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UNIT-I
PN JUNCTION DIODE
1.0 INTRODUCTON
Based on the electrical conductivity all the materials in nature are classified as insulators,
semiconductors, and conductors.
Insulator: An insulator is a material that offers a very low level (or negligible) of conductivity when
voltage is applied. Eg: Paper, Mica, glass, quartz. Typical resistivity level of an insulator is of the order
of 1010 to 1012 Ω-cm. The energy band structure of an insulator is shown in the fig.1.1. Band structure
of a material defines the band of energy levels that an electron can occupy. Valance band is the range
of electron energy where the electron remain bended too the atom and do not contribute to the
electric current. Conduction bend is the range of electron energies higher than valance band where
electrons are free to accelerate under the influence of external voltage source resulting in the flow of
charge.
The energy band between the valance band and conduction band is called as forbidden band
gap. It is the energy required by an electron to move from balance band to conduction band i.e. the
energy required for a valance electron to become a free electron.
1 eV = 1.6 x 10-19 J
For an insulator, as shown in the fig.1.1 there is a large forbidden band gap of greater than 5Ev.
Because of this large gap there a very few electrons in the CB and hence the conductivity of insulator is
poor. Even an increase in temperature or applied electric field is insufficient to transfer electrons from
VB to CB.
CB
CB CB
o
Forbidden band Eo =≈6eV
gap Eo ≈6eV
VB
VB
VB
Insulator Semiconductor Conductor

FiG:1.1 Energy band diagrams insulator, semiconductor and conductor
Conductors: A conductor is a material which supports a generous flow of charge when a voltage is
applied across its terminals. i.e. it has very high conductivity. Eg: Copper, Aluminum, Silver, Gold. The
resistivity of a conductor is in the order of 10-4 and 10-6 Ω-cm. The Valance and conduction bands
overlap (fig1.1) and there is no energy gap for the electrons to move from valance band to conduction
band. This implies that there are free electrons in CB even at absolute zero temperature (0K).
Therefore at room temperature when electric field is applied large current flows through the
conductor.
Semiconductor: A semiconductor is a material that has its conductivity somewhere between the
insulator and conductor. The resistivity level is in the range of 10 and 104 Ω-cm. Two of the most
commonly used are Silicon (Si=14 atomic no.) and germanium (Ge=32 atomic no.). Both have 4 valance
electrons. The forbidden band gap is in the order of 1eV. For eg., the band gap energy for Si, Ge and
GaAs is 1.21, 0.785 and 1.42 eV, respectively at absolute zero temperature (0K). At 0K and at low
temperatures, the valance band electrons do not have sufficient energy to move from V to CB. Thus
semiconductors act a insulators at 0K. as the temperature increases, a large number of valance
electrons acquire sufficient energy to leave the VB, cross the forbidden band gap and reach CB. These
are now free electrons as they can move freely under the influence of electric field. At room
temperature there are sufficient electrons in the CB and hence the semiconductor is capable of
conducting some current at room temperature.
Inversely related to the conductivity of a material is its resistance to the flow of charge or
current. Typical resistivity values for various materials’ are given as follows.
Insulator Semiconductor Conductor

10-6 Ω-cm (Cu) 50Ω-cm (Ge) 1012 Ω-cm
(mica)
50x103 Ω-cm (Si)
Typical resistivity values
1.0.1 Semiconductor Types
A pure form of semiconductors is called as intrinsic semiconductor. Conduction in

intrinsic sc is either due to thermal excitation or crystal defects. Si and Ge are the two most important
semiconductors used. Other examples include Gallium arsenide GaAs, Indium Antimonide (InSb) etc.
Let us consider the structure of Si. A Si atomic no. is 14 and it has 4 valance electrons. These 4
electrons are shared by four neighboring atoms in the crystal structure by means of covalent bond. Fig.
1.2a shows the crystal structure of Si at absolute zero temperature (0K). Hence a pure SC acts has poor
conductivity (due to lack of free electrons) at low or absolute zero temperature.
Covalent bond
Valence electron
Fig. 1.2a crystal structure of Si at 0K
At room temperature some of the covalent bonds break up to thermal energy as shown in fig
1.2b. The valance electrons that jump into conduction band are called as free electrons that are
available for conduction.
Free electron
Valance electron
hole
Fig. 1.2b crystal structure of Si at room

temperature0K

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UNIT-I

Insulator Semiconductor Conductor

Insulator Semiconductor Conductor

50x103 Ω-cm (Si)

Typical resistivity values

1.0.1 Semiconductor Types

A pure form of semiconductors is called as intrinsic semiconductor. Conduction in

Fig. 1.2a crystal structure of Si at 0K

Fig. 1.2b crystal structure of Si at room

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