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Roll No. : Time -

Date : MM - 52

1. The molality of pure water is 1

(a) 55.5 (b) 50.5
(c) 18 (d) 60.5

Ans : (a) Molality = Number of moles/kg of solvent

= 55.5 moles/kg

2. The number of moles of NaCl in 3 litres of 3M solution is 1

(a) 1 (b) 3
(c) 9 (d) 27

Ans : (c) 3M solution means 3 moles in 1 litre.

∵ 9 moles in 3 litre.

3. 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of 1
the resultant solution is _____________.

(a) 0.004 (b) 0.008

(c) 0.012 (d) 0.016

Ans : (d) M1V1 = M2V2

0.02 × 4 = M2 × (4 + 1) ⇒ M2 = = 0.016

4. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to 1
____________.
(a) low temperature
(b) low atmospheric pressure
(c) high atmospheric pressure
(d) both low temperature and high atmospheric pressure

Ans : (b) Low atmospheric pressure will lead to low concentration of oxygen blood.

5. Considering the formation, breaking and strength of hydrogen bond, predict which of the 1
following mixtures will show a positive deviation from Raoult’s law?
(a) Methanol and acetone.
(b) Chloroform and acetone.
(c) Nitric acid and water.
(d) Phenol and aniline.

Ans : (a) CH3OH and acetone, on mixing force of attraction will decrease.

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6. Which of the following aqueous solutions should have the highest boiling point? 1
(a) 1.0 M NaOH (b) 1.0 M Na2SO4
(c) 1.0 M NH4NO3 (d) 1.0 M KNO3

Ans : (b) Because i = 3, ∆Tb ∝ i, Boiling point ∝ ∆Tb.

7. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M 1

MgCl2 solution is _____________.
(a) the same (b) about twice
(c) about three times (d) about six times

Ans : (c) It will be nearly 3 times because number of particles in MgCl2 → Mg2+ + 2Cl– are
thrice than glucose.

8. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because 1
_____________.
(a) it gains water due to osmosis.
(b) it loses water due to reverse osmosis.
(c) it gains water due to reverse osmosis.
(d) it loses water due to osmosis.

Ans : (d) Concentrated salt solution is hypertonic solution, therefore, fluids inside mango will
come out and it shrivels.

9. Which of the following statements is false? 1

(a) Two different solutions of sucrose of same molality prepared in different solvents will have the
same depression in freezing point.

(b) The osmotic pressure of a solution is given by the equation ∏ = CRT (where C is the molarity of
the solution).

(c) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride,
potassium chloride, acetic acid and sucrose is
BaCl2 > KCl > CH3COOH > sucrose.

(d) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is
directly proportional to its mole fraction in the solution.

Ans : (a) is false because ∆Tf will depend upon nature of solvent and their Kf .

10. The value of Henry’s constant KH is _____________. 1

(a) greater for gases with higher solubility.
(b) greater for gases with lower solubility.
(c) constant for all gases.
(d) not related to the solubility of gases.

Ans : (b) Higher the value of KH, lower will be solubility.

11. Consider the figure and mark the correct option. 1

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(a) water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on
piston (B).
(b) water will move from side (B) to side (A) if a pressure greater than osmotic pressure is applied
on piston (B).
(c) water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on
piston (B).
(d) water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on
piston (A).

Ans : (b) Reverse osmosis will take place.

12. We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M, 1
0.01M and 0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the
order _____________.

(a) iA < iB < iC (b) iA > iB > iC

(c) iA = iB = iC (d) iA < iB > iC

Ans : (c) van’t Hoff factor (i) does not depend upon concentration.

13. A solution containing 10 g per dm3 of urea (molar mass 60 g mol–1) is isotonic with 5% solution 1
of non-volatile solute, MB of solute is
(a) 300 g mol–1 (b) 350 g mol–1
(c) 200 g mol–1 (d) 250 g mol–1

Ans :
(a)

⇒ x = 300 g mol–1
1000 cm3 contains 10 g
100 cm3 contains 1 g, i.e., 1%.

