DAV Sushil Kedia Vishwa Bharati Jawalakfiel, Lalitpur 2” Pre- board Examination 2024-24 Chemistry XII (Science) Dara: 16 Jan. 2024 Jhrs, FA: 70 PA a6 GENERAL INSTRUCTIONS: Read the following Instructions carefully. There are 33questions in this qt tion paper. 1 SECTIONA carrying 1 mark each. SECTION B carrying 2 marks aach we SECTION C carrying 3 marks oach. SECTION D carrying 4 marks each. 2 3 4 wet 5 SECTION E carrying 5 marks each we 6 All questions are compulsory v 7. Use of log tables and calculators is not allowed. ® ap SECTION-A ho 1, Value of Henry's constant Kx is ’ a, Greater for gases with higher solubility oe vb. Greater for gases with lower solubility ° oe c. Constant for all gases. d. Not related to the solubility of gases. An electrochemical cell can behave like an electrolytic cell when 2. Eat 0 bEww rEg Burm SEs * ae 3. The cell constant of a conductivity call a. Changes with change of electrolyte b. Changes with change of concentration of electrolyte c. Changes with temperature of electrolyte d, Remains constant for a cell 4, The role of a catalyst is to change a, Gibb's energy of reaction b. Enthalpy of reaction vc. Activation energy of reaction J. Equilibrium constant @) ‘lectronic configuration of transition element X in +3 oxidation state is{.) 30° What is it's atomic number? a. 25 ~ 26 ¢.27 4.24 6) When 1mol C,Cls.6H20 is treated with excess of AgNO3.3mol of AgCl are obtained. The formula of the complex is a. [C:Cls(H20)].3H20 b. [C,Cl(H20).JC1L2H,0 ©. [C:Cl(H20)s]Cle.H20 d. [C(H2O)eJCls fF 7. The correct IUPAC name of [Pt(NHs)2 Chl is a. Diamminedichloridoplatinum(!I) ~ b> Diamminedichloridopiatinum (IV) ¢c. Diamminedichloridoplatinum (0) ‘ dy DiChloridodiammineplatinum (IV) 8, Which of the following are secondary bromides? ACH) CHB, b. (CHs)sCCH:B, ¢. CHxCH:CH:B, —_d. (CHs)2 CB:CH:CHs unc e ty $ Class XII (Sci) Chemistry [2 Pre Board Exam} 16 Jan. 2024 Page tof 4CHyCH,OH can be converted into CHiCHO by Catalytic hydrogenation > Treatment with LiAIH, ¢ Treatment with pyridinium Chlorochromate 4 Treatment with KMnO. 10, The reagent which does not react with both acetone and benzaldehyde a Sodium hydrogensulphite ) b. Phenyl hydrazine _§ Fehling’s Solution Grignard Reagent 11,)n Clemmensen reduction, carbonyl compound is treated with x 73-Zinc Amalgam +HCt b. Sodium amalgam + HCI ©. Zinc amalgam+HNOs d. Sodium amalgam+HNOs : > 0 12, Treatment of compound Ph C-Ph with NaOH Solution gives a product Phenol At Sodium Phenoxide ¢. Sodium Benzoate —d, Benzophenone sertion (A): 2-Methgxy-2-methyl propane reacts with hydrogen iodide to form methyl alcohol and 2-lodo-2-methylpropane. Reason (R): The reaction given in (A) follows SN2 mechanism a. Both A and R are true, and R is a correct explanation of A b. Both A and R are true, but R is not the correct explanation of A. c. Ais true, but Ris false. is false, but Ris tue sertion (A): Halogens are ortho and para-directing groups Reason (R): Halogens are electron-withdrawing Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A. c. Ais true but R is false. 5 dAis false but R is true. 15. Assertion (A): Hoffman Bromamide Degradation reaction is given by primary amides. Reason(R): Primary amines are more basic than secondary amines a. Both A and R are true and R is the correct explanation of A . Both A and R are true but R is not the correct explanation of A jc. Ais true but R is False d. Ais false but R is true Cospeseon (A): Vitamin D can be stored in our,oody A Reason(R): Vitamin D is fat soluble vitamin” a. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A c. Ais true but R 1s False d. Ais false but R is true SECTION-B + 17, From the given cell: Lead storage cell, Mercury cell, Fuel cell and dry cell Answer the following Which cell is used in hearing aids? B. Which cell was used in Apollo space programme? “© c. Which cell is used in automobiles and inverters? UV © Which cell does not have long life? » nto A Page 2of4 ryLEP Ren wis aarca va comer save wanton ae @ Fete MnOe oH edeta (beth a AMT Melle Gq b 1 OHO eh * . me . . ite the mechanism of ——— © Muda ST IHD of Ome © by CHCH OH M CH) CH) HO Z ai. oie cal Lost 10 istinguieh between yd etnanwc acd HCHO and CH,CHCOCH: ferentiate between the tallo#ng 24 ) and Amylopectin at fephiae linkage and glycosidic inkage % + SECTION-C I Ec for the given redox reaction is 2.71 A Mg(S) + Cu"(0.01M) Mg?"