Semi Major-1 Jee (Main Advanced) 30 June.pdf
Semi Major-1 Jee (Main Advanced) 30 June.pdf
Semi Major-1 Jee (Main Advanced) 30 June.pdf
9610ZJA801238240005 JA
PART 1 : PHYSICS
SECTION-I (i)
1) A collar of mass m is to be moved along a long fixed rough straight vertical rod by applying a
force F which is constant in magnitude and whose direction is continuously changing such that θ is
increased from 0° to 90° linearly with time. Initially the collar is at rest at ground and again comes
(A)
(B)
(C)
(D)
2) To verify Ohm's law, a student connects the voltmeter across the battery as, shown in the figure.
The measured voltage is plotted as a function of the current, and the following graph is obtained:
0
4) Two long straight wires, carrying currents I1 and I2, are placed perpendicular to each other. The
line of shortest distance between them.PQ, has length r. The magnitude of the magnetic field at the
centre O of PQ is
(A)
(B)
(C)
(D)
SECTION-I (ii)
1) A charged particle moving in x-y plane enters a region of uniform magnetic field of intensity
at P(0, 0) with velocity and leaves the magnetic field at Q(a, b) with velocity
2) Consider a cube of side 'a' as shown. Eight point charges are placed at the corners. The cube is
rotated about the axis with constant angular velocity 'ω':
(B)
Net magnetic field at the centre of cube is
(C)
Net magnetic field at the centre of cube is
(D)If polarity of any four charges are reversed, then magnetic field at the centre of cube will be
zero.
3) Two blocks of masses m1 and m2 are connected through a massless inextensible string. Block of
mass m1 is placed at the fixed rigid inclined plane while the block of mass m2 hanging at the other
end of the string, which is passing through a fixed massless frictionless pulley shown in figure. The
coefficient of static friction between the block and the inclined plane is 0.8.
4) A parallel plate air capacitor has initial capacitance C. If plate separation is slowly decreased from
d1 to d2, then mark the correct statement(s).
[Throughout the process it remains connected to battery]
(B)Work done by external force where is the electric force of attraction between the
plates at plate separation x.
(C)Work done by electric force ≠ Negative of work done by external agent.
(D)Work done by battery = 2 times the change in electric potential energy stored in capacitor.
5) A cylindrical conductor has a resistance R. When the conductor is at a temperature (T) above its
surrounding temperature (T0), the thermal power dissipated by the conductor is proportional to
excess temperature (ΔT = T – T0) above surrounding and proportionalty constant k. The conductor is
connected to ideal cell of emf V. Initially, the conductor was at room temperature T0. Mass and
specific heat capacity of the conductor are m and s respectively. Assume no change in resistance due
to temperature.
The time (t) dependence of the temperature (T) of the conductor after it is connected to the cell
(A)
is .
The time (t) dependence of the temperature (T) of the conductor after it is connected to the cell
(B)
is
(C)
the temperature of the conductor after a long time is
(D)
the temperature of the conductor after a long time is
6) ABCDFPA is a network of three batteries of the e.m.f's E, 12 V and 4 V respectively and three
resistance 2 Ω, 4 Ω and 6 Ω connected as shown in the diagram. An ideal ammeter connected
between F and P shows a current reading of 0.5 A from P to F. Then the value of the e.m.f. E is
(A)6 V
(B)9 V
(C)8 V
(D)11 V
(A)the y-coordinate of the position of the projectile at time t is (v sin α) , where v is the
velocity of projection
(B)the x-coordinate of the position of projectile at time t is (v cos α) t, where v is the velocity of
projection
(C)
tan β = tan α – , where v is the velocity of projection
(D)
velocity of projection is
8) A point mass is moving in the x-y plane. Its acceleration is a constant vector perpendicular to
the x-axis. Which of the following do/does not change with time?
