 2  16x for which |PR – PQ| is maximum, where
R = (-4, 0), Q = (0, 4) is ........

1) (4, 8) 2) (7, -8) 3) (16, 16) 4) (16, -16)

Key: 1
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Sol: |PR  PQ| is maximum when P is the point of intersection of parabola and line QR. Here it
becomes a Tangent. So P is point of contact of tangent QR

04. Let P and Q be distinct points on the parabola y 2  2x such that a circle with PQ as
diameter passes through the vertex O of the parabola. If P lies in the first quadrant and the
area of triangle  OPQ is 3 2 , then P can be ……..


1) 4, 2 2  
2) 9, 3 2  1 1 
3)  ,
4 2
 4) (2, 2)

Key: 1

 16a 8a 
Sol: P  at 2 , 2at  , Q  2  
 t t 

a  4  16
1 1
OPQ  OP. OQ  at t 2  4.
2 2 t t2

 4  3 2  P  1, 2 ,Q  4, 2 2  
05. Two circles one of radius 8 and other of radius 18, are tangent (i.e., they intersect at
exactly one point). There are two lines each of which is tangent to both circles, as shown
in the diagram. The distance from the point of intersection of these lines to the centre of
the circle with radius 8, is equal to

1) 18.5 2) 20.8 3) 22.6 4) 24.4

Key: 2

18 8
Sol: sin   
x  26 x

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104
 18x  8x  26  8   10x  26  8   x   20.8
5

06. If two distinct chords of a parabola y 2  4kx drawn from the point (k, 2k) are bisected by
the line x + y – 1 = 0, then the length of the latus rectum can be:
1) 4 2) 3 3) 5 4) 6

Key: 2

Sol: Let  , 1    be any point on the line x + y – 1 = 0

The chord with mid-point  , 1    is S1  T

1   
2
 4k  2k  2k  2k 2  2k

1     2k  2k 2  2k 1  k   0
2

k 1  k   0  k  k  1  0

0  k 1

 0  4k  4

Latus rectum   0, 4 

07. In a right angled triangle BC = 5, AB= 4, AC = 3. Let S be the circum circle. Let S1 be
the circle touching both sides AB and AC and circle S internally. Let S2 be the circle
touching the produced sides AB and AC of  le ABC, and touching the circle S externally
If r1 , r2 are radii of circles S1 and S2 respectively then r1 r2 =
1) 12 2) 20 3) 15 4) 24

Key: 4

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Sol: Let A= (0, 0), B= (4, 0), c = (0, 3)
Circumcentre of circle S is (2, 3/2) and circumradius = 5/2
25
Equation of S is  x  2    y  3 / 2   ......1
2 2

If circle S1 is having radius r1 and touching AB and AC  its centre is  r1 , r2 

If S2 is having r2 and touching AB and AC  centre of S2   r1 , r2 

S2 touches S externally   r2  2    r2  3 / 2    r2  5 / 2 
2 2 2

 r22  12r2  0  r 2  12  r1r2  24

08. A circle passing through the vertex C of a rectangle ABCD and touches its sides AB and
AD at M and N respectively. If  lar distance from C to the line segment MN is equal to
5 then area of rectangle ABCD is K then the digit in unit place of K is
1) 2 2) 1 3) 5 4) 3

Key: 3

Sol: Let r be the radius of the circle and A = (0, 0) AB is along x-axis and AD is along
y-axis.
Equation of circle is  x  r    y  r   r 2 ...... i 
2 2

now  lar dis tan ce from C  p, q  to the above line is 5

pqr
 5   p  q  r   50.......  2 
2

2

 p, q  lies on circle 1  p 2  q 2  2r  p  q   r 2  0


50  2pq  0  pq  25

 area of rec tan gle ABCD is 25

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(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

The length of the latus rectum of the parabola169  x  1   y  3    5x  12y  17 


2 2 2
09.
 
is l then 26l is ..........
Key: 56
2
5x  12y  17 
 x  1   y  3  
2 2
Sol: 
 13 
S = (1, 3) directrix is 5x – 12 + 17 = 0
10. The number of integral values of ‘k’ for which the line, 3x + 4y = k intersects the circle
x 2  y 2  2x  4y  4  0 at two distinct points is …..

Key: 9
38 k
Sol: c 1, 2   1  k   6, 16 
5

 k  7, 8, 9, 10, 11, 12, 13, 14, 15


 ans  9

1
11. Locus of a point P which divides all chords of slope of parabola x 2  4y in the ratio
2
8 
1:2 internally is another parabola with vertex  ,  and the length of latus rectum is
 9 
      
  , then the value of   is ………….
   3 
Key: 5

t1  t 2 1
Sol: Slope of AB    t1  t 2  1
2 2

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2 2
 3h  2   3h  2   8 4 2
 3k  3    2  1  h     k  
 2   2   9 9 9

  9,   2

    924
 5
3 3

12. Let the centre of a circle, passing through the point (0, 0), (1, 0) and touching the circle
x 2  y 2  9, be (h, k). Then for all possible values of the coordinates of the centre (h, k),
4  h 2  k 2  is equal to

Key: 9

Sol:

x  h   y  k   h2  k2
2 2

x 2  y 2  2hx  2ky  0

 passin g through 1, 0 

OP
 OC 
2
2
1 3
  k 
2

2 2

1  1 
 possible coordinate of c  h, k   , 2  ,  2 
2  2 

1  9
4 h2  k2   4  2   4   9
4  4
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13. If one of the diameter of the circle, given by the equation x 2  y 2  4x  6y  12  0 is a
chord of circle ‘S’, whose centre is at (-3, 2). Then radius of circle ‘S’ is ‘r’. Then r 2 =
Key: 75
Sol: Conceptual

14. Let A and B be two distinct points on the parabola y 2  4x . If the axis of the parabola
touches a circle of radius of one unit having AB as its diameter. Then the slope of the
joining A and B be can be ….
Key: 2
2 2
Sol: Slope =  2
r 1

If parabolas y 2   x and 25  x  3    y  2     3x  4y  2  are equal then   .......