(9.00114) * Guts) a ‘ cj Esa for the TEBION Using valarice bond theory. predict the ty/badzaton and inagraie character of ow f . ace rico |. What happens when orn? nt a. Salicylic acid 1s treated with (CHiCO),OM"? = ™ nde b. Phenol is oxidized with NaCr, Ov" al we c ole is treated with CHiCVAnhydtousAiCl,? < ‘ Lacan compound with the molecular formu ms 2A-ONP deneative reduces tollen’s reagent and undergoes can faction on Gndation it benzoic acid Identify the compound and state the reactions involved. vy ¥~ 26, Give reasons for the following ¥ AA ote, ine does not undergo friedel-crat’s reactions tap -t FAS (CHsFaNH is more basic than (CHs):N in an aqueous olution ey fimary amines have higher boiling point than tertiary amines. * Write the name of the reaction, structure and IUPAC name of the product Mia! when (any 2): . °° Phenol reacts with CH fo 7 ii, CH (CHs)CH(CHs)ONa reacts with CzHeBr d 7 CHsCHZCN reacts with stannous chloride in the presence of hydrochloric acid followed by hydrolysis 28, rate constants of a reaction at 200K and 500K are 0 02s~' and 0 205~" respectively. Calculate the value of Ea (Grven 2.303R = 19.15 JK" mot") o 0 ety ECTION- ted * 29, Read the given passage and answer the questions ito 4 that follow. ‘ The d block of the periodie table coniain the elamenis of the groups 72 and ar \ known as transition element. In general the electronic configuration of these element 1s Wn | (0-1)0""*ns'?, The d- orbitals of the penuitimate energy level in their atorns receive |” 1 ‘\* | electron giving rise to the three rows of the transition metal 1¢ 3¢.4dand 4 senes 74 However Zn,Cd and Hg are not regarded as transition elements Transition elements | << exhibit certain characteristic properties like variable oxidation state, complex formation s of coloured ions and alloys catalytic activity etc transition metals are hard(except Zn Ca iting point. Wis Cu” ion Zam is Zn Bn transition element wnere as copper is transition metal? y does Zn have lower melting point than \ron? why 1s Fe** good reducing agent? a Class XI (S01) Chamnisty [2 Pre Board Exam) 16 Jan 2024 Page hata30. Read the given passage and answer the question 1 10 4 that flows [Organic compound containing amine as funchon group are present in a vivid variety # | compounds namely amino acid. harmones . neorotransmitters ONA.wkaiod dyes etc Drug inchuding nicotine . morphine. codeine and heroine etc Which have phytcogecal | effect on human also contain amino group in one form of another Amines ae basic | because of the presence of lone pair of electron or nitrogen Addition of nitrogen into an | organic framework leads to the formation of two families of molecuias namely amwres [and amides As chemistry students, we must appreciate the versatility of nitrogen ‘amino acids? reas nn eau ‘are amino acids amphotenc? 3a van't Hoff factor? What possible values cant it have if the solute molecules go dissolution? >t Mpa aqueous solution containing 12.489 of barium chloride in 1.0Kg of water boils ‘at 373,08K.Calculate the degree of dissolution of barium chionde [Given Ke for H,0=0.52Km"';Molar mass of BaClz=208.34gmot" _] eS ‘certain chemical reaction variation in concentration In{A] Vs time (t) plot s ven bel low: . ws Intercept a o x0 <— Slope b cS t woe ei cmseae reaction ? ° ‘What does the slope of the line and intercept? oe is the unit of rate constant K? _B siescorder reaction is 60% complete in 50 minutes at 300K and the same reaction is “Bgain 50% compiete in 25 minutes at 350K calculate activation energy of the reaction’: Jhat is main product from when propanal reacts with the following reagents. 1oles of CHsOH in presence of dry HCI(g) FAY _Dittle NaOH followed by heating (i NHz-NH; followed by heating with KOH in ethylene glycol. Arrange the following compounds in increasing order property indicated: (QD FCH:COOH, O:N-CH;-COOH , CH:COOH, HCOOH (acid character) Acetone, Acetaldehyde, Benzaldehyde, Acetophenone (reactivity towards addition of HCN) a w 5 wepestOr tuck gk oy De 2 w6 3 ected 7 alt ue Meare Class Xi (Sei) Chemistry [2° Pre Board Exam) 16 Jan 2024 Paged cts