SECTION-II
1) The velocity of a particle traveling in a straight line is given by m/s, where time t
is in seconds and t ≥ 0. If the particle is observed at x=7m at the instant t=0, its position x is
2) James's bond is standing on a bridge above the road and his pursuers are getting too close for
comfort. He spots a flatbed truck loaded with mattresses approaching at 30 m/s which he measures
by knowing that the telephones pole ; the truck is passing are 20 m apart in this country. The bed of
truck is 20m below the bridge and bond quickly calculates how many poles away the truck should be
when he jumps down the bridge onto the truck making his get away. How many poles is it ? (Take g
= 10 m/s2)
3) The diagram shows combination of three cuboidal spaces (1), (2) and (3). Space 1 and 3 contain
electric field E as shown while space 2 has magnetic field B. A particle of charge q and mass m is
4) A conducting rod of length meter and mass m = 4 kg lies on the horizontal table.
Coefficient of friction between the rod and the table is . If the current in the conductor is 2
ampere, then find the minimum magnitude of magnetic field strength (in Tesla) such that conducting
rod just starts to translate along x-axis. (take g = 10 m/s2). [neglect the radius of rod]
5) Find out the net emf of the three batteries between A & B when the point P is the null point,
measured by the potentiometer arrangement shown in the figure.
6) A non-conducting ring of mass m and radius (R = 20cm) is charged as shown. The charged
density i.e. charge per unit length is (l = 2C/m) It is then placed on a rough non-conducting
horizontal surface plane. At time t = 0, a uniform electric field is switched on and the ring
start rolling without sliding. Determine the friction force in newton acting on the ring, when it starts
moving if E = 5N/C
PART 2 : CHEMISTRY
SECTION-I (i)
(A)Z = 3, n = 3
(B)Z = 2, n = 10
(C)Z = 6, n = 6
(D)Z = 4, n = 3
2) Methyl acetate was hydrolyzed in HCl aqueous solution at 298K, samples of reaction mixture were
withdrawn at different time intervals and titrated with 0.12N NaOH sample whose volumes were
obtained as : Half- life for the reaction below is :
CH3COOCH3(aq.) + H2O(ℓ) CH3COOH(aq.) + CH3OH(aq.)
(A)12.5 minutes
(B)25 minutes
(C)37.5 minutes
(D)50 minutes
The is :
(A)1.26 V
(B)1.34 V
(C)2.96 V
(D)2.07 V
SECTION-I (ii)
1)
For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the mole
fraction of M in solution is shown in the following figure, here XL and XM represent mole fractions of
L and M, respectively, in the solution. the correct statement(s) applicable to this system is(are)
(A)Attractive intramolecular interactions between L–L in pure liquid L and M–M in pure liquid M
are stronger than those between L–M when mixed in solution
(B)The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed when XL → 0
(C)The point Z represents vapour pressure of pure liquid L and Raoult's law is obeyed when XL → 1
(D)The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed from XL = 0
to XL = 1
2) A photon of wavelength 124 nm is absorbed by a metal having work function 6 eV. If the
maximum uncertainity in momentum of ejected photoelectron is
then choose correct statements ?
(A) y – x = 80 ml
(B)y + x = 160 ml
(C)If the titration is started with phenolphthalein indicator and methyl orange is added at the end
point, 2x ml. HCl would be required further to reach end point.
(D)y + x = 120 ml.
4) In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The
correct option(s) among the following is (are)
(A)The value of frequency factor predicted by Arrhenius equation is higher than that determined
experimentally
(B)The activation energy of the reaction is unaffected by the value of the steric factor
(C)Since P = 4.5, the reaction will not proceed unless an effective catalyst is used
(D)Experimentally determined value of frequency factor is higher than that predicted by Arrhenius
equation
6) The halogen form compounds among themselves with formula XX, XX'3, XX'5 and XX'7 where X is
the heavier halogen. Which of the following pairs representing their structures and being polar and
non-polar are correct?
(A)Cr2+ (g) ion has greater magnetic moment as compared to Co3+ (g) ion
(B)Atomic size of B < Ga < Al < Tl
(C)Lanthanide contraction is the cause of lower I.E. of Pb than Sn
(D)If successive ionization energy of an element are 332, 738, 849, 4080, 4958 (in kJ/mol). Then
this element can be of 15th group
8) Which of the following compound(s) has same no. of 1°, 2° & 3° carbons.
(A)
(B)
(C)
(D)
SECTION-II
1) Find the number of different functional groups present in the given compound?
2) ICl3 is an orange colored solid that dimerizes in solid state as I2Cl6. Based on VSEPR theory,
number of ~90 degree Cl – I – Cl bond angles is ...................... in the dimeric species.