2 2 2
15.
 
Key: 6
Sol: Two parabolas are equal then their length of latusrectum are equal to   6

16. A circle is drawn to pass through the extrimities of a latusrectum of parabola y 2  8x .


Then the minimum radius of the circle is ………
Key: 4
Sol: Minimum radius  LL' as diameter  r  2a  4
17. A circle touches y-axis at (0, 3) and makes an intercept of 2 units on the positive x-axis.
Intercept made by the circle on the line 10x  3y  1 in units is ‘k’. Then k 2 =

Key: 40
Sol: Chord passes through the centre of the circle, length of the chord = diameter

18. The length of double ordinate of parabola y 2  8x which subtends an angle 600 at vertex
is ‘l’. Then 3 l is ………
Key: 48

Sol: Length of the double ordinate = 16 3  l , 3l  48

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-11
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
2 2
01. Let A and B be the points (A has positive ordinate) common to the ellipse E: x + 4y =
20 , hyperbola H: 4y2 – x2 = 20. Four lines two from each focus of the hyperbola are
drawn that touch the ellipse at P, Q, R and S in quadrants I, IV, III and II respectively.
Then, the area of the hexagon APQBRS is
1) 4( 5  1) 2) 8( 5  1) 3) 8( 5  2) 4) 4( 5  2)
Key: 2
Sol:

A, B are points of contact of E  A(0, 5), B (0,  5)


Equation of tangents to the ellipse y  mx  20m2  5 ...(1)
Eq. (1) passing through (0, 5), 5  20m 2  5  m  1
Eq. of tangents: (use symbols) y = -x + 5 at P(4, 1)
y = x – 5 at Q(4, -1)
y = -x – 5 at R(-4, -1)
y = x + 5 at S(-4, 1)
(Find P, Q, R, S by solving any tangent equation with E)
1
Area of hexagon = 2 trapezium (APQB)  2  (2 5  2)(4)  8( 5  1)
2
x2 y2
02. P ( a sec  , b tan  ) and Q ( a sec  , b tan  ) are the ends of a focal chord of 2  2  1 , then
a b
   
tan   tan   equals to
2 2

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e 1 1 e 1  2e e 1
1) 2) 3) 4)
e 1 1 e 1  2e e 1
Key: 2
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

x2
03. Let the hyperbola H : 2  y 2  1 and the ellipse E: 3x2 + 4y2 = 12 be such that the length
a
of latus rectum of H is equal to the length of latus rectum of E. If eH and eE are the
eccentricities of H and E, respectively, then the value of 12(eH2  eE2 ) is equal to________
Key: 42
x2 y2 x2 y2
Sol:  1  1
a2 1 4 3

1 3 1
eH  1  2
eH  1  
a 4 2

2 23
.R.  R  3
a 2
2
3
a
2
a
3

9 13
eH  1  
4 2

2  13 1  12 14
12(eH  eE2 )  12      42
 4 4 4

x2 y 2
04. Let C be the largest circle centered at (2, 0) and inscribed in the ellipse   1. If
36 16
(1, ) lies on C, then 10 2 is equal to_______
Key: 118
x2 y2
Sol: Equation of normal of ellipse   1 at any point P (6 cos  , 4 sin  ) is
36 16
3sec  x  2cosec  y  10 this normal is also the normal of the circle passing through the

point (2,0) So, 6sec   10 or sin   0 (not possible )


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3 4  18 16 
cos   and sin   so point P   , 
5 5  5 5

320
So the largest radius of circle r 
5
64
So the equation of circle ( x  2) 2  y 2 
5

Passing it through (1,  )


59
then  2 
5

10 2  118

05. The locus of the point of intersection of the lines ( 3) kx  ky  4 3  0 and


3 x  y  4( 3)k  0 is a conic, whose eccentricity is______
Key: 2
Sol: 3kx  ky  4 3

3kx  ky  4 3k 2

Adding equation (1) & (2) 2 3kx  4 3(k 2  1)


 1
x  2 k  
 k

Subtracting equation (1) & (2) y  2 3   k 


1
k 

x2 y 2
  4
4 12

x2 y2
  1 Hyperbola
16 48
48
 e2  1 
16
e=2
06. Consider ellipses Ek: kx2 + k2y2 = 1, k = 1, 2, …, 20. Let Ck be the circle which touches
the four chords joining the end points (one on minor axis and another on major axis) of
20
1
the ellipse Ek. If rk is the radius of the circle Ck, then the value of  2 is_______.
k 1 rk

