ściągi 3

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dP ∆H d ln P ∆Hp(s) dP ∆H d ln P ∆Hp(s)

= = = =
dT T∆V dT RT 2 dT T∆V dT RT 2
P ∆Hp,(s)  1 1 P ∆Hp,(s)  1 1
ln 2 = −  −  ln 2 = −  − 
P1 R  T2 T1  P1 R  T2 T1 
∆Hp,(s) ∆Hp,(s)
ln P = − + const ln P = − + const
RT RT

PA = PA0 ⋅ x A PB = PB0 ⋅ x B x A + x B = 1 PA = PA0 ⋅ x A PB = PB0 ⋅ x B x A + x B = 1


P P P P
yA = A yB = B y A + yB = 1 yA = A yB = B y A + yB = 1
P P P P
P = PA + PB = PA0 ⋅ x A + PB0 ⋅ x B P = PA + PB = PA0 ⋅ x A + PB0 ⋅ x B
X A (nc + np ) = n A,c + n A,p = nc ⋅ x A + np ⋅ y A X A (nc + np ) = n A,c + n A,p = nc ⋅ x A + np ⋅ y A
WA (mc + mp ) = m A,c + m A,p = m c ⋅ w A + np ⋅ z A WA (mc + mp ) = m A,c + m A,p = m c ⋅ w A + np ⋅ z A
np XA - xA mp WA - w A np XA - xA mp WA - w A
= = = =
nc yA - X A mc z A - WA nc yA - X A mc z A - WA

∆P PA0 - P ∆P PA0 - P
P = PA0 ⋅ x A = = xB P = PA0 ⋅ x A = = xB
PA0 PA0 PA0 PA0

∆Hp  1 1  ∆Hp  1 1 
lnx A = −  −  lnx A = −  − 
R  Tw Tw,A  R  Tw Tw,A 
∆Tw = Tw - Tw,A = K e ⋅ m ∆Tw = Tw - Tw,A = K e ⋅ m
2
RTw,A ⋅ MA 2
RTw,A ⋅ MA
Ke = Ke =
∆Hp ⋅ 1000 ∆Hp ⋅ 1000

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