14. Conc. H SO is 98 % H SO by mass has d = 1.84 g cm–3. Volume of acid required to make 1
2 4 2 4
one litre of 0.1 M H2SO4 is
(a) 5.55 mL (b) 10 mL
(c) 20 mL (d) 30 mL

Ans :

15. What is mole fraction of solute in 1.00 m aqueous solution? 1

(a) 0.0354 (b) 0.0177
(c) 0.177 (d) 1.770

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Ans :

16. When 1 mole of benzene is mixed with 1 mole of toluene (vapour pressure of benzene = 12.8 1
kPa, Toluene = 3.85 kPa)
(a) The vapour will contain equal amount of benzene and toluene.
(b) Not enough information is given for prediction.
(c) The vapour will contain a higher percentage of benzene.
(d) The vapour will contain higher percentage of toluene.

Ans : (c) It is because benzene has high vapour pressure, it will form more vapours as
compared to toluene.

17. At 100°C, the vapour pressure of a solution of 6.5 g of solute in 100 g of water is 732 mm. If Kb 1
is 0.52 K/m, the boiling point of solution will be
(a) 102°C (b) 103°C
(c) 101°C (d) 100°C

Ans :

18. Which of the following is incorrect for an ideal solution? 1

(a) ∆Hmix = 0 (b) ∆Vmix = 0
(c) ∆P = Pobs – Pcalculated = 0
(d) ∆Gmix = 0

Ans : (d) ∆G cannot be equal to zero because mixing does not lead to equilibrium.

19. If molality of dilute solution is doubled, the value of molal depression constant (Kf ) will be 1
(a) halved (b) tripled
(c) unchanged (d) doubled

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Ans : (c) Kf does not depend upon ‘m’. It depends upon nature of solvent.

20. The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic 1
pressure of 16.4 atom is (R = 0.082 L atom K–1 mol–1)
(a) 360°C (b) 180 K
(c) 300 K (d) 360 K

Ans :

21. Which has the highest freezing point? 1

(a) 1 M glucose (b) 1 M NaCl
(c) 1 M CaCl2 (d) 1 M AlF3

Ans : (a) 1 M glucose solution has highest freezing point because it has lowest ∆Tf because i =
1.

22. Which of the following is correct. 1

(a) KH increases with increase in temperature (KH is Henry’s law constant).
(b) Solubility of gas in liquid decreases with increases in temperature.
(c) KH decreases with increase in temperature.
(d) Solubility of gas in liquid increases with increase in temperature.

Ans : (a) and (b) are correct pgas = KH × xgas

KH increases with increase in temperature, xgas decreases, i.e., solubility of gas in liquid
decreases with increase in temperature.

23. Benzoic acid, when dissolved in benzene, which of the following is correct. 1
(a) The benzoic acid will undergo dissociation.
(b) The benzoic acid will undergo association.
(c) Observed molar mass of benzoic acid in benzene will less than normal molar mass.
(d) Observed molar mass of benzoic acid in benzene is more than normal molar mass.

Ans :

Molar mass will be nearly double due to dimerisation.

24. Relative lowering of vapour pressure is a colligative property because _____________. 1

(a) It depends on the concentration of a non electrolyte solute in solution and does not depend on
the nature of the solute molecules.
(b) It depends on number of particles of electrolyte solute in solution and does not depend on the
nature of the solute particles.
(c) It depends on the concentration of a non electrolyte solute in solution as well as on the nature of
the solute molecules.
(d) It depends on the concentration of an electrolyte or nonelectrolyte solute in solution as well as
on the nature of solute molecules.

Ans : (a) and (b) colligative property depends upon number of particles of solute in both
electrolyte and nonelectrolyte.

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25. In the following question a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices.
(a) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion and reason both are incorrect statements.
(e) Assertion is wrong statement but reason is correct statement.

Assertion: When methyl alcohol is added to water, boiling point of water increases.
Reason: When a volatile solute is added to a volatile solvent elevation in boiling point is observed.

Ans : (d) Assertion and reason both are incorrect statements.

26. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid 1
solvent does not depend upon ____________.
(a) Temperature (b) Nature of solute
(c) Pressure (d) Nature of solvent

Ans : (c) Pressure does not affect solubility of solid in liquid.

27. On the basis of information given below mark the correct option. Information: 1
(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are
nearly same as A–B type interactions.
(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than
A–B type interactions.
(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than
A–B type interactions.
(a) Solution (B) and (C) will follow Raoult’s law.
(b) Solution (A) will follow Raoult’s law.
(c) Solution (B) will show negative deviation from Raoult’s law.
(d) Solution (C) will show positive deviation from Raoult’s law.