Key: 3080

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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
x y
Sol: Given, Ek : kx 2  k 2 y 2  1  Ek : 2
 1
 1  1
   
 k k
 1 
Now equation of the chord joining the points  , 0  &  0,  will be,
1
 k   k
x y
Lk :   1  k x  ky  1  0
 1  1
   
 k  k
Now rk = Perpendicular distance of Lk from (0, 0) we get,
1 1
rk   rk2 
k  k2 k  k2
1
Now putting the value of rk2 in  20
k 1 we get,
rk2
1 2 20  21 20  21 41
 20 20
k 1 2   k 1 k  k    210  2870  3080
rk 2 6
07. The area (in sq. units) of the quadrilateral formed by the tangents at the end points of the
x2 y2
latus rectum to the ellipse   1 , is________.
9 5
Key: 27
x2 y2
Sol: Equation of given ellipse is   1  a 2  9, b2  5
9 5
2 2 2 2
Now, b  a (1  e )  5  9(1  e )  e  2 / 3
One of the end points of the latus rectum is P(ae, b 2 / a)  (2,5 / 3)
2x 5 y x y
Equation of tangent to the ellipse at P is   1 or 2 x  3 y  9 or  1
9 15 9/2 3
Therefore, area of quadrilateral  4     (3)  27 sq.units
1 9
 2  2 
08. Let a and b, respectively, be the semi-transverse and semi-conjugate axes of a hyperbola
whose eccentricity satisfies the equation 9e2 – 18e + 5 = 0. If S(5, 0) is a focus and 5x = 9
is the corresponding directrix of this hyperbola, then a 2  b 2  ______.
Key: 7
Sol: We have 9e2 – 3e – 15e + 5 = 0
1 5
3e(3e – 1) – 5(3e – 1) = 0  e  ,
3 3
5
For hyperbola, e > 1, that is, e 
3

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PS = ePM (see Fig. 15.9)


5 (5 x  9) 1
( x  5) 2  y 2   (5 x  9)
3 5 3
1
( x  5) 2  y 2  (25 x 2  81  90 x )
9
9 x 2  225  90 x  ( y 2  9)  25 x 2  90 x  81
16 x 2  ( y 2  9)  225  81  144
x2 y2
Now,  1
9 16
Therefore, a2 = 9 and b2 = 16. Hence,
Hence, a 2  b 2  7 .
09. The locus of the foot of perpendicular drawn from the centre of the ellipse x2 + 3y2 = 6 on
any tangent to it is (x2 + y2)2 = ax2 + by2 where a, b  N then a2 + b2 = ______.
Key: 40
x2 y2
Sol: Ellipse is  1
( 6) 2
 2
2

x cos  y sin 
Equation of tangent at P is  1
6 2


Equation of tangent at ( ,  ) is y    ( x   ) or  y   2   x   2

or  x   y   2   2
Comparing Eq. (1) and Eq. (2), we get
cos  sin  1 cos 2   sin 2  1 1
  2 or  
6 2    2 2
6  2  2
6 2  2  2  2
2

 6 2  2 2  ( 2   2 ) 2 ,Therefore, locus is (x2 + y2)2 = 6x2 + 2y2.


Hence, a = 6, b = 2, so a2 + b2 = 40.
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SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
RPTM-12
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

01. Let  ,  be the roots of the equation x 2  x  2  0 with Im    Im    then

 6   4   4  5 2  5 is equal to
1) 13 2) 18 3) 23 4) 28
Key: 2
Sol:  2    2,  2    2
 6   4   4  5 2  5
  4  2  1  5 2   4  5

   2    2  1  5   2      2   5
2 2

  2  4  4    1  5  10   2  4  4  5
  3  2   1  5    2  4   19
 3 2  5  2  5  3  17
 3   2   3  15  3      21  3 1  21  18

1
02. For all z  C on the curve c1 : z  4 , let the locus of the point z  be the curve c2 then
z
1) The curves c1 and c2 intersects at 4 points 2) The curves c1 lies inside c2
3) The curves c1 and c2 intersect at 2 points 4) The curves c2 lies inside c1
Key: 1
1 1
Sol: w z  4 Cis  Cis   
z 4
17 15
w  x  iy  Cos  i Sin
4 4
2
x y2
Locus of w is 2
 2
1
 17   15 
   
 4 4
Locus of z is x 2  y 2  16
So intersect at 4 points.

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2 2
03. For  ,  , z  C and   1 , if   1 is the radius of the circle z    z    2 then
  
1) 2 2) 3 3) 4 4) 5
Key: 1
2 2 2
Sol: z  z1  z  z2  z1  z2
2
z1   , z2        2
     2
 2   1  2  4  4  2  2  4
    2

  z  z  z z  
04. If the set Re   : z  C ,Re  z   3  is equal to the interval  ,   then
  2  3 z  5 z  
8     
1) 12 2) 9 3) 10 4) 8
Key: 4
zzzz
Sol: z1  , z  3 i y
2  3z  5 z
z  3  iy
2iy  9  y 2
z1   Re  z1   3
8  8 iy
9  y2  2 y2 1  10 
  Re  z1   Re  z1     1
8 1  y  8 1  y
2 2

10  1 9
1  y 2  1,      0,10  Re  z1     , 
1 y 2
 8 8
1 9
   , 
8 8
9 1
8     8    8
8 8

05. If  ,  ,  ,  are the roots of the equation x 4  x 3  x 2  x  1  0 then

1   2026   2026   2026   2026 

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1) 0 2) -1 3) 1 4) 4
Key: 1
Sol: x5  1  x5  1  0

  x  1  x 4  x 3  x 2  x  1  0
x 5  1 roots 1, ,  ,  , 
1        0
 1   2026   2026   2026   2026  0
18
 2π 2π 
 1+sin +icos
06. The value of  9 9  is
2π 2π 
 1+sin -icos 
 9 9 
1) -1 2) 0 3) 1 4) 2
Key: 1
18 18
 5 5   5 5 
 1  Cos  i Sin   Cos  i Sin 
18 18 36 36
Sol:  5 5   5 5   Cos5  i Sin5  1
 1  Cos  iSin   Cos  iSin 
 18 18   36 36 
07. Let z and w be complex numbers such that z  w and arg z denotes the principal
argument of z.
Statement 1: If arg z  arg w   then z  w
Statement 2: z  w , implies arg z  arg w  
1) Statement 1 is true, statement 2 is false
2) Statement 1 is true, statement 2 is true,Statement 2 is a correct explanation for
statement 1
3) Statement 1 is true, statement 2 is true, Statement 2 is not a correct explanation for
statement 1
4) Statement 1 is false, statement 2 is true.
Key: 1
Sol: z  w r

z  r Cis1, w  rCis  2 

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1   2    w  r Cis   2 
z  r Cis    2   r Cis   2    w
Statement 1 is true but statement 2 is false.

