Jee Main 2025 Brahmanda Practice Material-2
Jee Main 2025 Brahmanda Practice Material-2
Jee Main 2025 Brahmanda Practice Material-2
10 KJ
L 5 KJ / Kg
2 Kg
5. Assertion(A) : The total translational KE of all the molecules of a given mass of ideal gas
is 1.5 times the product of its pressure and volume
Reason(R) : Molecules of gas collide with each other and the velocities of molecules
change due to the collision
1) Both A & R are correct and R is the correct explanation of A
2) Both A & R are correct but R is not the correct explanation of A
3) A is correct but R is not correct 4) A is not correct but R is correct
Key: 2
3 3
Sol: Total translational KE = nRT PV 1.5 PV
2 2
(NUMERICAL VALUE TYPE)
Therefore, t
2 4200 600 100 s 300 s
0.7 2000
7. Two identical calorimeter A and B contain equal quantity of water at 200 C . A 5 gm piece
of metal X of specific heat 0.2 cal g 1 0 C is dropped into A and a 5 gm piece of metal Y
1
into B. The equilibrium temperature in A is 220 C and in B 230 C . The initial temperature
of both the metals is 400 C . If specific heat of metal Y in cal / gm / 0 C is X . Find X+Y.
Y
[Here, X and Y have no common factor]
Key: 112
Sol: Quantity of water : (m=mass of water)
In calorimeter A,
Heat lost by metal X = Heat gained by water
5 0.2 40 22 m 1 22 20 m 9 gms
In calorimeter B, Heat lost by metal Y = Heat gained by water
5 S y 40 23 9 1 23 20 S y 9 3 27 x y 27 85 112
5 17 85
8. A steam engine intakes 50 g of steam at 1000 C per minute and cools it down to 200 C . If
latest heat of vaporization of steam is 540 cal g 1 , then the heat rejected by the steam
engine per minute is ____ 103 cal.
Key: 31
9. A non-isotropic solid metal cube has coefficients of linear expansion as : 5 105 / 0 C along
the x-axis and 5 106 / 0 C along the y and the z-axis. If the coefficient of volume
expansion of the solid is C 106 / 0 C then the value of C is __________
Key: 60
Sol: The coefficient of volume expansion
60 106 ; C 60 ;
10. The total internal energy of two mole monoatomic ideal gas at temperature T 300 K will
be ______ J. (Given R 8.31 J / mol.K )
Key: 7479
3
Sol: U nCV T 2 R 300 900 R 900 831 7479 J
2
11. The water equivalent of a calorimeter is 10 g and it contains 50 g of water at 150 C . Some
amount of ice initially at 100 C is dropped in it and half of ice melts till equilibrium is
reached; The initial amount of ice that was dropped is ________ (gms)
( sice 0.5 cal gm 1 0C 1; swater 1 cal gm 1 0C 1 ; Lice 80 cal gm 1 )
Key: 20
Sol: Heat lost = Heat gained by caloriemeter system by ice
m
m 0.5 10 80 50 10 1 15 m 20 gms
2
12. If the coefficient of real expansion r is 1% more than coefficient of apparent expansion,
r
then the linear expansion of the material is . The value of N is _________
N
Key: 303
Sol: R A 3 R 1.01 A
R 100 R A 1 R R
A R
1.01 101 3 3 101 303
1) 20 cm 2) 30 cm 3) 40 cm 4) 50 cm
Key: 2
R1
Sol: For the lens in air, f 0
2 2 1
R1
20 R1 20cm
2 1.5 1
R1 R2 R1
3 1 2 1 2 3
v u R1 R2
here 3 2, 1 1.2, 2 1.5
Lens forms a virtual image I1 at a distance of 50cm from it. This act as real object to the
concave mirror.
If PL1 R 80cm, the rays after reflection from mirror retrace, their path and the final
image is formed at ‘O’ itself. Hence d Pl1 50 80 50 30cm
2. A converging lens of refractive index 1.5 has a power of 25D. When it is completely
immersed in a liquid, it behaves as diverging lens of focal length 40 cm. Find the
refractive index of the liquid.
1) 1.58 2) 1.34 3) 1.43 4) 1.88
Key: 1
1 1
Sol: fa m 4cm
p 25
1 1 1
a g 1
fa R1 R2
1 1 1
1.5 1
4 R1 R2
1 1 1
R1 R2 2
1) A S , B R, C Q, D P 2) A S , B R, C Q, D Q
3) A S , B R, C P, D P 4) A P, B R, C Q, D S
Key: 1
Sol: Conceptual
4
4. A container is filled with water n up to height of 40cm. A concave mirror is placed
3
20cm above water level and the image of an object placed at the bottom is formed 25 cm
below the water. The focal length of mirror (in cm) approximately equal to
1) 29 2) 22 3) 30 4) 35
Key: 2
40 3
Realdepth
Sol: Apparent depth 30cm
4
25
Distance of image from mirror 20 38.79cm
4
3
40 3
Distance of object from mirror 20 50cm
4
Key: 2
1
Sol: For total internal reflection
sin
1.41
7. A compound microscope consists of an objects lens of focal length 1 cm and an eye piece
of focal length 5cm with a separation of 10 cm. The distance between an object and the
n
objective lens, at which the strain on the eye is minimum is cm . Then value of n is ?
40
Key: 50
Sol: Length of compound microscope, L 10cm
f 0 1cm; f e 5cm
0 f c 5cm
Final image formed at
ve
V0 10 5 5
Using lens formula
1 1 1 1 1 1
V u f V0 u0 f 0
1 1 1 5
u0
5 u0 1 4
n 1.5 n 1.2
R 14cm
Key: 40
1 1 1 0.5
Sol: or the first lens 1.5 1
f1 14 14
1 1 1 0.2
For the second lens 1.2 1
f2 14 14
0.5 0.2 1
Focal lens of biconvex lens
14 14 20
1 1 1
Acc to thin lens formula
40 20
v 40cm
9. A lens is placed between a candle and on fixed screen forms a real triply magnified image
of the candle on the screen. When lens is moved away from the candle by 0.8m without
changing the position of the candle, a real image one third the size of the candle is formed
x
on the screen. The focal length of the lens (in m ) is . The value of x is
10
Key: 3
Sol: As the object and image position are interchangeable when the lens is moved by 0.8 the
image distance becomes x
I
O
x 0.8m x
50cm
8cm
Key: 98
1
Sol: x 1 d
1
Image distance formed in plane mirror h x n 1 d 48
From the bottom the distance is = 48+50= 98cm
12. A plano convex lens of refractive index 1.5 and radius of curvature 30 cm is silvered at the
curved surface. Now this lens has been used to form the image of an object. At what
distance from this lens an object needs to be placed in order to have a real image of the
same size as that of the object.
Key: 20
Sol: As the curved surface of a plano convex lens is silvered, the focal length of the lens is given
1 2
by
F R
1 2 1 2
5 u 20
u 8cm
For second case u 40 8 32cm
1 2 1 2
v 80cm
v 32 20
14. A fish looking up through the water sees outside world, contained in circular horizon. If
the R.I of water is 4/3 and the fish is 10cm below the water the radius of the circle is
30
cm x is
x
Key: 7
h 10 30
Sol: R
1
43 7
2 2
1
The real image will be the size of the object if the object distance u 2 F 20cm
At 2V2 3
Sol: V2 V1
Ai V2 V1 4
I A2
2. Which one of the following does not represent a travelling wave?
1) y sin x vt 2) y ym sin k x vt
3) y ym log x vt
4) y f x 2 vt 2
Key: 4
Sol: Conceptual
3. A pressure of 100 kPa causes a decrease in volume of water by 5 103% . The speed of
sound in water is
1) 712 m / s 2) 340 m / s 3) 1414 m / s 4) 1000 m / s
Key: 3
P
Sol: B V 1000 kg / m3
V
V
4 The maximum number of possible interference maxima for slit separation equal to twice
the wavelength in young’s double slit experiment is
1) 3 2) 5 3) infinite 4) zero
Key: 2
Sol: d sin n
Given d 2
2 sin n
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n
sin
2
n 0,1,1,2, 2
5. Statement-1: Pitch of sound depends on intensity of wave
Statement-2: loudness of sound depends on frequency of wave
1) Both statement 1 and 2 are true 2) Statement-1 is true statement-2 is false
3) Statement-1 is false statement-2 is true 4) Both statements are false
Key: 4
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. A tuning fork is vibrating at 250 Hz. The length of the shortest closed organ pipe that will
resonate with a tuning fork will be _____cm. (Speed of sound = 340 ms 1 )
Key: 34
V
Sol: 250 L 0.34 m
4L
L 34 cm
7. If the length of stretched string is shortened by 40% and tension is increased by 44%,
then the ratio of final and initial fundamental frequencies is x:1, where x =_____
Key: 2
T
Sol: n
n1 T 100 60 1
1 2
n2 T2 1 144 100 2
8. The ratio of speed of sound in nitrogen gas to that in helium gas at 300K. (both are
assumed to be ideal gases) is x : 5 , where x
Key: 3
Sol: V
M
9. A string of length hangs freely from a rigid support. The time required by a transverse
x
pulse to travel from bottom to half-length of string is where x
g
Sol: Conceptual
10. A sonometer is set on the floor of a lift. When the lift is at rest, the sonometer wire
9g
vibrates with frequency 256 Hz. When the lift goes up with acceleration a , the
16
frequency of vibration of same wire in Hz changes to _____
Key: 320
Sol: n g
n' ga
n g
11. A light ray incident on a transparent medium of 1.732 at the polarizing angle. The
angle of refraction is ____degrees.
Key: 30
Sol:
12. When temperature rises by 10 C then velocity of sound in air increases by ____cm/s.
[given: initial temperature is 0ºC)
Key: 61
Sol: Conceptual
13. Two sound waves of frequency 210 Hz and 225 Hz travel in the same direction and
superimpose on each other, the number of beats heard by a person are _____
Key: 0
Sol: Conceptual
B
C
D
E
1) B is radian 2) C is radian 3) D is > 2 radian 4) E is 2 radian
2
KEY: 1
SOL: In diagram, B particle is at extreme position, so phase difference is , In ‘C’ phase
2
difference is < .
2. Statement (I): The force of attraction due to a hollow spherical shell of uniform density
on a point mass situated inside it is always positive.
Statement (II): The force of attraction between a hollow spherical shell of uniform
density and a point mass situated outside is same just as if the entire mass of the shell is
at the centre of the shell.
1) Both statements I and II are true 2) Statement I is true, but statement II is false
3) Statement II is true, but statement I is false 4) Both statements I and II are false
KEY: 3
SOL: Inside the shell, E 0
Also hollow spherical shell behaves like point mass placed at center of shell for point
outside the shell so (II) is correct
4. 9 kg solution is poured into a glass U-tube as shown in the figure below. The tube's inner
diameter is 2 and the solution oscillates freely up and down about its position of
5
equilibrium (x = 0). The period of oscillation in seconds is (1 m³ of solution has a mass
1) 0.1 2) 10 3) 4) 1
KEY: 1
SOL: Diameter of tube, D 2 m
5
Radius of tube (r ) m
5
Mass of solution m = 9 kg
We know that, Mass (m) v
2
2 5
m L 9 900
2
L 9 900 L ...(i )
5 5 100 2
L
Time period of oscillation of solution T 2
2g
5. Two particles execute S.H.M of the same amplitude and frequency along the same
straight line. They pass one another when going in opposite directions each time their
displacement is half their amplitude. The phase difference between them is
1) / 3 2) / 4 3) 2 / 3 4) 3 / 4
KEY: 3
SOL: S.H.M equation y A sin t
A
Since A sin(t ) t 300 or 1500
2
Since the two particle are going in opposite direction the phase of one is 300 and other is
150 0 hence phase difference = 120 0 .
1) 9 cm 2) 6 cm 3) 4.5 cm 4) 3 cm
KEY: 4
SOL: Angular frequency 2 f 4 rad / s
Where A is amplitude
2 A g
g 0.5 10
A 3cm
2 16 2
7. What is the period of the small oscillation of the block of mass m if the springs ideal and
pull is massless?
KEY: 1
m
SOL: T 2
keq
8. Two identical balls A and B each of mass 0.1 kg are attached to two identical massless
springs. The spring mass system is constrained to move inside a rigid smooth pipe bent in
the form of a circle as shown in the figure. The pipe is fixed in a horizontal plane. The
centres of the balls can move in a circle of radius 0.06 m. Each spring has a natural length
of 0.06 m and force constant 0.1N/m. Initially both the balls are displaced by an angle =
π/6 radian with respect to the diameter PQ of the circle and released from rest. The
frequency of oscillation of the ball B is
1 1
1) Hz 2) Hz 3) 2 Hz 4) Hz
2
KEY: 2
SOL: As here two masses are connected by two springs this problem is equivalent to the
oscillation of a reduce mass mr of a spring of effective spring constant.
mr
T 2
keff
m1m2 m
here mr ; K eff . K1 K 2 2 K
m1 m2 2
1 K eff 1 2K 1 K 1 0.1 1
n 2 Hz
2 mr 2 m m 0.1
M
9. The time period of simple harmonic motion of mass M in the given figure is ,
5k
where the value of is
KEY: 12
2k k 5k
SOL: keq k
3k 3
keq
Angular frequency of oscillation ( )
M
5k
( )
3M
2 3M 12m
Period of oscillation ( ) 2
5k 5k
10. In the given spring block system if k 25 2 Nm 1 , then find time period of oscillation.
KEY: 1
m1m2 m
SOL: 2.5kg
m1 m2 2
k
2k
2 2k 2 25 10 2
2
Keq
k 5 5
2k
2
11. A binary star consists of two stars A (mass 2.2M s ) and B (mass 11M s ), where M s , is the
mass of the sun. They are separated by distance d and are rotating about their centre of
mass, which is stationary. The ratio of the total angular momentum of the binary star to
the angular momentum of star B about the centre of mass is :-
KEY: 6
SOL: Conceptual
12. A satellite is seen after each 8 hours over the equator at a place on the earth when its
sense of rotation is opposite to the earth. The time interval after which it can be seen at
the same place when the sense of rotation of earth & satellite is same will be:
KEY: 24
SOL: Let angular velocity of earth is 1
Let angular velocity of satellite is 2 then relative angular velocity when both are rotating
in opposite direction = 1 2
2
T
1 2
2
8
2 2
T1 T2
24T2
8 (T1 24 Hr for earth)
24 T2
T2 12 Hr
relative 2 1
2
T
2 1
T 24 Hr
GM e
g
( Re ) 2
2
g 1 Re 6.25
g Re h 100
h 3Re
14. In the reported figure of earth, the value of acceleration due to gravity is same at point A
and C but it is smaller than that of its value at point B (surface of the earth). The value of
OA: AB will be x:5. The value of x is..........
KEY: 4
SOL:
15. If one wants to remove all the mass of the earth to infinity in order to break it up
x GM 2
completely. The amount of energy that needs to be supplied will be where x is
5 R
(Round off to the Nearest Integer) (M is the mass of earth, R is the radius of earth, G is
the gravitational constant)
KEY: 3
GM
gC 2
R
R
2
g A gC
r 1 4r
r
R 3
9 2 9
R
4
OA : AB 4 : 5
16. A block of mass 5kg moves along the x-direction subject to the force F (20 x 10) N,
with the value of x in meter. At time t = 0 s, it is at rest at position x = 1 m. The
magnitude of momentum of the block at t s is
4
KEY: 5
SOL: Given F 20 x 10 N
1
F 20( x )
2
F Kx1
so K 20
K 20
2
m 5
2
T
so t particle is at mean position
4
Now P m( A)
P 5kg m / s .
3. A point charge Q is located on the axis of a disc of radius R at a distance “a” from
the plane of the disc. If the flux from the charge that passes through the disc is
2 3
times the total flux, then the relation between a and R is.
4
1) a R 3 2) a R 2 3) a R 5 4) a 2R
Key: 1
Sol:
R
a q
a
2 1
a2 R2
q
Flux through disc
4 0
q 2 3 q
4 0 4 0
2 a 1 3
1
4 2 4
a2 R2
1 a 1 3
2 2 a2 R2 2 4
a 3
2 a2 R2 4
a 3
4 a2 R2 16
4a 2 3R 2 3a 2
a 2 3R 2
a 3R
Sol:
x
F1 F2 0
k 4q 0 2q 0 k q 0 2q 0
0
x2 x 15 2
4 1
0
2
x x 15 2
4 1
x2 x 15 2
2 1
x x 15
2x 30 x
x 30 cm
5. The volume charge density of a sphere of radius 6m is 8.89 C cm3 . The number of
lines of force per unit surface area coming out from the surface of sphere is
_____________ 1010 NC 1 . 8.89 10 12 C 2 / N m 2
Key: 200
2 1012
200 1010 N /C
6. An electric dipole of dipole moment is 6 109 cm placed in a uniform electric field of
2.5 106 N /C; in such a way that dipole is along the electric field. The work done in
rotating dipole by 180 0 in this field will be________________ milli Jouls.
Key: 30
Sol: w PE cos 1 cos 2 1 0
2PE 2 180
2 6 10 9 2.5 106
30 10 3
30 mJ
7. An electric charge 10 3 C is placed at the origin (0,0) of x-y co-ordinate system. Two
A 5,2 5
B
103c (5,0)
Key: 0
Sol: . For A
A 5,2 5
B
(5,0)
2
2 2
OA 5 0 5 0
a 5 20 5
VA
kq
k 10 3
a2 25
For B
OB 5 b
VB
kq
k 10 3
b2 25
VA VB 0
9. If the electric potential of the inner shell is 15V and that of the outer shell is 4V,
then the potential at the center will be
Key: 15
1 q 9 109 4 10 8 360
v 72
4 t0 d 5 5
11. Two small dipoles of moment “P” are placed as shown in the figure. The force between
nkp2 1
the two dipoles is Find “n” [where k ]
x4 4 0
P P
x
Key: 3
1 3P1P2
Sol: F
4 0 d 4
12. Find the magnitude of potential difference between point A and B in an electric field
E 2i 3j 4k NC 1 where rA i 2j k m and r B 2i j 2k m .
Key: 1
Sol: We know that dV E.d r
(1, 2,1)
(1, 2,1)
(1, 2,1)
(2,1, 2)
(2dx 3dy 4 dz ) (2 x 3 y 4 z )
(2,1, 2)
1 volt
Sol:
2. In the adjoining figure the potential difference between the points D and B will be
5 4 8 10
1) V 2) V 3) V 4) V
3 3 9 3
Key: 1
Sol:
1) 4 0 2) 4 0
1 1 1 abc bc
3) 4 0 a b c 4) 4 0
a b c ab bc ca
cb
Key: 4
Sol:
CV 2 CV 2 CV 2
1) Zero 2) 3) 4)
20 4 5
Key: 1
Sol: Effective capacitance remains uncharged.
6. Initially the system is as shown in figure and s1, s2 , s3 are open. Now s1, s2 , s3 are closed.
As a result, the charges on 6µF and 3µF respectively
Key: 2
Sol: Let each plate moves a distance ‘x’ from initial position. Let q be the charge flows in the
loop
Key: 6
Sol: Effective potential difference across the circuit is veff 8V 2V 6V
VB Vc 2 4 V 0
9. In an electric circuit, a cell of certain emf provides a potential difference of 1.25 V across
a load resistance of 5 . However, it provides a potential difference of1 V across a load
x
resistance of 2 . The emf of the cell is given by v. Then the value of x is_____
10
Key: 15
Sol: Let the emf be E and let the internal resistance is r.
