Isomerism - PYQ Sheet (Questions) - Manzil JEE 2025

1
Manzil JEE - Practice (2025)

Isomerism
Most Important JEE PYQs
1. Given below are two statements. The total number of structures/compounds which
[29 July, 2022 (Shift-II)] possess asymmetric atoms is______.
[29 June, 2022 (Shift-I)]
4. Total number of possible stereoisomers of dimethyl
cyclopentane is__________.
5. Among the following compounds, geometrical

isomerism is exhibited by:
[5 Sept, 2020 (Shift-II)]
(a) (b)
In the light of the above statement, choose the most
appropriate answer from the options given below.
(a) Both statement-I and Statement-II are correct
(c) (d)
(b) Both statement-I and Statement-II are
incorrect
(c) Statement-I is correct but Statement-II is
incorrect
(d) Statement-I is incorrect but Statement-II is 6. Which of the following compounds shows
correct geometrical isomerism?
[6 Sept, 2020 (Shift-I)]
2. Total number of isomers (including steroisomers) (a) 2 – methylpent – 2 – ene
obtained on monochlorination of methylcyclohexane (b) 4 – methylpent – 2 – ene
is ________. (c) 4 – methylpent – 1 – ene
[26 July, 2022 (Shift-II)] (d) 2 – methylpent – 1 – ene
3. Observe structure of the following compounds 7. The number of chiral carbons present in the
molecule given below is __________.
[2 Sept, 2020 (Shift-I)]
2
8. The total number of chiral compound/s from the (b) CH₃–CH₂–O–CH₃

following is _________. (c) CH₃–CH₂–CH₂–OH
[1 Feb, 2023 (Shift-I)] (d) CH₃–CH₂–CH₂–CH₂–OH
14. Which of the following compounds exhibits

geometrical isomerism?
[8 April, 2023 (Shift-I)]
(a) 1-Butene (b) 2-Butene
(c) 1-Butyne (d) 2-Butyne
15. Identify the pair of compounds that are functional

group isomers.
[10 April, 2023 (Shift-II)]
(a) Ethanol and Dimethyl ether
(b) Propanal and Propanone
(c) But-1-yne and But-2-yne
(d) Propanoic acid and Methyl ethanoate
9. Identify the compound among the following that
exhibits geometrical isomerism: 16. Which of the following compounds can exhibit
[27 Jan, 2024 (Shift-II)] tautomerism?
(a) Propene (b) 2-Methylpropene [13 April, 2023 (Shift-I)]
(c) 2-Butene (d) 2-Methyl-2-butene (a) Acetone (b) Acetoacetic ester
(c) Benzaldehyde (d) Acetophenone
10. Which of the following compounds is not chiral?
[29 Jan, 2024 (Shift-II)] 17. Two isomers (A) and (B) with a molar mass of 184
(a) 1-Chloropentane g/mol and elemental composition C: 52.2%, H:
(b) 3-Chloro-2-methylpentane 4.9%, and Br: 42.9% gave benzoic acid and p-
(c) 1-Chloro-2-methylpentane bromobenzoic acid, respectively, on oxidation with
(d) 2-Chloropentane KMnO₄. Isomer 'A' is optically active and gives a
pale yellow precipitate when warmed with
11. Determine the total number of optical isomers alcoholic AgNO₃. Identify isomers 'A' and 'B'.
possible for 2-chlorobutane. [29 June, 2022 (Shift-II)]
[30 Jan, 2024 (Shift-I)]
(a) 2 (b) 3 (a)
(c) 4 (d) 6
12. Which of the following compound will have a

(b)
meso isomer?
[30 Jan, 2024 (Shift-II)]
(a) 2-Chlorobutane
(b) 2-Hydroxypropanoic acid (c)
(c) 2,3-Dichloropentane
(d) 2,3-Dichlorobutane
(d)
13. Which of the following is an example of
metamerism?
[6th April, 2023 (Shift-II)]
(a) CH₃–O–CH₂–CH₃
3
18. Which of the following compounds does not

exhibit geometrical isomerism?
[25 July, 2022 (Shift-II)]
(a) 1,2-Dichloro-1-pentene (c) (d)
(b) 1,3-Dichloro-2-pentene
(c) 1,1-Dichloro-1-pentene
(d) 1,4-Dichloro-2-pentene
24. The number of possible isomeric products formed
19. In the following structures, which one is a having when 3-chloro-1-butene reacts with HCl through
staggered conformation with maximum dihedral carbocation formation is ____________.
angle? [27 June, 2022 (Shift-I)]
25. Which of the following pairs is an example of
metamerism?
(a) (b) [4 Sep, 2020 (Shift-I)]
(a) Diethyl Ether and Ethyl Methyl Ether
(b) n-Propylamine and Isopropylamine
(c) Ethanol and Methoxy Methane
(c) (d) (d) Propanal and Acetone
26. How many stereoisomers are possible for 2,3-

dichloropentane?
20. How many optical isomers are possible for 2,3-
dihydroxybutanoic acid?
[24 Feb, 2021 (Shift-I)] 27. Consider the compound 2,3-dimethylpentane. How
many structural isomers are possible for this
21. Which of the following compounds is chiral?
compound?
[27 Feb, 2021 (Shift-II)]
[9 Jan, 2019 (Shift-I)]
(a) 2-Chlorobutane (b) 2-Chloropropane
(c) 2-Bromopropane (d) 2-Bromobutane 28. How many geometrical isomers are possible for
2,3-dichlorobut-2-ene?
22. How many structural isomers are possible for
[10 April, 2019 (Shift-II)]
C₅H₁₂?
[18 March, 2021 (Shift-II)] 29. How many stereoisomers are possible for 2,3-
dibromobutane?
23. Which will have the highest enol content?
[7 Jan, 2020 (Shift-II)]
30. How many structural isomers are possible for
C₄H₈?
[2 Sep, 2020 (Shift-II)]
(a) (b)
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Manzil JEE - Practice (2025)

5. Among the following compounds, geometrical

[5 Sept, 2020 (Shift-II)]

8. The total number of chiral compound/s from the (b) CH₃–CH₂–O–CH₃

14. Which of the following compounds exhibits

15. Identify the pair of compounds that are functional

12. Which of the following compound will have a

18. Which of the following compounds does not

26. How many stereoisomers are possible for 2,3-

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