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
1
08. If  is a non real fifth root of 1, then log 2 1     2   3   ______.

Key: 1
Sol: x5  1   5  1   1

1  2  3  4  0
1
log12 1     2   3 

4
 log 2  4   4  log 22   log 22  1

x3 x 6 x9 x 4 x7 x 2 x 5 x8
09. If a  1     ...., b  x    ... and c     .... then
3 6 9 4 7 2 5 8

a 3  b 3  c 3  3abc  ____ .
Key: 1
Sol: a  b  c  ex
a  bw  cw2  e wx
2
a  bw2  cw  e w x
2
a 3  b3  c 3  3abc  e x wx  w x  eo  1
10. If cosα+cosβ+cosγ = 0=sinα+sinβ+sinγ then

cos  2       cos  2        cos  2       _____ .


Key: 3
Sol: x  Cis , y  Cis  , z  Cis

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x  y  z  0  x  y  z  3xyz
3 3 3

x2 y2 z2
   3
yz zx xy

 1  x2 
The least value of n  N such that 1  i    1  i  2Sin 
n n 1
11.  is =------
 2x 
Key: 4
1  x2 1  1 
Sol:    x 1
2x 2 x 

1  i  .  1  i  2.Sin1 1
n n

n n
1 i  2  1 i 
   .   1
1 i   2 1 i 
Least value of n is 4
1 1 1
12. If w  1 is a cube root of unity satisfying    2w2 and
aw bw cw
1 1 1 1 1 1
   2w then    ____.
aw bw cw
2 2 2
a 1 b 1 c 1
Key: 2
1 1 1 2
Sol:   
a x b x c x x
x  1, w, w2
1 1 1
  2
a 1 b 1 c 1
13. If z1 and z2 are two non-zero complex numbers such that z1  z2  z1  z2 then

arg z1  arg z2  ___ .


Key: 0
Sol:
z1  z2  z1  z2
 z1 , z2 , o
are collinear and z1, z2 are same side of origin (o)

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 arg z1  arg z2  0
14. If z  4  3 then maximum value of z  1 is _______.
Key: 6

Sol: z  1  z  4  3   z  4   3
 33
6
15. If z1 , z2 and z3 , z4 are two pairs of conjugate complex numbers then

z  z 
arg  1   arg  2   _ .
 z4   z3 
Key: 0

z  z  z   z1 
Sol: z1  z2 , z 3  z4  arg  1   arg  2   arg  1   arg    0
 z4   z3   z4   z4 
1  i 3
If a and b are real numbers such that  2     a  b where  
4
16. then a  b 
2
Key: 9

     2      2      4   2  4 
4 4 2
Sol:

  2  4 2   9  a  b
2

ab 099

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RPTM-13
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. The parabolas; ax 2  2bx  cy  0 and dx 2  2ex  fy  0 intersect on the line y=1. If a ,b,
c, d, e, f are positive real numbers and a, b, c are in G.P., then

d e f
1) d, e, f are in A.P. 2) , , are in G.P.
a b c

d e f
3) , , are in A.P 4) d, e, f are in G.P.
a b c
Key: 3
Sol: Given ax 2  2bx  c  0
Since a,b,c in GP

 
2
So, b2  ac  ax 2  2 acx  c  0  x a  c 0

c
x -------------- (1)
a

c  c
Now, dx 2  2ex  f  0  d    2e    f 0
a  a 
dc c d f 1
  f  2e    2e
a a a c ac

d f 2e  d e f
    as b  ae   , , are in A.P.
a c b a b c

2. Let  and  be the roots of the quadratic equation


 n  1n  
x sin   x  sin  cos  1  cos  0  0    45  , and    . Then    
2 0
 is
  n 
n 0
 
equal to:

1 1 1 1
1)  2) 
1  cos 1  sin  1  cos 1  sin 
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1 1 1 1
3)  4) 
1  cos 1  sin  1  cos 1  sin 
Key: 3
Sol: x 2 sin   x  sin  .cos   1  cos  0

 x2 sin   x sin  .cos  x  cos  0


 x sin  x  cos   1 x  cos   0

  x  cos  x sin  1  0

 x  cos  ,cos ec ,   0, 450 

  cos ,   cosec

1

n 0
n
 1  cos  cos 2   .... 
1  cos
1
 1  sin   sin 2   sin 3   .... 
1  sin 
  n  1 n   n   1n 1 1
  

     n 
  n0
n
n 0 

1  cos 1  sin 
n 0

3. If  x 2  px  1 is a factor of  ax 3  bx  c  , then

1) a2  c 2  ab 2) a2  c 2  ab 3) a2  c2  ab 4) None of these

Key: 3
Sol: Since,  x 2  px  1 is a factor ax3  bx  c , hence we can assume that zeros of

x 2  px  1 are  ,  and that of ax3  bx  c be  ,  , 


     p --------- (i)
  1 --------------- (ii)
And       0 -------- (iii)
b
      ---------- (iv)
a