V 1.25
Case I: current, I
r 5
As, Ir V
1.25
r 1.25
5
V 1
Case II: current, I
r 2
1
Also, e Ir V or r 1
2
x
On comparing the given value with V , we get x 15
10
10. In a meter-bride when a resistance in the left gap is 2 and unknown resistance in the
right gap, the balance length is obtained at 40 cm from left end. On shunting the unknown
resistance with 2 , the balance length changes by x cm then the value of 2x is ____
Key: 45
Sol: Conceptual
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11. Wheatstone bridge principle is used to measure the specific resistance S1 of given wire
having length L and radius r. If X is the resistance of wire ,then specific resistance is;
r2
S1 X . If the length of the wire gets doubles the value of specific resistance is x S1
L
then x is ____
Key: 1
Sol: Specific resistance S1 length =L, radius =r
r2
S1 X where X is the resistance
L
Now, L’ =2L, as specific resistance does not depend on the geometry of wire
13. Find out the value of current in ampere through 2Ω resistance for the given circuit is
Key: 0
Sol: Current in the respective loop will remain confined in the loop itself. Therefore, current
through 2Ω resistance is zero
14. Water boils in an electric kettle for 15 min. If length of heating wire is decreased to 2/3 of
its initial value (keeping cross-section area constant), then same amount of water will boil
with same supply voltage in____min
Key: 10
Sol: Let water requires H joule of heat to boil Then,
15. Twelve identical cells connected in series are kept in a closed box. Some of the cells are
wrongly connected. This battery is further connected in series with two more cells
identical with others. The current in the circuit is 3A when cells and battery aid each
other and 1A when cells and battery oppose each other. The number of cells in the battery
that are wrongly connected is
Key: 4
Sol: Let ‘m’ wrongly connected
16. Six plates of equal area A and separation as shown in figure are arranged. The equivalent
xA 0
capacitance between A and B is Then x is _____
d
Key: 1
3. Statement I: If the number of turns in the coil of a moving coil galvanometer is doubled
then the current sensitivity becomes double.
Statement II: Increasing current sensitivity of a moving coil galvanometer by only
increasing the number of turns in the coil will also increase its voltage sensitivity in the
same ratio.
In the light of the above statement, choose the correct answer from the options given
below
1) Statement I is false but Statement II is true
2) Both Statement I and Statement II are true
3) Both Statement I and Statement II are false
4) Statement I is true but Statement II is false
Key: 4
I BNA
Sol: current sensitivity
k
Key: 2
60 1
Sol: T1 2(sec); T1
30 B
T2 B1 B 1
T1 B2 2B 2
T1 2
T2 2(sec)
2 2
5. If a magnet is suspended at angle 300 to the magnetic meridian, the dip needle makes at
1
3
450 with horizontal. The real dip is tan , Then x is
x
Key: 2
BV
tan
BH cos 30
45
BV
tan 45 1 or cos 30 3
Sol: BH
BV 3
tan
BH 2
3
tan 1
2
6. What is the radius of then path of the electron ( 9 1031 kg & ch arg e1.6 1019 C ) moving at a
speed of 3 107 m / s in a magnetic field of 6 104 T perpendicular to it? Find the answer in
cm.
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Key: 28
mv 9 1031 3 107
Sol: r 19 4
28 102 m 28cm
qB 1.6 10 6 10
7. An element l xiˆ is placed at the origin carries a large current I = 10A shown in fig.
The magnetic field on the y- axis at a distance of 0.5 m. [Take x 1cm ] is ___________
10 8 T
Y
y 0.5m
X
x 1 cm
Key: 4
0 idl sin 107 (10)102 Sin 900
Sol: dB = 4T
4 r2 (0.5)2
900 ,sin 1
l x 102 m
10 A, r
r 0.5m 4
8. A straight wire of mass 200 g and length 1.5 m carries a current of 2 A. It is suspended in
mid-air by a uniform horizontal magnetic field B. The magnitude of the magnetic field is
_______ 10 2 T [Take g= 9.8]
Key: 65
Sol: We find that there is an upward force F of magnitude Bil. For mid-air suspension this
must be balanced by the force due to gravity
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mg Bil
mg 0.2 9.8
B 0.65T 65 102
il 2 1.5
Key: 14
Sol: Here v parallel to B
4 y z
2 3 6
y 6 & z 12
B 16 36 144 196 14 T
10. The force exerted by the conductor AB on the loop CDFG shown in figure is n 104 N
Key: 7
i1i2
Sol: F1 2 107
1 102
i1i2
F2 2 107
10 102
Key: 1
3. Sol: W Fl NIBl l
BVNl
W NBl 2
R
N 2 B 2l 4
W
RT
104 16 10 2 625 10 8
W
100
4
W 1 10 J
05. A solenoid is of length 50 cm and has a radius of 2 cm it has 500 turns. Around its central
section of a coil of 50 turns is wound. The mutual inductance of the system is
788.76 10 x H . Then the value of ‘x’ is
Key: 7
0 N p N s A
4. Sol: M
l
M 788.76 107 H
0.5
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 44
SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
06. For a given series LCR circuit it its found that maximum current drawn when value of
variable capacitance is 25 nF. If the resistance 100 and 400 mH in inductor is being
10 x
used in a given circuit. The frequency of source is HZ then the value of ‘x’ is______
2
Key: 4
1
5. Sol: f
2 Lc
1
f
2 400 103 25 10 9
1
f
2 104 1012
1 1
f
2 108 2 10
4
104
f x4
2
07. A uniform magnetic field B exists in a cylindrical region of radius 10 cm as shown in
figure. A uniform wire of length 80 cm and resistance 4.0 is bent into a square frame
and is placed with one side along a diameter of the cylindrical region. If the magnetic
field increases at a constant rate of 0.01 T/s The induced current in frame is x 106 A
Then the value of ‘x’ is
Key: 39
d dB
6. Sol: e A
dt dt
e 1.57 104 v
e 1.57 104
i
R 4
i 3.9 10 39 106
5
09. A series LCR circuit is connected to AC source of 220 V, 50 HZ the circuit contains a
resistance R 60 , an inductor of inductive reactance xL 40 and a capacitor of
x
capacitive reactance xC 120 The power factor of circuit is The value of ‘x’ is
10
Key: 6
R 60
8. Sol: cos , cos
R ( xL xC ) 60 120 40
2 2 2 2
60 60 60 6
cos , cos , cos
36 10 64 10
2 2
100 10 2 100 10
10. In an LC oscillator, if values of inductance and capacitance become four and nine times,
1
respectively, then the resonant frequency of oscillator becomes times its initial
x
resonant frequency 0 . The value of x is:
Key: 6
1
9. Sol: f
LC
f1 L2 C2
f2 L1 C1
0 4 L 9c
f2 l c
0
36
f2
0
f2
6
1. The de Broglie wavelength of an electron moving with a velocity 1.5 108 ms 1 is equal
to that a photon. The ratio of the kinetic energy of the electron to that of the photon is
1 1
1) 2 2) 4 3) 4)
2 4
Key: 4
Sol: 1. The speed of photo c 3 108 ms 1. Wavelength of photon is, say, .
h
Wavelength of electron = .
m
1
K.E of electron 2 m 2
1 m 2
K.E of photon h 2 hc
v 1 c
v
2c 2 2
7.6 MeV/nucleon dissociated into middle mass nuclide A 118 , having binding energy
of 8.6 MeV/Nucleon. The energy released in the process would be …….. MeV
Key: 236
3. A nucleus with mass number 242 and binding energy per nucleon as 7.6 MeV breaks into
two fragment each with mass number 121. If each fragment nucleus has bind energy per
nucleon as 8.1 MeV, the total gain in binding energy is ……. MeV
Total gain in binding energy = Final binding energy -initial bind energy
242 8.1 7.6 121 MeV
4. The wavelength of the radiation emitted is 0 when an electron jumps from the second
excited state to the first excited state of the hydrogen atom. If the electron jumps from the
third excited state to the second orbit of the hydrogen atom, the wavelength of the
20
radiation emitted will be 0 . The value of ‘x’ is ……
x
Key: 27
Sol: Second excited state first excited state
n 3 n 2
hc 1 1
13.6 2 2 ........ i
0 2 3
Third excited state second order
n 4n 2
hc 1 1 200
13.6 2 2 '
' 2 4 x
hc 1 1
13.6 2 2 ......... ii
200 / x 2 4
1 1 1 1 4 1 3
x 2 4 2 2
Divide equation (ii) by (i) 4 16 16 16 x 27
20 1 1 1 1 94 5
2
2
2 3 4 9 36 36
5. An atom absorbs a photon of wavelength 500 nm and emits another photon of
wavelength 600 nm. The net energy absorbed by the atom in this process is n 104 eV .
The value of ‘n’ is …. [Assume the atom to be stationary during the absorption and
emission process] (Take h 6.6 1034 Js and c 3 108 m / s )
Key: 4125
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Sol: Net energy absorbed
hc hc 1 1
E E1 E 2 hc
1 2 1 2
1 1
6.6 1034 3 108 9
9
6.6 1020 J
500 10 600 10
6.6 1020
19
eV 4.125 101 eV
1.6 10
6. An X-ray tube operates at 20 kV. A particular electron loses 5% of its kinetic energy to
emit an X-ray photon at the first collision. The wavelength corresponding to this photon
is____× 102 nm.
Key: 124
hc
K 20 103 eV E 0.05 20 103 eV 103 eV 103 eV ;
Sol:
hc
4.14 1015 eV S 3 108 m / s
103 eV 103 eV
12.42 1010 m 1.24nm
7. The ionization energy of hydrogen atom is 13.6 eV. Hydrogen atoms in the ground state
are excited by electromagnetic radiation of energy 12.1 eV. How many spectral lines will
be emitted by the hydrogen atom?
Key: 3
Sol: When an electron in the ground state receives 12.1 eV of energy, it jumps to a level where
its energy = 13.6 – 12.1 = 1.5 eV. This corresponds to the third excited state corresponding
to n = 3. It can have three transitions, namely from n = 3 to n = 2, from
n = 2 to n = 1 and from n = 3 to n = 1. Hence three spectral lines will be emitted.
8. A uranium nucleus (atomic number 92, mass number 238) emits an alpha particle and the
resultant nucleus emits a particle. The atomic number of new nucleus is
Key: 91
Sol: The emission of an -particle decreases the mass number by 4 and atomic number by 2.
The emission of a -particle increases the atomic number by 1. Hence the final nucleus
has a mass number = 238 – 4 = 234 and atomic number = 92 – 1 + 1 = 91.
Key: 32
Sol: Q ne
1) 2)
3) 4)
Key: 4
(50 10) x
Equation of line AB v ( x 0) 10(0 x 200) v 10
(200 0) 5
dv 1
Differentiate equation (i) w.r.t.x, we get
dx 5
dv dv dx dv
Acceleration, a
dt dx dt dx
x 1
a 10
5 5
3. A ball is projected from a point A with some velocity at an angle 30 o with the horizontal
as shown in the figure. Consider a target at point B. The ball will hit the target if it is
thrown with a velocity v0 equal to
4. The velocity time graph of a body is shown in fig. The ratio during the intervals OA and
AB of:
1
1) Average velocities is 1:1 2) Displacement is
4
1
3) Average acceleration is same as distances covered 4) Distances covered is
2
Key: 1
u v 0v v
Sol: During interval OA acceleration is same. vavg
2 2 2
u v 0v v
During interval AB acceleration is same. vavg
2 2 2
Ratio of average velocity is 1 : 1
During interval OA, a = tan600 = 3
1 2 1
S at 3t 2
2 2
1
During interval AB, a = tan300 =
3
1 2 1 1 2
S at t
2 2 3
S1 1
Ratio of displacements
S2 3
1 2
3t1 t
a1t1 a2t2 3 3t1 t2
aavg
t1 t2 t1 t2 3(t1 t 2 )
1 1 2 1 (3 1)
S S1 S2 3t 2 t (t1 t2 ) 2
2 2 3 2 3
4 MLg
5. In the determination of Young's modulus (Y length L = 2m and diameter d =
ld 2
0.5mm is used. For load M = 2.5kg an extension l 0.25mm in the length of the wire is
observed. Quantities d and l are measured using a screw gauge and a micrometer.
Respectively. They have the same pitch of 0.5 mm. The number of divisions on their
circular scale is 100 the contributions to the maximum probable error in the measurement
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of Y is
1) Same due to the errors in the measurements of d and l
2) Due to the error in the measurement of d is twice that due to the error in the
measurement of l
3) Due to the error in the measurement of l is twice that due to the error in the
measurement of d
4) Due to the error in the measurement of d is four time that due to the error in the
measurement of l
Key: 1
MLg Y l d
Sol: Y
2 2
ld Y max l d
l
0.02
l
d
0.01
d
l d
2
l d
6. A fighter jet is flying horizontally at a certain altitude with a speed of 200 m s 1 .When it
passes directly overhead an anti-aircraft gun, a bullet is fired from the gun, at an angle
with the horizontal, to hit the jet. If the bullet speed is 400 m/s, the value of will
be____________( in degrees).
Key: 60
jet u 200 m / s
Sol:
So, 400 cos t 200t
1
cos 600
2
7. The acceleration due to gravity is found upto an accuracy of 4% on a planet. The energy
supplied to a simple pendulum of known mass m to undertake oscillations of time period
T is being estimated. If time period is measured to an accuracy of 3%, the accuracy to
which E is known as___________ %.
Key: 14
2 T 2 2
The energy is given by E mgl mg 2 (From (i))
2 8 2
dE dg dT
Differentiate above eqn, we get, 2 2(4 3) 14%
E g T
M 0 LT 0 M x 1L3 xT 3 y z
x y 0 ...(i )
3 x 1 ...(ii )
3 y z 0 ...(iii )
As d S1/3 n 3
a 50m / s 2
a
Distance travelled in (t+1)th second is St 1 u 2(t 1) 1 u 25(2t 1)
2
125m u 50t 25 u 125 (50t 25)
a
Distance travelled in (t+2)th second is St 2 u 2(t 2) 1 u 25(2t 3)
2
125 50t 25 50t 75 St 2 175 m
11. Airplanes A and B are flying with constant velocity in the same vertical plane at
angles 300 and 600 with respect to the horizontal respectively as shown in the figure. The
speed of A is 100 3 m/s. At time t = 0s, an observer in A finds B at a distance of 500m.
The observer sees B moving with a constant velocity perpendicular to the line of motion
of A. If at t=t0, A just escapes being hit by B, t0 in seconds is .
Key: 5
Sol: Conceptual
Column-I Column-II
(a) normal reaction (p) 5 N
(b) Force of friction when F 15 N (q) 10 N
(c) Minimum value of F for stopping the block moving down (r) 15 N
(d) Minimum value of F for stopping the block moving up (s) None of the above
1) a P; b P; c s; d r 2) a s; b p; c s; d s
3) a s; b p; c r ; d r 4) a s; b p; c s; d r
Key: 2
Sol:
a) N 10 ma
N 10 2 5 N 20 N
at 2 mg
g :t
2m a
1) 40 N 2) 30 N 3) 50 N 4) 60 N
Key: 3
f ma m at2 ar 2
Sol:
Rw2
2
Rd
2
m
m Rd
2
R t
2 2
2
1 1
2 2
3
0.36 10 0.25 0.25 2
3 3
50 N
4. In the arrangement shown, m1 1kg , m2 2kg , the pulleys and strings are ideal and all
surfaces in contact are frictionless. The value of M for which the mass m1 moves with
constant velocity is
1) 6 kg 2) 4 kg 3) 8kg 4) 10kg
Key: 3
Sol: Since mass m1 moves with const velocity
so, T 10 N
2T 20
Acceleration of ' M ' is a
M M
From pulley 2 frame of reference
20
20 10 2 2a
M
40 20
10 2
M M
80
10
M
M 8kg
5. Blocks A and C start from rest and move to the right with acceleration a A 12t ms 2 and
aC 3 ms 2 Here t is in second. The time when block B again comes to rest is
3 1
1) 2 s 2) 1s 3) s 4) s
2 2
Key: 4
Sol: Apply constrain relations
VB 1.5t 3t 2
1
VB 0 at t s
2
6. A ball of mass 1 kg is released from position A inside a wedge which has a hemispherical
cut of radius 0.5 m as shown. Assuming all surfaces to be smooth, the force exerted by
the vertical wall OM on wedge, when the ball is in position B is g 10ms 2
15 3
1) 5 3 N 2) 10 N 3) N 4) 15 N
2
Key: 3
1 2
mv mgh
Sol: 2
v 2 gh
1
h R cos 60 0.5 0.25m V 2 5m 2 s 2
2
mv 2
N mg cos 60
R
mv 2
N mg cos 60o
R
N 15N
Force excreted by vertical wall on edge is F N sin 60
3
F 15 N
2
7. Statement-I: A cloth covers a table. Some dishes are kept on it. The cloth can be pulled
out without dislodging the dishes from the table.
Statement-II: For every action there an equal reaction and opposite reaction.
1) Both statement I & II are correct and statement II is correct explanation of statement-I
2) Both statement I & II are correct and statement II is not correct explanation of
statement I.
3) Both statements I & II are false
4) Statement I is correct & statement II false
Key: 2
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
8. A body of mass ‘m’ is launched up on a rough inclined plane making an angle of with
3
the horizontal. The coefficient of friction between the body and plane is if the time of
5
ascent is half of the time of descent. The value of is___degree.
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Key: 45
a A g sin g cos
Sol:
1
s ut at 2
2
2s
t
a
1
ta t2
2
2s 1 2s
aa 2 ad
aa 4ad
9. A block of mass 40 kg just don’t slide over a surface, when a mass of 4 kg is suspended
through an inextensible massless string passing over frictionless pulley as shown below.
If a mass of 8 kg is hanging in place of 4 kg mass, then the acceleration of block is
Key: 12
Sol: By adding 8 kg in place of 4 kg additional force F 4mg Net mas 40 8 48kg
This additional force creates motion 4 g 48a
10. A bag is gently dropped on a conveyor belt moving at a speed 2 m / s. The coefficient of
friction between the conveyor belt and bag is 0.4. Initially, the bag slips on the belt before
it stops due to friction. The time in which the slipping between the bag and the belt stops
is
( x +0.5) second. The value of x is Take g 10 ms 2
Key: 0
Sol: f N
ma N
N
a
m
a g
v u at
0 2 gt
2 2 2
t 0.5 s
g 0.4 10 4
F is nearly: Given g 10 ms 2
Key: 35
Sol: N mg F sin
12. In the arrangement shown in figure, mA 1kg and mB 2 kg , while all the pulleys and
strings are massless and frictionless. At t 0, a force F 10 t starts acting over central
pulley in vertically upward direction. If the velocity of A is x 10 m / s when B loses
contact with floor, find x .
Key: 1
Sol: F 2T
10t 2T T 5t
' A ' looses contact
1g 5t
10 5t
t 2s
' B ' looses contact
2 g 5t
20
t
5
t 4s
dv 5t 10 dt
0 2
4
5t 2
v 10t
2 2
5
v 16 4 10 4 2
2
5
12 10 2
2
30 20 10m / s
13. A piece of wire is bent in the shape of a parabola y kx 2 y axis vertical with a bead
of mass ‘m’ on it. The bead can slide on the wire without friction. The wire is now
accelerated parallel to the x-axis with an acceleration ‘a’. the distance of the new
a
equilibrium position of the bead is where the bead can stay at rest with respect to the
xgk
wire from y-axis. The value of ‘x’ is
Key: 2
Sol: N cos mg
14. A long block B rests on a smooth horizontal plane. A small block A of mass half that of
B is placed at one end of B and given a horizontal velocity u. if is the co-efficient of
friction between the blocks, then the time elapsed before the two blocks attain a common
2u
velocity is where n is
n g
Key: 3
Pi Pf
Sol:
mu M o m M V
mu
v
m M
Maximum value of friction between A & B is mg
a g
v u at
mu
u gt
mM
m
gt u 1
M m
u M m m
t
g M m
Mu
t
g M m
Mu 2u
t
M 3 g
Mo M
2
Time after which total acceleration of the particle makes 45o with radial acceleration is
____sec.
Key: 2
Sol: at 2t m / s 2
r 4m
uo
at
tan 45o
ac
at ac
dv
2t
dt
t
dv 2t dt
0
t
2t 2
v
2 0
vt 2
ac at
v2
2t
r
t4
2t
r
2r t 3
1
t 2 4 3
t 2s
Key: 1
Sol: Using m ArA mB rB
mA a A mB aB
Further, aCOM
mA mB
g 10m / s 2
As aA ag g
2
vCOM uCOM
2
2aCOM h
2
100
0 2 10 h
3
100
2
h 55.55m
180
H 60 55.55 115.55m
02. A pump is required to lift 1000kg of water per minute from a well 20m deep and eject it
at a rate of 20ms 1 . What HP (horse power) engine is required for the purpose of lifting
water?
