Quantum Mechanics Chemistry

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De Shoie a
h- Plalk's tonta
m ) t paalcle
vcet
urel egk

- apdde to are
-vele

- Le panhicles is moU ndneho)


n 3-D

LAPLACIAN
oPERA ToR
This itrespic
bodi e mayim 3-D
P

she,
rt ho
Nod, Aaudna
2 Laureo.jin
dndon
A a Di
- )
fon e

- --
Actdito de Bo.ogli Lafelen
e

d
m 192
2

2 m (.E
e ku U
FE KE+V.

Then Cam le tan

2 m E-

2 (E-V

3(E-V)¥

(E-) p-ol| 2N

ine
3-DT1-t:2dpemt love
Fe ee mmoi19 pwhl, P t e h 0 So VoD
Sclorodgew Wae a(Tw -D ependant)
t e ndeorpic_bo
oaure malune 7

> > ldaue Aebim

ey-vv]-o
Gen
-herioe 1 ik-v m

2m

t a i Utoam cpensle
-is.bo e-iot

E
-h
STIW
dugukorpRauvey (e 2 TU-aquae
=

2T E h
E
Plehs hadsin)

-
Sdordnpo Tuine
mdepsndet iyeut g
E-y) b
Pantole al-Dimeniignal Benc
Crsden a
fatide Aar u tmtauned ts
V-0
V
Dye 6n X-diielon um
L
Selonndinper aue
9 enaln
E V O

T Hal towiam opeln


- 2 X-dusion)

Putb voalue w O Plameks cn

d
- A(E-o)=d
&n
- ey{
P(E-v)-
8nm d
d k 2mE
2

d wwe fnehn an be keprnaek


No, tane ane wo ndihng
he tehn e ço icgehog
Okde ona
A &un kx +8 s kr
de Tsha A , B a t
thann ngkans
Lshen FD(at
ukide t br, V=0 )
Sn 0Dd
e Valuo Ces0=
4 0 A Sm 0+ BCas
d
4 (E-)-D
E-o)y 0 0+ B

T Posi bke tln lshen D , h =LL% pa-hde \


uy-d
Pauhle 0 A sm kL +D
ouhco
i mo p t n t Aun kL =D SkL =o
KL=nTT
L L

X4T Pohele ia 1-D Bo


L r

mL Aahide i a l Lohen mC7ma


(shene h t
miiwm enwro a l
LtR e coan alt ]
1 2 , 3,4 ( Phuncipal qm wo Jelhn u st a a wen al
Plaek's t 0 K enp Thu miuim
m may na alld 3 eu p 2uat1

ny fanh'e m - D
Quahsat
2 mea md,i a e
X 4,, 1bX... AE E,-6
fn L,- vhen n=|/imei pal DE' E-E,.
AE=- AE'
hen khee
E,h , nz2,E,- 4h
8ma

Poz
A Sun kx
Aainx * k
She PrbalL kdi te
ponhiele in
m l Apace behweei L a+dn

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