Polystyrene_MSDS

Conforms to US OSHA Hazard Communication 29CFR1910.
1200
SAFETY DATA SHEET

Polystyrene
Section 1. Identification
1.1 Product identifier
Product name : Polystyrene
Part no. : PL2010-0000, PL2010-0200, PL2010-0201, PL2010-0202, PL2010-0203, PL2010-0300,
PL2010-0301, PL2010-0302, PL2010-0303, PL2010-0400, PL2010-0401, PL2010-0402,
PL2010-0403, PL2010-0501, PL2010-0505, PL2010-0601, PL2010-0605, PL2012-5001,
PL2012-5005, PL2012-5010, PL2012-6001, PL2012-6005, PL2012-6010, PL2012-7001,
PL2012-7005, PL2012-7010, PL2012-8001, PL2012-8005, PL2012-8010, PL2012-9001,
PL2012-9005, PL2012-9010, PL2013-0001, PL2013-0005, PL2013-0010, PL2013-1001,
PL2013-1005, PL2013-1010, PL2013-2001, PL2013-2005, PL2013-2010, PL2013-3001,
PL2013-3005, PL2013-3010, PL2013-4001, PL2013-4005, PL2013-4010, PL2013-5001,
PL2013-5005, PL2013-5010, PL2013-6001, PL2013-6005, PL2013-6010, PL2013-7001,
PL2013-7005, PL2013-7010, PL2013-8001, PL2013-8005, PL2013-8010, PL2013-9001,
PL2013-9005, PL2013-9010, PL2014-0001, PL2014-0005, PL2014-0010, PL2014-1001,
PL2014-1005, PL2014-1010, PL2014-2001, PL2014-2005, PL2014-2010, PL2014-3001,
PL2014-3005, PL2014-3010, PL2014-4001, PL2014-4005, PL2014-4010, PL2014-5001,
PL2014-5005, PL2014-5010, PL2014-6001, PL2014-6005, PL2014-6010, PL2014-7001,
PL2014-7005, PL2014-7010, PL2014-8001, PL2014-8005, PL2014-8010, PL2014-9001,
PL2014-9005, PL2014-9010
Validation date : 11/7/2023
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Reagents and Standards for Analytical Chemistry Laboratory Use
Bottle
PL2010-0000 Broad Polystyrene 1g
PL2010-0200 EasiVial PS-H 4 ml
PL2010-0201 PS-H EasiVial 2 ml
PL2010-0202 PS-H 2 ml tri-pack (90 vials)
PL2010-0203 PS-H 4 ml tri-pack (90 vials)
PL2010-0300 EasiVial PS-M 4 ml
PL2010-0301 EasiVial PS-M 2 ml
PL2010-0302 EasiVial PS-M 2 ml tri-pack
PL2010-0303 EasiVial PS-M 4 ml tri-pack
PL2010-0400 EasiVial PS-L 4 ml
PL2010-0401 EasiVial PS-L 2 ml
PL2010-0402 PS-L 2 ml tri-pack (90 vials)
PL2010-0403 PS-L 4 ml tri-pack (90 vials)
PL2010-0501 EASICAL PS-1 (SINGLE PACK)
PL2010-0505 EASICAL PS-1 (PACK OF 5)
PL2010-0601 EASICAL PS-2 (SINGLE PACK)
PL2010-0605 EASICAL PS-2 (PACK OF 5)
PL2012-5001 PS nominal Mp 2k 1g
Date of issue : 11/07/2023 1/12

Polystyrene
PL2014-1001 PS nominal Mp 1m 1g
PL2014-2001 PS nominal Mp 1.5m 1g
Date of issue : 11/07/2023 2/12

Polystyrene
1.3 Details of the supplier of the safety data sheet
Supplier/Manufacturer : Agilent Technologies, Inc.
5301 Stevens Creek Blvd
Santa Clara, CA 95051, USA
800-227-9770
1.4 Emergency telephone number

In case of emergency : CHEMTREC®: 1-800-424-9300
Section 2. Hazards identification