Key: 2
Sol: Work done in lifting water = gain in PE (potential energy)
1 1
Work done (per minute) in giving it K.E. mv 2 1000 20 2 105 J min 1
2
2 2
1
Power of the engine = work done per second = 1.96 2 105 J 6.6 103 w
60
Since 1 HP = 746w, HP required = 8.85
03. The linear mass density of a rod of length 5m varies with distance from its end fixed at
the origin as represented in the graph shown below:
Then find the position of centre of mass of the rod w.r.t origin.
25 5 25 5
1) m 2) m 3) m 4) m
16 9 9 16
Key: 3
Sol: 5 x kg / m
X CM
xdm dm 5 x dx
dm
5
X CM
x 5 x dx 25
0
5
5 x dx 9
0
04. A system of two identical particles loses 25% of its energy during collision where one
particle was initially at rest. The coefficient of restitution will be
1
1) 0.25 2) 2 3) 4) 0.5
2
Key: 3
m1m2vr2 KE m2 1
Sol: KE
2 m1 m2
1 e2
KE m1 m2
1 e 2 where KE m1v 2 ,
2
25 1 1
m1 m2 m 1 e2 KE of 25% of KE of m1
100 4 2
1
e
2
Key: 9
Sol: If AC l then according to question, BC 2l and AB 3l
06. A car of mass m is accelerating on a level smooth road under the action of a single force
F. The power delivered to the car is constant and equal to P. If the velocity of the car at
xmv3
an instant is v, then after travelling a distance , it becomes double. Then x is _____
3P
Key: 7
2
d 2 P s 3 Ps 7m 3
Sol: Power, P F . m . . .d . ds
2
3 m or s 3P
ds m 0
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RPTM-14
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. Velocity of the centre of smaller cylinder is v. There is no slipping anywhere. The
velocity of the centre of larger cylinder is:
3v
1) 2v 2) v 3) 4) none
2
Key: 2
Sol: B 2 C
0 C
2
02. A yo-yo arranged as shown, rests on a frictionless surface. When a force F is applied to
the string as shown, the yo-yo:
F
1) Moves to the left and rotates counterclockwise
2) Moves to the right and rotates counterclockwise
3) Moves to the left and rotates clockwise
4) Moves to the right and rotates clockwise
Key: 2
Sol: Conceptual
a
r F>f
F
f
03. A spherical ball of mass m and radius r is released from top of a fixed rough circular
track of radius R so that it always rolls purely. Its velocity at the bottom does not depend
on:
10
g (R r)
7
04. Two particles A, B are moving on two concentric circles of radii R 1 and R2 with equal
angular speed ω. At t=0, their positions and direction of motion are shown in the figure
(R2= 2R1). The relative angular velocity of B with respect to A at t is given by
2
1) iˆ 2) iˆ 3) k̂ 4) k̂
Key: 4
V V A R2 R1
Sol: BA B Anti clockwise
R2 R1 R2 R1
05. Statement – 1: When a sphere is rolling without sliding it is possible that no point on it is
at rest.
Statement – 2: For rolling without sliding vCM R ( and R have usual meaning and
vCM is w.r.t. ground)
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1) Statement-1 is true, Statement-2 is true and statement-2 is correct explanation for
statement-1.
2) Statement-1 is true, statement-2 is true and statement-2 is not the correct explanation
for statement -1.
3) State-1 is true, statement-2 is False.
4) Statement -1 is false, statement-2 is true.
Key: 3
Sol: Think what if the surface on which rolling takes place is moving with respect to ground.
06. A thin-walled hollow sphere shell of mass m and radius r starts from rest and moves
along a track as shown in figure. Assume that the shell successfully negotiates the loop.
R
V
cos
R
h R R cos
08. A rod OB of length l , hinged about its end O is rotating with an angular velocity . The
rod breaks at its midpoint A and as a result the part OA starts rotating with angular
velocity 2. Then the angular velocity of AB about its centre of mass is:
O A B
1) 2) 3 3) 4 4) None
Key: 2
Sol: For OA :
m l
l 2 2
J (2 )
2 3
ml
J .......(i )
12
For AB : About its C.M.
2 2
l 1 m l
J (1 2 ) .....(ii)
4 12 2 2
From (i) and (ii)
1 3
1 2
Case1: mgh1 K .E K mv
2
Whole gravitational potential energy is converted into translation K.E only
FL FL L L
Angular impulse is Q dt
2
dt
2
dt Fdt J
2 2
0.3
0.2 0.03
2
A
J
B MOI of rod
ML3 2 0.3
2
0.09
I cm 0.015
12 12 6
Q I cm 2 1
5
K P 3105 5 105 Pa 'He'is a mono-atomicgas
3
02. Two rods of different metals but of equal cross-section and length 1 m each are joined to
make a rod of length 2m. The metal of one rod has a coefficient of linear thermal
expansion 105 / C and young’s modulus 31010 N / m2 . The other metal has the values
2105 / C and 1010 N / m2 respectively. How much pressure must be applied to the ends
of the composite rod to prevent its expansion when the temperature is raised by 100C
1) 2.75107 N / m2 2) 2.25107 N / m2 3) 2107 N / m2 4) 3107 N / m2
Key: 2
Fl Pl F
Sol: e where =pressure
AY Y A
Ye YY l l
P HereY 1 2 1 2 , l l1 l2
l Y1l2 Y2l1
e 1t 2t
P 2.25107 N / m 2
03. Read the two statements carefully to mark the correct option out of the options given
below
Size of hollow shaft will be greater than solid shaft made of same amount of material.
04. Two equal and opposite forces F & -F on a rod of uniform cross-sectional area ‘A’, as
shown in figure then sum of maximum longitudinal stress and maximum shearing stress
will be
A
F
F
F 2F 3F F
1) 2) 3) 4)
A 3A 2A 2A
Key: 3
F
Sol: Longitudinal stress cos 2
A
F
If 0 then L.S is maximum L.S max
A
F
Tangential (or) shearing stress = sin 2
2A
F
S .S max
2A
3F
Now L.S max S .S max
2A
05. Assertion (A): Rain drops falling from a large height, accelerate initially and then fall
with constant velocity
Reason (R): For a spherical body falling with constant velocity then Buoyancy force is
equal and opposite to the weight of the drop
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not correct explanation of (A)
3) (A) is true and (R) is false
4) Both (A) and (R) are false
Key: 3
Sol: Initially W FB FV then ball accelerates after falling through certain distance
Fv
FB
m
a
W mg
W FB
06. Assertion (A): The impurities always decrease the surface tension of liquid
Reason (R): The change in surface tension of the liquid depends on the degree of
contamination of the impurity
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not correct explanation of (A)
3) (A) is true and (R) is false
4) (A) is False and (R) is True
07. Statement -1: A piece of ice floats in water then level of water remains unchanged when
ice melts completely
Statement -2: According to Archemedis principle, the loss of weight of the body in the
liquid is equal to Buoyancy force acts on a immersed part of the body
1) If both the statements are true and the statement -2 is the correct explanation of
statement-1
2) If both the statements are true and the statement -2 is not the correct explanation of
statement-1
3) If both the statement-1 true but statement -2 is false
4) Both the statement-1 and statement -2 are true
Key: 1
Sol: According to Archemedis principle and laws of floation.
08. A wind with speed 40 m/s blows parallel to the roof of a house. The area of the roof is
250m2 , Assuming that the pressure inside the house is atmospheric pressure, the force
exerted by the wind on the roof and the direction of the force will be air 1.2 kg / m3
09. In a cylindrical water tank, there are two small holes A and B on the wall at a depth of h1 ,
from the surface of water and at a height of h2 from the bottom of water tank. Surface of
water is at height H from the bottom of water tank. Water coming out from both holes
strikes the ground at the same point S. Find the ratio of h1 and h2
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h1
A
H
h2 B
S
1) Depends on H 2) 1:1 3) 2:2 4) 1:2
Key: 2
G.T R1 R2 , after solving H h1 h2 this relation is not satisfied for given figure.
h
Because holes are at different heights, Hence h1 h2 1 1:1
h2
10. Two capillary tubes of equal length and inner radii 2r and 4r respectively are added in
series and a liquid flows through it. If the pressure difference between the ends of the
whole system is 8.5 cm of mercury, find the pressure difference between the two ends of
the first capillary tube.
1) 8.0 cm of Hg 2) 9.0 cm of Hg 3) 10.0 cm of Hg 4) 11.0 cm of Hg
Key: 1
Pr 4 P P
Sol: According to poiseulli’s equation volume rate of flow V
8l 8l R
r 4
8l
Where R = resistance of fluid. In series combination of pipes
r 4
V constant P R
P1 R1 r2
4
1
R 4 ,l , constants
P2 R2 r1 r
r1 2r , r2 4r
P1
16, P P1 P2 8.5cm of Hg
8 P1
17P1 16 8.5
16 8.5
P1 8 cmof Hg
17
11. Let T1 be surface tension between solid and air, T2 be the surface tension between solid
and liquid and T be the surface tension between liquid and air. Then in equilibrium, for a
drop of liquid on a clean glass plate, the relation is ( is angle of contact)
T T T T2 T T2
1) cos 2) cos 3) cos 1 4) cos 1
T1 T2 T1 T2 T T
Key: 4
Sol: T1 T cos T2
T1 T cos T2
T cos T1 T2
2T sin
L L
P Q
T
x T
L1 L 1
T cos T cos
M
Mg
x
If ' ' is small then sin tan
L
YAL
T =tension in string
2L
L total elongation
2 L1 2 L 2
L2 x 2 2 L
x 2 2
1/2
2 L 1 2 2 L 2 L 1
2 1 x 2L
L
2 L 2
x2
L
L
x2
YA
YAL L YAx 2 YAx 2 YAx p
Now T
2L 2L 2 L2 2 L2 2 Lq
p 2, q 2
pq4
13. Consider a water tank as shown in the figure. It’s cross-sectional area is 0.4m2 . The tank
has an opening B near the bottom whose cross-section area is 1cm2 . A load of 24kg is
applied on the water at the top when the height of the water level is 40 cm above the
bottom, the velocity of water coming out the opening B is v ms1 . The value of v, to the
Key: 3
Sol: According to Bernoulli’s theorem,
T .E A T .E B
mg 1 2 1
P0 A hA g P0 hB g B2
A 2 2
A 0, B , hB 0, hA h
2 9.2 9.2 3m / s
14. Two soap bubbles ‘A’ and ‘B’ are kept in a closed chamber where the air is maintained at
pressure 8N / m2 . The radii of bubbles ‘A’ and ‘B’ are 2 cm and 4 cm respectively.
Surface tension of soap water used to make bubbles is 0.04 N / m . Then the ratio of
number of moles of air in soap bubble ‘B’ and ‘A’ is.
Key: 6
Sol: PV nRT
PV n
Pv n
1 1
1
P2v2 n2
n2 P2v2
n1 Pv
1 1
P 4T 4 r 3
n2 0 r2 3 2
n1 4T 4 3
P0 r2
r1 3
G.T P0 8 N / m 2
r1 2cm, r2 4cm
T 0.04 N / m
4
8 4 0.04 4
3
n2 4 10 3
2
n1 4 0.04 4
8 4 102 3 2
3
n2 12 64
6
n1 16 8
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RPTM-16
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01. The potential barrier 'V0 ' volts exist across a p-n junction. An electron with velocity v
approaches P-N junction from N side. The velocity of electron across the junction is
2V e 2V e 2ve
1) v 2 0 2) v 2 0 3) v 4)
m m m
Key: 2
1 2 1 2 2eV0 2eV0
Sol: mv2 mv1 eV0 V22 V12 V12 V22
2 2 m m
2eV0
V1 V22
m
02. The V-I characteristics of diode is shown in figure. The ratio of forward to reverse bias
resistance is ____
I mA
20
15
10
-10
7 8
1 v volt
I A
5 3
1) 10 2) 10 3) 10 2 4) 10 7
Key: 1
87 1 10 0 7 RFB 100
Sol: RFB 3
100 RRB 6
10 7 105
20 10 10 10 1 10 RRB 10
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
03. In the semiconductor, the number density of intrinsic charge carries at 27 0 C is
1.5 1016 / m 3 . If the semiconductor doped with impurity atoms, the hole density increased
to 4.5 10 22 / m 3 . The electron density in the doped semiconductor is P 109 m 3 then P is
__
Key: 5
2.25 1032
Sol: ni ne nL 1.5 10 ne 4.5 10 ne
2 16 2 22
0.5 1010 5 109
4.5 122
CHEMISTRY
RPTM-01
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. In 321 the sum of angular momentum, spherical nodes and angular nodes is ________
6h 8h 6 6h 4 8h 4
1) 3 2) 3) 4)
2 2 2 2
Key: 3
h h 6h
Sol: Angular momentum = l l 1 2 2 1
2 2 2
No. of spherical nodes = n l 1 3 2 1 0
No. of angular nodes = l =2
6h 6h 4
Sum of the above = 2
2 2
2. The minimum energy needed for excitation of an electron present in the ground state of
H-atom is _____
1) + 13.6 eV 2) + 3.4 eV 3) + 12.09 eV 4) + 10.2 eV
Key: 4
Sol: Minimum energy needed is excitation of electron from ground state to 2 nd orbit
-3.4
-13.6
n =1
n =2
4. Given below are two statements one is labelled as Assertion(A) and the other is labelled
as Reason(R).
Assertion(A): In the photo electric effect electrons are ejected from the metal surface as
soon as the bulb of light of frequency is greater than the threshold frequency strikes the
surface.
Reason(R): When the photon of any energy strikes an electron in the atom, transfer of
energy from photon to the electron takes place.
In the light of the above statements, choose the appropriate answer from the options
given below.
1) Both A & R are correct, and R is the correct explanation of A
2) Both A & R are correct, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is correct
Key: 3
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
th
5. In H-atom an electron jumps from 5 orbit to first orbit. The number of visible lines
emitted are _________
Key: 3
Sol: Visible lines means Balmer series.
5
4 Brackett=1
3 Pascher=2
2 Balmer = 3
1
Lyman=4
5 1 5 1 1 45
= 10 lines
2 2
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In which Balmer = 3
6. In an atom an electron is moving with a speed of 600 m/sec with an accuracy of 0.005%
3
certainty with which the position of electron can be located as x 10 m . Then x is
______) (Nearest integer)
Key: 2
Sol: V 600 m / s
0.005
Accuracy = 0.005% of 600 = 600 0.03
100
h 6.625 10 34
x 1.9 2
4 mV 22
4 9.11 10 31 0.03
7
7. Maximum number of electrons that can be accommodated in a P-orbital is ________
Key: 2
Sol: Any orbital can accommodate a maximum of two-electrons only. With opp. spin.
0
8. The shortest wavelength in Lyman series is 912 A . The longest wavelength in Balmer
Key: 7
Sol: Lyman: n1 1, n2
1 1 1
Z 2R 2 2
n1 n2
1 1 1
z2 R 2 2
912 1 …..(1)
Balmer: n1 2, n2 3
1 1 5
z2 R 2 2 Z 2
R
2 3 36 ……..(2)
(1) by (2)
1 5 912 5
Z 2R
36
9. C5H10 O is a carbonyl compound, the number of structural isomers possible for this
molecular formula are
Key: 7
CH 3 CH 2 CH CHO
CH 3
Sol: (1) CH 3 CH 2 CH 2 CH 2 CHO (2)
CH 3
CH 3 CH CH 2 CHO
CH 3 C CHO
CH 3 CH 3
(3) (4)
CH 3CO CH CH 3
CH 3
(7)
10.
H 2 / Ni Cl2 / hv
M
Alkyne
N
(No. of mono-chloro
structural products)
CN
Br
Key: 7
Sol: Principal functional group is CN, OH, Br are substituents
OH
5
4
3
2 1 CN
Br 257
12. In Duma’s method for estimation of nitrogen, 0.29 g of an organic compound gave 50 ml
of Nitrogen collected at 300 K temperature and 715 mm pressure. Calculate the
percentage composition of nitrogen in the compound. (Aqueous tension at 300 K = 15
mm)
Key: 18
Sol: Volume of Nitrogen collected at 300 K and 715 mm pressure is 50 ml.
3 4
2 Fe CN 6 H 2O2 2OH 2 Fe CN 6 2 H 2O O2
3. Considering the basic strength of amines in aqueous solution, which one has the smallest
pK b value?
1) C6 H 5 NH 2 2) CH 3 2 NH 3) CH 3 NH 2 4) CH 3 3 N
Key: 2
Sol: CH 3 2 NH is a stronger base in aqueous medium than Me3 N . So its pKb value is smallest
4. Statement-1: The electron gain enthalpy of N is +ve while that of P is –ve.
Statement-2: This is due to the smaller atomic size of N in which there is a considerable
electron-electron repulsion and hence the additional electron is not accepted easily.
1) Statement-1 is True; Statement-2 is True; Statement-2 is correct explanation for
Statement-1.
2) Statement-1 is True; Statement-2 is True; Statement-2 is NOT a correct explanation
for Statement-1.
3) Statement-1 is True; Statement-2 is False.
4) Statement-1 is False; Statement-2 is True.
Key: 1
Sol: Statement-2 is the correct explanation for Statement-1.
5. Which of the following pairs is chemically similar?
1) Zr Hf 2) Cu Ag 3) Fe Au 4) Hf La
Key: 1
xC xH 0 208
CHO NO2 Cl NH 2
Key: 3
Sol: – I effect increases the Acidity
8. The total number of hydrogen’s contributing structures showing hyperconjugation
(involving C – H bonds) for the following carbocation is
H 3C CH 2CH 3
Key: 6
(a) (b)
H 3C CH 2CH 3
(c)
Key: 3
Sol: - I effect
11. How many pairs in their first species have lower ionization energy than second species?
a) N and O b) Li and Li c) O and S d) Sr and Ba.
Key: 1
Sol: Conceptual
12. I.E. and E.A. of an element are 13 eV and 3.8 eV respectively. The electronegativity of
the element on Pauling’s scale is.
Key: 3
13 3.8 16.8
Sol: On Mulliken Scale E.N . 8.4 eV
2 2
33.6
Hence, molarity 3M
11.2
14. Find the total number of species having magnetic moment value of 5.9 B.M. from
following species. Fe 2 , Cr , Cr 3 , Fe3 , Ti 2 , Mn 2 ,V 3
Key: 2
Sol: Fe3 , Mn2
2. Given below are two statements: One is labeled as Assertion (A) and the other is labeled
as Reason (R)
Assertion (A) Treatment of bromine water with propene yields 1-bromopropan-2-ol.
Reason (R) Attack of water on bromonium ion follows Anti Markovnikov rule and
results in the formation of 1-bromopropan-2-ol.
In the light of the above statements, choose the most appropriate answer from the options
given below.
1) Both Assertion and reason are true, but reason is not the correct explanation of
assertion.
2) Assertion is false, but reason is true.
3) Both assertion and reason are true, and reason is the correct explanation of assertion.
4) Assertion is true, but reason is false
Key: 4
Sol: Both Assertion and Reason are true and Reason is correct explanation of Assertion.
