Sample Rb Sr Ba Pb La Ce Pr Nd Sm Eu Gd

1 SN13 20 19 736 381 5.6 33.6 62.3 6.53 23.5 4.15 1.33 3.85
2 SN15 25 22 825 536 5.0 33.6 56.5 5.97 21.8 4.17 1.33 3.93
3 SN17 43 42 723 416 11.0 37.8 65.8 6.44 21.3 3.55 1.02 3.37
4 SN19 24 22 669 321 5.1 30.3 53.3 5.46 19.1 3.39 1.14 3.3
5 SN32 16 12 535 213 2.2 22.5 42.8 5.34 21.6 4.52 1.44 4.31
SN39 8 6 789 297 2.7 26.1 50.7 6.06 23.6 4.78 1.62 4.74
6 SN16 52 48 644 408 15.54 33.95 62.1 5.92 18.97 3.21 1.06 3.78
7 SN21 65 63 332 302 9.9 16.3 33.9 3.52 12.9 2.64 0.73 2.47
SN35 24 23 433 418 5.6 16.8 33.6 3.54 13.2 2.78 0.95 2.76
8
9
10 Rb Sr Ba Pb La Ce Nd Y Nb Th U
Sn 13 20.07 712.16 355.64 4.85 31.60 60.45 22.17 20.03 25.33 4.05 0.81

Sn15 24.58 799.54 558.03 5.01 34.45 59.12 23.62 19.53 20.72 4.58 0.72
Sn17 42.72 708.18 426.00 8.03 40.42 69.12 28.22 16.33 21.66 8.64 1.59
Sn 19 24.31 667.58 322.86 5.19 30.15 51.65 19.46 17.45 18.27 4.99 1.28
Sn32 16.36 520.20 236.00 3.33 25.19 48.36 22.58 22.37 14.20 1.17
Sn39 8.11 761.41 288.03 2.77 26.82 51.01 23.44 25.52 22.40 1.10
Sn16 51.64 578.45 398.00 10.33 36.94 59.68 22.09 16.90 20.92 9.42 1.71
Sn21 64.56 321.36 308.92 6.65 16.46 30.35 14.98 15.15 8.01 3.86 1.91
Sn35 23.54 412.45 448.14 5.13 18.22 30.65 13.69 16.36 10.00 1.71 1.37

Rb Sr
70 900

800
60
700
50
600
40 500

30 400

300
20
200
10
100
50
600
40 500

30 400

300
20
200
10
100

0 0
0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 300.00 400.00 500.00 600.00 700.00 800.00 900.00

Pb La
18.0 40.0

16.0 35.0

14.0 30.0
12.0
25.0
10.0
20.0
8.0
15.0
6.0
10.0
4.0

2.0 5.0

0.0 0.0
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00

Th U
14.0 3.5

12.0 3.0

10.0 2.5

8.0 2.0

6.0 1.5

4.0 1.0

2.0 0.5

0.0 0.0
0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00
6.0 1.5

4.0 1.0

2.0 0.5

0.0 0.0
0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00
Tb Y Dy Ho Er Yb Lu Nb Hf Ta Th U Zr
0.57 18.5 3.06 0.61 1.75 1.74 0.26 28.4 3.18 1.48 6.4 1.5 177
0.59 19.2 3.35 0.69 1.84 1.77 0.26 22.3 3.36 1.35 7.8 1.8 161
0.49 15.4 2.59 0.54 1.62 1.41 0.23 26.8 3.28 1.45 11.8 3.0 189
0.49 16.2 2.72 0.57 1.58 1.55 0.23 20.1 2.82 1.15 7.4 1.7 164
0.67 21.3 3.79 0.76 2 1.96 0.28 16.0 3.85 1.09 3.8 0.7 151
0.74 25.2 4.28 0.9 2.42 2.39 0.35 24.5 4.12 1.58 2.7 0.7 211
0.64 15.25 2.46 0.5 1.38 1.49 0.28 28.03 3.98 1.6 11.91 2.96 216
0.38 13.9 2.29 0.49 1.46 1.33 0.23 12.0 2.49 0.64 5.3 1.8 133
0.42 15.4 2.4 0.52 1.53 1.47 0.24 13.6 2.79 0.84 3.8 1.4 146

All graphs are represented in X axis XRF and Y axis ICP

Ba
600

500

400

300

200

100
 400

300

200

100

0
800.00 900.00 200.00 250.00 300.00 350.00 400.00 450.00 500.00 550.00 600.00

Ce
70.0

60.0

50.0

40.0

30.0

20.0

10.0

0.0
40.00 45.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 60.00 65.00 70.00 75.00

60 1.80 2.00
60 1.80 2.00
Eu Eu Con. Eu N Sm Sm Con.
1.33 0.058 22.93103 4.15 0.153
1.33 0.058 22.93103 4.17 0.153
1.02 0.058 17.58621 3.55 0.153
1.14 0.058 19.65517 3.39 0.153
0.058 0.153
0.058 0.153
1.44 0.058 24.82759 4.52 0.153
1.62 0.058 27.93103 4.78 0.153
0.058 0.153
1.06 0.058 18.27586 3.21 0.153
0.73 0.058 12.58621 2.64 0.153
0.95 0.058 16.37931 2.78 0.153
Sm N Gd Gd Con. Gd N Eu/Eu* (Sm N +Gd N)2 Ba/Th Sr/Nd
27.12418 3.85 0.2055 18.73479 1.000067 22.92949 #REF! 31.29252
27.2549 3.93 0.2055 19.12409 0.988854 23.18949 #REF! 37.93103
23.20261 3.37 0.2055 16.39903 0.888155 19.80082 #REF! 34.02353
22.15686 3.3 0.2055 16.05839 1.028656 19.10763 #REF! 34.95298
0.2055 0
0.2055 0
29.54248 4.31 0.2055 20.97324 0.982965 25.25786 #REF! 24.75706
31.24183 4.74 0.2055 23.06569 1.028625 27.15376 #REF! 33.50318
0.2055 0
20.98039 3.78 0.2055 18.39416 0.928308 19.68728 #REF! 33.94834
17.2549 2.47 0.2055 12.01946 0.859879 14.63718 #REF! 25.73643
18.16993 2.76 0.2055 13.43066 1.036646 15.8003 #REF! 32.87775