Ans : (b) Solution ‘A’ is ideal solution, will follow Raoult’s law.

28. K value for Ar(g), CO (g), HCHO(g) and CH (g) are 40.39, 1.67, 1.83 × 10–5 and 0.413 1
H 2 4
respectively. Arrange these gases in the order of their increasing solubility. [NCERT Exemplar
Problem]
(a) HCHO < CH4 < CO2 < Ar
(b) HCHO < CO2 < CH4 < Ar
(c) Ar < CO2 < CH4 < HCHO
(d) Ar < CH4 < CO2 < HCHO

Ans : (a) Gas with higher KH has lower solubility.

29. If P° = 100 mm, P° = 200 mm and mole fraction x = 0.4, what will be y (mole fraction) in 1
A B A A
vapour phase?
(a) 0.25 (b) 0.30
(c) 0.75 (d) 0.50

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Ans :

30. Which of the following is maximum boiling azeotropic? 1

(a) CH3COOH + C5H5N (pyridine)
(b) H2O + ethanol
(c) cyclohexane + ethanol
(d) H2O + methanol

Ans : (a) is maximum boiling azeotropic due to increase in force of attraction on mixing
whereas others are minimum boiling azeotropes.

31. Kb (molal elevation constant) is inversely proportional to [NCERT Exemplar Problem] 1

(a) boiling point of solvent
(b) ∆vapH of solvent
(c) Molar mas of solvent
(d) all of these

Ans : (b) It is inversely proportional to ∆vapH of solvent.

32. Out of 1m solution of following dissolved in water. Which one will have lowest freezing point 1
(assuming all are fuel, ionised)
(a) Urea (b) NaCl
(c) Na2SO4 (d) Al2(SO4)3

Ans : (d) ∵ Higher ∆Tf , lower will be freezing point and ∆Tf ∝ number of ions.

33. Which of the following will have lowest vapour pressure? (Boiling points are given in brackets) 1
(a) H2O (373 K) (b) CHCl3 (334 K)
(c) Anilines (457 K) (d) Benzene (353 K)

Ans : (c) Aniline has highest boiling point, therefore, it will have lowest vapour pressure.

34. The pgas dissolved a liquid is directly proportion to its 1

(a) mole fraction
(b) molar mass
(c) boiling point of liquid
(d) molar mass of solvent

Ans : (a) It is directly proportional to mole fraction of gas.

35. Henry’s law constant of oxygen is 1.4 × 10–3 mol L–1 atm–1 at 298 K. How much oxygen will be 1
dissolved in 100 ml at 298 K when its partial pressure is 0.5 atm?
(a) 1.4 g (b) 3.2 g
(c) 22.4 mg (d) 2.24 mg

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Ans :

36. In isotonic solutions ________________. 1

(a) solute and solvent both are same.
(b) osmotic pressure is same.
(c) solute and solvent may or may not be same.
(d) solute is always same solvent may be different.

Ans : (b) and (c) isotonic solution will have same osmotic pressure but solute and solvent may
be different.

37. Which of the following binary mixtures will have same composition in liquid and vapour phase? 1
(a) Benzene-Toluene (b) Water-Nitric acid
(c) Water-Ethanol (d) n-Hexane - n-Heptane

Ans : (b) and (c) as they form ideal solution.

38. For a binary ideal liquid solution, the variation in total vapour pressure versus composition of 1
solution is given by which of the curves?

Ans : (a) and (d) are correct.

∵ Vapour pressure is directly proportional to mole fraction in a binary ideal solution.

39. Match the laws given in Column I with expresions given in Column II. 1

Column I Column II
(a) Raoult’s law (i) ∆Tf = Kf m
(b) Henry’s law (ii) ∏ = CRT

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(c) Elevation of boiling point (iii)

(d) Depression in freezing point (iv) ∆Tb = Kbm

(e) Osmotic pressure (v) p = KH.x

Ans : (a) (iii) (b) (v) (c) (iv) (d) (i) (e) (ii)

40. In the following question a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices.
(a) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion and reason both are incorrect statements.
(e) Assertion is wrong statement but reason is correct statement.
Assertion: When a solution is separated from the pure solvent by a semipermeable membrane, the
solvent molecules pass through it from pure solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration solution to a region of low
concentration solution.