Br
CH 3CH CH 2
Br2
CH 3 CH CH 2
H O
CH 3 CH OH CH 2 Br
2
Markownikoff product
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
3. Total number of covalent bonds between carbon and carbon atoms in C3O2 molecule is
____
Key: 4
Sol: O C C C O
4. The number of species given below that have two lone pairs of electrons on their central
atom is
SF4 , BF4 , ClF3 , AsF3 , PCl5 , BrF5 , XeF4 , SF6
Key: 2
Sol: SF4 1 L. P
BF4 O L. P
XeF4 2 L. P
*
6. Total number of e Present in ^ (pi*) molecular orbital of O2 , O2 , O2
Key: 6
O2 O2
O2
2 Pn1 2 p 1e 3e
Sol:
7. Number of molecules from the following which can exhibit hydrogen bonding is --------
(nearest integer)
NO2
CH 3OH ; H 2O; C2 H 6 ; C6 H 6 ; HF , NH 3
OH
Key: 5
NO2
Sol: OH
8. The number of different chain isomers possible for C6 H14
Key: 5
Sol: Total six different chain isomers for C6 H14 is possible. These are as follows.
Cl2 excess / hv
9.
How many dichloro products are formed in the above reaction (including stereoisomers)?
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Key: 7
Cl
Cl Cl Cl
* Cl
Cl2 excess
*
3stereoisomers
Cl
Sol: 3stereoisomers
10. 3-methylpent 2-ene on reaction with HBr in presence of peroxide forms an addition
product (A). The number of possible stereoisomers for ‘A’ is……..
Key: 4
Sol: The complete reaction is as follow
HBr * *
CH 3 CH C CH 2 CH 3 CH 3 CH CH CH 2 CH 3
Peroxide
CH 3
3 methylpent 2 ene Br CH 3
A
Number of stereocenter n 2
H 2 Pt
H 2 Pt
H 2 Pt
Sol:
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 97
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RPTM-04
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Statement–I: Sulphate of element ‘A’ has the formula A SO4
Statement –II: Nitride of same element has the formula A3 N 2
1) Statement – I is true, statement – II is true; Statement – II is correct is a correct
explanation for statement – I.
2) Statement – I is true, statement – II is true; statement – II is not correct explanation for
statement – I
3) Statement – I is true; statement – II is false
4) Statement – I is false; statement – II is true
Key: 1
Sol: The valency of ‘A’ Is +2 and Nitride is -3.
2. If 1.15% by mass of sodium is present in 500g of solution of NaOH in water. The
molality of the solution is
1) 0.15 2) 0.75 3) 0.25 4) 0.5
Key: 4
wt of solute 1000
Sol: m
molecular weight of solute Weight of solvent
3. ' P ' gm of sodium hydrogen carbonate on strong heating gives ' Q ' gm of solid residue and
0.112 L of CO2 at S.T.P. The normality of solution obtained by dissolving solid residue
in
500ml water is
1) 0.5 2) 0.3 3) 0.1 4) 0.02
Key: 4
527
7. 0.6g of an organic compound (A) with 40% carbon will produce _______ 103 liter of
CO2 at STP on complete combustion (Molar volume 22.4 )
Key: 448
6 *
5 * 2 2 H 2 / pt
4 * *
7 3 1
Sol:
4,5,6-trimethyl -1-hept ne
* 2 2 H 2 / pt
* 1
7 6 5 4
3
O
C O CH3
Sol: is a meta directing group
11. One litre of an alkene with the formula C x H y [mol. wt- 56 ] reacts with ‘X’ litres of
oxygen for its complete combustion at STP. The value of ‘X’ is
Key: 6
Sol: C4 H 8 6O2 4CO2 4 H 2O
12. The number of atoms present in 32g of oxygen gas is [At wt of ' O ' 16 ] A 1023
N 6 1023 the value of ‘A’ is
A
Key: 12
Sol: moles N A 2
cold dil alk KMnO4
1 Butyne A CO2
13. The total number of SP 2 hybrid orbitals
present in
product A.
Key: 3
cold .dil.alk
CH 3 CH 2 C C H CH 3 CH 2 COOH CO2
KMnO4
Sol:
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RPTM-05
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The decreasing order of reactivity of the following compounds towards nucleophilic
substitution reaction is
1) (II>(III)>((I)>(IV) 2) (II)>(III)>(IV)>(I)
3) (III)>(II)>(IV)>(I) 4) (IV>(II)>(III)>(I)
KEY: 2
SOL: Conceptual
2. An 'Assertion' and 'Reason' are given below. Choose the correct answer from the
following options.
Assertion (A): Vinyl halides and Aryl halides do not undergo nucleophilic substitution
easily.
Reason (R): Even though the intermediate carbocation is stabilized by loosely held π-
electrons, the cleavage is difficult because of strong bonding.
1) Both (A) and (R) are wrong statements
2) Both (A) and (R) are correct statements and (R) is the Correct explanation of (A)
3) Both (A) and (R) are correct statements but (R) is not the correct explanation of (A)
4) (A) is a correct statement but (R) is a wrong statement.
KEY: 4
SOL: Conceptual
3.
Aqueous . KOH
Product
NO2
The product mixer obtained is treated with AgNO3 solution correct statement is
1) 6: 5 2) 5 : 6 3) 5 : 3 4) 3 : 5
KEY: 1
SOL: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
5. The total number of monohalogenated organic products in the following (including
stereoisomers) reaction is ….
( i ) H 2 / Ni /
A ( ii ) X 2 /
( simplet optically
active hydrocarbon alkene )
KEY: 8
SOL: Conceptual
H 3C Cl Br
CH 2 Br O Cl
CH 3 Br , Ph H 3C
, , ,
OTf
Br Cl
Cl
O CH 3 CH 2 Cl
, , , ,
Br
KEY: 6
SOL: Conceptual
7. CHCl3 Ag
powder
‘A’
5000 C
’B’
Cu red hot
CH 3COCl
AlCl3
‘C’
PCl5
‘D’
3 NaNH
‘E’ 2
KEY: 1
SOL: Conceptual
8. Total number of species from the following which can undergo disproportionation
reaction is ……. H 2O2 , ClO3 , P4 , Cl2 , Ag , Cu 1 , F2 , NO2 , K
KEY: 6
7 3 4
SOL: K MnO4 H 2 C2 O4 Mn 2 C O2 (Unbalanced) (n factor =5) (n factor = 1 2 2 n factor of
KMnO4
By law of equivalence:
M KMnO4 8M
eqn.(1) 1 eqn(2) 5
M 1V1 M 2V2
1 5
1 1
M1 KMnO4 is mol per litre
50 50
1
Thus KMnO4 is 158g per litre
50
3.16 g/L
316×10-2 g/L
10. 2MnO 4 bI x I 2 yMnO2 z O H . If the above equation is balanced with integer
11. One gram of metallic chloride was found to contain 0.835 g of chlorine. Its vapour
density is 85.5. If its molecular formula is M x Cl y , then what is value of ( x y ) ?
KEY: 5
SOL: Molar mass of M 2 Cl y =85.5×2= 171 g/mol
On solving y = 4 and x = 1
X+y=5
12. When BrO3 ion reacts with Br ion in acidic medium, Br2 is liberated. Calculate the ratio
of molecular mass and equivalent mass of KBrO3
KEY: 5
5 1 0
SOL: BrO Br H Br2 (l )
3
n-factor =5
M KBrO3
EKBrO3
5
13. A sample of 28 ml of H2O2 (aq) solution required 10mL of 0.1 M KMnO4 (aq) solution for
complete reaction in acidic medium. What is the volume strength of H2O2 ?
KEY: 1
SOL: eq. of H 2O2 Eq of KMnO4
(25×M×2)=(10×0.1×5)
M=0.089
The constant ‘a’ measures the intermolecular force of attraction of gas molecules and the
constant ‘b’ measures the volume correction by gas molecules after a perfectly inelastic
binary collision of gas molecules.
For gas A and gas C given value of ‘b’ is 0.05196 dm3 mol 1 .Here, a intermolecular
force of attraction compressibility real nature 1/volume occupied value of
a / (kPa dm6 mol 1) for glass A (642.32)>gas C (431.91) So, gas C will occupy more
volume than gas A. Similarly, for a given value of a say 155.21kPa dm3 mol 1 for gas B
and gas D 1/b intermolecular force of attraction compressibility real nature 1/
volume occupied
2. Two flasks I and II shown below are connected by a value of negligible volume.
When the value is opened, the final pressure of the system in bar is x 102 . The value of
x is ………… (integer answer) [Assume, Ideal gas, 1 bar = 105 pa, molar mass of
N 2 28.0 g mol 1; R 8.31 J mol 1k 1 ]
1) 34 2) 59 3)84 4) 14
Key: 3
Sol: .
On mixing the temperature of gas become T. Internal energy lost by has A is the internal
energy gained by gas B.
U A U B
f f
n A RTA nB RTB (As both gases are diatomic, f is same on both sides)
2 2
n ATA nB TB
2.8 0.2
T1 T T T2
28 28
1 1
300 T T 60
10 140
T 248K
4. An open steel vessel has an ideal gas at 270 C . The fraction of the gas escaped if the
vessel and its contents are heated to 1270 C is x 102 . (Neglect the expansion of the
steel). x value is ___
Key: 25
Sol: n1T1 n2T2
300
n2
400
5. A balloon has a maximum capacity of 20L. At one atmosphere pressure less than 10L of
air is filled in the balloon. It will burst when pressure is x 101 atm. (assuming
isothermal condition). x value is ___
Key: 5
Sol: The balloon would burst when V> 20 L
1 1 P2V2
PV
110 P2 20
6. Calculate the kinetic energy of 1 mole of oxygen molecules in cal mol 1 at 270 C is--------
---
Key: 900
3 3
Sol: KE nRT 1 2 300 = 900
2 2
7. Two grams of hydrogen diffuse from a container in 10 minutes. How many grams of
oxygen would diffuse through the same container at the same time under similar
conditions?
Key: 8
nH 2 MO2
Sol:
nO2 M H2
2
2
2 3 16 4
wO2 2
32
32
wO2 8 gm
4
8. How many structural cyclic ethers are possible for C 4H8O _________
Key: 6
Sol:
9. How many monohydric phenols are possible for the molecular formula C7 H8O _______
Key: 3
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OH OH OH
CH 3
CH 3
CH 3
Sol:
10. How many structural primary alcohols are possible for C5H12O ________
Key: 4
C
C C C C C OH C C C C OH
Sol:
C C
CCCOH CCCOH
C C
11. How many given compounds can react with NaOH _______
C2H5OH,CH3COOH,C6H5OH,Picric acid
Key: 3
Sol: CH3COOH , C6 H5OH , Picric acid.
2. Assertion (A): In the dissociation of PCl5 at constant pressure and temperature addition of
helium at equilibrium increases the dissociation of PCl5
Reason (R): Helium removes Cl2 from the equilibrium mixture.
1) Both A and R are true, and R is correct explanation of A
2) Both A and R are true, but R is not correct explanation of A
3) A is true but R is false.
4) Both A and R are false.
Key: 3
Sol: Conceptual
3. The major product of the following reaction is:
1)DIBAL H
2)H 3O
CHO
1) CH2-CHO 2) CH2OH
OH
3) CH2-CHO 4)
Key: 3
DIBAL II
Sol: a ) R CN R CHO
DIBAL II
b) RCOOR ' R CHO R ' OH
1) AlH i Bu 2 ?
R C N
2)H 3O
4.
Consider the above reaction, when in reagent hydrogen atom is replaced by deuterium.
The product formed is
1) R CHO 2) R CONH 2 3) R COND2 4) R CDO
Key: 4
N-Al (i-Bu2)
D
Sol: DIBAL D
R C N R
5. Statement-(I): A buffer solution is the mixture of a salt and an acid or a base mixed in any
particular quantities.
Statement-(II) Blood is naturally occurring buffer solution whose pH is maintained by
H 2CO3 / HCO 3 concentrations
Choose the most appropriate answer from the options given below.
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1) Statement I is incorrect, but statement II is correct
2) Both statement I and statement II are incorrect
3) Statement-I is correct but Statement II is incorrect
4) Both statement -I and statement II are correct
Key: 1
Sol: Acidic buffer: solution of weak acid and its salt with strong base.
Basic buffer: solution of weak base and its salt with strong acid
CHO
CHO CHO
* 3) 4)
1) CHO 2)
Sol:
3CH CH
Fe
A
CH 3Cl
B
1 2Cl2 / h X
7. AlCl3
2 H 2O /
How many C-atoms are present in x
Key: 7
A C6 H 6
Sol: B C6 H 5CH 3
C C6 H 5CHO
8. A buffer solution contains 0.2 mole of NH 4OH and 0.2 mole of NH 4Cl per liter. The P of kb
NH 4OH is 4.75 calculation the P H of the buffer (Round off to nearest integer)
Key: 9
salt 0.2
Sol: P kb log 4.75 log
base 0.2
11. If Ksp of Ag2CO3 is 8 1012 , the molar solubilities of Ag2CO3 in 0.1 M AgNO3 is___ 1010
Key: 8
2
Sol: K SP Ag CO32
CO3 2 8 1010
OH
Pcc excess
OH A
12.
Number of oxygen atoms in product ‘A’ is
Key: 2
O
OH
CHO
OH
PCC
Sol:
13. Vanillin compound obtained from vanilla beans. The ratio of number of SP 2 hybridised
carbon atoms and the number of pi bonds present in vanillin is “X”. Find the value of
4X?
Key: 7
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Sol:
14. Calculate the approximate PH of a 0.1M H 2 S aq solution. The first and second
dissociation constant of H 2 S are 1 10 7 and 1.3 1014 respectively
Key: 4
Sol: H 2S 0.1 x 0.1
H HS x Ka Ka
2
1 2
P H 4.
NH 3 H 2 S is Kp 12
NH 4 HS
15. If 250 C , the equilibrium constant for the reaction
s g g
A 10.0 liter flask is discharged with 1 atm of pure NH 3 g at 250 c what is the minimum
mass in grams of NH4 HS , that must be added to the flask in order to achieve equilibrium?
(round off the nearest integer)
Key: 63
NH 4 HS NH 3 H 2 S KP PNH 3 .PH 2S
Sol: S g g 12 p 1 p
p 1 p p 3 atm
PV nRP
3 10 n 0.0821 298, n 1.2262
moles of NH 4 HS is =1.2262
Key: 2
OCH3
DIBAL-H CHO
O NAOH(aq)
OH CHO aldol
CHO OH
Sol: .
CHO
NH2NH2/KOH
ethylene glycol
OH
2. In the given reaction the main product will be
1) 2)
3) 4)
Key: 1
CH MgBr
3
O O OMgBr
H
O O
Sol: Me
3. Reagent that can be differentiate 2-propanol from acetone is
3) Ce NO3 4
2
1) NaOH / I 2 2) Ag NH 3 2 4) Cu NH 3 4
Key: 3
Sol: Ce NO3 4 is used to differentiate
4. Me3B, BH3 and BF3 are three Lewis acids, which one of the following is the correct
sequence of acid strength?
1) Me3 B BH 3 BF3 2) Me3 B BF3 BH3
3) BF3 BH3 Me3 B 4) BF3 Me3 B BH3
Key: 4
Sol: Lewis acids are electron deficient species, A species with more deficient central atoms
will be a strong Lewis acid. F being an electron with drawing group, makes B more
deficient but on the other hand, it decreases the deficiency by back bonding. H is unable
Reason (R): As the size of alkali metal ion increases the lattice energy increases and
hence the stability of super oxides increases
1) Both (A) and (R) are true and (R) is correct explanation of (A)
2) Both (A) and (R) are true but (R) is not correct explanation of (A)
3) (A) is true but (R) is not true
4) (A) is not true (R) is true
Key: 1
Sol: Both (A) and (R) are true and (R) is the correct explanation of (A)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. How many of the following can be used to distinguish acetaldehyde and benzaldehyde
(i) Tollen’s (ii) Fehling’s (iii) Benedict’s (iv) NaHSO3 (V) NaOI
(vi) 2,4-DNP (vii) CAN (viii) NaHCO3 (ix)NaOH/I2 (X) Lucas
reagent (xi) Neutral FeCl3
Key: 4
Sol: ii, iii, v, ix, +ve test with Acetaldehyde
I, iv,vi, +ve test with both Acetaldehyde and Benzaldehyde
Vii,viii, x, xi -ve test with both
7.
Number of halogens, hydrogen and carbon atoms in the molecular formulae of compound
‘A’ are x, y, z respectively. Find x+ y- z value.
Key: 3
Sol: A is CHCl3
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X =3 , Y = 1 , Z = 1
X +Y –Z = 3 +1 – 1= 3
8.
Find the value of 2 x 3 y ________
Key: 17
Sol: Butanone +4 KOH +3 I 2 CH I 3
X=4,y =3
2x + 3y = 2 (4)+3(3) = 8 + 9 = 17
Cl
Cl Cl
CH3
9.
Calculate the number of SP 2 hybrid orbitals of carbon atoms in the structure of ‘D’
Key: 21
Cl
CrO3 / Pg / HCl
3NaNH2 NBS
Cl
Cl
CH3
CH2Br CH2OH O=C-H
CH3 (B) (C) (D)
Sol: (A)
1S 2 P 3SP 2
7 3 21
10. How many of the following undergo disproportionation on reaction with NaOH
11. How many water molecules are associated with “EPSOM Salt”?
Key: 7
Sol:
12. How many of the following pairs show similarity in their radii?
Li ; Mg 2 ; Na , Ca 2 ; K , Sr 2 ; Be2 , Al 3 ; B , Si; N , S ; F , Ar ; Mg 2 , Al 3
Key: 2
Sol: MgSO4 7 H 2O
13. How many of the following salts gives Borax bead test.
1) Copper salts 2) Cobalt salts 3) Nickel salts 4) Aluminium salts
Key: 3
Sol: ‘3’ [Copper salt, cobalt salts, Nickel salts]
14. How many compounds given below are correctly matched with their uses?
1) Borax solution : Buffer
2) AlCl3 : Friedel-crafts reaction
3) Ca OH 2 : Bleaching powder
2. The increasing order of the acidity of the following carboxylic acids is?
Note: Ortho substituted benzoic acid is stronger acid (due to ortho effect)
3.
The major product is.
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1) 2)
3) 4)
Key: 2
Sol:
SIX Pi ( ) bonds
7. How many moles of CO2 will released when following compound on heating?
Key: 4
Sol: - Keto carboxylic acids undergo decarboxylation
8. Sodium benzoate
NaOH CaO Conc H 2 SO4
X
Cl2 , FeCl3
310 320 K
Y
Z ( Major product )
Gram molecular weight of the major product (in grams) is __________ (Nearest Integer)
Key: 193
Sol: Molecular weight = 192.5
9. How many bromine atoms are there in the final product in the reaction? __________
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Key: 3
Sol:
10. How many of the following reagents can be used to convert carboxylic acid to the
corresponding acid chloride?
i) NaCl ii) Cl2 iii) PCl3 iv) PCl5 v) SOCl2
Key: 3
Sol: PCl3, PCl5, and SOCl2 can be used for this conversion.
Key: 2
XeF3 SbF6
sp3d sp3d 2
T-shaped octahedral
2. The correct order of Cl–O bond length in ClO , ClO2 , ClO3 , ClO4
Sol: Bond length is inversely proportional to bond order. Greater than delocalization of e (-
ve charge) shorter the bond length.
3. The major product (70% to 80%) of the reaction between m-dinitrobenzene with NH 4 HS
is
1) 2) 3) 4)
Key: 3
CH3
|
CH3 CH 2 CH 2 C H NH Et
N-ethyl-2-pentamine)
2 0
a min e
5. The product of a reaction between methyl isocyanate (MIC) and ethanol is urethane with
formula
1) CH 3 NHCOOC2 H 5 2) C 2 H 5 NHCOOCH 3
Key: 1
CH3 N C OH
Sol: CH3 N C O CH3 CH2 O H |
Tautomerises
OCH CH3
Methyl isocyanate 2
7. A compound (x) with molar mass 108 g mol1 undergoes acetylation to give product with
molar mass 192 g mol1 . The number of amino groups in the compound (x) is ….