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c
  -------------- (v)
a
On solving (ii) and (v), we get   c / a
On solving (i) and (iii), we get   p
p    c / a
Using equations (i), (ii) and (iv), we get
b
1   p 
a
 c  c  b
 1         p  c / a 
 a  a  a
c2 b
 1  2   a 2  c 2  ab
a a

1 1
4. Let  ,  are roots of the equation x 2   20  4 x  5 2  0 and  8   8  k then 2K=

1) 10 2) 50 3) 100 4) 160

Key: 3
Sol: x 2  51/2    20  x
1/4

x  51/2   20.x 2
2 2

x4  5  2 5x2  2 5x2
x 4  5  x8  25

5. Let a, b, c, p, q be real numbers. Suppose  ,  are the roots of the equation


1
x 2  2 px  q  0 and  , are the roots of the equation ax 2  2bx  c  0 , where

  1,0,1
2

Statement-1: p 2
 q  b 2  ac   0 and

Statement-2: b  pa or c  qa

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1) Statement -1 is True, Statement -2 is True; STATEMENT-2 is a correct explanation
for Statement -1

2) Statement -1 is True, Statement -2 is True; Statement -2 is NOT a correct explanation


for Statement -1

3) Statement -1 is True, Statement -2 is False

4) Statement -1 is False, Statement -2 is True

Key: 2
Sol: As a, b, c, p, q  R and the two given equations have exactly one common root
 Either both equations have real roots
Or both equations have imaginary roots
 Either D1  0 and D2  0 or D1  0 and D2  0

 p 2  q  0 and b2  ac  0

Or p 2  q  0 and b2  ac  0   p 2  q  b 2  ac   0

Statement 1 is true.
 c
Also we have   q and 
 a
 q qa
 a  2 
/ c c
qa
As   1 or -1   2  1   1 or c  qa
c
Again as exactly one root  is common, and   1
1 2b
       2 p  b  ap
 a
Statement 2 is correct.
6. If a  b  c  d then the roots of  x  a  x  c   2  x  b  x  d   0 are

1) real and equal 2) real and distinct 3) imaginary 4) real

Key: 2
Sol: f  a   2  a  b  a  d  is + ve; f  b    b  a  b  c 

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Is ve f  c   2  c  d  c  d  is –ve,

f  d    d  a  d  c  is +ve

7. If the equation x 2  5 x  6   x  7  0 has exactly three solutions then  is equal to

1) 7  23 2) 9  4 5 3) 7  23 4) 9  4 5

Key: 2
Sol: x 2  5 x  6   x  7  0 has three solutions

x 2  5 x  6   x  7

f  x   x2  5x  6

  x 2  5 x  6    x  7  0

b2  4ac  0

   5  4  6  7   0
2

  2  10  25  24  28  0   2  18  1  0

18
2
15  4
  9  80  9  4 5
2

H1  2 H 20  3
8. If H1 , H 2 ,....H 20 harmonic means between 2 and 3, then  
H1  2 H 20  3

1) 20 2) 21 3) 40 4) 38

Key: 3
Sol: 2, H1 , H 2 ......H 20 ,3 are in H.P
1 1 1 1
 
H1  2 H 20  3 2 H1 3 H 20
  
H1  2 H 20  3 1  1 1

1
2 H1 3 H 20

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1 1 1 1 2 2
 d  d d 1
2 2 3 3 1 d 3 3
  =    2,  2  21  2  40
1 1 1 1  d d d
d  d 
2 2 3 3

xy log  xy  yz log  yz  zx log  zx 


9. If   then
x y yz zx

y
1) x x  y  z z 2) x  y  2 z 3) x  y  z  0 4) x  y  z  1

Key: 1
log xy log yz log zx log x  log y  log z log x log y log z
Sol:        xx  y y  zz
1 1 1 1 1 1 1 1 1 1 1 1
    
x y y z z x x y z x y z

SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

10. Consider the equation x2  2 x  n  0 , n  N and n  5,100 , the number of different


values of ‘n’ so that the given equation has integral roots, is K. Then 5K =______

Key: 40
2  4  4
Sol: x  1  1  
2
n  1 is a prefect square
  8,15,24,35, 48,63,80,99...... -------------(8)

11. The minimum value of the quantity


a 2
 3a  1 b 2  3b  1 c 2  3c  1
where
abc
A
a, b, c  R  is A. Then =________
25
Key: 5

Sol: Let A 
a 2
 3a  1 b 2  3b  1 c 2  3c  1
abc
 a  3a  1  b  3b  1  c 2  3c  1  
2 2
1  1  1
   
  a  3   b  3   c  3  
 a  b  c   a  b  c

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1 1
And a   2 a  35
a a
1 1
b  2b 35
b b
1 1
c  2c 35
c c
 1  1  1 
 a   3  b   3  c   3   125
 a  b  c 
A   5 5 5  A  125

12. Given a, b, c are positive integers forming an increasing G.P, b-a is a prefect square of a
natural number, and log 6 a  log 6 b  log 6 c  6 . Then the value of
a  b  c  105  _____ .