Ans : (e) Assertion and reason both are correct statements but reason is not correct
explanation of assertion. The reason for flow is from higher vapour pressure to lower
vapour pressure.

41. Increasing the temperature of an aqueous solution will cause 1

[CBSE 2021]

(a) Increase in Molarity

(b) Increase in Molality
(c) Decrease in Molarity
(d) Decrease in Molality

Ans : (c)

42. The molarity of the solution containing 7.1 g of Na2SO4 in 100 ml of aqueous solution is [KVS] 1

(a) 2 M
(b) 0.5 M
(c) 1 M
(d) 0.05 M

Ans :

43. The number of moles of NaCl in 3L of 3M solution is 1

(a) 1
(b) 3
(c) 9
(d) 27

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Ans :

Number of moles = Molarity × Volume of solution = 3 × 3 = 9 moles

44. The value of KH (Henry’s law constants) for the given gases in water at 293 K are 1

I. He – 144.97 k bar
II. H2 – 69.16 k bar
III. N2 – 76.45 k bar
IV. O2 – 34.86 k bar
Which gas has the lowest solubility in water?
(a) He
(b) H2
(c) N2
(d) O2

Ans : (a) Higher KH means, lower solubility.

45. Solubility of CO2 in soda water increases with 1

(a) Increase in pressure and temperature.

(b) Increase in pressure and decrease in temperature.
(c) Decrease in pressure and increase in temperature.
(d) Decrease in pressure and temperature.

Ans : (b) Solubility of CO2 in soda water increases with increase in pressure and decrease in
temperature.

46. If concentration of N2 gas in water at constant pressure increases quadratically, how will value of 1
KH change?

Higher the value of KH, the lower is the solubility of gas in the liquid.

Solubility of a gas in liquid decreases with increase in temperature because KH increases with increase in temperature, so, solubility
decreases.

Application: Cold drink bottles are filled at high pressure so as to increase solubility of CO2 gas in water.

[CBSE Learning Framework]

(a) Remains same

(b) Increases linearly

(c) Decreases linearly

(d) Decreases quadratically

Ans : (a) Because the value of KH only depends upon temperature.

47. The value of KH (Henry’s law constant) 1

[CBSE 2023]

(a) increases with decrease in temperature

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(b) decreases with increase in temperature
(c) increases with increase in temperature
(d) remains constant

Ans : KH increases with increase in temperature.

48. KH value for H2, He(g), N2(g) and O2(g) are 69.16, 144.97, 76.48, 34.86 respectively. Identify the 1
correct order of their increasing solubility in water.

(a) O2 < H2 < He < N2

(b) He < N2 < H2 < O2
(c) He < H2 < N2 < O2
(d) N2 < He < O2 < H2

Ans : (b) Higher the KH, Lower will be solubility.

49. Solubility of gas in liquid decreases with increrase in 1

[CBSE 2023]

(a) Pressure
(b) Temperature
(c) Volume
(d) Number of solute molecules

Ans : (b) At higher temperature gas escapes from liquid.

50. Which of the following conditions is correct for an ideal solution? 1

[CBSE 2021]

(a) ΔHmix = 0 and ΔVmix = 0

(b) ΔHmix > 0 and ΔVmix > 0
(c) ΔHmix < 0 and ΔVmix < 0
(d) ΔHmix > 0 and ΔVmix < 0

Ans : (a) ΔHmix = 0 and ΔVmix = 0

51. Pure water boils at 373.15 K and nitric acid boils at 359.15 K. An azeotropic mixture of H2O and 1
HNO3 boils at 393.55 K. Distilling the azeotropic mixture will cause [CBSE 2021]

(a) Pure nitric acid to distil over first.

(b) Pure water to distil over first.
(c) One of them to distil over with a small amount of the other.
(d) both of them to distil over in the same composition as that of the mixture being distilled.

Ans : Both of them to distil over in the same composition as that of the mixture being distilled.

52. Which of the following liquid pairs shows a positive deviation from Raoult’s law? [KVS] 1

(a) Water - Nitric acid

(b) Benzene - Methanol
(c) Water - Hydrochloric acid
(d) Acetone – Chloroform

Ans : (b) Benzene - Methanol

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