Key: 2
O O
|| ||
Sol: R NH 2 CH 3 C Cl R NH C CH 3
Key: 5
Sol:
9. The number of moles of electrons involved in the reduction of one mole of nitrobenzene
by H 2 gas with Ni-catalyst is:
Key: 6
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Ni catalyst
Sol: CH 3 NO2 6 H CH 3 NH 2 2H 2O
10. Reaction of benzamide with Br2 in aqueous NaOH gives aniline, sodium carbonate and
sodium bromide. The stoichiometric coefficient of NaOH in the reaction is :
Key: 4
O
||
Sol: C6 H 5 C NH 2 Br2 4NaOH C6 H 5 NH 2 2NaBr Na 2CO3 2H 2O
Sol:
12. The sum of bond order in O 2 and O3 molecules is ……. (nearest integer)
Key: 4
Sol:
O=O
Bond order O 2 = 2, Bond order O3 = 1.5
13. The sum of lone pairs present in interhalogen BrF5 and IF7 is …….
Key: 37
Sol: BrF5 has 1 lone pair and IF7 has zero lone pair on central atom
F has 3 lone pairs
Total no. of lone pairs = [1 + 3(5)] + [0 + 7(3)] = 37
14. The ratio of number of p p bonds to p d bonds in XeO 3 is
Key: 0
Sol: p p 0, p d 3
15. What is covalency of chlorine atom in second excited state?
Key: 5
Sol: Conceptual
8. (A): Polluted water may have a value of BOD of the order of 17 ppm.
(R): BOD is a measure of oxygen required to oxidize both the biodegradable and non-
biodegradable organic material in water.
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct and R is correct
Key: 3
Sol: A: Clean water should have B.O.D < 5ppm. While highly polluted water have
10. In a polymer sample, 25% molecules have a molecular mass of 14,000, 50% have
molecular mass of 40,000 and rest have 50,000. Calculate the sum of mass average and
K
number average molecular masses = K then, _____________(Nearest integer)
100
Key: 769
Sol: K = 76944
K/100 = 769.4
13.
CH2OH
C=O
H OH
(i) NaBH4
HO H (P)
(ii) H+, H2O
H OH
CH2OH
D-sorbose
Numbers of stereoisomer of product (p) is: ____________
Key: 10
Sol: 241 2(4/2)1 10
14. An atomic substance A of molar mass 12 g mol 1 has a cubic crystal structure with edge
length of 300 pm. The no, of atoms present in one unit cell of A is __________. (Nearest
integer). Given the density of A is 3.0 g mL1 and N A 6.02 1023 mol 1
Key: 4
d N A a3
Sol: Z
M
15. Atoms of an element B form hcp lattice and those of the element A occupy 2/3 rd of
tetrahedral voids. How many number of atoms of A and B (in total) are present in the
help lattice?
Key: 7
Sol: The ratio of A : B = 4 : 3
A4B3 A + B = 4 + 3 = 7
16. In CsCl with cubic structure, Cl- ions are located at each corner and Cs+ ions at the centre
of the unit cell. If rCs and rCl are 1.69 A and 1.81 A respectively. Find the value of edge
length of cube.
Key: 4
Sol: Body diagonal 3a AB
2(rCs rCl ) 3a
22(1.81 1.69) 3a
a 4.04 A
17. An element crystallizes into a structure which may be described by a cubic of unit cell
having one atom on each corner of the cube and two atoms on one of its diagonals.
Volume of the unit cell is 2.4 x 10-23 cm3 and density is 13.82 g cm-3. Number of atoms
present in 200 g of the element is y x 1023. What is the value of y?
Key: 18
ZM
Sol: d 3 30
g / cm3
N A a 10
18. Calcium crystallizes in fcc unit cell with 0.556nm. Calculate the density in (g/cm3). It
contains 0.2% Frenkel defects and 0.1% Schottky defects. (Round off Nearest Integer)
Key: 2
Z eff Aw
Sol: d
N A a3
w2 100 g
3. The strength as oxidizing agent of following species in acidic medium decreases in the
order
2
2 2
1) S 2O8 Cr2O7 MnO4 2) C r2 O 2
7 S 2 O 8 M nO 4
2 2
3) MnO4 Cr2O7 S2O8 4) S 2O8 2 MnO4 Cr2O72
Key: 4
Sol: S 2O82 2e 2So42 E 0 2.01V
Yb Eu Lu Gd Ce
5. Assertion (A): Zn 2 is diamagnetic nature.
Reason (R): The electrons are lost form 4s orbital to from Zn 2
Choose the correct option from following for above.
1) Both A and R are true, and R is the correct explanation of ‘A’
2) Both A and R true and R is not the correct explanation of ‘A’
3) A is true and R is false
4) A is false and R is true
Key: 2
Sol: Zn Ar 3d 10 4s 2
Zn 2 Ar 3d 10 4 s 0
Zn 2 ion is diamagnetic nature due unpaired electrons absent in d orbitals both (A) and (R)
K so Glu cos e
2 4
i X 0.004 X RT 0.01 X RT
0.01
i i 2.5
0.004
i 1 (n 1)
For K 2 So4 ( for dissociation ) i 1 2.5 1 0.75
n 1 3 1
Dissociation = 75
7. How many of the following show positive deviation.
CS 2 CH 3 CO CH 3 ; CS 2 CH 3 CO CH 3 ; C6 H 6 C6 H 5CH 3 ;
CH 3 CO CH 3 CHCl3 ; C2 H 5OH H 2O ; C2 H 5 Br C2 H 5Cl ;
C6 H 5OH C6 H 5 NH 2 ; C2 H 5OH CH 3 CO CH 3
Key: 3
Sol: Positive deviation of Negative deviation
Of ideal solution of ideal solution.
H2 0 CH3COOH
H 2O CH 3OH O
H 2O C2 H 5OH CHCl3 CH3 C CH3
CHCl3 CCl4
H2O HNO3
+ CH3OH
O
10 Fe c2o4 6 KMno4
20 mole s x
206
x 12 moles
10
10. The sum of the sigma and pie ( ) bonds are present in dichromate ion?
Key: 12
2
Sol: Dichromate ion Cr2o 7
O O
O O O
Cr Cr
O O
11. Total number for ions from the following with noble gas configuration is ___________
Sr 2 ( z 38) Cs ( z 55) , La 2 ( z 57)
pb2 ( z 82) : Yb 2 ( z 70) , Fe 2 ( z 26)
Key: 2
Sol: Sr 2 ( z 38) Kr 4s 0 ( noble gas )
Cs ( z 55) Xe 6s 0 (noble gas ).
12. Number of colorless lanthanide ions among the following is _______________
E u 3 , L u 3 , N d 3 , L a 3
Key: 2
Lu 3 Xe 4 f 14 f 14 n o colourless
Sol:
La 3 Xe 4 f o f o n o colourless
13. When HCl is passed over one mole of K 2Cr2O7 , the no moles of Cl2 formed is _______
Key: 3
K 2Cr2O7 14 HCl 2 KCl 2CrCl3 7 H 2O 3Cl2
Sol:
One mole of K 2Cr2O7 reacts HCl produces 3 moles of Cl2
Key: 1
0
Sol: Ecell becomes zero
2. Resistance of 0.2M solution of an electrolyte is 50 . The specific conductance of the
solution is 1.4 S m 1 . The resistance of 0.5M solution of the same electrolyte is 280 .
Key: 1
1 1
Sol: cm
k 1.4 102
l 1
R 50 1.4 102 cm
a
1
k 50 1.4 102 2.5 103 S cm1
280
3. When aq. AgNO3 is subjected to electrolysis using inert electrodes, 10.8 grams of silver
is deptosited at cathode. Weight of oxygen liberated at anode will be
WAg E Ag
WO2 E O2
10.8 108
Sol:
WO2 8
WO2 0.8g
4. Statements are given below:
A) Leclanche cell -------- Reaction at anode Zn Zn2 2e
B) Ni-Cd cell --------- Rechargeable
C) Fuel cell --------- Does not involve any ion in solution and is used in hearing
aids
D) Mercury cell --------- Converts energy of combustion into electrical energy
Choose the correct answer from the options given below:
1) A,B & C are correct 2) A and B are correct
Key: 2
Sol: A. Leclanche cell: It is commonly used dry cell in our clocks the cell consists of a zinc
container that also acts as anode and the cathode is a carbon (graphite) rod surrounded by
powdered managanese dioxide and carbon. The space between the electrodes is filled by
a moist paste of ammonium chloride and zinc chloride.
Anode reaction; Zn s Zn 2 2e
Cd s 2 Ni OH 3 s CdO s 2 Ni OH 2 s H 2O l
C. Fuel cell: these are galvanic cells that are designed to convert the energy of
combustion of fuels like hydrogen, methance methanol, etc. directly into electrical
energy.
D. Mercury cell:
Zn Hg HgO s ZnO s Hg l
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The cell potential is approximately 1.35 V and remains constant during its life as the
overall reaction does not involve any ion in solution whose concentration can change
during its life time.
5. Regarding the process involving discharge of lead storage battery, the correct statements
are
A) Lead sulphate is formed. B) Sulphuric acid is consumed.
C) Specific gravity of sulphuric acid decreases. D) Lead undergoes oxidation.
1) B and D only 2) A, B and D only
3) A, B, C and D 4) B and C only
Key: 3
Sol: During the discharge of lead storage battery,
0 4 2F 2
Pb Pb O 2 2H 2 SO4 2 Pb SO4 2H 2O
6. The number of linkage isomers for the compound K 4 Fe Cl2 CN 2 C2O4 are
1) 4 2) 6 3) 3 4) 2
Key: 4
Sol: With respect to –CN two linkage isomers. (ambidentate)
SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
7. Molar conductivities at infinite dilution of KCl , HCl and CH 3COOK are 0.013, 0.038
provided below; their max values are marked as A, B and C respectively. The correct
match between the complexes and their max values is:
6 n
i) M NCS 6
6n
ii) MF6 iii) M NH 3 6
n
3. A heat engine absorbs heat Q1 at temperature T1 and heat Q2 at temperature T2. Work
done by the engine is (Q1 + Q2). This data
1) Violates 1st law of thermodynamics
2) Violates 1st law of thermodynamics if Q1 is -ve
3) Violates 1st law of thermodynamics of Q2 is -ve
4) Does not violate 1st law of thermodynamics.
Key: 4
Sol: According to first law of thermodynamics, energy can neither be created nor be destroyed
although it can be converted from one form to another. Hence, the given data does not
violate 1st law of thermodynamics but it violates 2nd law of thermodynamics.
5
2.303 0.25 2 300log
10
10
2.303 0.25 2 300log
5
bipyramidal geometries respectively, the sum of the 90,120 and 180 L - M - L angles
in the two complexes is _____
Key: 20
Sol: (Trigonal bipyramidal)
L
L
M L
L
L
120 3, 90 6, 180 1 Total 10
L
L L
M
L L
(square pyramidal)
(0, 0)
C
1/T
373
vaporization of water are 334kJ kg 1 and 2491kJ kg 1 respectively; ln 0.31
273
1) 9.19 kJ kg 1k 1 2) 9.26 kJ kg 1k 1 3) 7.9kJ kg 1k 1 4) 8.49 kJ kg 1k 1
Key: 1
Ice S water S water S watervapour
Sol: 273 K
1
273 K
2
373 K
3
373 K
334
S1 1.22
273
373
S 2 4.2ln 1.30
273
2491
S 3 6.67
373
4. Assertion: For every chemical reaction at equilibrium, standard Gibbs energy change of
reaction is zero.
Reason: At constant temperature and pressure, chemical reactions are spontaneous in the
direction of decreasing Gibbs energy.
1) Both Assertion and Reason are correct and Reason is a correct explanation of
Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation of
Assertion
3) Assertion is correct but Reason is incorrect
4) Assertion is incorrect but Reason is correct
Key: 4
Sol: At equilibrium G is zero but not G 0
5. Statement-1: Enthalpy and entropy of any elementary substance in the standard state are
taken as zero
Statement-2: The absolute value of enthalpy and entropy of chemical substance can be
determined by using 3rd law of thermodynamics.
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1) Both statement-1 and statement-2 are true
2) Statement-1 is true, statement-2 is false
3) Statement-1 is false, statement-2 is false
4) Both statement-1 and statement-2 is false
Key: 3 or 4
Sol: Enthalpy of elements in the standard state is taken as zero. The absolute value of entropy
can be determined by using 3 rd law of thermodynamics
6. K 2Cr2O7 X conc H 2 SO4
heat
A
NaOH
B.
In the above reaction, “A” is reddish brown gas soluble in NaOH forming yellow solution
of “B”. ‘X’ and ‘A’ are
1) NaCl , CrO2Cl2 2) CrO2Cl2 , Na2CrO4 3) SO2 , NO2 4) NaCl , Na2CrO4
Key: 1
Sol: It is chromyl chloride test
7. Statement-1: Addition of NH 4OH to an aqueous solution of BaCl2 in the presences of
NH 4Cl (excess) precipitate Ba OH 2
3 SO H
Sol: Sulphanilic acid is
9. Which of the following is a bactericidal antibiotic?
1) Ofloxacin 2) Tetracycline 3) Chloramphenicol 4) Erythromycin
Key: 1
Sol: Ofloxacin is a bactericidal antibiotic.
10. Which of the following is a cationic detergent?
1) Sodium Stearate 2) Sodium lauryl Sulphate
3) Cetyltrimethyl ammonium bromide 4) Glyceryl oleate
Key: 3
Sol: Cetyltrimethyl ammonium bromide is cationic detergent
11. Drugs used to bind to receptors, inhibiting its natural function and blocking a message are
called
1) Agonists 2) Antagonists 3) Anti histamines 4) Allosterists
Key: 2
Sol: Antagonist inhibits the natural function and blocks the message
Sol: CH 3 C C CH 3 6 I 2 CI 3 C C CI 3
|| || || ||
O O O O
NaOH
COONa
2CHI 3 |
COONa
13. Number of following metal ions are precipitated on reaction with NH 4Cl NH 4OH H 2 S
Cu 2 , Cd 2 , Mn 2 , Zn2 , Ni 2 , Hg 2 , Ba 2 , Ca 2 , Mg 2
Key: 6
Sol: Cu 2 , Cd 2 , Mn 2 , Zn 2 , Ni 2 and Hg 2 are precipitated
14. The number of chlorine atoms in bithionol is ____
Key: 4
Cl OH OH Cl
Cl
Sol: Cl
MATHEMATICS
RPTM-01
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
01.
Let f x a 5 a 4 x3 6a 5a 1 x tan x sgn x , be an even function
2 2
for all x R , then sum of all possible values of a is (where [.] and . denote the greatest
integer function and fractional part function respectively)
17 53 31 35
1) 2) 3) 4)
6 6 3 3
Key: 4
Now put y 1
3 3
f x f 1 f f 3 2 f x f x f x 0 ….(i)
x x
3 3
f x f f f x 2 f 3
x x
3
f x f 1 …….(ii)
x
From (i) and (ii)
f 2 x 1 x 0 f x 1 x 0
03. If x 1 3 x 2 5 x 4 , R , then which of the following is not true?
1) for 9 equation has one solution 2) for 10 equation has no solution
3) for 0 equation has two solution 4) for 9 equation has only one solution
Key: 4
1 x 6 3 x 20 5 x, x 1
x 1 6 3 x 20 5 x,1 x 2
Sol: x 1 3 x 2 5 x 4
x 1 3 x 6 20 5 x,2 x 4
x 1 3 x 6 20 5 x, x 4
13 x, x 1
15 3 x,1 x 2
27 9 x,2 x 4
13 x, x 4
Graph of the function is as shown in the following figure.
m3 n3 m
3 3
m, n Z then
1 1
05. Range of sin x cos x is ,
32 32 n
1 1
1) 7 2) 3) 28 4)
7 28
Key: 4
3 3 1
3 3 2
1 1 1
Sol: sin x cos x sin x sin x
8 2 2
3 3 1 3 3 3 3 1
2 2
sin x sin x
8 2 4 32 8 2 4
3 7 3
Range = ,
32 8
1 sin x 1 sin x
06. If y x cot
1
, x , then y x
1 sin x 1 sin x 2
x x x x
1) 2) 3) 4)
2 2 2 2 2 2
Key: 2
x x x x
cos sin sin cos x
Sol: y x cot
1 2 2 2 2
x x x x ,
cos sin sin cos 2 4 2
2 2 2 2
x
sin
cot 1 2 cot 1 Tan x cot 1 cot x
x
cos 2 2 2
2
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x
y x
2 2
n
12 r
If Sn Tan 2 r 1
1
07. 2 r 1
then Lt S n
r 1 3 4 n
1 4 1 4 1
1) Cot 2) Tan 3) 4) Tan 4
3 3 2
Key: 1
4r
r 2r
n
1 12 / 3 1 n 1 3 r 1
Sol: Sn Tan Tan
r 1
4
2 r 1
r 1
4 r 1 4 r
1 1
3
3 3
4 r 1 4 r
n 1
n
3 3 4 1 4
Tan 1 r 1 r Tan 1
Tan
r 1
4 4 3 3
1
3 3
n 1
4 4 4 4
Sn Lt Tan 1 Tan 1 Tan 1 Cot 1
n
3 3 2 3 3
1 2 1
1 4 2
2Tan 2 2 2Tan Tan
1
08. 96 Tan 3 Cos
5 2 7
1) 6 2) 8 3) 11 4) 7
Key: 4
2 1
Sol: Tan 3 Cos 1 2 Tan 1 2 Tan 3Tan 1 2Tan 1 2
5 2
1 1 1 1 4 2
Tan Tan 1 2 Tan 1 Tan 1 2 Tan Tan 1 , Tan
2 2 2 2 7
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
x 3 1
09. Let S x 6,3 2,2 :
x 2
0 and T x : x 2 7 x 9 0
Then the number of elements in S T :
Key: 3
Sol: S T in only integers satisfies integers are 5, 4,3
1 3n
10. Let f n n , where [n] denotes the greatest integer less than or equal to
3 100
56
n. Then f n is equal to :
n1
Key: 1399
Sol:
Let
1 3n
f n n
3 100
3n
Where n is greatest integer function = 0.33 n
100
For n 1,2,...22, we get f n 0
And for n 23, 24....,55 we get f n 1 n
For n 56, f n 2 n
56
So, f n 1 23 1 24 .... 1 55 2 56
n1
33 33
23 24 ..... 55 112 46 32 112 78 112 1399
2 2
11. If f x and g x are periodic functions with periods 7 and 11, respectively then the
x x
period of F x f x g g x f is
5 3
Key: 1155
f x 7
Sol: The period of .
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x
So, the period f 21
3
The period of g x 11
x
So, the period of g
5 55
x
Hence T1 Period of f x . g 385
5
x
T2 Period of g x . f 231
3
Period of F x LCM T1 , T2 = LCM 385,231 = 1155
12. If f x ax 7 bx 3 cx 5 (a,b,c are real constants) and f 7 7 , then the
range of f 7 17 cos x is m, 0 then m is
Key: 34
Sol: f x ax bx cx 5
7 3
f x ax 7 bx3 cx 5
f x f x 10
x7
f 7 f 7 10
f 7 7 10
f 7 17
1 cos x 1
17 17 cos x 17
34 f 7 17 cos x 0
m 34 m 34
2 2 1 2
13. Let A and B Then the number of elements in the set
1 1 1 2
n, m : n, m 1, 2,....2024 and nAn mB m I is
Key: 3
Sol: sin 1 x 0,1, 1
sin 1 x 0,1, 1
x 0, x I x I 2 …..(iii)
x 2,3
1 12 x x
3
1 x
16. If Tan aTan a, b 0 then a b _____
8 6 x 2
b
Key: 5
12 x3
x
Sol: Tan 8
1 8 aTan 1 x
1 6 x2 b
8
x x 3
3
2 2 1 x 1 x
Tan 1 aTan 3Tan a 3, b 2
x
2
b
2
1 3.
