1. PFMC - Fuel Cell - ToT For Submarines

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AIP Technologies/Stored Energy

Devices
N
M
M PATRI R
Naval Materials Research Laboratory
Ambernath-421506 L
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Air independent propulsion (AIP)
for Diesel-electric class of
Submarines
Time for resurfacing
Snorkeling mode of
Battery charging by submarine – most
Diesel generators vulnerable phase

Resurfaced for
Conventional battery charging
mode (Snorkeling mode)
Underwater
propulsion on
Battery
Extending Time for resurfacing

AIP mode

Battery charging by Underwater propulsion on Resurfaced for


Diesel generators AIP battery charging

AIP : Additional power plant added to the Diesel-Electric


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submarine for extending the underwater endurance
The AIP ……..
It is an non-nuclear alternative
Longer endurance under submerged
condition by supplementing the lead acid
batteries
Provides higher stealth (acoustic silence)
characteristics underwater
Reduces the risk of exposure by avoiding
frequent surfacing
How AIP works……..
Flue management /
containment system

Fuel
storage

Electric load

Oxidant
(O2) storage

Objective :- to preserve battery power while underwater


Comparison of global AIP technologies

• Closed cycle Diesel (CCD) – Russia – (*****)


– Noisy, discarded by the modern Navy
• Steam alternator MESMA – France (*****)
– Noisy, exported to Pakistan Navy
• Sterling engine – Sweden {*****}
– Adopted in Kockum class and technology exported to China
• Fuel cell system {*****}
– Metal hydride / PEMFC – Germany (used by many countries)
– Diesel reformer/ AFC – Russia – prototype level
– Diesel reformer / PEMFC – France|Spain – prototype level
– Borohydride / PAFC – DRDO India – prototype level(advanced)

(***** Ratings based on AIP efficiency, low signature and safety)


Selection of Hydrogen-Oxygen Fuel Cells…a trade off
Fuel Cell Types Efficiency Life Size Reactant quality
required
Alkaline Fuel High Poor medium Ultra high purity
Cells (AFC) < 2000 hrs
Polymer Medium Medium small High purity
Electrolyte Fuel < 5000 hrs
cells (PEMFC)
Phosphoric Medium High > big Low purity
Acid Fuel Cells 45000 hrs
(PAFC)
Solid oxide fuel Technology under development
cells (SOFC)
Molten Technology under development
Carbonate fuel
Cells (MCFC)
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Onboard Hydrogen storage/generation ..
Primary driver
Technology Additional Gaseous Life Hydrogen
LOX effluent qty
complime (cause
nt noise)
Metal hydride Nil Nil Low Low
Diesel High High Uncertain Medium
Reforming
Methanol Low Low High high
reforming
Borohydride nil nil high high
hydrolysis

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NMRL competence in fuel cells technology
• Materials for Phosphoric acid fuel cells (PAFC)
– Complete material solutions for PAFC 1996-1998
• Catalyst, moulded graphite bipolar plate, carbon paper, sealants, acid
holder matrix etc. (innovations patented)
– Indian Industry partner developed for all materials
• Fuel cell Stack 1998-2003
– PAFC stacks 1-3kw
– PAFC technology for production transferred to industry
• Fuel cell power plant 2003-2009
– Compact packaged methanol reformer for fuel cell Field use
(any fuel cell) with filters if required upto 15kw power plant

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Upgradation of Fuel cell Stacks for Marine grade
ruggedization & Compaction

• 6kw, N6 • 9kw, N9 • 11.5 kw, N11


(2011) • Shock/vibration –ok • Rugged cocoon
(2013) • Shock /vibration –ok
(2015)

Knowhow transferred to Industry partner & is completely


industrialized
Possible to use upto 500kw power generation by series
/parallel connection
Air Independent Propulsion (AIP) Technology
Conceptualized & Developed in NMRL
• Present system configuration is customized for P-75
Submarines;
• Flexible modular design approach allows adaptation
to any submarine – new or retro fitment
In-house
developed
Fuel Cell : PAFC
& H2 generator

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NMRL developed Fuel Cell AIP for
integration to ongoing P-75 Submarine

•Fuel Cell based AIP is


integrated in a additional section
(AIP plug) and inserted to the
Submarine
•Open architecture plant proven
•Prototype conforming to
Submarine stds. Under
advanced phase of development
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Novel H2 Provision for futuristic FC
based AIP
• Ammonia electrolysis
- Advantages
•Small fraction of power required for splitting ammonia
•Quick startup and simple system
•Highly suitable for very long endurance
-Challenges
•Safety solution for carrying pressurised fuel
•Noise reduction due to Nitrogen (by-product) bubbling out
• Al / Gallium liquid metal alloy based generator
-Advantages
•Quick startup and pumpable liquid alloy (>40°C)
•All solid by products, possible to contain within submarine
-Disadvantages
•Safety solutions for explosive reaction with water in case of storage
breach 12
1000 F ELECTROCHEMICAL SUPER CAPACITOR

Polymer based electrochemical super capacitors with


very high capacitance and high power density,
excellent cycle life.
 Configuration
 Capacitance: 100 F-1000 F
 Voltage: 0-2.5 V ( Vmax:2.75 V)
 ESR: 15 to 35 m ohm
 Operating Temp.: -40 to 55 °C
 Applications
 Fuel cells
 Sonar
 Telecommunication systems
 Portable Power Pack Systems
 Cranking of engines
 Electric vehicle
 Status:
 Technology available for transfer
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