Key: 216
Sol: a,b,c are in G.P. b2  ac
log 6 a  log 6 b  log 6 c  6
abc  66 , b3  66 , b  62  36
ac  36  36  24  34 ; b  a  N 2 ;36  a  N 2
A is factor of 2434 a  27 is possible value
36  27  9   3  a  27
2

b  36, c  48 a  b  c  111

7 9 13 19
13. S     ......... Then 32S=_______
5 52 53 54
Key: 61
7 9 13 19
Sol: S     ....... (1)
5 52 53 54
1 7 9 13 19
s  2  3  4  5  ..... (2)
5 5 5 5 5
Eq (1) and ( 2)
4 7 2 4 6
.s   2  3  4  ....
5 5 5 5 5
7 1 2 3 
s   1   2  .... 
4 10  5 5 
2
7 1  1 7 1 25 61
s   1   , s    s  32s  61
4 10  5  4 10 16 32

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RPTM-14
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. If (2 x 2  x  1)5  a0  a1x  a2 x 2 ........  a10 x10 , then a2  a4  a6  a8  a10  ____


1) 15 2) 30 3) 16 4) 17
Key: 4
Sol: Put x = 1 : x = -1
Adding i and ii
7
2. If the coefficient of x in the expansion of (1  3 x  2 x3 )10 . is k then k
1) 26,244 2) 2, 04,120 3) 1,73,556 4) 62,640
Key: 4
Sol: n1  n2  n3  10 and n2  3n3  7
The possible values of (n1 n2 n3 ) are (3,7, 0) (5, 4,1) (7,1, 2)
3. Let n  1!  4!  7!  .........  (199)! . If  is the digit in the hundredth place of n then
2025  _____
1) 0 2) 2025 3) 12150 4) 8100
Key: 3
Sol: n  1!  4!  7!  10!  13!  16!  .......
We have 5!  120 , 10!  3628800 , 15!  1307674368000
From (15)! onwards hundredth place is 0
So n = 1 + 24 + 5040 + 3628800 + 6227020800 +……
 hundredth place digit is   6
 2025   (2025)6  12150
4. There is a regular decagon. By joining 4 vertices of it, a quadrilateral is formed. Then, the
number of such quadrilaterals that can be formed, none of the sides of which coincide
with a side of the decagon, is
1) 25 2) 35 3) 44 4) 65
Key: 1
Sol: Number of quadrilaterals having no side is common with the sides of the polygon.

 3

= nC4  n n 5C2  n  n  5   n . Substitute n=10.
2
5. In the coming IPL – 2025 cricket tournament, there will be 10 teams, which are divided
equally in to two groups. Teams of each group will play a match against each other.
From each group 3 top teams will qualify for quarter finals. In this round each team will
play against others once. Four top teams of this round will quality for semi - finals where
each team will play against the others once. Two top teams of this round will go to the
finals. Where they will play the best of three matches, then the minimum number of
matches in the IPL 2025 is ____

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1) 44 2) 43 3) 41 4) 50
Key: 3
Sol: Each group contains 5 teams
In the first round the number of matches  5C  5C  10  10  20
2 2
65
The number of matches in quarterfinals  6C2   15
2
43
The number of matches in semifinals  4C2  6
2
In finals, the minimum number of matches = 2
So, Required ways  20  15  6  2  43
6. The maximum number of points of intersection of 6 straight lines and 6 circles is
________ 1) 117 2) 110 3) 72 4) 82
Key: 1
Sol: Given circles = 6, straight lines = 6
Case (i )
 for circles
Two circle intersect at two different points

65
For 6 circle we have 6C2  2   2  30
2 1
Case (ii )

 For straight lines
Two straight lines intersect at one point

For 6 straight lines 6C2  1  15


Case (iii )

 One circle & one straight line
One circle & one line intersect at two different points

So we have 6C1  6C1  2  6  6  2  72

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7. If 2n  1 p : 2n  1 p  11: 21, then the number of proper positive divisors of 2024n
n 1 n
are 1) 32 2) 31 3) 30 4) 5
Key: 3
2 n 1 4
Sol: p n 1 : 2 n 1 p n  11 : 21  n  5,  2024 n  (2024) 5  10120 , So
11
10120  23.51.111.231Number of proper divisions  (3  1).(1  1)(1  1)(1  1)  2
 4.2.2.2  2  30
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
14C , 14C , 14C
8. r 1 r r 1 are in AP. then minimum value of r = ________
Key: 5
Sol: n 2  (4r  1)n  4r 2  2  0 , n  14  r 2  14r  45  0  r  9,5
9. The number of 4 letter words with or without meaning that can be formed from all the
letters of word IITJEE is ______
Key: 102
Sol: Given word I I T J E E contains I  2, E  2, J  1, T  1 , Total 6 letters
Case (i )
 all different
If all the letters are different, then number of words
4
 p  4.3.2.1  24
4
Case (ii )

 If 2 letters are same and 2 are different
Then number of words  2C  3C  4!  2  3  4  3  72
1 2 2!
Case (iii )

 If 2 letters are same of one kind and 2 letters are same of other kind,
4! 4  3  2 1
then number of words.  2C   1  6 Total number of words
2 2!.2! 2 1 2 1
 24  72  6  102
10. The number of onto functions that can be defined from a set A  a, e, i, o, u to the
set B  1, 2,3 is ________
Key: 150
Sol: n( A)  5  a, n( B )  3  b Number of on to functions
 bC 0 . b a  bC1 .(b  1) a  bC 2 .(b  2) a ...........  3C . 35  3C1 . 25  3C 2 . 15
0
 35  3.25  3.1  243  96  3  150
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RPTM-15
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Let  be a complex cube root of unity with   1 . A fair die is thrown three times. If
r1 , r2 and r3 are the numbers obtained on the die, then the probability that

 r1   r2   r3  0 is
1 1 2 1
1) 2) 3) 4)
18 9 9 36
Key: 3
Sol: Given  r1   r2   r3  0 .
Possibilities for r1 , r2 , r3  are
1, 2,6,1,2,3,4,5,6,4,5,3,2, 4,3,2, 4,6,5,1,3,5,1,6
8 cases
 Number of ways of selecting r1 , r2 , r3  8  3!