2
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1 x 2
1 2 x 2
17. Sum of all solutions of Tan
1
Cot 2
1 x 1, x 0 is
2 x 1 x 3
n n 2 3
n N then n3
3
Key: 3
1 x2
1 1 1 x
2
2
Sol: If 0 x 1 then Tan Tan
2x 2x 3
1 1 x 1 x2
2
Tan 3 x 2 3
2 x 3 2 x
1 1 x2 1 1 x
2
2
If 1 x 0 Tan Tan
2x 2x 3
1 1 x 1 1 x 1 x 2 1
2 2
2 Tan Tan
2 x 3 2 x 6 2 x 3
64 3 1
Sum of solutions = 2 3
n 6 n3 3
3 3
x 2025 y 2025 x 2024 y 2024
If cos x cos y cos z 3 then 2023
1 1 1
18. 2023 2022
x y x y
2022
Key: 3
1 1 1
Sol: cos x cos y cos z 3 x 1 y z
12025 12025 12024 12024
1 3
12023 12023 12022 12022
Key: 4
Sol: Since g is inverse of f , f g x x
f g f g x 1 g x 1 g x
5
log10 x 2 x 2
03. lim (where . is G.I.F =
x
1
r
x
r 0 2
1) 1 2) 0 3) 2 4) does not exist
Key: 1
log10 x 2
log x 2 x 2 log x 2 x
Sol: lim 10 1 lim 10 1 1 lim 1 0 1
x x 2 x x 2 x x 2
x x
sin 1 x .cos 1 x
1 1
1) –1 2) 0 3) 1/2 4) 1
Key: 4
sin 1 1 x .cos 1 1 x
Sol: We have f x
2 x 1 x
sin 1 1 0 h .cos 1 1 0 h sin 1 1 h .cos 1 1 h
(D) R lim f x lim f 0 h lim lim
x 0 h 0 h0
2 0 h 1 0 h h 0 2h 1 h
sin 1 1 h cos 1 1 h
lim lim
h0 1 h h0 2h
sin 1 1 h
in second limit put 1 h cos lim
h 0 1 h
cos 1 cos sin 1 1 h
lim lim lim sin 1 1.1 / 2 100 R 50
0
2 1 cos h 0 1 h 0 2sin / 2
dy dy dy dy
3
d 2 y dx d 2 x
2 . 2 0
dx dy dy
d2y dy
08. If 2x y1/5 y 1/5 and x 2 1 2
x Ky, K R then K ___
dx dx
1) –5 2) 5 3) 25 4) –25
Key: 3
5
Sol: y x x2 1
dy 5 y
dx x2 1
2 x a 1 a a 2 2 ax 1 0
2x 4x2 4
a
2
a x x2 1
y 5 x x2 1
1
5
y x x2 1
0 , x0
Statement-1: f x is continuous everywhere in 1 x 1
Statement-2: f x is differentiable everywhere in 1 x 1
1) Both statements are true
2) Both statements are false
3) Statement 1 is true, statement 2 is false
4) Statement 1 is false, statement 2 is true
Key: 1
Sol:
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
P x
, x2
10. Consider the function f x sin x 2 , where P x is a polynomial such that
7, x2
P x is always a constant and P 3 9 . If f x is continuous at x 2 , then P 4 is equal
to_______.
Key: 22
Sol: Therefore, P x is a polynomial of degree 2.
f 2 f 2 f 2
P x
lim 7
x 2 sin x 2
lim
x 2 ax b 7 2a b 7 ... 1
x2 sin x 2
P x x 2 ax b and P 3 9 (gives)
3 2 3a b 9 3a b 9 ... 2
Solving (1) and (2) we get, a 2, b 3
P 4 4 2 2 4 3 2 11 22
1
, x 2
11. If the function f x x is differentiable on R , then 48 a b is equal
ax 2b , x 2
2
to____.
Key: 15
1 1
, x2 2 , x 2
x x
Sol: f x ax 2b, 2 x 2 and f x 2ax, 2 x 2
2
1 1
, x 2 2, x 2
x x
1 a
f x is continuous at x 2 and –2, if 2b
2 4
Key: 5
x
3
x x
2
.... 3 x3
x3 ....
3! 3!
Sol: lim 1 lim 1
x 0 x 3
x 0 x 3
x 5
x x .... 1 x ...
3! 3! 5!
3 x3
x
3
....
3! 1 1 or 1
lim
x 0 x3 x 5
1 ...
3! 5!
3
x 2 ...
3 1 1
lim 2
x 0 1 x 3! 6
...
3! 5!
1
6 6 1 5
6
18. If graph of y f x is symmetric about the point 5, 0 and f 7 3 , then the value of
f 3 3 is______.
Key: 6
Sol: We have f 5 x f 5 x
or f 5 x f 5 x f 5 2 f 5 2
or f 3 f 7 3
f 3 3 6
2 2
Sol:
Clearly at x=0 f has local maximum
02. Which one of the following curves the parabola y 2 4ax at right angles
x
1) x 2 y 2 a 2 2) y e 2 a 3) y ax 4) x 2 4ay
Key: 4
Sol: Equation of Tangent is y y1 m x x1
2
03. For the function f x sin x 3x x 2
x where x 0,
2
Consider the following two statements
I: f is increasing in 0,
2
II: f 1 is decreasing in 0,
2
Among the above two statements
1) Neither I nor II is true 2) Both I and II are true 3) Only I is true 4) Only II is true
Key: 2
2 4x 2
Sol: f 1 x cos x 3 2 x 1 cos x 3 When x 0, , f 1 x 0 f x is increasing
2
Now f 1 x 0, when x 0, , f 1 x is decreasing
2
04. A point ‘P’ moves with an angular velocity 2 radians / sec on the circumference of a
circle with center ‘O’ and radius 2cm. PM is perpendicular to the diameter of the circle
such that POM . If the velocity of the Point M is zero, then values of ' ' are
x3 4
y x 2 c passes through 2, 0 , C
2 3
x3 4
y x2
3 3
4
y max
3
f 1 2 1 C 7
2 x3
f x 7x k
3
26
f 2 0 c
3
2 3 26
f x x 7x
3 3
1
f x
3
2 x 3 21x 26
1
f 1 2 21 26 15
3
09. A soft drink manufacturer wants to fabricate cylindrical cans for its products. The can is
to have a volume of 343.75cu.cm if r is the radius for can to require least amount of
material then 8 r 2 is equal to
Key: 1375
Sol: Let r be the radius and h be the height of the can,
343.75
We need to minimize ‘s’ so that V r 2 h 343.5 h
r2
343.75 687.5
S r 2 r 2 2 r 2 r
2
r 4
2
ds 687.5
0 r2 8 r 2 1375 cm 2
dr 4
10. If P1 and P2 are the lengths of the perpendiculars from origin on the tangent and normal to
2 2
the curve x 3 y 2/3 6 3
then the value of 4P12 P22 is equal to
Key: 36
dy
tan
dx p
the value of P 2 is
Key: 0
P x P x
Sol: Let 1 2 2 Let 2 1
x 0
x x 0 x
32a0 12a1 4
1
Solivng a0 , a1 1
4
1 4
P x x x3 x 2 P 2 0
4
2
12. The number of critical points of the function f x x 2 3 2 x 1
Key: 2
Sol: f 1 x 0 x 1, 2
Key: 40
Sol: x 3 y 2 215
3x 2y
3x 2 y 3 2
3 2
A.M G.M
3 x 2 y 410
5 3 2
14. If the function f x 2 x 3 9ax 2 12a 2 x 1 where a 0 attains its maximum and minimum at
Key: 2
Sol: f 1 x 0 x a , x 2a
f 11 a 0 f x will be maximum
at x a pa
Again f 11 2a 0
f x Will be maximum at x 2a
q 2a
Given
p2 q a 2
15. If f x is continuous and differentiable over 2,5 and 4 f 1 x 3 for all x in 2,5 then
7 f 1 x f 5 f 2 But 4 f 1 x 3
28 7 f 1 x 21 28 f 5 f 2 21
Maximum value 21
16. The value of k for which to length of the sub tangent to the curve xy k c 2 is constant is
Key: 1
Sol: Conceptual
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2 Page 169
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RPTM-04
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
1 1 2 tan x
01. If cos2 x 1 4tan 2 x dx k log c then 4k ____ .
1 2 tan x
Key: 1
e,2014 e , then the term independent of x in F x is ' k ' , then sum of digits of ' k ' is
___ .
Key: 7
2 1
Sol: F x log log x log x dx x log log x x log x c
Passes e,2014 e
c 2014
k 2 0 1 4 7
x2 x
03. If dx A log x 1 x 2 B C then A B _____ .
1 x 2 32
1 x 2
Key: 2
x2 1 1 dx 1 1
Sol: dx dx
1 x
2 32 1 x 2
1 x
2 32
x
put x tan sinh 1 x c
2
1 x
A 1, B 1
A B 2
sin x 2 tan x 1
04. If sin3 x cos3 x dx log 1 tan x log 1 tan x tan
2
x tan 1 c,
3
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18 2 3
dx 2x 1 2x 1
05. If a tan 1 b c , x 0 , where c is constant of
2 3 2
2
x x 1 x x 1
Key: 15
dx
Sol: I
2
1
2
3
x
2 4
1
Put x t
2
dt
I
2
2 3
t
4
3
Put t tan
2
4 3 2x 1 1 2x 1
I tan 1 c
9 3 3 x2 x 1
9
3a b 15
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1 1 x3 1
06. If 3
dx a log
3
b , then 3a _____ .
x 1 x 1 x 1
Key: 1
1
Sol: I dx
3
x 1 x
Put 1 x3 t 2
3 x 2 dx 2t dt
2 1 1 t 1 1 1 x3 1
I dt log c log c
3 1 t2 3 t 1 3 3
1 x 1
1
a 3a 1
3
5 tan x
07. If dx x b log sin x 2cos x k , then b _____ .
tan x 2
Key: 2
5tan x 5sin x
Sol: tan x 2 sin x 2cos x dx
dx
sin x 2cos x 2 cos x 2sin x dx
sin x 2cos x
1dx 2
cos x 2sin x dx
sin x 2cos x
x 2log sin x 2cos x c
b2
1) n 2) n! 3) (n+1)! 4) n.n!
KEY: 4
n
SOL: The given integrand is a prefect differential coefficient of (x r)
r 1
1
n
I ( x r ) ( n 1)! n ! n n !
r 1 0
1 1
02. If A x (2 x) dx, B x50 (1 x)50 dx, which of the following is true?
50 50
0 0
KEY: 3
1 1
SOL: Given A x50 (2 x)50 dx; B x50 (1 x)50 dx
0 0
/2
cos x sin 2 x
03. If A dx then dx is equal to
0
( x 2) 2 0
x 1
1 1 1 1 1 1
1) A 2) A 3) 1 A 4) A
2 2 2 2 2 2
1 1
A
2 2
2
dx
04. The value of
[ x] [sin x ] 4
, where [t] denotes the greatest integer less than or equal to
2
t, is
1 1 3 3
1) (7 5) 2) (7 5) 3) (4 3) 4) (4 3)
2 12 20 10
KEY: 3
/2
dx
SOL: I
/2
[ x ] [sin x ] 4
1 /2
dx dx
0
dx
1
dx 1 1 1
/ 2
2 1 4 1 1 1 4 0 0 0 4
1 0 4 1 2 2 (0 1) 4 (1 0) 5 2 1
1
3 9 3
(4 3)
5 20 20
1a 2a ....... n a 1
05. If lim a 1
for some positive real number a, then a is
n (n 1) [(na 1) ( na 2) ... (na n)] 60
equal to:
15 17
1) 7 2) 8 3) 4)
2 2
KEY: 1
SOL: Conceptual
2 n 4
1 22 n2
If U n 1 2 1 2 .... 1 2 , then lim(
2
06. U n ) n is equal to
n n n n
16 4 4 e2
1) 2) 3) 4)
e2 e e2 16
KEY: 4
1
log L 4 x log(1 x 2 ) dx
0
put 1 x t 2
2xdx dt
2
log L 2 log(t )dt 2[t log t t ]12 log L 2(2 log 2 1)
1
4 4 2
2(2log 2 1)
2 log log e2
Le e e
e e
16
/2
dx
07. The value of the integral
/2
(1 e )(sin 6 x cos 6 x)
x
1) 2 2) 0 3) 4)
2
KEY: 3
/2
dx
SOL: 2 I
/2
sin x cos 6 x
6
/2
dx
I
0
sin x cos 6 x
6
/2 /2
dx (1 tan 2 x ) sec 2 x
0
(sin x cos x )(sin x sin 2 x cos 2 x cos 4 x)
2 2 4
0
tan 4 x tan 2 x 1)
dx
1 r 2
t
0
4
t2 1
dt ( putting tan x t )
1 1
1 1
t2 t 2 dt
0 2 1
dt 0 1 2
t 1 2
t t 1
t
dy 1
1 y
2 putting t
t
y
tan 1 y ) .
2 2
1) 2) 3) 4)
4 3 2 6
KEY: 1
1 3sin x sin 3 x
SOL: dx
40 x
3 sin x 1 sin 3 x
40 x
dx
40 x
dy
3 1 sin t dt
4 2 4 0 t 3
(3x t )
3
3 1
4 2 4 2
1
(2)
4 2 4
/2 /4
09. If f : R R be continuous function satisfying
0
f (sin 2 x) sin xdx
0
f (cos 2 x) cos xdx
then
1) 3 2) 2 3) 3 4) 2
KEY: 2
/2
SOL: I1
0
f (sin 2 x ) sin xdx
/2
2I 0
f (sin 2 x )(sin x cos x ) dx
/4
2I 2
0
f (sin 2 x)(sin x cos x) dx
/4
I 2
0
f (sin 2 x )(cos( x ) ) dx
4
x
4
t
/4
I 2
0
f (cos 2 x) cos( x )dx
/4
10. Statement –I:
0
log(1 tan )d
8
log 2.
/2
Statement-II:
0
log sin d log 2
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
x
1 t
11. Let f ( x) g (t ) log e dt where g is a continuous odd function. If
0 1 t
/2 2
x 2 cos x
/ 2
f ( x ) x
1 e
dx then equal to _____ .
KEY: 2
SOL: clearly f ( x ) odd function
/2
x 2 cos x
I
/ 2
1 ex
/2
2I
/2
x 2 cos xdx
/2
2I 2
0
x 2 cos xdx
2
By integration by parts I 2
2
1
(1 x
7 k
) dx 10
1
12. Let rk 0
, k N . Then the value of 7(r is equal to ….
k 1)
1
(1 x
7 k 1 k 1
) dx
0
KEY: 65
SOL: I k 1.(1 x 7 )k dx
1 1
1 x 7 x 7 k (1 x 7 ) k 1 x 6 .xdx
k
0 0
1
7 k (1 x 7 )k 1 ((1 x 7 ) 1)dx
0
KEY: 0
5
SOL: let I ( x 1)( x 2)( x 3)( x 4)( x 5) dx
1
5
(6 x 1)(6 x 2)(6 x 3)(6 x 4)(6 x 5)dx
1
5
(5 x)(4 x )(3 x)(2 x)(1 x) dx
1
5
( x 1)( x 2)( x 3)( x 4)( x 5)dx
1
I I
2I 0
I 0
KEY: 1
SOL: Conceptual
2
8 7 cos x a
15. (7 8 cos x)
0
2
dx
7
Then a = ____ .
KEY: 1
/2 /2 /2
8 7 cos x cos x(7 8cos x) 8sin 2 x cos x 8sin 2 x
SOL:
0
(7 8cos x ) 2
dx
0
(7 8 cos x) 2
(7 cos x) 2
dx 0 (7 8cos x) (7 cos x)2 dx
KEY: 27
SOL: Conceptual
p a7
a 3
17. x (ax x ) 2 dx then p q = _____ .
3 2
0
2q
KEY: 20
/2
SOL: x a sin , dx 2a sin cos d , 2a sin10 cos 4
2 7
b
sin 3 (1 b x )
I dx............(ii)
a
sin 3 (a b x) sin 3 x
Adding (1) and (ii) ,we get
b
2 I 1dx b a 2
a
I 1
120 x 2 sin x cos x
3 0 sin 4 x cos4 x
19. dx is equal to …
KEY: 15
SOL: Conceptual
interval , x 8,8 ,
y
3
Q
2R
x
R
O p 3 8
1
2 3 2 2 4 sq.unit
The required area 2
02. The smaller area enclosed by y=f(x), when f(x) is a polynomial of least degree satisfying
1
f ( x) x 2 2
lim 1
3 e and the circle x y 2 above the x-axis is
x 0 x
3 3 3
1) 2) 3) 4)
2 5 2 5 2 5
Key: 3
A(1,1)
O B(1,0)
1
f(x) x
again lim 1 e
x 0 x3
a4 1 f(x) x 4
1
3
The required area 2 2 x 2 x 4 dx
2 5
0
03. The area bounded by the curve f x x sin x and its inverse function between the
ordinates x 0 to x 2 is
1) 4 Square units 2) 8 square units 3) 4 square units 4) 8 square units
Key: 4
Sol: Required area=4A, where A x sin x dx xdx
0 0
2 2
A cos cos0 2 squareunits.
