CH 6 To 11

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Test #:

Time: 3 hrs St#47, Main Bazar Sahowari


Mughalpura Lahore.
Marks: 85
TEST SESSION 2022-2023 03214370053

Name: Class: 1st year Subject: chemistry Date: 15/04/24

Part 1 (OBJECTIVE TYPE)


Sr (A) (B) (C) (D)
Which of the following has unpaired
1 O2+2 N2-2 B2 F2
electrons in anit-bonding molecular orbits:
Which of the following has bond angle of
2 CH4 NH3 H 2O BF3
107.5o:
3 In Al2 O3 ,the ratio between ions are: 1:2 2:1 2:3 3:2
If endothermic reaction is allowed to take
Remains
4 place very rapidly in the air, the temp. of Increases Decreases None
constant
surrounding air:
Energy Enthalpy Pressure
5 At constant volume, heat supplied is called: None
change change change
6 The highest amount of lattice energy has: NaI NaF NaBr NaCl
The electrolyte used in fuel cell is: Aqueous Aqueous Cu Metal
7 H2SO4
NaCl CuSO4
8 The partial pressure of oxygen in lungs is: 100 torr 116 torr 159 torr 200 torr
9 The lengths of hexagonal system is: a=b=c a≠b=c a≠b≠c None
10 Which one is the following is pseudo solid: CaF2 Glass NaCl All
In order to raise the boiling point water upto b/w 760 torr b/w 200 torr
11 760 torr None
110oC, the external pressure should be: & 1200 torr & 760 torr
The total no of spectral regions in white light
12 4 6 7 8
is:
13 Quantum no values four 2 p are: n = 2, l = 1 n = 1, l = 3 n = 1, l = 1 n = 2, l = 2
14 An orbital which is spherically symmetrical is: s p d f
15 Oxidation state of hydrogen in CaH2 is: +1 -1 +2 0
16 E.M.F OF Zn-Cu Cell is: 0.0V 0.5V 1.0V 1.10V
Fuel cell converts chemical energy into: Heat energy Electrical Magnetic Sound
17
energy energy energy
Part 2 (Short Question / Answers)
Q. NO. 2 Give short answers to the following questions. (Only 8) ¿]

Define ionization energy and write factors that affect Bond distance is the compromise distance between
1 4
it. two atoms.
2 Differentiate between sigma and pi bond. 5 Define system and surroundings.
3 Define bond order. 6 Define Hess’s law with mathematical form.
7 Shortly explain atomic radius? 8 π bond is more diffused than σ bond?
The Dipole moment of CO2 and CS2 are zero, but
9 Second ionization energy of Mg is very high? 10
that of SO2 is 1.61D. justify with reason?

Q. NO. 3 Give short answers to the following questions. (Only 8) ¿]

Explain burning of candle is spontaneous


1 4 Define hydration and hydrolyses.
process.
2 Define pka and pkb. 5 Define conjugate solution with example.
3 Define types of buffer solutions. 6 Write function of salt bridge.
7 Limitation of lewis model? 8 Explain fractional distillation?
The sum of mole fraction of all components is 1 Relative lowering of vapour pressure is independent of
9
always equal to unity for any solution? 0 the temperature. Explain with reason?
Q. NO. 4 Give short answers to the following questions. (Only 6) ¿]

1 Describe Silver Oxide Battery. 4 Define zero and second order reactants.
Write two characteristics of enzyme
2 Explain prediction of feasibility of a chemical reaction. 5
catalysis.
3 Lead accumulator is a rechargeable battery. 6 The radioactive decay is 1st order reaction.
Difference between electrolytic cell
7 Impure Cu can be purified by electrolysis method? 8
and Voltaic cell?

Give detail answers of the following questions. (Only 3) ¿]

a) Define colligative properties and explain elevation


Q.5 a) Define sp2 hybridization and explain structure of BF3. Q.6
of boiling point.
b) Explain glass calorimeter with diagram. b) Explain electrolytic cells in detail.
Q.7 a) Explain Common ion effect. Write its use in making buffer solution?
b) Write four characteristics of a catalyst.
a) What is Oxidation Number, What are the
Q. 8 Q.9 a) Explain HESSES law of constant heat summation?
rules for assigning Oxidation Number?
b) MOT of O2? b) How do you explain Arrhenius Equation?

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