2.1 Classification of the substance or mixture
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the substance or mixture
COMBUSTIBLE DUSTS
2.2 GHS label elements

Signal word : Warning
Hazard statements : May form combustible dust concentrations in air.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
Supplemental label : Keep container tightly closed. Keep away from heat, hot surfaces, sparks, open flames
elements and other ignition sources. No smoking. Prevent dust accumulation.
2.3 Other hazards
Hazards not otherwise : None known.
classified
Section 3. Composition/information on ingredients

Substance/mixture : Substance
Ingredient name % CAS number

Styrene, oligomers 100 9003-53-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Date of issue : 11/07/2023 3/12

Polystyrene
Section 4. First aid measures

4.1 Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel.
4.2 Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the eyes.
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the nose, throat and lungs.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
irritation
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : No specific data.
Ingestion : No specific data.
4.3 Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
See toxicological information (Section 11)
Section 5. Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical powder.
media
Unsuitable extinguishing : Avoid high pressure media which could cause the formation of a potentially explosible
media dust-air mixture.
5.2 Special hazards arising from the substance or mixture

Specific hazards arising : May form explosible dust-air mixture if dispersed.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Date of issue : 11/07/2023 4/12

Polystyrene
Section 5. Fire-fighting measures
5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing dust. Put on appropriate
personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
6.2 Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Vacuum or sweep up material and place in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Section 7. Handling and storage

7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing dust. Avoid the creation of dust
when handling and avoid all possible sources of ignition (spark or flame). Prevent dust
accumulation. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust
coming into contact with hot surfaces, sparks or other ignition sources. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Date of issue : 11/07/2023 5/12

Polystyrene
Section 7. Handling and storage

7.2 Conditions for safe : Store in accordance with local regulations. Store in a segregated and approved area.
storage, including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
7.3 Specific end use(s)

Recommendations : Industrial applications, Professional applications.
Industrial sector specific : Not available.
solutions
Section 8. Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Styrene, oligomers ACGIH TLV (United States).
TWA: 10 mg/m³ Form: Inhalable
TWA: 3 mg/m³ Form: Respirable
Biological exposure indices
No exposure indices known.
8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
controls or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields. If operating conditions cause high dust concentrations to be produced, use
dust goggles.
Skin protection
Date of issue : 11/07/2023 6/12

Polystyrene
Section 8. Exposure controls/personal protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Section 9. Physical and chemical properties and safety characteristics

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Appearance
Physical state : Solid. [Powder.]
Color : White.
Odor : Odorless.
Odor threshold : Not available.
pH : Not available.
Melting point/freezing point : 240°C (464°F)
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: 345 to 360°C (653 to 680°F)
Evaporation rate : Not available.
Flammability : Flammable in the presence of the following materials or conditions: open flames, sparks
and static discharge and heat.
Lower and upper explosion : Not applicable.
limit/flammability limit
Vapor pressure : Not available.
Relative vapor density : Not applicable.
Relative density : 1.05
Density : 1.05 g/cm³ [20°C (68°F)]
Solubility(ies) : Media Result
water Insoluble
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : 427°C (800.6°F)
Decomposition temperature : 100 to 300°C (212 to 572°F)
Viscosity : Not applicable.
Particle characteristics
Median particle size : Not available.
Date of issue : 11/07/2023 7/12

Polystyrene
Section 10. Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame). Take precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during transfer by grounding and
bonding containers and equipment before transferring material. Prevent dust
accumulation.
10.5 Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products should
decomposition products not be produced.
Section 11. Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
Styrene, oligomers - 3 -
Reproductive toxicity
Conclusion/Summary : Impurity : May cause damage to organs.
Teratogenicity
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Date of issue : 11/07/2023 8/12

Polystyrene
Section 11. Toxicological information

Information on the likely : Not available.
routes of exposure
Potential acute health effects
Eye contact : Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the eyes.
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the nose, throat and lungs.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
irritation
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : No specific data.
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Numerical measures of toxicity