2 2
04. If [x] is the greatest integer x , then area bounded by min {x [x], x [ x]} in the
interval [-2, 2] with x-axis
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1) 1 2) 2 3) 3/2 4) 0
Key: 1
Sol: The graph of f(x) = min{x [x], x [ x]}
2
1 1
min{x [x], x [ x]}dx Area of shaded region 4 2 1 2 1
2
2
1
2 1 0 2
1
05. A square ABCD is inscribed in a circle of radius 4. A point P moves inside the circle
such that d(P,AB) min(d(P,BC),d(P,CD),d(P,DA)) where d(P,AB) is the distance
of a point P from line AB. The area of region covered by moving point P is
1) 4 2) 8 3) 8 16 4)16
Key: 1
r 2
Sol: Shaded area of the required region= 4
4
A B
C D
06. If the area of the region bounded by the curves y x 2 1 , y=x and the pair of the Lines
x 2 y 2 2xy 5x 5y 4 0 is k units, then the area of the region bounded by the curve
1) k2 2) 2k 3) k/2 4) k+2
Key:
Sol: y x2 1 and y x 1 are inverse of each other.
y x2 1
yx
y x 1
x y 4 0
X
x y 10
1
2
07. The area bounded by the curve f(x) max.{4 x ,|x 2|,(x 2) 3 } for x [ 1, 4] and x-
axis is
45 23 59 53
1) sq units 2) sq units 3) sq units 4) sq units
4 4 4 4
Key: 1
Sol: y 4 x 2 is the parabola
1
y (x 2) 3 is the curve
Put x= b sin 3 t
y a cos3 t
09. If x-intercept of any tangent is 3 times x-coordinate of the point of tangency, then the
equation of the curve lying in the first quadrant, given that it passes through (1, 1) is
1 1 1
1) y 2) y 2 3) y 4) y x
x x x
Key: 3
dy
Sol: Equation of the tangent is Y y ( X x)
dx
dy y dy 1 dx
For Y 0, X 3x, We get y
dx 2x y 2 x
1 c
ln | y | ln | x | ln c y
2 x
1
y (c=1, as the curve passes through(1,1))
x
xdy y
10. The solution of the 1 dx is
x 2 y 2 x 2 y 2
1 y y2
1) y x cot( c x ) 2) cos x c 3) y x tan( c x ) 4) x tan(c x)
x x2
Key: 3
xdy y
Sol: 1 dx
x 2 y 2 x 2 y 2
xdy ydx y
dx d tan 1 dx
2 2 x
x y
y y
tan 1 x c tan(c x )
x x
xdx ydy a2 x2 y2
11. The solution of the is
xdy ydx x2 y 2
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y y
1) x 2 y 2 a sin tan 1 C 2) x 2 y 2 a cos tan 1 C
x x
y y
3) x 2 y 2 a tan sin 1 C 4) x 2 y 2 a cot sin 1 C
x x
Key: 1
Sol: Taking x r cos and y r sin , so that
rdr a2 r 2 dr
a2 r 2
r 2d r2 d
C sin 1 r / a tan 1 y / x
r
sin 1 c
a
r
sin( c)
a
y
r a sin(tan 1 c)
x
y
x 2 y 2 a sin(tan 1 c)
x
1 y2 x 2 1
12. Solution of the differential equation dx
2 y
dy 0 is
x ( x y ) 2 ( x y )
x xy xy xy xy
1) ln c 2) ce x / y 3) ln xy c 4) ce y / x
y x y x y x y x y
Key: 1
Sol: The given equation can be written as
dx dy x 2dy y 2dx
0
2
x y ( x y )
dy dx
dx dy y 2 x 2
or 0
x y 1 1 2
y x
dy dx
dx dy y 2 x 2
or 0
x y 1 1 2
x y
x xy
Integrating we get or ln c
y ( x y)
x xy
or ln c
y ( x y)
3
Equation of tangent to the curve y x , at point (-1,-1) is
y 1 3( x 1) y 3x 2
2 2 4 2
(3 x 2) x3 dx 3 x x 27
So, area= 2
2 x
4
4 sq. units
1 1
( x 0)( x 0) ( y 2)( y 2) x 0
x2 y 2 4 x 0 ....(i )
dy dy
2x 2 y 0 2 x 2 y
dx dx
Y
(0,2)
X' X
O
(0,2)
Y'
dy dy
x 2 y 2 4 x 2 x 2 y 0 2 xy ( x 2 y 2 4) 0
dx dx
dy
15. If y(x) is the solution of the differential equation 2 x( y 1) with y(0) =1 then
dx
lim y( x) , equals to __________.
x
Key: 1
dy dy
Sol: . 2 x( y 1) 2 xy 2 x
dx dx
2
Integrating factor= e
2xdx
ex
2 2 2 2
Solution of the d.e. is ye x 2 xe x dx c ye x e x c
2 2
Given y(0)=1 c 0. So ye x e x
dy
16. Let the solution y=y(x) of the differential equation y 1 4sin x satisfy y ( ) 1 .
dx
Then y 10 is equal to ___________.
2
Key: 7
Sol: Given, dy y 1 4sin x, Which is a linear differential equation.
dx
integrating factor
x x
Hence the solution is ye (1 4sin x )e dx …..(i)
e x 2e x ( sin x cos x) C
y( ) 1 i.e., at x , y 1
Now, y 10 1 2 sin cos 10
2 2 2
1 2(1) 10 7
17. If the solution y(x) of the given differential equation (e y 1)cos xdx e y sin xdy 0 passes
y
through the point ,0 , then the value of e 6 is equal to_______________.
2
Key: 3
Sol: Given,(e y 1) cos xdx e y sin xdy 0
dy
y 1
The curve passes 4sin x, the
through ,0
dx 2
C 2 e y sin x sin x 2
dx 1 x y 2
19. If , x(1) 1, then 5 x(2) is equal to __________.
dy y
Key: 5
Sol: We have,
1
dy
1
I .F . e y
e log y
Now, y
dx 1 x y 2 dx x 1 y 2
dy y dy y y
x 1 y2 x 1
dy C yC
y y2 y y
x 1 y 2 Cy
x(1) 1 1 1 1 C C 3
x 1 y 2 3 y
5 x(2) 5(1 4 6) 5
2 1
ln
x dx x2 1
e e 2ln| x| e
x2
1 1 2 x y2 2
So., t. x 2 x 2 3 dx x 2
3
ln | x | C
When,x 1, y 1
2 y 2 2
1 ln(1) C C 1 ln | x | 1
3 x2 3
y 2 (e) 2 2 e2
At x e, 1 y ( e ) 6 y 2 (e) 2e 2
2 3 3
e
21. If the solution of the curve y=y(x) of the differential equation
(1 y 2 )(1 loge x)dx xdy 0, x 0 passes through the point and (1,1) and
3
tan
y ( e) , then 2 is___________.
2
3
tan
2
Key: 3
Sol: . we have (1 y 2 )(1 log e x) dx xdy 0
dy (1 log e x ) dx
Integrating both sides, we get
1 y2 x
1 1 1
tan 1 y (1 log e x) 2 C , At (1,1), C C
2 4 2 4 2
3 3
tan tan 1 tan
1 3
y tan 1 (1 (log e x) 2 y (e) tan 4 2 2
4 2
4 2 1 tan tan 3 3
1 tan
4 2 2
So, 1 and 1 2 3
having dr’s 0,1,1 intersects. L1 and L2 at A and B respectively. Then the length of AB is
1) 5 2 2) 6 3 3) 2 2 4) 6 3
Key: 1
x y 1 z 1
Sol: L2 :
1 2 2
x 1 y 1 z 3
L1 :
1 4 3
B , 2 1, 2 1 , A 1, 4 2,3 3
A 4,14,12 B 4,9,7 ;
AB 02 52 52 5 2
x 1 z 2 x 2 y 1 2z 3
02. If the two lines L1 : , y 1 and L2 : perpendicular, then an angle
2 1 1 2
x 1 2 y z 1
between the lines L2 and L3 : is
2 3 1
2
1) cos 1 2) sec1 3) cos 1
29 29 2
4) cos 1
4 4 29 29
Key: 4
x 2 y 1 z 2
Sol: L1
1 0 1
3 1
z y
x 2 y 1 x
2 ,L : 2 z 1
L2 :
1 2 3
2 3 1
2 2
3 4
1 2 2 1
2 2
cos
9
5 5
4
3 2 2
cos 1
29 29 29
3
2
03. Statement-1: The point A(1,0,7) is the mirror image of the point B(1,6,3) in the line
x y 1 z 2
1 2 3
x y 1 z 2
Statement-2: The line: bisects the line segments joining
1 2 3
A 1, 0, 7 and B 1,6,3
1) Statement-1 is true, Statement -2 is false
2) Statement-1 is false, Statement -2 is true
3) Statement-1 is true, statement-2 is true: statement -2 is a correct explanation for
statement-1
4) Statement-1 is true, statement-2 is true: statement -2 is not a correct explanation for
statement-1
Key: 4
Sol: Statement-I Any point on line P= (t,2t+ 1,3t+2)
D.r ' s of PB t 1; 2t 5,3t 1
PB to the line
1 t 1 2t 5 3 3t 1 0
P 1,3,5
M .Pt of AB
11 6 0 7 3
, ,
2 2 2
04. If a,b,c be three distinct real numbers, non equal to one. If the vectors ai j k , i b j k
1 1 1
and i j ck are coplanar then ____
1 a 1 b 1 c
1) 0 2) 2 3) 1 4) 3
Key: 3
Sol: Given that vectors are coplanar
a 1 1
a b c 0 1 b 1 0
1 1 c
R1 R1 R2 and R2 R2 R2
a 1 1 b 0
0 b 1 1 c 0
1 1 c
07.
a. b c b. c a c. a b
c a .b a b .c b c .a
1) 3 2) a b c 3) a b c 4) 0
Key: 1
Sol: Conceptual
08. Statement1: The vectors a, b and c lie in the same plane if and only if a. b c 0
Statement 2: The vectors u and v are perpendicular if and only if u.v 0 and u v is
vector perpendicular to plane of u and v .
1) Statement 1 is true, statement 2 is false
2) Statement 1 is true, statement 2 is true, Statement 2 is correct explanation for statement
1
3) Statement 1 is false, statement 2 is false.
4) Statement 1 is true, statement 2 is true, Statement 2 is a not correct explanation for
statement 1
Key: 2
Sol: The vectors a , b and c lie in the same plane a, b and c are coplanar
We know, the necessary and sufficient conditions for three vectors to be coplanar is that
a, b, c 0 a. b c i 0
Key: 3
Sol: Conceptual
x 1 y 2 z 3
1 2 3 0
3 1 2
x 1 7 y 2 7 z 3 7 0
x 1 y 2 z 3 0 x y z 0
P 2121 1
2 2 1 5
PQ
111 3
25
3 PQ 3
2
25
3
x 1 y 6 z 5
11. Let P be a plane containing the line and parallel to the line
3 4 2
x3 y 2 z 6
If the point 1, 1, lies on the plane P, then the value of | 5 | is equal
4 3 7
to __.
Key: 38
x 1 y 6 z 5
Sol: Equation of plane is 3 4 2 0
4 3 7
0 6 5
1, 1, 3 4 2 0
4 3 7
5 21 8 5 9 16 0
Key: 3
Sol: Point of intersection
x 1 y 3 z 1
t;
2 4 3
x 3 y 2 z 1
s
2 6
2t 1, 4t 3,3t 1 2 s 3, 6s 2, s 1
1 1
By solving, we get t , s , 7
2 2
1
a.b a b cos cos 60
2
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15. If b c c a 3c then b c c a a b _____ .
Key: 9
Sol: b c a c 3c a b c 3
2
then b c c a a b a b c 9
2 2 2 2 2
16. Let a and b be two vectors such that , a b a 2b , a b 3 and a b 75. then a is
equal to _____ .
Key: 14
2 2 2
Sol: ab a 2 b
2 2 2 2 2
a b 2a.b a 2 b b 6
2 2 2 2 2
a b a b a.b a 14
17. Let a 2i j 2k and b i j. If c is a vector such that a.c | c |,| c a | 2 2 and the angle
between a b and c is 300 , then a b c ____ .
Key: 3
i j k
Sol: a b 2 1 2 i 0 2 j 0 2 k 2 1
1 1 0
a b 3, c a 2 2, a 3
2 2
c a 2 ca 8
2
c 9 2 c 8 0
c 1
2
0 c 1
a b, c 30 0
02. Let S be the set of all integer solutions x, y , z of the system of equations
x 2 y 5 z 0, 2 x 4 y z 0, 7 x 14 y 9 z 0 . Such that 15 x 2 y 2 z 2 150 .
Then the number of elements in the set S is equal to
1) 4 2) 6 3) 8 4) 2
Key: 3
Sol: Given system equations
x 2 y 5 z 0 (1)
2 x 4 y z 0 (2)
7 x 14 y 9 z 0 (3)
solve (1), (2) z 0
Substitute z=0 in (1) we get x 2 y
15 x 2 y 2 z 2 150
15 4 y 2 y 2 150
3 y 2 30
x 2 y, z 0
y 2, 3, 4, 5
8 points
If AK O for some value of K. I A I A A2 ... AK 1 , where A is nil potent
P
03.
with Index K. Then P
1) - 1 2) - 2 3) - 3 4) 0
Key: 1
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Sol: Let Let B I A A ... A 2 n 1
B I A I A A2 .... A K 1
1
1 0 0 1 0 0
05. If the matrix A 0 2 0 satisfy the equation A20 A19 A 0 4 0 for some
3 0 1 0 0 1
real number , . Then = _________
Key: 4
1 0 0 1 0 0 1 0 0
Sol: A2 0 4 0 A3 0 23 0 , A4 0 24 0
0 0 1 3 0 1 0 0 1
1 0 0
A A A 0 4 0
20 19
0 0 1
1 0 0 1 0 0
0 2 2
20 19
0 0 4 0
3 3 0 1 0 0 1
4
1 x 5
0
10 x
2 11x 10 5 0
A2 11A 10 5 I 0
(10 5 ) A1 A 111 ( A1 A I )
1 11
Compare we get ,
10 5 10 5
1 11
, , 3
5 5
1 1 2 3
07. Let X 1 ; A 0 1 6 for k is even naturalnumber. If X 1 AK X 33 then K=
1 0 0 1
____
Key: 10
Sol: Conceptual
1 2
08. Let A be matrix such that A. is a scalar matrix and 3 A 108 then sum of
0 3
elements of principal diagonal of A2 is ____
Key: 40
1 2 k 0
Sol: A scalar matrix 0 t
0 3
1 2 k 0
A
0 3 0 k
1
k 0 1 2
A
0 k 0 3
2 2
1 k k
k 0 3 3
A
0 k 1 0 k
0
3 3
3 A 10 8
3k 2k
1 08
0 k
k 6
1 Tan 2
1 2
I 2 A
1
1 Tan 2 Tan 1
2 2
cos sin
I 2 A I 2 A
1
sin cos
b c
a b
10. If a, b, C and a c 0 Then __________
a b c
a b
Key: 0
b c
Sol: a c 0
a b
a b b a c a b c 0
Dividing by a b c
2 B 2 K then K _________
Key: 16
B A 4 , 2 or 4 , 4 2
2
Sol: B adj A ,
2 1
12. Let A if B I 5C1 (adjA) 5C2 (adjA) ...... 5C5 ( adjA) . Then the sum of all
2 5
0 2
elements of the matrix B = k then k _____________
Key: 7
2 1 2 1
Sol: A adj A
0 2 0 2
5
1 1 1 5
I adjA
5
0 1 0 1
a b c
13. A b c a where a, b, c are real positive number abc = 1 and AT A I then the
c a b
value of a 3 b3 c3 ___
Key: 4
Sol: AT A I
a 2 b 2 c 2 1, ab bc ca 0
a 3 b3 c 3 a b c (a 2 b 2 c 2 ab bc ca) 3abc
a 3 b3 c 3 a b c 3
( a b c ) 2 1 2(0) 1
a b c 1
a 3 b3 c3 1 3 4
y nx
2
a 2 (1 n2 )
It form rhombus
4
02. If x
i 1
2
i yi2 2 x1 x3 2 x2 x4 2 y2 y3 2 y1 y4 the points
x1 , y1 , x3 , y3 , x2 , y2 and x4 , y4 are
1) Vertices of a rectangle 2) Collinear
3) Vertices of trapezium 4) Vertices of a parallelogram
Key: 1
4
Sol: x
i 1
2
1 y12 2 x1 x3 2 x2 x4 2 y2 y3 2 y1 y4
x1 x3 x2 x4 y2 y3 y1 y4 0
2 2 2 2
x1 x3 , x2 x4 , y2 y3 , y1 y6
is angle between (1) & (2)
4
a cos b sin
cos
4 a 2 b2 1
a b p
cos sin p 0
sin cos 0
a cos b sin 1
1 1
from(3) a2 b2 2
a2 b2 2
r4 3 3 3 2 3 2 3 2
a r b r c r d r 60
16 4 4 4 4
6
OA.OB.OC.OD r1r2 r3r4 96
1 / 16
05. The reflection of the pair of straight lines x 2 y 2 2 x 1 0 in the point (1, -1) is
1) x 2 y 2 6 x 4 y 5 0 2) x 2 y 2 6 x 4 y 4 0
3) x 2 y 2 6 x 4 y 5 0 4) x 2 y 2 6 x 4 y 4 0
Key: 1
Sol: Given pair of straight lines x 2 y 2 2 x 1 0 (1)
x2 y2 6x 4 y 5 0
1 1 25
max PQ.. CR 6.25
2 2 4
given max
No point satisfied
07. The number of integral values of a for which the point P a 2 , a lies in the region
corresponding to the acute angle between the lines 2 y x and 4 y x is_____ .
Key: 1
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Sol: a 2
4a a 2a 0
2
a 2 ( a 2)(a 4) 0
2a4
a3
08. If the pair of lines 6 x 2 axy 3 y 2 24 x 3 y 0 intersect on x- axis then the value
of 20 is _______ .
Key: 6
Sol: 6 x 2 2 xy 3 y 2 24 x 3 y 0
y0
6 x 2 24 x 0
0
2 y 2 4.6 0
24
x 6 y 3 0
Put y 0
3
2,
2
3
20 20. 24 30 24 6
2
09. n1 is the number of points on the line 3x 4 y 5 which is at distance 1 sin 2 units
from (2,3) and n2 denotes the no of points on the line 3x 4 y 5 which is at distance of
sec2 2cosec 2 unit from the (1,3) then the sum of roots equation n2 x 2 6 x n1 0 is
_.
Key: 3
13
1 sin 2
5
x1 0
3 12 5
er distance from (1,3) to the line 3 x 4 y 5 0 is 2
5
sec 2 2cos ec 2 3 2 2
Number of points 2
n2 2
nL n 2 6 x n1 0
2n 2 6 x 0 0
x 2 3x 0
x 0,3
10. The base of an isosceles triangle is the intercept made by the line x 2 y 4 with the
coordinate axis. If the equations of the equal sides be x 4 and y mx c then the value
of 8m c is _____ .
Key: 8
Sol: CA CB
8m 6
8m c 8
11. The slope of one of lines given by ax 2 2hxy by 2 0 be square of the slope of the
other, if ab(a b) abh h3 0 then is equal to ______ .
Key: 2
Sol: ax 2 2hxy by 2 0
a
m3
b
8h3
m m 3m (m m ) 3
3 6 3 2
a a 2 6ah 8h3
3 0
b b2 b 2 b
ab 2 a 2b 6abh 8h3 0
6, 8
2
12. If A (1,1) B (2,3), C (-1,1) are three points. If P is a point such that the area of the
quadrilateral PABC is 3 sq. units and locus of P is y 2 y 0 then ____.
Key: 6
Sol: p ( x, y ) A(1,1) B (2,3)C ( 1,1) are vertices
Area =3
1 x2 2
3
2 y 3 0
( y 3) 3
( y 3)2 9
y2 6 y 0 y2 y
6
B C
1) 2 2 3 2) 4 2 3 3) 4 4 3 4) 6 4 3
Key: 4
Sol: a si de 2 3 2
3
2
area 2 32 64 3
4
02. Let ABCD be a quadrilateral with area 18, side AB parallel to the side CD & AB = 2CD.
Let AD be perpendicular to AB and CD. If a circle is drawn inside the quadrilateral
ABCD touching all the sides. Then its radius is
1) 3 2) 2 3) 3/2 4) 1
Key: 2
Sol: ABCD a 2a 2r 18 ar 6
2r 2 ar 4ar
r r2
4r dt
2
03. The point ‘P’ on the parabola y 2 16x for which |PR – PQ| is maximum, where
R = (-4, 0), Q = (0, 4) is ........
Key: 1
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Sol: |PR PQ| is maximum when P is the point of intersection of parabola and line QR. Here it
becomes a Tangent. So P is point of contact of tangent QR
04. Let P and Q be distinct points on the parabola y 2 2x such that a circle with PQ as
diameter passes through the vertex O of the parabola. If P lies in the first quadrant and the
area of triangle OPQ is 3 2 , then P can be ……..
1) 4, 2 2
2) 9, 3 2 1 1
3) ,
4 2
4) (2, 2)
Key: 1
16a 8a
Sol: P at 2 , 2at , Q 2
t t
a 4 16
1 1
OPQ OP. OQ at t 2 4.