Neglect any minor deviations from ideal bond angle.
4) A current of 3.7A is passed for 6hrs. between Ni electrodes in 0.5L of 2M solution of Ni(NO3)2.
What will be the molarity of solution at the end of electrolysis ?
–223
5) A solution of NaSO is standardize d iodometrically against 125.25 mg of KBrO3 where BrO3
changes to Br–. This process requires 45 mL of the Na2S2O3 solution. What is the molarity of the
Na2S2O3? [Mw. of KBrO3 = 167]
6) A 500 gm mixture of KHCO3 and silica on strong heating evolves gases which occupies 24 litre of
volume at 2 atm & 300 K. Mass percentage of silica in original sample: [R = 0.08 atm-L/mole-K]
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
PART 3 : MATHEMATICS
SECTION-I (i)
1) If graph of the expression y = x2 – 8x + 12 is shown in the figure then area of the square
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)None of these
List-I List-II
(I) (P) 1
If number of points
where f(x) is continuous is
(II) If where (Q) 3
, then
(III) (R) 2
then a – b =
(IV) (S) 4
(T) 0
The correct option is
(A)I–T; II–S; III–R; IV–R
(B)I–P; II–R; III–Q; IV–S
(C)I–P; II–S; III–Q; IV–R
(D)I–T; II–R; III–R; IV–S
(A)
(B)
(C)
(D)
SECTION-I (ii)
(A)
(B)4
(C) rational
(D) irrational
2) The figure illustrates graph of the function y = f(x) defined in [–3, 2]. Identify the correct
statement.
(A)Range of y = f(–|x|) is [–2, 2]
(B)Domain of y = f(|x|) is [–2, 2]
(C)Domain of y = f(|x| + 1) is [–1, 1]
(D)Range of y = f(|x| + 1) is [–1, 0]
(A)
(B)
(C)
(D)
(A)
(B)
(C)c = 0
(D)
6) Let and be function defined by ƒ(x) = [x2 – 3] and g(x) = |x| ƒ(x) +
|4x – 7| ƒ(x), where [y] denotes the greatest integer less than or equal to y for y ∈. Then
(A)
ƒ is discontinuous exactly at three points in
ƒ is discontinuous exactly at four points in
(B)
(C)
g is NOT differentiable exactly at four points in
(D)
g is NOT differentiable exactly at five points in
7)
(A)
maximum value of x2y3z2 is
(B)maximum value of x2y3z2 is 1.
(C)
minimum value of is 18
(D)
maximum value of xyz is
SECTION-II
1) Least positive integral value of k for which the equation e2x + (1 – 2k)ex + k2 – 1 = 0 does not have
any real solution, is (where e is Napier's constant)
5) then equal to
6)
If f(2016) = , f(x) = f(2x) ∀ x ∈ R and f(x) is a continuous function for all x ∈ R, and a =
PART 1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4
A. A C B C
SECTION-I (ii)
Q. 5 6 7 8 9 10 11 12
A. B C,D A,B,C B,D A,C D A,B,C,D B,C,D
SECTION-II
Q. 13 14 15 16 17 18
A. 2.00 3.00 2.00 2.00 8.00 2.00
PART 2 : CHEMISTRY
SECTION-I (i)
Q. 19 20 21 22
A. A B A D
SECTION-I (ii)
Q. 23 24 25 26 27 28 29 30
A. A,C B,D A,B,C B,D A,C,D A,B,C,D A,C,D A,C
SECTION-II
Q. 31 32 33 34 35 36
A. 8.00 8.00 8.00 2.00 0.10 2.00
PART 3 : MATHEMATICS
SECTION-I (i)
Q. 37 38 39 40
A. D A B A
SECTION-I (ii)
Q. 41 42 43 44 45 46 47 48
A. A,D A,B,C,D A,B,C,D A,B,C A,B,C,D B,C A,B,C A,C,D
SECTION-II
Q. 49 50 51 52 53 54
A. 2.00 0.30 5.00 8.00 1.00 1.75
SOLUTIONS
PART 1 : PHYSICS
1)
θ = ωt (ω = constant)
N = F sin ωt
∴ Also
2)
V = E – Ir
when V = V0 = 0 ⇒ 0 = E – Ir
∴E=r
when I = 0, V = E = 1.5V
∴ r = 1.5 Ω.