Acute toxicity estimates
N/A
Section 12. Ecological information

12.1 Toxicity
Not available.
12.2 Persistence and degradability

Not available.
Date of issue : 11/07/2023 9/12

Polystyrene
Section 12. Ecological information

12.3 Bioaccumulative potential
Not available.
12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
12.5 Other adverse effects : No known significant effects or critical hazards.
Section 13. Disposal considerations

13.1 Waste treatment methods
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Waste should not be disposed of untreated to the
sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
Section 14. Transport information

DOT / TDG / Mexico / IMDG / : Not regulated.
IATA
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Transport in bulk according : Not available.

to IMO instruments
Section 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: All components are listed or exempted.
Clean Air Act Section 112 : Not listed

(b) Hazardous Air
Pollutants (HAPs)
Date of issue : 11/07/2023 10/12

Polystyrene

Class I Substances
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.

SARA 311/312
Classification : COMBUSTIBLE DUSTS
Composition/information on ingredients
No products were found.
State regulations
Massachusetts : None of the components are listed.
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.
California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Japan : Japan inventory (CSCL): All components are listed or exempted.
Japan inventory (ISHL): All components are listed or exempted.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Date of issue : 11/07/2023 11/12

Polystyrene

Taiwan : All components are listed or exempted.
Thailand : All components are listed or exempted.
Turkey : All components are listed or exempted.
United States : All components are active or exempted.
Viet Nam : All components are listed or exempted.
Section 16. Other information

Procedure used to derive the classification
Classification Justification
COMBUSTIBLE DUSTS On basis of test data
History
Date of issue/Date of : 11/07/2023
revision
Date of previous issue : 04/07/2022
Version : 8
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
Disclaimer: The information contained in this document is based on Agilent’s state of knowledge at the time of
preparation. No warranty as to its accurateness, completeness or suitability for a particular purpose is expressed
or implied.
Date of issue : 11/07/2023 12/12

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Conforms to US OSHA Hazard Communication 29CFR1910.

SAFETY DATA SHEET

Date of issue : 11/07/2023 1/12

Date of issue : 11/07/2023 2/12

1.4 Emergency telephone number

Section 2. Hazards identification

2.2 GHS label elements

Section 3. Composition/information on ingredients

Ingredient name % CAS number

Occupational exposure limits, if available, are listed in Section 8.

Date of issue : 11/07/2023 3/12

Section 4. First aid measures

4.2 Most important symptoms/effects, acute and delayed

See toxicological information (Section 11)

Section 5. Fire-fighting measures

5.2 Special hazards arising from the substance or mixture

Date of issue : 11/07/2023 4/12

Section 5. Fire-fighting measures

5.3 Advice for firefighters

Section 6. Accidental release measures

6.3 Methods and materials for containment and cleaning up

Section 7. Handling and storage

Date of issue : 11/07/2023 5/12

Section 7. Handling and storage

7.3 Specific end use(s)

Section 8. Exposure controls/personal protection

8.2 Exposure controls

Individual protection measures

Date of issue : 11/07/2023 6/12

Section 8. Exposure controls/personal protection

Section 9. Physical and chemical properties and safety characteristics

Date of issue : 11/07/2023 7/12

Section 10. Stability and reactivity

10.2 Chemical stability : The product is stable.

10.5 Incompatible materials : Reactive or incompatible with the following materials:

Section 11. Toxicological information

Date of issue : 11/07/2023 8/12

Section 11. Toxicological information

Symptoms related to the physical, chemical and toxicological characteristics

Numerical measures of toxicity

Section 12. Ecological information

12.2 Persistence and degradability

Date of issue : 11/07/2023 9/12

Section 12. Ecological information

12.4 Mobility in soil

12.5 Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Section 14. Transport information

Transport in bulk according : Not available.

Section 15. Regulatory information

Clean Air Act Section 112 : Not listed

Date of issue : 11/07/2023 10/12

Section 15. Regulatory information

SARA 304 RQ : Not applicable.

Date of issue : 11/07/2023 11/12

Section 15. Regulatory information

Section 16. Other information

Date of issue : 11/07/2023 12/12

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