n s   6 6  6

8  3! 2
 Required Probability  
666 9
2. If X is a random variable with the following distribution
X  xi a b
P  X  xi  p q

Where p  q  1 then the variance of X is

3) pq  a  b 4) pq  a  b
2 2
1) ap  bq 2) ap  bq
Key: 3
Sol: Mean of X   xi p  X  xi   ap  bq

Variance of X   2   xi2 p  X  xi    2  a 2 p  b 2 q   ap  bq 
2


 a 2 p 1  p   b 2 q 1  q   2abpq  pq a 2  b 2  2ab 
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3. A tosses an unbiased coin 3 times. If he gets a head all the 3 times he is to get a prize of
Rs. 160/- along with his entry fee of Rs.16/- otherwise he loses his entry fee. The
mathematical expectation of his profit is
1) 20 2) 14 3) 6 4) 12
Key: 3
Sol: E  X    xi p  X  xi 

4. Consider the system of equations ax  by  0, cx  dy  0 where a, b, c, d  0,1

3
Statement – I: The probability that the system of equations has unique solution is
8
Statement – II: The probability that the system of equations has a solution is 1
1) Both the statements are true and the statement -2 is the correct explanation of
statement-1
2) Both the statements are true and the statement -2 is not the correct explanation of
statement-1
3) The statement-1 true but statement -2 is false
4) The statement-1 false but statement -2 is true
Key: 2
Sol: I :   0  ad  bc  0  ad  1and bc  0

 OR ad  0 and bc  1
6 3
Probability is 
24 8
II : Either   0 or   0, system always has a solution

24
 Probability= 4  1
2
5. A and B stand in a ring with 10 other persons. If the arrangement of the 12 persons is at
random. What is the probability that there are exactly 3 persons between A and B.
7 5 2 1
1) 2) 3) 4)
12 12 11 11

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Key: 3
Sol: ‘n’ men among whom A and B sit along a circle then the probability that there will be
2
exactly ‘r’ persons between A and B= (in both directions)
n 1
6. A person flips 4 fair coins and discards those which turn up tails. He again flips the
remaining coins and then discards those which turn up tails. The probability that he
discards at least 3 coins is
135 189 27 198
1) 2) 3) 4)
256 256 64 256
Key: 2
Sol: 4 coins tossed twice
X= no. of coins discarded
Probability : 1  P  X  0  P  X  2

1-P(HHHH, HHHH)-[P(HHHT, HHH)/( HHHH, HHHT)]-[P(HHHH, HHTT)/( HHHT,


HHTT)/( HHTT, HH)]
1 1 1 1 1 1  1 6 4 3 6 1 67 189
1  4   4 4 3  4 4  4   4  4  4  3  4  2   1  
4
2 2  2 2 2 2   2 2 2 2 2 2  256 256
7. If the letters of the word MATHEMATICS are arranged at random. The probability that
C comes before E, E come before H, H before I and I before S is
1 1 1 1
1) 2) 3) 4)
75 24 120 720
Key: 3
Sol: If n things are arranged in a row at random, then the probability that K different things
1
occur in a specified order=
K!
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
8. Let the mean of the data
x 1 3 5 7 9

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Frequency(f) 4 24 28  8

be 5. If m and  2 are respectively the mean deviation about the mean and the variance of
3
the data, then is equal to ________
m  2
Key: 8
4  72  140  7  72
Sol: Given, mean=5= x   320  5  288  7  2  32    16
64  
4  4  24  2  28  0  16  2  8  4 8

M .D. x 
80

5
4  16  24  4  0  16  4  8  16 352
 
80 80
3 3  16
  8
m 2
128 352

80 80
9. A fair die is tossed repeatedly until a six is obtained. Let X denote the number of tosses
bc
required and let a  P  X  3 , b  P  X  3 and c  P  X  6 / X  3 . Then is
a
equal to______
Key: 12
5 5 1 25
Sol: 12 a  P  X  3    
6 6 6 216
b  P  X  3
3 4
5 5 1 5 1 5 1 25
=          ...... 
6 6 6 6 6 6 6 36
5 6 5
 5 1  5 1  5
P  X  6    .    .  ......   
 6 6  6 6  6
3 4 3
5 1 5 1 5
P  X  3    .    . ........   
6 6 6 6 6

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5
5
P  X  6   6  25
P  X  6 / X  3   
P  X  3  5  3
36
 
6
2 2
 5  5

b  c  6   6 
 2  12
a  5 1
 
6 6

10. If the variance of 10 natural numbers 1,1,1,…..,1, k is less than 10, then the maximum
possible value of k is ______
Key: 11
x   x
2 2
2
9  k2  9  k
Sol: We have,  2
    10   10   10
n  n 

 90  10k 2  81  k 2  18k  1000  9k 2  18k  991  0

1000 10 10
  k  1 
2
k  1  k  11
9 3
Maximum value of k is 11
11. An electric instrument consists of two units. Each unit must function independently for
the instrument to operate. The probability that the first unit functions is 0.9 and that of the
second unit is 0.8. The instrument is switched on and it fails to operate. If the probability
that only the first unit failed and second unit it functioning is p, then 98 p is equal to
______
Key: 28
Sol: E1  first unit is functioning , E2  sec ond unit is functioning