3)
q1 =
q2 =
In steady state
4)
5)
θ = 60
6)
7)
If the tendency of relative motion along the common tangent does not exist, then component of
contact force along common tangent will be zero.
8)
Wb = V × charge flown
9)
Power dissipated in resistance = Rate of heat dissipation to surrounding + Rate of heat absorption
by conductor
when
11)
y-coordinate is
[C is correct]
Rearranging
[∴ D is correct]
12)
ax = 0 ay = –g
vx = constant
(B) only x-component of velocity vector.
(C) only y-component of acceleration vector.
13)
14)
20 =
∴ t = 2s
S = vt = 60 m
∴ no. of poles = =3
15)
tA → B = ....(1)
t=
....(2)
....(3)
....(4)
From eq. (2)
∴k=2
16)
iℓBcosθ + N = mg
N = mg – iℓBcosθ
iℓBsinθ = µN
= µmg – µiℓBcosθ
18)
PART 2 : CHEMISTRY
19)
Given En – E1 = 108.9 eV
...(i)
Given
∴ n–1=2
n=3
Putting n back in eq. (i)
Z=3
20)
21)
∴
= –2 × 96500 ×
= 1.26 V
22)
(B) Solvent flow from its higher concentration to its lower concentration.
(C) NaCl is non volatile so decrease vapour pressure. While CH3OH is more volatile than water
so vapour pressure increases.
(D) ΔTf = iKf × m = 2 × 1.86 × 1 = 3.72 °C
T = T°ff –ΔTf = 0–3.72 = –3.72 °C
24)
25)
x = 40 ml
With MeOH only :
0.05 × y = (0.05 × 40 × 2) + (0.05 × 40 × 1)
y = 120 ml
26)
27)
28)
(A) I–Cl, linear and polar because of the difference in the electronegativities of iodine and
chlorine.
(B)
(C)
(D)
30)
(A)
(B)
(C)
(D)
31)
32)
2ICl3 → I2Cl2
33)
⇒ 3 × 10–4 = R (0.1)
k = 3 × 10–3 sec–1
t1/2 =
34)
With Ni electrode, cathode reaction, Ni2+ + 2e– → Ni, Anode reaction, Ni → Ni2+ + 2e
No. Change in molarity of solution.
N × 45 =
N = 0.1
M=
36)
% wt of silica = × 100 = 60 %
PART 3 : MATHEMATICS
37)
y = x2 – 8x + 12
(–2k) = (k + 4)2 – 8(k + 4) + 12
⇒ k2 + 2k – 4 = 0
⇒
So area = 4k2 =
38)
Case-1:
&
Case-2:
39)
function is continuous at x = 0.
(R)
1 – a = 0, –b = 2
(S)
.....(A)
Again, function is differentiable at everywhere.
at x = –1
40)
41)
(a – 2)b = 1
a(b – 2) = 1
a(1 – 2a + 4) = a – 2
5a – 2a2 = a – 2
2a2 – 4a – 2 = 0
a2 – 2a – 1 = 0
a= ⇒
a+b=
43)
44) Let
...(i)
...(ii)
...(iii)
45)
For limit to be exist coeff. of below x3 must be zero
a+b=0 ...(1)
1+a–b+c=0 ...(2)
...(3)
by eq. (1) & (3) c = 0
by eq. (1) & (2) a + b = 0
1+a–b=0
46)
=
at x = where n = 1, 2, 3, 4
so f(x) is discontinuous at x = , ∀ n = 1, 2, 3, 4.
48)
and
⇒ and
49)
e2x + (1 – 2k)ex + k2 – 1 = 0
ex = t > 0
t2 + (1 – 2k)t + k2 – 1 = 0
Either D < 0
(1 – 2k)2 – 4(k2 – 1) < 0
Let
So,
Hence,
51) Put n = 0
(f(1))2 – (f(0))2 = 6f(0) + 1
x2 – y2 = –8
Only possible solution x = 1, y = 3
f(1) = 1 f(0) = 0
Now,
β – α = 2f(2n)
β = 2f(2n) + α
bmin = 2f(2n) + 1 ≥ 2f(n) + 1
βmin = 2f(n) + 1
52)
if
=0=a