2 2 t t2
4 3 2 P 1, 2 ,Q 4, 2 2
05. Two circles one of radius 8 and other of radius 18, are tangent (i.e., they intersect at
exactly one point). There are two lines each of which is tangent to both circles, as shown
in the diagram. The distance from the point of intersection of these lines to the centre of
the circle with radius 8, is equal to
Key: 2
18 8
Sol: sin
x 26 x
104
18x 8x 26 8 10x 26 8 x 20.8
5
06. If two distinct chords of a parabola y 2 4kx drawn from the point (k, 2k) are bisected by
the line x + y – 1 = 0, then the length of the latus rectum can be:
1) 4 2) 3 3) 5 4) 6
Key: 2
1
2
4k 2k 2k 2k 2 2k
1 2k 2k 2 2k 1 k 0
2
k 1 k 0 k k 1 0
0 k 1
0 4k 4
Latus rectum 0, 4
07. In a right angled triangle BC = 5, AB= 4, AC = 3. Let S be the circum circle. Let S1 be
the circle touching both sides AB and AC and circle S internally. Let S2 be the circle
touching the produced sides AB and AC of le ABC, and touching the circle S externally
If r1 , r2 are radii of circles S1 and S2 respectively then r1 r2 =
1) 12 2) 20 3) 15 4) 24
Key: 4
S2 touches S externally r2 2 r2 3 / 2 r2 5 / 2
2 2 2
08. A circle passing through the vertex C of a rectangle ABCD and touches its sides AB and
AD at M and N respectively. If lar distance from C to the line segment MN is equal to
5 then area of rectangle ABCD is K then the digit in unit place of K is
1) 2 2) 1 3) 5 4) 3
Key: 3
Sol: Let r be the radius of the circle and A = (0, 0) AB is along x-axis and AD is along
y-axis.
Equation of circle is x r y r r 2 ...... i
2 2
pqr
5 p q r 50....... 2
2
2
Key: 9
38 k
Sol: c 1, 2 1 k 6, 16
5
1
11. Locus of a point P which divides all chords of slope of parabola x 2 4y in the ratio
2
8
1:2 internally is another parabola with vertex , and the length of latus rectum is
9
, then the value of is ………….
3
Key: 5
t1 t 2 1
Sol: Slope of AB t1 t 2 1
2 2
9, 2
924
5
3 3
12. Let the centre of a circle, passing through the point (0, 0), (1, 0) and touching the circle
x 2 y 2 9, be (h, k). Then for all possible values of the coordinates of the centre (h, k),
4 h 2 k 2 is equal to
Key: 9
Sol:
x h y k h2 k2
2 2
x 2 y 2 2hx 2ky 0
OP
OC
2
2
1 3
k
2
2 2
1 1
possible coordinate of c h, k , 2 , 2
2 2
1 9
4 h2 k2 4 2 4 9
4 4
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13. If one of the diameter of the circle, given by the equation x 2 y 2 4x 6y 12 0 is a
chord of circle ‘S’, whose centre is at (-3, 2). Then radius of circle ‘S’ is ‘r’. Then r 2 =
Key: 75
Sol: Conceptual
14. Let A and B be two distinct points on the parabola y 2 4x . If the axis of the parabola
touches a circle of radius of one unit having AB as its diameter. Then the slope of the
joining A and B be can be ….
Key: 2
2 2
Sol: Slope = 2
r 1
Key: 40
Sol: Chord passes through the centre of the circle, length of the chord = diameter
18. The length of double ordinate of parabola y 2 8x which subtends an angle 600 at vertex
is ‘l’. Then 3 l is ………
Key: 48
x2
03. Let the hyperbola H : 2 y 2 1 and the ellipse E: 3x2 + 4y2 = 12 be such that the length
a
of latus rectum of H is equal to the length of latus rectum of E. If eH and eE are the
eccentricities of H and E, respectively, then the value of 12(eH2 eE2 ) is equal to________
Key: 42
x2 y2 x2 y2
Sol: 1 1
a2 1 4 3
1 3 1
eH 1 2
eH 1
a 4 2
2 23
.R. R 3
a 2
2
3
a
2
a
3
9 13
eH 1
4 2
2 13 1 12 14
12(eH eE2 ) 12 42
4 4 4
x2 y 2
04. Let C be the largest circle centered at (2, 0) and inscribed in the ellipse 1. If
36 16
(1, ) lies on C, then 10 2 is equal to_______
Key: 118
x2 y2
Sol: Equation of normal of ellipse 1 at any point P (6 cos , 4 sin ) is
36 16
3sec x 2cosec y 10 this normal is also the normal of the circle passing through the
320
So the largest radius of circle r
5
64
So the equation of circle ( x 2) 2 y 2
5
10 2 118
3kx ky 4 3k 2
x2 y 2
4
4 12
x2 y2
1 Hyperbola
16 48
48
e2 1
16
e=2
06. Consider ellipses Ek: kx2 + k2y2 = 1, k = 1, 2, …, 20. Let Ck be the circle which touches
the four chords joining the end points (one on minor axis and another on major axis) of
20
1
the ellipse Ek. If rk is the radius of the circle Ck, then the value of 2 is_______.
k 1 rk
Key: 3080
x cos y sin
Equation of tangent at P is 1
6 2
Equation of tangent at ( , ) is y ( x ) or y 2 x 2
or x y 2 2
Comparing Eq. (1) and Eq. (2), we get
cos sin 1 cos 2 sin 2 1 1
2 or
6 2 2 2
6 2 2
6 2 2 2 2
2
6 4 4 5 2 5 is equal to
1) 13 2) 18 3) 23 4) 28
Key: 2
Sol: 2 2, 2 2
6 4 4 5 2 5
4 2 1 5 2 4 5
2 2 1 5 2 2 5
2 2
2 4 4 1 5 10 2 4 4 5
3 2 1 5 2 4 19
3 2 5 2 5 3 17
3 2 3 15 3 21 3 1 21 18
1
02. For all z C on the curve c1 : z 4 , let the locus of the point z be the curve c2 then
z
1) The curves c1 and c2 intersects at 4 points 2) The curves c1 lies inside c2
3) The curves c1 and c2 intersect at 2 points 4) The curves c2 lies inside c1
Key: 1
1 1
Sol: w z 4 Cis Cis
z 4
17 15
w x iy Cos i Sin
4 4
2
x y2
Locus of w is 2
2
1
17 15
4 4
Locus of z is x 2 y 2 16
So intersect at 4 points.
z z z z
04. If the set Re : z C ,Re z 3 is equal to the interval , then
2 3 z 5 z
8
1) 12 2) 9 3) 10 4) 8
Key: 4
zzzz
Sol: z1 , z 3 i y
2 3z 5 z
z 3 iy
2iy 9 y 2
z1 Re z1 3
8 8 iy
9 y2 2 y2 1 10
Re z1 Re z1 1
8 1 y 8 1 y
2 2
10 1 9
1 y 2 1, 0,10 Re z1 ,
1 y 2
8 8
1 9
,
8 8
9 1
8 8 8
8 8
x 1 x 4 x 3 x 2 x 1 0
x 5 1 roots 1, , , ,
1 0
1 2026 2026 2026 2026 0
18
2π 2π
1+sin +icos
06. The value of 9 9 is
2π 2π
1+sin -icos
9 9
1) -1 2) 0 3) 1 4) 2
Key: 1
18 18
5 5 5 5
1 Cos i Sin Cos i Sin
18 18 36 36
Sol: 5 5 5 5 Cos5 i Sin5 1
1 Cos iSin Cos iSin
18 18 36 36
07. Let z and w be complex numbers such that z w and arg z denotes the principal
argument of z.
Statement 1: If arg z arg w then z w
Statement 2: z w , implies arg z arg w
1) Statement 1 is true, statement 2 is false
2) Statement 1 is true, statement 2 is true,Statement 2 is a correct explanation for
statement 1
3) Statement 1 is true, statement 2 is true, Statement 2 is not a correct explanation for
statement 1
4) Statement 1 is false, statement 2 is true.
Key: 1
Sol: z w r
z r Cis1, w rCis 2
1 2 3 4 0
1
log12 1 2 3
4
log 2 4 4 log 22 log 22 1
x3 x 6 x9 x 4 x7 x 2 x 5 x8
09. If a 1 ...., b x ... and c .... then
3 6 9 4 7 2 5 8
a 3 b 3 c 3 3abc ____ .
Key: 1
Sol: a b c ex
a bw cw2 e wx
2
a bw2 cw e w x
2
a 3 b3 c 3 3abc e x wx w x eo 1
10. If cosα+cosβ+cosγ = 0=sinα+sinβ+sinγ then
x2 y2 z2
3
yz zx xy
1 x2
The least value of n N such that 1 i 1 i 2Sin
n n 1
11. is =------
2x
Key: 4
1 x2 1 1
Sol: x 1
2x 2 x
1 i . 1 i 2.Sin1 1
n n
n n
1 i 2 1 i
. 1
1 i 2 1 i
Least value of n is 4
1 1 1
12. If w 1 is a cube root of unity satisfying 2w2 and
aw bw cw
1 1 1 1 1 1
2w then ____.
aw bw cw
2 2 2
a 1 b 1 c 1
Key: 2
1 1 1 2
Sol:
a x b x c x x
x 1, w, w2
1 1 1
2
a 1 b 1 c 1
13. If z1 and z2 are two non-zero complex numbers such that z1 z2 z1 z2 then
arg z1 arg z2 0
14. If z 4 3 then maximum value of z 1 is _______.
Key: 6
Sol: z 1 z 4 3 z 4 3
33
6
15. If z1 , z2 and z3 , z4 are two pairs of conjugate complex numbers then
z z
arg 1 arg 2 _ .
z4 z3
Key: 0
z z z z1
Sol: z1 z2 , z 3 z4 arg 1 arg 2 arg 1 arg 0
z4 z3 z4 z4
1 i 3
If a and b are real numbers such that 2 a b where
4
16. then a b
2
Key: 9
2 2 4 2 4
4 4 2
Sol:
2 4 2 9 a b
2
ab 099
1. The parabolas; ax 2 2bx cy 0 and dx 2 2ex fy 0 intersect on the line y=1. If a ,b,
c, d, e, f are positive real numbers and a, b, c are in G.P., then
d e f
1) d, e, f are in A.P. 2) , , are in G.P.
a b c
d e f
3) , , are in A.P 4) d, e, f are in G.P.
a b c
Key: 3
Sol: Given ax 2 2bx c 0
Since a,b,c in GP
2
So, b2 ac ax 2 2 acx c 0 x a c 0
c
x -------------- (1)
a
c c
Now, dx 2 2ex f 0 d 2e f 0
a a
dc c d f 1
f 2e 2e
a a a c ac
d f 2e d e f
as b ae , , are in A.P.
a c b a b c
1 1 1 1
1) 2)
1 cos 1 sin 1 cos 1 sin
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1 1 1 1
3) 4)
1 cos 1 sin 1 cos 1 sin
Key: 3
Sol: x 2 sin x sin .cos 1 cos 0
x cos x sin 1 0
cos , cosec
1
n 0
n
1 cos cos 2 ....
1 cos
1
1 sin sin 2 sin 3 ....
1 sin
n 1 n n 1n 1 1
n
n0
n
n 0
1 cos 1 sin
n 0
3. If x 2 px 1 is a factor of ax 3 bx c , then
Key: 3
Sol: Since, x 2 px 1 is a factor ax3 bx c , hence we can assume that zeros of
1 1
4. Let , are roots of the equation x 2 20 4 x 5 2 0 and 8 8 k then 2K=
1) 10 2) 50 3) 100 4) 160
Key: 3
Sol: x 2 51/2 20 x
1/4
x 51/2 20.x 2
2 2
x4 5 2 5x2 2 5x2
x 4 5 x8 25
Statement-1: p 2
q b 2 ac 0 and
Statement-2: b pa or c qa
Key: 2
Sol: As a, b, c, p, q R and the two given equations have exactly one common root
Either both equations have real roots
Or both equations have imaginary roots
Either D1 0 and D2 0 or D1 0 and D2 0
p 2 q 0 and b2 ac 0
Or p 2 q 0 and b2 ac 0 p 2 q b 2 ac 0
Statement 1 is true.
c
Also we have q and
a
q qa
a 2
/ c c
qa
As 1 or -1 2 1 1 or c qa
c
Again as exactly one root is common, and 1
1 2b
2 p b ap
a
Statement 2 is correct.
6. If a b c d then the roots of x a x c 2 x b x d 0 are
Key: 2
Sol: f a 2 a b a d is + ve; f b b a b c
f d d a d c is +ve
1) 7 23 2) 9 4 5 3) 7 23 4) 9 4 5
Key: 2
Sol: x 2 5 x 6 x 7 0 has three solutions
x 2 5 x 6 x 7
f x x2 5x 6
x 2 5 x 6 x 7 0
b2 4ac 0
5 4 6 7 0
2
18
2
15 4
9 80 9 4 5
2
H1 2 H 20 3
8. If H1 , H 2 ,....H 20 harmonic means between 2 and 3, then
H1 2 H 20 3
1) 20 2) 21 3) 40 4) 38
Key: 3
Sol: 2, H1 , H 2 ......H 20 ,3 are in H.P
1 1 1 1
H1 2 H 20 3 2 H1 3 H 20
H1 2 H 20 3 1 1 1
1
2 H1 3 H 20
y
1) x x y z z 2) x y 2 z 3) x y z 0 4) x y z 1
Key: 1
log xy log yz log zx log x log y log z log x log y log z
Sol: xx y y zz
1 1 1 1 1 1 1 1 1 1 1 1
x y y z z x x y z x y z
SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
Key: 40
2 4 4
Sol: x 1 1
2
n 1 is a prefect square
8,15,24,35, 48,63,80,99...... -------------(8)
Sol: Let A
a 2
3a 1 b 2 3b 1 c 2 3c 1
abc
a 3a 1 b 3b 1 c 2 3c 1
2 2
1 1 1
a 3 b 3 c 3
a b c a b c
12. Given a, b, c are positive integers forming an increasing G.P, b-a is a prefect square of a
natural number, and log 6 a log 6 b log 6 c 6 . Then the value of
a b c 105 _____ .
Key: 216
Sol: a,b,c are in G.P. b2 ac
log 6 a log 6 b log 6 c 6
abc 66 , b3 66 , b 62 36
ac 36 36 24 34 ; b a N 2 ;36 a N 2
A is factor of 2434 a 27 is possible value
36 27 9 3 a 27
2
b 36, c 48 a b c 111
7 9 13 19
13. S ......... Then 32S=_______
5 52 53 54
Key: 61
7 9 13 19
Sol: S ....... (1)
5 52 53 54
1 7 9 13 19
s 2 3 4 5 ..... (2)
5 5 5 5 5
Eq (1) and ( 2)
4 7 2 4 6
.s 2 3 4 ....
5 5 5 5 5
7 1 2 3
s 1 2 ....
4 10 5 5
2
7 1 1 7 1 25 61
s 1 , s s 32s 61
4 10 5 4 10 16 32
3
= nC4 n n 5C2 n n 5 n . Substitute n=10.
2
5. In the coming IPL – 2025 cricket tournament, there will be 10 teams, which are divided
equally in to two groups. Teams of each group will play a match against each other.
From each group 3 top teams will qualify for quarter finals. In this round each team will
play against others once. Four top teams of this round will quality for semi - finals where
each team will play against the others once. Two top teams of this round will go to the
finals. Where they will play the best of three matches, then the minimum number of
matches in the IPL 2025 is ____
65
For 6 circle we have 6C2 2 2 30
2 1
Case (ii )
For straight lines
Two straight lines intersect at one point
r1 r2 r3 0 is
1 1 2 1
1) 2) 3) 4)
18 9 9 36
Key: 3
Sol: Given r1 r2 r3 0 .
Possibilities for r1 , r2 , r3 are
1, 2,6,1,2,3,4,5,6,4,5,3,2, 4,3,2, 4,6,5,1,3,5,1,6
8 cases
Number of ways of selecting r1 , r2 , r3 8 3!
n s 6 6 6
8 3! 2
Required Probability
666 9
2. If X is a random variable with the following distribution
X xi a b
P X xi p q
3) pq a b 4) pq a b
2 2
1) ap bq 2) ap bq
Key: 3
Sol: Mean of X xi p X xi ap bq
Variance of X 2 xi2 p X xi 2 a 2 p b 2 q ap bq
2
a 2 p 1 p b 2 q 1 q 2abpq pq a 2 b 2 2ab
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3. A tosses an unbiased coin 3 times. If he gets a head all the 3 times he is to get a prize of
Rs. 160/- along with his entry fee of Rs.16/- otherwise he loses his entry fee. The
mathematical expectation of his profit is
1) 20 2) 14 3) 6 4) 12
Key: 3
Sol: E X xi p X xi
3
Statement – I: The probability that the system of equations has unique solution is
8
Statement – II: The probability that the system of equations has a solution is 1
1) Both the statements are true and the statement -2 is the correct explanation of
statement-1
2) Both the statements are true and the statement -2 is not the correct explanation of
statement-1
3) The statement-1 true but statement -2 is false
4) The statement-1 false but statement -2 is true
Key: 2
Sol: I : 0 ad bc 0 ad 1and bc 0
OR ad 0 and bc 1
6 3
Probability is
24 8
II : Either 0 or 0, system always has a solution
24
Probability= 4 1
2
5. A and B stand in a ring with 10 other persons. If the arrangement of the 12 persons is at
random. What is the probability that there are exactly 3 persons between A and B.
7 5 2 1
1) 2) 3) 4)
12 12 11 11
Frequency(f) 4 24 28 8
be 5. If m and 2 are respectively the mean deviation about the mean and the variance of
3
the data, then is equal to ________
m 2
Key: 8
4 72 140 7 72
Sol: Given, mean=5= x 320 5 288 7 2 32 16
64
4 4 24 2 28 0 16 2 8 4 8
M .D. x
80
5
4 16 24 4 0 16 4 8 16 352
80 80
3 3 16
8
m 2
128 352
80 80
9. A fair die is tossed repeatedly until a six is obtained. Let X denote the number of tosses
bc
required and let a P X 3 , b P X 3 and c P X 6 / X 3 . Then is
a
equal to______
Key: 12
5 5 1 25
Sol: 12 a P X 3
6 6 6 216
b P X 3
3 4
5 5 1 5 1 5 1 25
= ......
6 6 6 6 6 6 6 36
5 6 5
5 1 5 1 5
P X 6 . . ......
6 6 6 6 6
3 4 3
5 1 5 1 5
P X 3 . . ........
6 6 6 6 6
10. If the variance of 10 natural numbers 1,1,1,…..,1, k is less than 10, then the maximum
possible value of k is ______
Key: 11
x x
2 2
2
9 k2 9 k
Sol: We have, 2
10 10 10
n n
1000 10 10
k 1
2
k 1 k 11
9 3
Maximum value of k is 11
11. An electric instrument consists of two units. Each unit must function independently for
the instrument to operate. The probability that the first unit functions is 0.9 and that of the
second unit is 0.8. The instrument is switched on and it fails to operate. If the probability
that only the first unit failed and second unit it functioning is p, then 98 p is equal to
______
Key: 28
Sol: E1 first unit is functioning , E2 sec ond unit is functioning
P E1 0.9, P E2 0.8; P E1 0.1, P E2 0.2
P E1 .P E2 P E1 .P E2 P E1 .P E2 0.1 0.2 0.9 0.2 0.1 0.8
0.8 0.1 8 8
P , 98 P 98 28
0.1 0.2 0.9 0.2 0.1 0.8 28 28
3 3 3
1) 2) 3 3) 4) 3 3
4 2
Key: 2
SinA Sin A C
5. Let , where A, B, C are angles of a triangle ABC. If the lengths of the
SinB Sin C B
3) b 2 a 2 a 2 c 2 4) a 2 , b 2 , c 2 are in AP
Key: 1
sin B C sin A C
Sol: sin 2 C sin 2 B Sin 2 A sin 2 C
sin A C sin C B
1)
p 2 q 2 cos
2) 2
p2 q2
3)
p 2
q 2 sin
4)
p 2
q 2 sin
p cos q sin p cos q 2 sin p cos q sin p cos q sin
2
Key: 4
Sol: Applying sin rule
AB
BD
p2 q2
AB
p 2 q 2 sin
sin sin sin cos cos sin p cos q sin
1) 2 2) 2 3) -1 4) -2
Key: 4