   
P  E1   0.9, P  E2   0.8; P E1  0.1, P E2  0.2

P  Instrument not functioning 

       
P E1 .P E2  P  E1  .P E2  P E1 .P  E2   0.1  0.2  0.9  0.2  0.1  0.8

P  First unit failed and sec ond unit functioning   P

0.8  0.1 8 8
P   , 98 P   98  28
0.1  0.2  0.9  0.2  0.1  0.8 28 28

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RPTM-16
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Statement-I: In a  ABC , if a<b<c and r is in radius and r1 , r2 , r3 are the ex-radii opposite
to angle A, B, C respectively then r  r1  r2  r3
r1r2r3
Statement-II: For  ABC , r1r2  r2 r3  r3r1 
r
1) Statement-I is true, statement-II is correct explanation for statement-I
2) Statement-I is true, statement-II is true, statement-II is not the correct explanation for
statement-I
3) Statement-I is true, statement-II is false
4) Statement-I is false statement-2 is true
Key: 2
   
Sol: a  b  c  r  r1  r2  r3  r  , r1  , r2  , r3 
S S a S b S c
2. 4sin 27 0  ____
1) 5 5  3 5 2) 5 5  3 5
3) 5 5  3 5 4) 5 5  3 5
Key: 3
     
Sol: 0    1  cos  cos  sin , 1  cos  cos  sin
4 2 2 2 2 2
   2 
3. If tan   tan      tan      3 then
 3  3 
 
1)    4n  1 , n  z 2)    4n  1 , n  z
4 2
 
3)    3n  1 , n  z 4)    4n  1 ,n z
4 12
Key: 4
   
Sol: tan   tan      tan      3tan 3
 3  3

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4. Let A0 , A1 , A2 , A3 , A4 A5 , A6 be the consecutive vertices of a regular hexagon inscribed in a

unit circle then  A0 A1  A0 A2  A0 A4   _____

3 3 3
1) 2) 3 3) 4) 3 3
4 2
Key: 2

Sol: a 2  b 2  2ab cos  1  1  1  3   A0 . A1  A0 . A2  A0 . A4   1. 3 3  3

SinA Sin  A  C 
5. Let  , where A, B, C are angles of a triangle ABC. If the lengths of the
SinB Sin  C  B 

sides opposite to these angles are a, b, c respectively, then _____


1) b 2 , c 2 , a 2 are in AP 2) c 2 , a 2 , b 2 are in AP

3) b 2  a 2  a 2  c 2 4) a 2 , b 2 , c 2 are in AP
Key: 1
sin  B  C  sin  A  C 
Sol:   sin 2 C  sin 2 B  Sin 2 A  sin 2 C
sin  A  C  sin  C  B 

 sin 2 C  sin 2 A  sin 2 B  2C 2  a 2  b 2


6. ABCD is a trapezium such that AB and CD are parallel and BC  CD. If ADB   ,
BC=p and CD=q then AB=______

1)
p 2  q 2 cos
2) 2
p2  q2
3)
p 2
 q 2  sin 
4)
p 2
 q 2  sin 
p cos  q sin  p cos  q 2 sin   p cos  q sin   p cos  q sin 
2

Key: 4
Sol: Applying sin rule

AB

BD

p2  q2
 AB 
 p 2  q 2  sin 
sin sin     sin  cos   cos sin  p cos   q sin 

7. If sin 4   4cos4   2  4 2 sin  cos  , ,    0,   then 2 cos      cos       ___

1) 2 2)  2 3) -1 4) -2
Key: 4

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 243


SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
Sol:   90,   45
8. In a triangle ABC, a is greater than angle B. If the measure of angles A and B satisfy the
equation 3sin x  4sin 3 x  k  0, O  k  1, then 2 C  ___
  2 4
1) 2) 3) 4)
2 3 3 3
Key: 4

Sol: sin3A=K  sin3A=sin3B 3A=180-3B  C=180-(A+B) =120  2C=240= 4
3

SECTION-II (NUMERICAL VALUE TYPE)


This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
1
9. The number of solutions of the equation |cotx|=cotx+ in the interval [0, 4] is ____
sin x
Key: 2
1 1
Sol: let cot x  0  2cot x   cos x  
sin x 2
cot x  0,cos x  0  x  2  noof solution  2
10.  
Let S  sin 2 2 : sin 4   cos 4   x 2  sin 2  x   sin 6   cos 6   0,has real roots . If α
and  be the smallest and largest elements of the set S, respectively then

6   2      1  ____
2 2

Key: 8
8 2 3
Sol: b 2  4ac  0sin 2 2  t  t 2  4t   0 2   t  1   2  , 1
3 3 3
11. In a  ABC , let AB  23, BC  3 and CA  4 then the value of
 cot A  cot C 
5   _____
 cot B 
Key: 10
cot A  cot C b 2  c 2  a 2  a 2  b 2  c 2 2b 2 2  16 32
Sol:   2   2
cot B a c b
2 2 2
a c b 2 2
3  23  16 16
abc
12. In a  ABC , AD is an altitude from A. given b>c, c  250 and AD  2 2 then B in
b c
degrees_
Key: 115
1 abc a abc
Sol:   BC . AD   . 2 2  b 2  c 2  2 Ra  sin 2   sin 2 C  sin A
2 4R 2 b  c
sin  B  C  .sin  B  C   sin A  sin  B  C   1  B  C  90  B  90  C

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 244

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